MATERIAL SAFETY DATA SHEET 3M(TM) PHENOLIC DISINFECTANT CLEANER CONCENTRATE (Product No. 18, Twist 'n
Fill (tm) System) 06/11/2008
Material Safety Data Sheet
Copyright, 2008, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) PHENOLIC DISINFECTANT CLEANER CONCENTRATE (Product No. 18,
Twist 'n Fill (tm) System)
MANUFACTURER: 3M
DIVISION: Building & Commercial Services Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 06/11/2008
Supercedes Date: 11/29/2005
Document Group: 07-3145-5
Product Use:
Intended Use: Disinfectant
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
WATER 7732-18-5 40 - 60
O-BENZYL-P-CHLOROPHENOL 120-32-1 9.5
O-PHENYLPHENOL 90-43-7 9.504
ETHYLENE GLYCOL 107-21-1 5 - 10
SODIUM HYDROXIDE 1310-73-2 0- 5
SODIUM MONO-C10-16-ALKYL SULFATES 68585-47-7 0- 5
ISOPROPYL ALCOHOL 67-63-0 1- 5
DODECYLBENZENESULFONIC ACID 27176-87-0 1- 5
EDTA TETRASODIUM SALT 64-02-8 1- 5
UREA 57-13-6 1- 5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Clear, light brown color with floral fragrance
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Contact with aluminum or zinc in a pressurized system may generate
hydrogen gas which could create an explosion hazard. May cause chemical eye burns. May cause chemical skin burns. May cause
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MATERIAL SAFETY DATA SHEET 3M(TM) PHENOLIC DISINFECTANT CLEANER CONCENTRATE (Product No. 18, Twist 'n
Fill (tm) System) 06/11/2008
chemical gastrointestinal burns. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or
other reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.
Skin Contact:
Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and
tissue destruction. May be absorbed through skin and cause target organ effects.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Prolonged or repeated exposure may cause:
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate,
bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea;
blood in the feces and/or vomitus may also be seen.
May be harmful or fatal if swallowed.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Cardiac Effects: Signs/symptoms may include irregular heartbeat (arrhythmia), changes in heart rate, damage to heart muscle, heart
attack, and may be fatal.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause:
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased
protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Ethylene Glycol has been shown to cause birth defects in studies with lab animals. The defects resulted from high, oral doses to
pregnant rats and mice. This is not an expected result from the recommended use of this product.
Contains a chemical or chemicals which can cause cancer.
O-Phenylphenol has been shown to cause cancer in studies with lab animals. The effect resulted from high oral doses. This is not an
expected result from the recommended use of this product.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
A 3M Product Environmental Data Sheet (PED) is available.
A conservative assessment of this product indicates that its use and proper disposal are likely to present a low environmental risk.
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MATERIAL SAFETY DATA SHEET 3M(TM) PHENOLIC DISINFECTANT CLEANER CONCENTRATE (Product No. 18, Twist 'n
Fill (tm) System) 06/11/2008
Potential use and misuse are unlikely to cause components to enter the environment in quantities or by routes that could cause adverse
environmental impacts.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15
minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.
Get immediate medical attention.
4.2 NOTE TO PHYSICIANS
Probable mucosal damage may contraindicate the use of gastric lavage.
Measures against circulatory shock, respiratory depression, and convulsion may be needed.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Not Applicable
Flash Point
Not Applicable
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Material will not burn.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Nonflammable.
Unusual Fire and Explosion Hazards: Not applicable. Contact with aluminum or zinc in a pressurized system may generate
hydrogen gas which could create an explosion hazard.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to prevent entry
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MATERIAL SAFETY DATA SHEET 3M(TM) PHENOLIC DISINFECTANT CLEANER CONCENTRATE (Product No. 18, Twist 'n
Fill (tm) System) 06/11/2008
into sewer systems or bodies of water. Dilute in a large excess of water. Carefully, and with stirring, add appropriate dilute acid such
as sulfamic acid or vinegar. Confirm neutrality. Working from around the edges of the spill inward, cover with bentonite, vermiculite,
or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an
absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible.
Clean up residue with water. Clean up residue with detergent and water. Place in a metal container approved for use in transportation
by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene.
Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Keep out of the reach of children. This product is not intended to be used without prior dilution as specified on the product label.
Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact. Do not eat, drink or smoke when using this
product. Wash exposed areas thoroughly with soap and water. Keep away from aluminum and zinc. Avoid creasing or impacting
container side walls.
7.2 STORAGE
Store away from areas where product may come into contact with food or pharmaceuticals. Keep container in well-ventilated area.
Store away from acids.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use in a well-ventilated area. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical
Dispenser, special ventilation is not required.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, eye
contact with the concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is
recommended: Indirect Vented Goggles, Full Face Shield.
