MATERIAL SAFETY DATA SHEET
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
PRODUCT NAME: BACRASAN PHENOLIC SANITISER
OTHER NAMES: NONE
RECOMMENDED USE: GENERAL SANITISER.
SUPPLIER NAME: CAMPBELL CLEANTEC (ABN 92 009 657 489)
ADDRESS: 32 PERIVALE STREET, DARRA, QLD, 4076
TELEPHONE: GENERAL + 61 7 3710 3200
ENQUIRIES:
CUSTOMER SERVICE: 1800 077 240
FAX: GENERAL + 61 7 3710 3210
ENQUIRIES:
CUSTOMER SERVICE: + 61 7 3710 3207
EMERGENCY TELEPHONE NUMBER: AUSTRALIA: 1800 628 724 (ALL HOURS)
INTERNATIONAL: + 61 7 3710 3184 (ALL HOURS)
2. HAZARDS IDENTIFICATION
Classified as hazardous according to the criteria of NOHSC.
HAZARD
Classified as a dangerous good UN 1719 according to the criteria of ADG Code (see section 14).
CLASSIFICATION:
Classified as schedule 5 according to the criteria of SUSDP (see section 15).
HAZARD CATEGORY: C ?Corrosive; N ?Dangerous for the environment
RISK PHRASES: R34 ?Causes burns.
R41 ?Risk of serious damage to eyes.
R51 ?Toxic to aquatic organisms.
SAFETY PHRASES: S1/2 ?Keep locked up and out of reach of children.
S24/25 ?Avoid contact with eyes and skin.
S26 ?In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 ?After contact with skin, wash immediately with plenty of soap-suds.
S36/37/39 ?Wear suitable protective clothing, gloves and eye/face protection.
S45 ?In case of accident or if you feel unwell, seek medical advice immediately (show the label
whenever possible).
S61 ?Avoid release to the environment. Refer to special instructions/Material Safety Data Sheets.
The information contained in this MSDS is specific to the product when handled and used neat. This product when diluted may not require the
same control measures as the neat product. Check with your technical representative if in doubt.
3. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT CAS No. PROPORTION (% w/w)
The ingredients below are considered either hazardous, dangerous goods or poison scheduled according to the criteria of NOHSC, ADG
Code and SUSDP (respectively) at the levels used in the product.
sodium hydroxide 1310-73-2 < 10%
ortho-phenyl phenol 90-43-7 10 - < 30%
ortho-benzyl-para-chlorophenol 120-32-1 < 10%
The ingredients below are not considered either hazardous, dangerous goods or poison scheduled according to the criteria of NOHSC,
ADG Code and SUSDP (respectively) at the levels used in the product.
Other ingredients are not determined to be hazardous to 100%
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MATERIAL SAFETY DATA SHEET
4. FIRST AID MEASURES
For advice, contact a Poisons Information Centre (Phone Australia 131126, New Zealand
INGESTION:
0800 764 766) or a doctor. If swallowed, do NOT induce vomiting.
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing
EYE CONTACT:
until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running
SKIN CONTACT:
water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor.
Remove from source of exposure to fresh air. Seek medical assistance if the effects persist.
INHALATION:
** SHOW THIS SAFETY DATA SHEET TO A DOCTOR **
Potable water should be available to rinse eyes or skin. Provide eye baths and safety showers.
FIRST AID FACILITIES:
Treat symptomatically.
NOTES TO PHYSICIAN:
5. FIRE FIGHTING METHODS
Water spray, foam, carbon dioxide or dry chemical powder.
SUITABLE EXTINGUISHING MEDIA:
The product is non-combustible; however, the packaging material may burn to emit
HAZARDS FROM COMBUSTION:
noxious fumes. Contact with metals may liberate hydrogen gas which is extremely
flammable.
Fire fighters should wear self-contained breathing apparatus to minimise risk of
PRECAUTIONS FOR FIRE FIGHTERS AND
exposure to vapour or products of combustion.
