RAID COMMERCIAL INSECTICIDE ODOURLESS FLY AND INSECT
PRODUCT NAME
KILLER
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Supplier Name JOHNSONDIVERSEY AUSTRALIA PTY LTD
Address 29 Chifley St, Smithfield, NSW, AUSTRALIA, 2164
Telephone (02) 9757 0300
Fax (02) 9725 5767
Emergency 1800 033 111 (24 hrs)
Email
Web Site http://www.johnsondiversey.com
Synonym(s) 739400 RAID ODOURLESS FLY AND INSECT KILLER 12 X 400G
Use(s) AEROSOL DISPENSED, FLY SPRAY, INSECTICIDE
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO NOHSC CRITERIA
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
UN No. 1950 Hazchem Code Pkg Group
2Y None Allocated
DG Class 2.1 Subsidiary Risk(s) EPG 2D1
None Allocated
3. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Formula Conc. CAS No.
LIQUEFIED PETROLEUM GAS (LPG) C3H8/C3H6/C4H10/C4H 30% 68476-85-7
8
HYDROTREATED HEAVY NAPHTHA (PETROLEUM) Not Available 1-7% 64742-48-9
PERMETHRIN C21-H20-Cl2-O3 <0.2% 52645-53-1
SODIUM NITRITE NaNO2 <0.2% 7632-00-0
NON HAZARDOUS INGREDIENTS Not Available >60% Not Available
TETRAMETHRIN C19-H25-N-O4 <0.5% 7696-12-0
4. FIRST AID MEASURES
Eye Hold eyelids apart and flush continuously with water. Continue until advised to stop by the Poisons Information
Centre, a doctor, or for at least 15 minutes. Keep patient calm.
Inhalation If over exposure occurs leave exposure area immediately. If irritation persists, seek medical attention.
Skin Gently flush affected areas with water. Seek medical attention if irritation develops.
Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor. If swallowed, do not
induce vomiting. Ingestion is considered unlikely due to product form.
Advice to Treat symptomatically
Doctor
First Aid Eye wash facilities should be provided.
Facilities
Page 1 of 4
RMT
Reviewed: 25 Oct 2006
Printed: 25 Oct 2006
RAID COMMERCIAL INSECTICIDE ODOURLESS FLY AND INSECT
PRODUCT NAME
KILLER
5. FIRE FIGHTING MEASURES
Flammability Highly flammable. Vapours may form explosive mixtures with air. May evolve toxic gases (carbon oxides,
hydrocarbons) when heated to decomposition.Eliminate all ignition sources including cigarettes, open flames,
spark producing switches/tools, heaters, naked lights, pilot lights, mobile phones etc. when handling. Aerosol cans
may explode when heated above 50 C.
Fire and Highly flammable - explosive vapour. Evacuate area and contact emergency services. Toxic gases may be
evolved when heated. Remain upwind and notify those downwind of hazard. Wear full protective equipment (see
Explosion
spill above) including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool
intact containers and nearby storage areas.
Extinguishing Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways, absorb runoff with
sand or similar.
Hazchem Code 2Y
6. ACCIDENTAL RELEASE MEASURES
Spillage If aerosol can damaged/leaking, ventilate and clear area of all unprotected personnel. Wear splash-proof goggles,
PVC/rubber gloves, a Type A-Class P1 (Organic vapour and Particulate) respirator (where an inhalation risk
exists) and coveralls. Collect and allow to discharge outdoors. Absorb residues with sand or similar and place in
clean containers for disposal.
7. STORAGE AND HANDLING
Storage Store in cool, dry, well ventilated area, removed from oxidising agents, acids, alkalis, direct sunlight, heat or
ignition sources, foodstuffs, out of direct sunlight and out of the reach of children. Ensure containers are
adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or
spills. Large storage areas should have appropriate fire protection.
Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin
contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating,
drinking and smoking in contaminated areas (eg. if container is damaged).
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ventilation Do not inhale vapours. Use in well ventilated areas. In poorly ventilated areas, mechanical extraction ventilation is
recommended.Flammable/explosive vapours may accumulate in poorly ventilated areas. Vapours are heavier
than air and may travel some distance to an ignition source and flash back.Maintain vapour levels below the
recommended exposure standard.
Exposure LIQUEFIED PETROLEUM GAS (LPG) (68476-85-7)
ES-TWA: 1000 ppm (1800 mg/m3)
Standards
WES-TWA: 1000 ppm (1800 mg/m3)
HYDROTREATED HEAVY NAPHTHA (PETROLEUM) (64742-48-9)
ES-STEL : 400 ppm (1800 mg/m3)
TETRAMETHRIN (7696-12-0)
ES-STEL : 10 mg/m3 - Pyrethrins (ACGIH)
ES-TWA: 5 mg/m3 - Pyrethrins (ACGIH)
PPE With prolonged use, wear safety glasses, splash-proof goggles and rubber or PVC gloves. Where an inhalation
risk exists, wear a Type A-Class P1 (Organic vapour and Particulate) Respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
DISPERSIBLE
Appearance: CLEAR LIQUID (AEROSOL DISPENSED) Solubility (water):
0.80 - 0.82
Odour: ODOURLESS Specific Gravity:
NOT AVAILABLE
pH: NOT AVAILABLE % Volatiles:
HIGHLY FLAMMABLE
Vapour Pressure: NOT AVAILABLE Flammability:
< 20 C (PROPELLANT)
Vapour Density: NOT AVAILABLE Flash Point:
NOT RELEVANT
Boiling Point: NOT AVAILABLE Upper Explosion Limit:
NOT RELEVANT
Melting Point: NOT AVAILABLE Lower Explosion Limit:
NOT AVAILABLE
Evaporation Rate: NOT AVAILABLE Autoignition Temperature:
Exposure Standard: 184 ppm Manufacturer's recommendation
Page 2 of 4
RMT
Reviewed: 25 Oct 2006
Printed: 25 Oct 2006
RAID COMMERCIAL INSECTICIDE ODOURLESS FLY AND INSECT
PRODUCT NAME
KILLER
10. STABILITY AND REACTIVITY
Incompatible with oxidising agents (eg. hypochlorites, peroxides), acids (eg. sulphuric acid), strong alkalis (eg.
