MATERIAL SAFETY DATA SHEET
Dahlar 9000 ?Issue Date: September 12, 2008
ADVANCED MATERIALS GROUP
Heated above 400癈 (750癋) can evolve as degradation products:
SECTION I - PRODUCT IDENTIFICATION
Hydrogen Fluoride as a degradation product
CAS #: 7664-39-3 Percentage: <1
Trade Name: Dahlar 9000
OSHA PEL: 3 ppm, 8 Hr. TWA, as F
Product Class:
ACGIH TLV: 3 ppm, 2.6 mg/m3, Ceiling as F
Supplier: Airtech International, Inc.
5700 Skylab Road
Carbonyl Fluoride as a degradation product
Huntington Beach, CA 92647
CAS #: 353-50-4 Percentage: <1
Telephone: 714-899-8100
OSHA PEL: None established
Fax: 714-899-8179
ACGIH TLV: 2 ppm, 5.4 mg/m3, 8 Hr. TWA
STEL 5 ppm, 13 mg/m3
Emergency Telephone: 800-424-9300
Perfluoroisobutylene as a degradation product
NFPA, NPCA - HMIS
CAS #: 382-21-8 Percentage: <0.01
NFPA Ratings: Health= 2 Flammability= 1 Reactivity= 0
OSHA PEL: None established
Formula: CAS #:
ACGIH TLV: Ceiling 0.01 ppm, 0.082 mg/m3
SECTION II ?HAZARDOUS INGREDIENTS
SECTION III ?PHYSICAL DATA
Exposure Limits for Particulates (Not otherwise regulated):
Description: Red Film
15 mg/m3, 8 Hr. TWA, total dust.
Odor: None
5 mg/m3, 8 Hr. TWA, respirable dust.
Melting point: 260-275 C (500-527 F)
Solubility in water: Insoluble
Tetrafluoroethylene-Hexafluoropropylene Copolymer
Specific gravity: 2.1 - 2.2
CAS #: 25067-11-2 Percentage: >98
Form: Film
OSHA PEL: None established
ACGIH TLV: None established
SECTION IV ?FIRE AND EXPLOSION DATA
Cadmium Sulfoselenide**
Flammable Properties
CAS #: 12626-36-7 Percentage <0.7
Flash Ignition Temperature: 530-550 C (986-1022 F) Method: ASTM D1929
OSHA PEL: 5 ug/m3, 8 Hr. TWA, as Cd
Self Ignition Temperature: 520-560 C (968-1040 F) Method: ASTM D1929
ACGIH TLV: 0.01 mg/m3, total dust, 0.002 mg/m3, respirable dust, as Cd, A2
UL-94 Flammability Rating: V-0
Limiting Oxygen Index: >95 Method: ASTM D2863
**Disclosure as a Toxic Chemical is required under Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372.
Difficult to ignite, and flame goes out when initiating source is removed (UL-94).
Limited flame spread and low smoke generation (NFPA 262-1990, UL-910). Complies
Titanium Dioxide
with NFPA definition of "limited combustible" material. High self-ignition and auto-
CAS #: 13463-67-7 Percentage: <0.1
ignition temperatures (ASTM D1929).
OSHA PEL: 15 mg/m3, total dust, 8 Hr. TWA
ACGIH TLV: 10 mg/m3, total dust, 8 Hr. TWA, A4
Fire and Explosion Hazard: Hazardous gases/vapors produced in fire
CORPORATE HEADQUARTERS PHONE: (714) 899-8100
Page 1 of 4
FAX: (714) 899-8179
5700 Skylab Road
Internet: http://www.airtechintl.com
Huntington Beach, CA 92647
e-mail: airtech@airtechintl.com
MATERIAL SAFETY DATA SHEET
Dahlar 9000 ?Issue Date: September 12, 2008
ADVANCED MATERIALS GROUP
Are hydrogen fluoride (HF), carbon monoxide, potentially toxic fluorinated compounds. ulceration; irritation of the upper respiratory passages; or temporary lung irritation effects
Fire Fighting Instructions: Wear self-contained breathing apparatus. Wear full with cough, discomfort, difficulty breathing or other shortness of breath. Symptoms may
protective equipment. Does not burn without an external flame. Protect from hydrogen be delayed.
fluoride fumes which react with water to form hydrofluoric acid. Wear neoprene gloves
when handling refuse from a fire. Perfluoroisobutylene is an extremely toxic gas for which inhalation is the most likely route
of human exposure. Inhalation exposure may cause severe symptoms of pulmonary
edema with wheezing, difficulty in breathing, coughing up sputum and bluish
CO2
Extinguishing media: Water, foam, dry chemical,
discoloration of the skin. Coughing and chest pain may occur initially. However, severe
symptoms of pulmonary edema may be delayed for several hours and then become rapidly
SECTION V ?HEALTH HAZARD DATA worse. Overexposure may cause death. (Inhalation 2-hour LC50 = 1.05 ppm in rats).
