WD-40 BULK
ChemWatch Material Safety Data Sheet CHEMWATCH 11350
Issue Date: Wed 11-Sep-2002 CD 2002/4 Page 1 of 9
IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
SUPPLIER
Company: WD-40 Company (Australia P/L) Company: WD-40 Company (USA)
Address:
41 Rawson Street
Epping
NSW, 2121
Australia
Telephone: (+61 2) 9868 2200
Fax: (+61 2) 9869 7512
Product Name: WD-40 Bulk
Other Names: Organic Mixture
Product Code 61114 4Lt; 61124 4Lt Bonus
Pack; 61115 5Lt Bonus Pk; 45020 20Lt,
45200 200Lt.
2/02
CAS RN No(s): None
UN Number: 1268
Packing Group: III
Dangerous Goods Class: 3(3.2)
Subsidiary Risk: None
Hazchem Code: 3[Y]
Poisons Schedule Number: S5
USE
Lubricant, rust preventative, penetrant with moisture displacing property
Cleaner which provides some corrosion protection.
May be applied by brushing, wiping or dipping.
Used according to manufacturers directions.
The use of a quantity of material in an unventilated or confined space may
result in increased exposure and an irritating atmosphere developing.
PHYSICAL DESCRIPTION/PROPERTIES
APPEARANCE
Cloudy light amber flammable liquid; floats on water. Sweet solvent odour.
Forms non-stable emulsions.
Boiling Point (掳C): 149 min.
Melting Point (掳C): Not available.
Vapour Pressure (kPa): Not available.
Specific Gravity: 0.816 @ 12 C.
Flash Point (掳C): 43 Open Cup
Lower Explosive Limit (%): 1.0
Upper Explosive Limit (%): 6.0
Solubility in Water (g/L): Immiscible
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WD-40 BULK
ChemWatch Material Safety Data Sheet CHEMWATCH 11350
Issue Date: Wed 11-Sep-2002 CD 2002/4 Page 2 of 9
IDENTIFICATION ...
INGREDIENTS
NAME CAS RN %
solvent naphtha petroleum, medium aliphatic 64742-88-7 >60
petroleum base oil as
paraffinic distillate, heavy, solvent-dewaxed (sev 64742-65-0. 10-30
corrosion inhibitor unregulated <10
wetting agent unregulated <10
fragrance 0-1
HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments.
The liquid is discomforting to the gastro-intestinal tract and may be harmful
if swallowed.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by
aspiration may cause potentially lethal chemical pneumonitis.
EYE
The liquid is discomforting to the eyes and may cause reddening and swelling.
The vapour is mildly discomforting to the eyes.
The material may produce severe irritation to the eye causing pronounced
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
SKIN
The liquid may produce skin discomfort following prolonged contact. Defatting
and/or drying of the skin may lead to dermatitis.
Open cuts, abraded or irritated skin should not be exposed to this material.
The material may accentuate any pre-existing dermatitis condition.
The material may cause skin irritation after prolonged or repeated exposure and
may produce a contact dermatitis (nonallergic). This form of dermatitis is
often characterised by skin redness (erythema) and swelling the epidermis.
Histologically there may be intercellular oedema of the spongy layer
(spongiosis) and intracellular oedema of the epidermis.
INHALED
The vapour is discomforting to the upper respiratory tract.
Acute effects from inhalation of high vapour concentrations may be chest and
nasal irritation with coughing, sneezing, headache and even nausea.
If exposure to highly concentrated solvent atmosphere is prolonged this may
lead to narcosis, unconsciousness, even coma and possible death.
Inhalation of vapour may aggravate a pre-existing respiratory condition such as
asthma, bronchitis, emphysema
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by accidental skin and eye contact and by
inhalation of vapours especially at higher temperatures.
Prolonged or continuous skin contact with the liquid may cause defatting with
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WD-40 BULK
ChemWatch Material Safety Data Sheet CHEMWATCH 11350
Issue Date: Wed 11-Sep-2002 CD 2002/4 Page 3 of 9
HEALTH HAZARD ...
drying, cracking, irritation and dermatitis following.
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS].