SPECIAL PROTECTIVE EQUIPMENT:
2R
HAZCHEM CODE:
6. ACCIDENTAL RELEASE MEASURES
Spillages are slippery. Ensure adequate ventilation. Keep spectators away ?rope off the area. Avoid
EMERGENCY
accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination.
PROCEDURES:
Contain the spill and prevent run off into confined areas, drains and waterways.
METHODS AND
Large spills: absorb with dry earth, sand or other similar material. Collect and seal in properly labelled
MATERIALS FOR
drums for disposal in an area approved by local authority by-laws. Wash area down with excess water to
CONTAINMENT AND
remove residual material.
CLEAN UP:
Small spills: may be safely mopped up and area washed with excess water.
Incineration of disposed material is not recommended, as it is unlikely to adequately burn.
7. HANDLING AND STORAGE
Keep containers closed at all times - check regularly for leaks or spills. Transport and store upright.
PRECAUTIONS FOR
Avoid eye contact and repeated or prolonged skin contact. Do not eat, drink or smoke in contaminated
SAFE HANDLING:
areas. Always remove contaminated clothing and wash hands before eating, drinking, smoking or using
the toilet. Wash contaminated clothing and other protective equipment before storage or re-use.
Store in the original container, in a cool dry well-ventilated area out of sunlight and away from
CONDITIONS FOR
incompatible materials and foodstuffs.
SAFE STORAGE:
Keep containers closed when not in use to ensure contamination does not occur. Do not combine part
drums of the same product, as this may be a source of contamination. Do not mix with other chemicals.
Do not store in aluminium or galvanised containers or use die-cast zinc or aluminium bungs; plastic
bungs should be used. At temperatures greater than 40癈, tanks must be stress relieved. Keep
containers closed when not in use - check regularly for leaks.
This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with
the relevant regulations.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No value assigned for this specific material by NOHSC, however as published by NOHSC
NATIONAL EXPOSURE
3
T.W.A. for Sodium hydroxide = 2 mg/m (Peak Limitation)
STANDARDS:
No biological limit allocated.
BIOLOGICAL LIMIT VALUES:
Ensure ventilation is adequate to maintain air concentrations below Exposure Standards.
ENGINEERING CONTROLS:
Use with local exhaust ventilation or while wearing a respirator. Keep containers closed when
not in use.
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MATERIAL SAFETY DATA SHEET
Protective equipment must be worn at all times. Risk assessments should always be conducted to
PERSONAL PROTECTIVE
identify the hazards and in turn determine the appropriate personal protective equipment for the
EQUIPMENT:
hazard.
Protective gloves: elbow-length laminate film, natural rubber, nitrile, neoprene, neoprene/natural
rubber blend or PVC impervious gloves. Always check with the glove manufacturer or your
personal protective equipment supplier regarding the correct type of glove to use. Consult AS/NZS
2161 for further information.
Eye protection: safety glasses/goggles with side shield protection and/or full-face shield. Consult
AS/NZS 1336 and AS/NZS 1337 for further information.
Clothing and footwear: waterproof apron, coveralls, trousers, long sleeved shirt, closed in shoes
and/or safety footwear. Consult AS/NZS 2210 and AS/NZS 2919 for further information.
Respiratory Protection: Avoid breathing mist, sprays or vapours. Where ventilation is not
adequate, respiratory protection may be required. Any air-purifying respirator with a particulate
and/or gas filters or any chemical cartridge respirator with cartridge(s) providing protection against
the compound of concerns meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Clear, dark grey-brown liquid
APPEARANCE:
Mild phenolic
ODOUR:
12.5
PH (NEAT):
1.05
SPECIFIC GRAVITY OR DENSITY:
No information available.
VAPOUR PRESSURE:
Approx. 70%
PERCENT VOLATILES:
No information available.
BOILING POINT / RANGE:
No information available.
FREEZING / MELTING POINT:
Emulsifiable in water.
SOLUBILITY:
No information available.
FLASH POINT:
No information available.
FLAMMABILITY LIMITS:
No information available.
