Material Safety Data Sheet
1 of 4
Page:
YSTS6 Issue Date : February 2002 ISSUED by BPAUST
Infosafe No.
Product Name : BP Autogas
Not classified as hazardous according to criteria of NOHSC
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY
Product Name BP Autogas
Product Code 882
Product Use Multi-purpose product with applications including gaseous fuel for domestic,
commercial and industrial uses; internal combustion engine fuel; aerosol
propellant; Chemical feedstock.
For specific application advice see appropriate Technical Data Sheet or
consult your BP representative
Company Name BP Australia Pty Ltd (ABN 53 004 085 616)
Address Melbourne Central, 360 Elizabeth Street, Melbourne,
Victoria 3000 Australia
Emergency Tel. 24hr 1800 638 556
Tel: 61 3 9268 4111 Fax: (03) 9268-3321
Telephone
Number/Fax
Other Names Name Product Code
Automotive LPG
Automix
Autopropane
Premium LPG
Other Information This data sheet and the health, safety and environmental information it
contains is considered to be accurate as of the date specified below. We have
reviewed any information contained herein which we received from sources
outside the BP Group of Companies. However, no warranty or representation,
expressed or implied is made as to the accuracy or completeness of the data
and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data
sheet may not be accurate for all individuals and/or situations. It is the
user's obligation to evaluate and use this product safely and to comply with
all applicable laws and regulations. No statement made in this data sheet
shall be construed as a permission, recommendation or authorization given or
implied to practise any patented invention without a valid licence. The BP
Group shall not be responsible for any damage or injury resulting from
abnormal use of the material, from any failure to adhere to recommendations,
or from any hazards inherent in the nature of the material.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Information on Hydrocarbon mixture of propane, propene (propylene), butane and butene
(butylene). A small quantity (typically up to 50 ppm) of ethyl mercaptan
Composition
(stenching agent) is commonly added to assist in leak detection.
CAS No. 68477-94-1
Contains <0.1% 1,3-butadiene
Hazardous Components
No component is present at sufficient concentration to require a hazardous
classification.
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Abuse involving willful inhalation of very high concentrations of vapour, even
for short periods, can produce unconsciousness or might prove fatal.
4. FIRST AID MEASURES
Inhalation If exposure to vapour, mists or fumes causes drowsiness, headache, blurred
vision or irritation of the eyes, nose or throat, remove immediately to fresh
air. Keep patient warm and at rest. If any symptoms persist obtain medical
advice.
Unconscious casualties must be placed in the recovery position. Monitor
breathing and pulse rate and if breathing has failed, or is deemed inadequate,
respiration must be assisted, preferably by the mouth to mouth method.
Administer external cardiac massage if necessary. Seek medical attention
immediately.
Material Safety Data Sheet
2 of 4
Page:
YSTS6 Issue Date : February 2002 ISSUED by BPAUST
Infosafe No.
Product Name : BP Autogas
Not classified as hazardous according to criteria of NOHSC
Skin If cold burns are present drench with water and obtain immediate medical
advice.
Keep contaminated clothes away from ignition sources.
Eye Wash eye thoroughly with copious quantities of water. Obtain IMMEDIATE medical
attention.
Advice to Doctor Treatment should in general be symptomatic and directed to relieving any
effects.
5. FIRE FIGHTING MEASURES
These materials are delivered, stored and used at temperatures above their
flash point. Avoid all naked flames, sparks, cigarettes, etc.
In case of fire, immediately alert the fire brigade.
Ensure an escape path is always available from any fire.
Fires in confined spaces should be dealt with by trained personnel wearing
approved breathing apparatus.
If gas has ignited, do not attempt to extinguish but stop gas flow and allow
to burn out. Use water spray to cool heat-exposed containers, and to protect
surrounding areas and personnel effecting shut-off. DO NOT USE water jets.
Every precaution must be taken to keep containers cool to avoid the
possibility of a boiling liquid expanding vapour explosion (BLEVE).
Pressurised containers are liable to explode violently when subjected to high
temperatures.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
Hazardous
Combustion Products
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe
fire and/or explosion hazard.
If a leak has not ignited, stop gas flow, isolate sources of ignition and
evacuate personnel.
Ensure good ventilation.
Liquid leaks generate large volumes of flammable vapour, heavier than air,
which may travel to remote sources of ignition (eg. along drainage systems).
Where appropriate, use water spray to disperse the gas or vapour and to
protect personnel attempting to stop leakage.
Vapour may collect in any confined space.
If spillage has occurred in a confined space, ensure adequate ventilation and
check that a safe, breathable atmosphere is present before entry.
Do not enter a vapour cloud except for rescue; self-contained breathing
apparatus must be worn.
Wear protective clothing. See Exposure Controls/Personal Protection, section
8, of this Safety Data Sheet.
In the event of a leak, contact the appropriate authorities.
Small quantities of spilled liquid may be allowed to evaporate. Vapour should
be dispersed by effective ventilation.
7. HANDLING AND STORAGE
Handling Ensure good ventilation.
Avoid inhalation of vapour.
Avoid contact with liquid and cold storage containers.