As with any chemical product, contact with unprotected bare skin; inhalation of
vapour, mist or dust in work place atmosphere; or ingestion in any form, should
be avoided by observing good occupational work practice.
FIRST AID
SWALLOWED
For advice, contact a Poisons Information Centre or a doctor.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconsciousness
Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
Seek medical advice.
EYE
If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running
water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a
doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
INHALED
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
Transport to hospital, or doctor.
ADVICE TO DOCTOR
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
Primary threat to life, from pure petroleum distillate ingestion and/or
inhalation, is respiratory failure.
Patients should be quickly evaluated for signs of respiratory distress (e.g.
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WD-40 BULK
ChemWatch Material Safety Data Sheet CHEMWATCH 11350
Issue Date: Wed 11-Sep-2002 CD 2002/4 Page 4 of 9
HEALTH HAZARD ...
cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen.
Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm
Hg) should be intubated.
Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported;
intravenous lines and cardiac monitors should be established in obviously
symptomatic patients. The lungs excrete inhaled solvents, so that
hyperventilation improves clearance
A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
Epinephrine (adrenalin) is not recommended for treatment of bronchospasm
because of potential myocardial sensitisation to catecholamines. Inhaled
cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred
agents, with aminophylline a second choice.
Lavage is indicated in patients who require decontamination; ensure use of
cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical
Toxicology]
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
None assigned. Refer to individual constituents.
INGREDIENT DATA
SOLVENT NAPHTHA PETROLEUM, MEDIUM ALIPHATIC:
TLV TWA: 300 ppm A3 [ACGIH]
CEL TWA: 100 ppm, 525 mg/m鲁 [Manufacturer]
as VM & P Naphtha (petroleum ether) (CAS RN: 8032-32-4)
TLV TWA: 300 ppm, A3
Naphthas of this type produce central nervous system depression and are mild
irritants of the eyes and upper respiratory tract. The carcinogenic potential
of middle petroleum distillates is recognised and is related to the content of
polynuclear aromatic hydrocarbons
(PAHs). The TLV is thought to be protective against the acute effects of upper
respiratory tract and eye irritation and chronic systemic effects.
CAUTION: This substance has been classified by the ACGIH as A3
Animal carcinogen (at relatively high doses).
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m鲁 (compare OSHA TWA)
PARAFFINIC DISTILLATE, HEAVY, SOLVENT-DEWAXED (SEV:
PEL TWA: 5 mg/m鲁 [OSHA Z1]
oil mist, mineral
TLV TWA: 5 mg/m鲁; STEL: 10 mg/m鲁.
NOTICE OF INTENDED CHANGE.
TLV TWA 0.2 mg/m鲁 inhalable fraction A2
WARNING: This substance has been classified by the ACGIH as A2
Suspected Human Carcinogen.
ES TWA: 5 mg/m鲁 (oil mist, refined mineral)
Human exposure to oil mist alone has not been demonstrated to cause health
effects except at levels above 5 mg/m鲁 (this applies to particulates sampled by
a method that does not collect vapour). It is not advisable to apply this
standard to oils containing unknown concentrations and types of additive.
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WD-40 BULK
ChemWatch Material Safety Data Sheet CHEMWATCH 11350
Issue Date: Wed 11-Sep-2002 CD 2002/4 Page 5 of 9
PRECAUTIONS FOR USE ...
ENGINEERING CONTROLS
Use in a well-ventilated area.
General exhaust is adequate under normal operating conditions. Local exhaust
ventilation may be required in specific circumstances. If risk of overexposure
exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Air contaminants generated in the workplace possess varying "escape" velocities
which, in turn, determine the "capture velocities" of fresh circulating air
required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air).
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in 1-2.5 m/s (200-500 f/min.)
shallow booths, drum filling, conveyer
loading, crusher dusts, gas discharge
(active generation into zone of rapid
air motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity
into zone of very high rapid air
motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood-local control only
motion
Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
PERSONAL PROTECTION
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WD-40 BULK
ChemWatch Material Safety Data Sheet CHEMWATCH 11350
Issue Date: Wed 11-Sep-2002 CD 2002/4 Page 6 of 9
PRECAUTIONS FOR USE ...