IGNITION TEMPERATURE:
2 years
SHELF LIFE:
Water thin. This product contains sodium salts of ortho-phenyl phenol and ortho-benzyl-
OTHER ?:
para-chlorophenol, and a small residual of unreacted sodium hydroxide.
10. STABILITY AND REACTIVITY
Stable under normal conditions of use. The shelf life is 2 years.
CHEMICAL STABILITY:
Do not combine part drums of the same product, as this may be a source of
CONDITIONS TO AVOID:
contamination.
Acids, aluminium, ammonium salts, tin or zinc coated metals.
INCOMPATIBLE MATERIALS:
The packaging material may burn to emit noxious fumes.
HAZARDOUS DECOMPOSITION PRODUCTS:
Reacts violently with acids. Reacts exothermically on dilution with water. Reacts
HAZARDOUS REACTIONS:
with ammonium salts and a toxic ammonia gas may be liberated.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
ACUTE EFFECTS
Swallowing can result in nausea, vomiting, diarrhoea, abdominal pain and chemical burns to the
INGESTION:
gastrointestinal tract.
Corrosive to eyes; contact can cause corneal burns. Contamination of eyes can result in permanent
EYE CONTACT:
injury.
Corrosive to skin - may cause skin burns.
SKIN CONTACT:
Breathing in mists or aerosols may produce respiratory irritation.
INHALATION:
No information available.
LONG TERM EFFECTS:
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MATERIAL SAFETY DATA SHEET
No toxicity data for this specific product, however toxicity data for the hazardous ingredient is listed
ACUTE TOXICITY /
below.
CHRONIC TOXICITY:
TOXICITY DATA FOR SODIUM HYDROXIDE:
Intrapertioneal LD50 (mouse) 40 mg/kg Oral Lowest Lethal Dose (rabbit) 500 mg/kg
Skin (rabbit) severe irritation 500 mg/24hr Eyes (rabbit) severe irritation 1 mg/30sec rinse
TOXICITY DATA FOR ORTHO-PHENYLPHENOL:
Oral LD50 (rat) 2000 mg/kg Oral LD50 (mouse) 1050 mg/kg
TOXICITY DATA FOR ORTHO-BENZYL-PARA-CHLOROPHENOL:
Oral LD50 (rat) 1700 mg/kg Oral LD50 (mouse) 65 mg/kg
12. ECOLOGICAL INFORMATION
Avoid contaminating waterways. The product is highly alkaline. If large spills occurred
ECOTOXICITY:
a water pH rise could be responsible for an environmental effect on aquatic
organisms. If not neutralised this product could potentially be toxic for aquatic
organisms because of its alkalinity (pH> 9 can have an effect on fish, with possible fish
death). pH> 8.5 could be destroying for algae.
ECOTOXICITY DATA FOR ORTHO-BENZYL-PARA-CHLOROPHENOL:
LC50 Bluegill fish (Lepomis macrochirus) 0.238mg/L/96hr
LC50 Rainbow trout (Onchorhynchus mykiss) 0.475mg/L/96hr
LC50 Daphnia magna 0.546mg/L/48hr
Surfactants are readily biodegradable to AS4351.
PERSISTENCE AND DEGRADABILITY:
No information available.
MOBILITY:
None.
OTHER:
13. DISPOSAL CONSIDERATIONS
Empty containers should be forwarded to an approved agent for recycling. Avoid
DISPOSAL METHODS:
unauthorised discharge to sewer.
The product is suitable for disposal by landfill through an approved agent. Incineration of
SPECIAL PRECAUTIONS FOR
the product is not recommended, as it is unlikely to adequately burn.
LANDFILL OR INCINERATION:
14. TRANSPORT INFORMATION
Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods
ROAD AND RAIL TRANSPORT:
Code (ADG Code) for transport by Road and Rail.