Reactivity
hydroxides), heat and ignition sources.
Decomposition May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition.
Products
11. TOXICOLOGICAL INFORMATION
Health Hazard This product has the potential to cause adverse health effects with chronic or high level exposure. Use safe work
Summary practices (ie. do not overspray or contaminate non target areas) to avoid eye-skin contact and vapour inhalation.
Contact may result in lacrimation, irritation, pain, redness and conjunctivitis. Prolonged contact - corneal burns
Eye
and possible permanent damage.
Over exposure may result in mucous membrane irritation of the respiratory tract and sneezing. At high levels,
Inhalation
pyrethrins may cause breathing difficulties (wheezing) and sensitisation with asthma like symptoms.
Prolonged contact may result in irritation, redness, rash, dermatitis and sensitisation. Toxic effects may result from
Skin
skin absorption.
Ingestion Due to product form (aerosol container) ingestion is considered highly unlikely.
PERMETHRIN (52645-53-1)
Toxicity Data
LC50 (Inhalation): 485 mg/m3 (rat)
LD50 (Ingestion): 383 mg/kg (rat)
LD50 (Skin): 1750 mg/kg (rat)
SODIUM NITRITE (7632-00-0)
LC50 (Inhalation): 5.5 mg/m3/4 hours (rat)
LD50 (Ingestion): 180 mg/kg (rat)
TETRAMETHRIN (7696-12-0)
LC50 (Inhalation): 2 g/m3 (mouse)
LD50 (Ingestion): 1000 mg/kg (mouse)
LD50 (Skin): 2500 ug/kg (rat)
12. ECOLOGICAL INFORMATION
Environment Limited ecotoxicity data was available for this product at the time this report was prepared. Ensure appropriate
measures are taken to prevent this product from entering the environment.
13. DISPOSAL CONSIDERATIONS
Waste Disposal For small amounts absorb contents with sand or similar and dispose of to an approved landfill site. Do not puncture
or incinerate aerosol cans. Contact the manufacturer for additional information.
Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION
Shipping Name AEROSOLS
UN No. 1950 Hazchem Code 2Y Pkg Group None Allocated
DG Class 2.1 Subsidiary Risk(s) None Allocated EPG 2D1
15. REGULATORY INFORMATION
Poison A poison schedule number has not been allocated to this product using the criteria in the Standard for the
Schedule Uniform Scheduling of Drugs and Poisons (SUSDP).
AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION
Contains < 0.1 % Benzene.
Additional
Information
SYNERGISM - ANTAGONISM: Ingredients in this product may act together to aggravate or reduce adverse
effects. Accordingly the time weighted average concentration (TWA) provided for single ingredients should be
considered as a guide only and all due care exercised when handling.
AEROSOL CANS may explode at temperatures approaching 50 C.
ABBREVIATIONS:
mg/m3 - Milligrams per cubic metre
ppm - Parts Per Million
Page 3 of 4
RMT
Reviewed: 25 Oct 2006
Printed: 25 Oct 2006
RAID COMMERCIAL INSECTICIDE ODOURLESS FLY AND INSECT
PRODUCT NAME
KILLER
TWA/ES - Time Weighted Average or Exposure Standard.
CNS - Central Nervous System
NOS - Not Otherwise Specified
pH - relates to hydrogen ion concentration - this value will relate to a scale of 0 - 14, where 0 is highly acidic and
14 is highly alkaline.
CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds.
M - moles per litre, a unit of concentration.
IARC - International Agency for Research on Cancer.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:
The recommendation for protective equipment contained within this Chem Alert report is provided as a guide
only. Factors such as method of application, working environment, quantity used, product concentration and the
availability of engineering controls should be considered before final selection of personal protective equipment is
made.
HEALTH EFFECTS FROM EXPOSURE:
It should be noted that the effects from exposure to this product will depend on several factors including:
frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and
method of application. Given that it is impractical to prepare a Chem Alert report which would encompass all
possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the
Report Status
manufacturer's Material Safety Data Sheet ('MSDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer or
obtained from third party sources and is believed to represent the current state of knowledge as to the
appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding
any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this MSDS, it does not
provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any
loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a
consequence of their reliance on the information contained in this MSDS.
Risk Management Technologies
Prepared By
5 Ventnor Ave, West Perth
Western Australia 6005
Phone: +61 8 9322 1711
Fax: +61 8 9322 1794
Email: info@rmt.com.au
Web: www.rmt.com.au
MSDS Date: 25 October 2006
End of Report
Page 4 of 4
RMT
Reviewed: 25 Oct 2006
Printed: 25 Oct 2006
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