EYE
Safety glasses with side shields; or as required, Chemical goggles. Contact
lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them.
HANDS/FEET
Barrier cream and Polyethylene gloves or.
Wear chemical protective gloves, eg. PVC.
Wear safety footwear.
DO NOT use this product to clean the skin
OTHER
Overalls.
Eyewash unit.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor Half-Face Respirator Full-Face Respirator
10 x ES A-AUS -
A-PAPR-AUS
50 x ES Air-line* -
100 x ES - A-3
100+ x ES - Air-line**
* - Continuous-flow; ** - Continuous-flow or positive pressure demand
^ - Full-face
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
SAFE HANDLING
STORAGE AND TRANSPORT
SUITABLE CONTAINER
Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers
STORAGE REQUIREMENTS
Store in original containers in approved flammable liquid storage area.
DO NOT store in pits, depressions, basements or areas where vapours may be
trapped.
No smoking, naked lights, heat or ignition sources.
Keep containers securely sealed.
Store away from incompatible materials in a cool, dry, well-ventilated area.
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WD-40 BULK
ChemWatch Material Safety Data Sheet CHEMWATCH 11350
Issue Date: Wed 11-Sep-2002 CD 2002/4 Page 7 of 9
SAFE HANDLING ...
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storing and handling recommendations.
TRANSPORTATION
Class 3 - Flammable liquids shall not be loaded in the same vehicle or packed
in the same vehicle or packed in the same freight container with:
Class 1 - Explosives;
Class 2.1 - Flammable gases (where both flammable liquids and flammable gases
are in bulk);
Class 2.3 - Poisonous gases;
Class 4.2 - Spontaneously combustible substances;
Class 5.1 - Oxidising agents;
Class 5.2 - Organic peroxides;
Class 7 - Radioactive substances.
SPILLS AND DISPOSAL
MINOR SPILLS
Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact by using protective equipment.
Contain and absorb small quantities with vermiculite or other absorbent
material.
Wipe up.
Collect residues in a flammable waste container.
MAJOR SPILLS
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
No smoking, naked lights or ignition sources.
Increase ventilation.
Stop leak if safe to do so.
Water spray or fog may be used to disperse / absorb vapour.
Contain spill with sand, earth or vermiculite.
Use only spark-free shovels and explosion proof equipment.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite.
Collect solid residues and seal in labelled drums for disposal.
Wash area and prevent runoff into drains.
If contamination of drains or waterways occurs, advise emergency services.
DISPOSAL
Consult manufacturer for recycling options and recycle where possible .
Consult State Land Waste Management Authority for disposal.
Incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.
thoroughly cleaned or reconditioned the drum seams may retain sufficient
solvent to generate an explosive atmosphere in the drum.
FIRE FIGHTERS' REPORT
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WD-40 BULK
ChemWatch Material Safety Data Sheet CHEMWATCH 11350
Issue Date: Wed 11-Sep-2002 CD 2002/4 Page 8 of 9
SAFE HANDLING ...
EXTINGUISHING MEDIA
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.
FIRE FIGHTING
Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
If safe, switch off electrical equipment until vapour fire hazard removed.
Use water delivered as a fine spray to control fire and cool adjacent area.
Avoid spraying water onto liquid pools.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 500 metres in all directions.
FIRE/EXPLOSION HAZARD
Liquid and vapour are flammable.
Moderate fire hazard when exposed to heat or flame.
Vapour forms an explosive mixture with air.
Moderate explosion hazard when exposed to heat or flame.
Vapour may travel a considerable distance to source of ignition.
Heating may cause expansion or decomposition leading to violent rupture of
containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include carbon dioxide (CO2)
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result
HAZCHEM
3[Y]
CONTACT POINT
COMPANY CONTACT
(+61 2) 9868 2200
AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEW ZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: (03) 4747 000
NZ EMERGENCY SERVICES: 111
End of Report
Issue Date: Wed 11-Sep-2002
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WD-40 BULK
ChemWatch Material Safety Data Sheet CHEMWATCH 11350
Issue Date: Wed 11-Sep-2002 CD 2002/4 Page 9 of 9
CONTACT POINT ...
Print Date: Thu 19-Dec-2002
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
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