1719
UN NUMBER:
CAUSTIC ALKALI LIQUID, N.O.S. (CONTAINS SODIUM SALTS OF MIXED
UN PROPER SHIPPING NAME:
PHENOLIC COMPOUNDS)
8
CLASS AND SUBSIDIARY RISK(S):
III
PACKAGING GROUP:
2R
HAZCHEM CODE:
Guide 37
INITIAL EMERGENCY RESPONSE GUIDE:
Not to be loaded with explosives (class 1), dangerous when wet substances (class
SEGREGATION DANGEROUS GOODS:
4.3), oxidising agents (class 5.1), organic peroxides (class 5.2), radioactive
substances (class 7), corrosives (strong acids of class 8), foodstuffs and foodstuff
empties, however exemptions may apply.
Classified as Dangerous Goods by the criteria of the International Maritime
MARINE TRANSPORT:
Dangerous Goods Code (IMDG Code) for transport by sea.
1719
UN NUMBER:
CAUSTIC ALKALI LIQUID, N.O.S. (CONTAINS SODIUM SALTS OF MIXED
UN PROPER SHIPPING NAME:
PHENOLIC COMPOUNDS)
8
CLASS AND SUBSIDIARY RISK(S):
III
PACKAGING GROUP:
Category A. "Away from" acids.
STOWAGE AND SEGREGATION:
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MATERIAL SAFETY DATA SHEET
Classified as Dangerous Goods by the criteria of the International Air Transport
AIR TRANSPORT:
Association (IATA) for transport by air.
1719
UN NUMBER:
CAUSTIC ALKALI LIQUID, N.O.S. (CONTAINS SODIUM SALTS OF MIXED
UN PROPER SHIPPING NAME:
PHENOLIC COMPOUNDS)
8
CLASS AND SUBSIDIARY RISK(S):
III
PACKAGING GROUP:
8L
ERG CODE:
15. REGULATORY INFORMATION
POISONS SCHEDULE (AUST.): 5
Approval number: 60300.
APVMA STATUS:
Not relevant.
TGA STATUS:
All the constituents of this product are listed.
AICS STATUS:
Not relevant.
AQIS STATUS:
None.
OTHER:
16. OTHER INFORMATION
Use good industrial hygiene.
GENERAL INFORMATION:
003
MSDS ISSUE NUMBER:
19 FEBRUARY 2007
MSDS ISSUE DATE:
In any event, the review and, if necessary, the re-issue of a MSDS shall be no longer than 5 years after the last date of issue.
Electronic versions of the MSDS's in a PDF format are also available on our Website at www.cleantec.com.au/product.asp
REASON(S) FOR ISSUE: 003: Addition of APVMA approval number and update to shipping names.
THIS ISSUE NUMBER REPLACES ALL PREVIOUS ISSUES.
LITERARY REFERENCE:
SOURCES FOR DATA:
LEGEND:
AICS Australian Inventory of Chemical Substances
APVMA Australian Pesticides and Veterinary Medicines Authority
AQIS Australian Quarantine and Inspection Service
AS Australian Standard (as issued by Standards Australia)
ERP Code Emergency Response Drill Code as found in the ICAO (International Civil Aviation Organisation) Doc 9481
MSDS Material Safety Data Sheet
NOHSC National Occupational Health and Safety Commission
STEL Short Term Exposure Limit - A 15 minute TWA exposure which should not be exceeded at any time during a
working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the STEL
should not be longer than 15 minutes and should not be repeated more than four times per day. There should be
at least 60 minutes between successive exposures at the STEL.
TGA Therapeutic Goods Administration
TLV Threshold Limit Value - TLV is a proprietary name registered by the American Conference of Governmental
Industrial Hygienists (ACGIH) and refers to airborne concentrations of substances or levels of physical agents to
which it is believed that nearly all workers may be repeatedly exposed day after day without adverse effect.
TWA Time Weighted Average - The average airborne concentration of a particular substance when calculated over a
normal eight-hour working day, for a five-day working week.
This MSDS has been prepared from current technical data and summarises at the date of issue our best knowledge of the health and safety
information of the product, and in particular how to safely handle and use the product in the workplace.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
Our responsibility for products sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also
available upon request. This MSDS may only be reproduced in full. Summaries or excerpts from this MSDS may not contain all the relevant
information and thus are not permitted.
End of MSDS
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