8.2.2 Skin Protection
Avoid skin contact. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, skin
contact with the concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective
clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing
manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl
Rubber, Neoprene, Polyvinyl Chloride. The following protective clothing material(s) are recommended: Apron - Neoprene, Boots
- Neoprene.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM)
Chemical Dispenser, respiratory protection is not required.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following NIOSH
approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Fullface air-
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MATERIAL SAFETY DATA SHEET 3M(TM) PHENOLIC DISINFECTANT CLEANER CONCENTRATE (Product No. 18, Twist 'n
Fill (tm) System) 06/11/2008
purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or
call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ETHYLENE GLYCOL ACGIH CEIL, as aerosol 100 mg/m3 Table A4
ETHYLENE GLYCOL CMRG CEIL, as vapor and 100 mg/m3
aerosol
ETHYLENE GLYCOL OSHA CEIL 50 ppm Table Z-1A
ISOPROPYL ALCOHOL ACGIH TWA 200 ppm Table A4
ISOPROPYL ALCOHOL ACGIH STEL 400 ppm Table A4
ISOPROPYL ALCOHOL OSHA TWA 400 ppm Table Z-1A
ISOPROPYL ALCOHOL OSHA STEL 500 ppm Table Z-1A
SODIUM HYDROXIDE ACGIH CEIL 2 mg/m3
SODIUM HYDROXIDE CMRG TWA 2 mg/m3
SODIUM HYDROXIDE OSHA CEIL 2 mg/m3 Table Z-1A
SODIUM HYDROXIDE OSHA TWA 2 mg/m3 Table Z-1
UREA AIHA TWA 10 mg/m3
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Clear, light brown color with floral fragrance
Odor, Color, Grade:
Liquid
General Physical Form:
Not Applicable
Flash Point
> 200 篎
Boiling point
Approximately 17.5 mmHg [Details: CONDITIONS: @ 20 C]
Vapor Pressure
Approximately 1.1 [Ref Std: WATER=1]
Specific Gravity
12 - 13
pH
Complete
Solubility in Water
Approximately 1 [Ref Std: WATER=1]
Evaporation rate
10 - 30 % [Test Method: calculated per CARB title 2]
Volatile Organic Compounds
65 - 100 %
Percent volatile
100 - 500 g/l [Test Method: calculated per CARB title 2]
VOC Less H2O & Exempt Solvents
< 100 centipoise
Viscosity
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MATERIAL SAFETY DATA SHEET 3M(TM) PHENOLIC DISINFECTANT CLEANER CONCENTRATE (Product No. 18, Twist 'n
Fill (tm) System) 06/11/2008
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong acids
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous
decomposition products may occur as a result of oxidation, heating, or reaction with another material.
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
CHEMICAL FATE INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. As a
disposal alternative, dispose of waste product in a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D002 (Corrosive)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number UPC ID Number UPC
70-0708-4018-9 00-48011-20786-0 70-0708-4026-2 00-48011-23955-7
70-0710-0976-8 00-48011-23886-4 70-0710-0977-6 00-48011-23956-4
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
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MATERIAL SAFETY DATA SHEET 3M(TM) PHENOLIC DISINFECTANT CLEANER CONCENTRATE (Product No. 18, Twist 'n
Fill (tm) System) 06/11/2008
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
O-PHENYLPHENOL 90-43-7 9.504
ETHYLENE GLYCOL 107-21-1 5 - 10
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification
O-PHENYLPHENOL 90-43-7 **Carcinogen
** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All the components of this product are listed on China's Inventory of Chemical Substances.
The components of this product are in compliance with notification requirements in the Philippines.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 3 Flammability: 0 Reactivity: 0 Special Hazards: None
Acid/Base: Alkaline Corrosive: Yes
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 3 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS? hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS?ratings are to be used with a fully implemented HMIS?program. HMIS?is a registered mark of the National Paint and Coatings
Association (NPCA).
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MATERIAL SAFETY DATA SHEET 3M(TM) PHENOLIC DISINFECTANT CLEANER CONCENTRATE (Product No. 18, Twist 'n
Fill (tm) System) 06/11/2008
Revision Changes:
Section 1: Product use information was modified.
Section 1: Division name was modified.
Copyright was modified.
Section 7: Handling information was modified.
Section 7: Storage information was modified.
Section 8: Eye/face protection comment was added.
Section 8: Skin protection comment was added.
Section 8: Respiratory protection comment was added.
Section 14: ID Number(s) and/or UPC(s) Template 1 was added.
Section 2: Ingredient table was added.
Section 15: EPCRA 313 information was added.
Section 15: EPCRA 313 text was added.
Section 8: Exposure guidelines ingredient information was added.
Section 8: Exposure guidelines data source legend was added.
Section 15: California proposition 65 ingredient information was added.
Section 15: California proposition 65 heading was added.
Section 15: California proposition 65 cancer warning was added.
Section 8: Eye/face protection information was deleted.
Section 8: Skin protection - recommended gloves information was deleted.
Section 8: Eye/face protection text was deleted.
Section 8: Skin protection - recommended gloves text was deleted.
Section 8: Skin protection - protective clothing text was deleted.
Section 8: Eye/face protection information - punctuation - was deleted.
Section 8: Skin protection - recommended gloves - punctuation was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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