When handling cylinders wear protective footwear and suitable gloves.
Avoid contact with the eyes.
Storage Store and use only in equipment/containers designed for use with this product.
Store and dispense only in well ventilated areas away from heat and sources of
ignition.
Do not enter storage tanks. If entry to tanks is necessary, contact the
supplier.
Containers must be properly labelled.
Do not remove warning labels from containers.
Other Information Fire Prevention
Ensure equipment is electrically bonded and earthed to prevent static
accumulation.
Explosive air/vapour mixtures may form at ambient temperature.
Note: Product spilt on clothing may give rise to delayed evaporation and
subsequent fire hazard.
Material Safety Data Sheet
3 of 4
Page:
YSTS6 Issue Date : February 2002 ISSUED by BPAUST
Infosafe No.
Product Name : BP Autogas
Not classified as hazardous according to criteria of NOHSC
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Exposure Limits Ensure good ventilation. Avoid, as far as reasonably practicable, inhalation
of vapour generated during use. The vapour is an asphyxiant at high
concentrations.
If vapour is generated, its concentration in the workplace air should be
controlled to the lowest reasonably practicable level.
Worksafe Australia recommend an Exposure Standard of 1000 ppm for liquefied
petroleum gas for an 8-hour time-weighted average (TWA).
Respiratory If operations are such that exposure to vapour, mist or fume may be
anticipated, then suitable approved respiratory equipment should be worn.
Protection
The use of respiratory equipment must be strictly in accordance with the
manufacturers' instructions and any statutory requirements governing its
selection and use.
Body Protection Wear suitable gloves and overalls to prevent cold burns and frostbite.
In filling operations wear protective clothing including impervious gloves,
safety goggles or face shield.
When handling cylinders wear protective footwear.
9. PHYSICAL AND CHEMICAL PROPERTIES
Odour Sulphurous/ distinctive when stenched
Boiling Point -45掳C Test Method: ASTM D 86
Vapour Pressure 800 - 1530 kPa @ 20掳C Test Method: ASTM D 5191
Physical State Liquid (gas at ambient pressure)
Colour Colourless
Density 520 kg/m鲁 @ 15掳C Test Method: ASTM D 1657
Flash Point -105掳C (PMC) Test Method: ASTM D 93
2.2%
Flammable Limits
LEL
9.5%
Flammable Limits
UEL
Other Information Grades: BP Autogas
10. STABILITY AND REACTIVITY
Stability Stable at ambient temperatures.
Hazardous polymerisation reactions will not occur.
Hazardous
Polymerization
Materials to Avoid Avoid contact with strong oxidizing agents.
Hazardous Incomplete combustion will generate hazardous gases, including carbon
monoxide.
Decomposition
Products
11. TOXICOLOGICAL INFORMATION
Inhalation Low vapour concentrations may cause nausea, dizziness, headaches and
drowsiness.
May have a narcotic effect if high concentrations of vapour are inhaled.
High vapour concentrations may produce symptoms of oxygen deficiency which,
coupled with central nervous system depression, may lead to rapid loss of
consciousness.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse
involving deliberate inhalation of very high concentrations of vapour, even
for short periods, can produce unconsciousness and/or result in a sudden
fatality.
Skin Will cause cold burns and frostbite if skin contact with liquid occurs.
Eye Will present a risk of serious damage to the eyes if contact with liquid
occurs.
12. ECOLOGICAL INFORMATION
Mobility Spillages are unlikely to penetrate the soil.
The product is volatile/gaseous and will partition to the air phase.
Material Safety Data Sheet
4 of 4
Page:
YSTS6 Issue Date : February 2002 ISSUED by BPAUST
Infosafe No.
Product Name : BP Autogas
Not classified as hazardous according to criteria of NOHSC
Unlikely to cause long term adverse effects in the environment.
Persistence /
Degradability
Bioaccumulation This material is not expected to bioaccumulate.
Unlikely to cause long term effects in the aquatic environment.
Acute Toxicity -
Other Organisms
13. DISPOSAL CONSIDERATIONS
Do not dispose of any LPG container. Return all cylinders/vessels to your
supplier.
Empty packages may contain some remaining product. Hazard warning labels are a
guide to the safe handling of empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product
residues and vapour. Never weld, solder or braze empty containers.
14. TRANSPORT INFORMATION
Classified as a highly flammable, liquefied gas for transport (ADG, UN,
IATA/ICAO):
UN No. 1075, Petroleum Gases Liquefied.
Class 2.1
Subsidiary Risk Nil
Packaging Group N/A
HAZCHEM Code 2WE
Forbidden for transport on passenger aircraft.
U.N. Number 1075
PETROLEUM GASES, LIQUEFIED
Proper Shipping
Name
DG Class 2.1
Hazchem Code 2WE
Packaging Method 5.9.2RT2
EPG Number 2.1.001
IERG Number 04
15. REGULATORY INFORMATION
Not classified using the criteria in the Standard Uniform Schedule for Drugs
and Poisons.
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Contact Person/Point BP Australia Limited,
A.C.N. 004 085 616
Melbourne Central
360 Elizabeth Street,
Melbourne, 3000
Victoria
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