The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.
DuPont Page 1
Material Safety Data Sheet
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"SURLYN" IONOMER RESIN ALL IN SYNONYM LIST SUR006
SUR006 Revised 27-JAN-1998
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CHEMICAL PRODUCT/COMPANY IDENTIFICATION
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Material Identification
"SURLYN" is a registered trademark of DuPont.
Tradenames and Synonyms
"SURLYN" AD8269, 8320
Company Identification
MANUFACTURER/DISTRIBUTOR
DuPont Packaging and Industrial Polymers
1007 Market Street
Wilmington, DE 19898
PHONE NUMBERS
Product Information : 1-(800)441-7515
Transport Emergency : 1-(800)424-9300
Medical Emergency : 1-(800)441-3637
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COMPOSITION/INFORMATION ON INGREDIENTS
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Components
Material CAS Number %
ETHYLENE COPOLYMERS, PARTIAL SODIUM SALT >99
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HAZARDS IDENTIFICATION
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Potential Health Effects
ADDITIONAL HEALTH EFFECTS
Before using "SURLYN" Ionomer Resins, read the bulletin on the
safe handling of these polymers. No information available for
this "SURLYN" Ionomer Resin or for the ethylene copolymer partial
metal salt. Based on its similarity to other polymers, this
"SURLYN" resin is predicted to have low toxicity.
Carcinogenicity Information
None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.
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Material Safety Data Sheet
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FIRST AID MEASURES
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First Aid
INHALATION
No specific intervention is indicated as the compound is not
likely to be hazardous by inhalation. Consult a physician if
necessary.
SKIN CONTACT
The compound is not likely to be hazardous by skin contact but
cleansing the skin after use is advisable.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.
INGESTION
No specific intervention is indicated as compound is not likely to
be hazardous by ingestion. Consult a physician if necessary.
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FIRE FIGHTING MEASURES
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Flammable Properties
The solid polymer can be combusted only with difficulty.
Hazardous gases/vapors produced in fire are carbon monoxide,
hydrocarbon oxidation products, including, organic acids,
aldehydes, alcohols, and, sodium oxides.
Extinguishing Media
Water, Foam, Dry Chemical, CO2.
Fire Fighting Instructions
Keep personnel removed and upwind of fire. Wear self-contained
breathing apparatus.
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ACCIDENTAL RELEASE MEASURES
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Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
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Material Safety Data Sheet
(ACCIDENTAL RELEASE MEASURES - Continued)
Spill Clean Up
Recover undamaged and minimally contaminated material for reuse
and reclamation.
Sweep up to avoid slipping hazard.
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HANDLING AND STORAGE
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Handling (Personnel)
See FIRST AID and PROTECTION INFORMATION SECTIONS
Storage
Store in a cool, dry place. Keep container closed to prevent
contamination.
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EXPOSURE CONTROLS/PERSONAL PROTECTION
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Engineering Controls
VENTILATION Use local exhaust to completely remove vapors and
fumes liberated during hot processing from the work area.
Personal Protective Equipment
EYE/FACE PROTECTION
Wear safety glasses. Wear coverall chemical splash goggles and
face shield when possibility exists for eye and face contact due
to splashing or spraying of molten material. A full face mask
respirator provides protection from eye irritation.
RESPIRATORS
A NIOSH/MSHA approved air purifying respirator with an organic
vapor cartridge with a dust/mist filter may be permissible under
certain circumstances where airborne concentrations are expected
to exceed exposure limits. Protection provided by air purifying
respirators is limited. Use a positive pressure air supplied
respirator if there is any potential for an uncontrolled release,
exposure levels are not known, or any other circumstances where
air purifying respirators may not provide adequate protection.
PROTECTIVE CLOTHING
If there is potential contact with hot/molten material, wear heat
resistant clothing and footwear.
Exposure Guidelines
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Material Safety Data Sheet
Exposure Limits
"SURLYN" IONOMER RESIN ALL IN SYNONYM LIST SUR006
PEL (OSHA) : Particulates (Not Otherwise Regulated)
15 mg/m3, 8 Hr. TWA, total dust
5 mg/m3, 8 Hr. TWA, respirable dust
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PHYSICAL AND CHEMICAL PROPERTIES
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Physical Data
Melting Point : NA
% Volatiles : Negligible
Solubility in Water : Negligible
Odor : Mild methacrylic acid
Form : Pellets
Color : White
Specific Gravity : NA
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STABILITY AND REACTIVITY
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Chemical Stability
Stable at normal temperatures and storage conditions.
Incompatibility with Other Materials
Incompatible or can react with oxidizing agents.
Decomposition
Decomposes with heat.
Decomposition temperature: 325 C (617 F)
Hazardous gases or vapors can be released, including carbon
monoxide, and, hydrocarbon oxidation products, including, organic
acids, alcohols, and, aldehydes.
Polymerization
Polymerization will not occur.
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ECOLOGICAL INFORMATION
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Ecotoxicological Information
AQUATIC TOXICITY:
No information is available. Toxicity is expected to be low based
on insolubility in water.
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Material Safety Data Sheet
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DISPOSAL CONSIDERATIONS
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Waste Disposal
Preferred options for disposal are (1) recycling, (2) incin-
eration with energy recovery, and (3) landfill. The high fuel
value of this product makes option 2 very desirable for material
that cannot be recycled. Treatment, storage, transportation, and
disposal must be in accordance with applicable federal,
state/provincial, and local regulations.
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TRANSPORTATION INFORMATION
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Shipping Information
DOT
Proper Shipping Name : Not regulated
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REGULATORY INFORMATION
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U.S. Federal Regulations
TSCA Inventory Status : In compliance with TSCA Inventory
requirements for commercial purposes.
State Regulations (U.S.)
STATE RIGHT-TO-KNOW LAWS
No substances on the state hazardous substances list, for the
states indicated below, are used in the manufacture of products on
this Material Safety Data Sheet.
SUBSTANCES ON THE PENNSYLVANIA HAZARDOUS SUBSTANCES LIST PRESENT
AT A CONCENTRATION OF 1% OR MORE (0.01% FOR SPECIAL HAZARDOUS
SUBSTANCES): None known.
WARNING: SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: None known.
SUBSTANCES ON THE NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE LIST
PRESENT AT A CONCENTRATION OF 1 % OR MORE (0.1% FOR SUBSTANCES
IDENTIFIED AS CARCINOGENS, MUTAGENS OR TERATOGENS): None known.
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Material Safety Data Sheet
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OTHER INFORMATION
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The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
Responsibility for MSDS : T. E. SCHROER
Address : DuPont Packaging and Industrial Polymers
CHESTNUT RUN PLAZA 713
WILMINGTON, DE 19880-0713
Telephone : 302-999-4664
This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.
End of MSDS
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