DAHLAR 9000 is not hazardous as shipped. The primary hazard associated with these Individuals with preexisting diseases of the lungs may have increased susceptibility to the
polymers is the inhalation of fumes from overheating or burning, which may cause toxicity of excessive exposures from thermal decomposition products.
"polymer fume fever". (See Human Health Effects Below).
Carcinogenicity Information
Tetrafluoroethylene-Hexafluoropropylene Copolymer (FEP) The following components are listed by IARC, NTP, OSHA or ACGIH as carcinogens.
Inhalation 4 hour LC50 > 4,900 mg/m3 in rats. At very high exposure levels, animals
were suffocated by accumulated dust in the lungs. Repeated exposure by ingestion caused IARC NTP OSHA ACGIH
no adverse effects. Cadmium Sulfoselenide X X X X
HUMAN HEALTH EFFECTS OF OVEREXPOSURE TO FEP COPOLYMER: Emergency and First Aid Procedure:
In case of Inhalation: No specific intervention is indicated as the compound is not likely
Inhalation of fumes from overheating FEP may cause polymer fume fever, a temporary to be hazardous by inhalation. Consult a physician if necessary. If exposed to fumes
flu-like illness with fever, chills, and sometimes cough, of approximately 24 hours from overheating or combustion, move to fresh air. Consult a physician if symptoms
duration. There are some reports in the literature of persistent pulmonary effects in persist.
individuals, especially smokers, who have had repeated episodes of polymer fume fever. In case of Skin Contact: The compound is not likely to be hazardous by skin contact but
Because of complicating factors, such as mixed exposures and smoking history, these cleansing the skin after use is advisable. If molten polymer gets on skin, cool rapidly with
findings are uncertain. Protection against acute exposure should also provide protection cold water. Do not attempt to peel polymer from skin. Obtain medical treatment for
against any potential chronic effects. Smokers should avoid contamination of tobacco thermal burn.
products, and should wash their hands before smoking. Significant skin permeation after In case of eye contact: Immediately flush eyes with plenty of water for at least 15
contact appears unlikely. There are no reports of human sensitization. Small amounts of minutes.. Call a physician.
carbonyl fluoride, hydrogen fluoride and perfluoroisobutylene may also be evolved when In case of Ingestion: No specific intervention is indicated as compound is not likely to be
FEP Copolymer is overheated or burned. hazardous by ingestion. Consult a physician if necessary.
Inhalation of low concentrations of Hydrogen Fluoride can initially include symptoms of
SECTION VI ?REACTIVITY DATA
choking, coughing, and severe eye, nose, and throat irritation. Possibly followed after a
symptomless period of 1 or 2 days by fever, chills, difficulty in breathing, cyanosis, and
Chemical stability: Stable at normal temperatures and storage conditions.
pulmonary edema. Acute or chronic overexposure to HF can injure the liver and kidneys.
Incompatibility with other materials: Incompatible or can react with finely divided
metal powders (e.g., aluminum and magnesium) and potent oxidizers like fluorine (F2)
Inhalation, ingestion, or skin or eye contact with Carbonyl Fluoride may initially include:
and related compounds (e.g., chlorine trifluoride, C1F3). Contact with incompatibles can
skin irritation with discomfort or rash; eye corrosion with corneal or conjunctival
cause fire, an explosion.
CORPORATE HEADQUARTERS PHONE: (714) 899-8100
Page 2 of 4
FAX: (714) 899-8179
5700 Skylab Road
Internet: http://www.airtechintl.com
Huntington Beach, CA 92647
e-mail: airtech@airtechintl.com
MATERIAL SAFETY DATA SHEET
Dahlar 9000 ?Issue Date: September 12, 2008
ADVANCED MATERIALS GROUP
Hazardous decomposition products: Heating above 275 C (527 F) may cause hot/molten material, wear heat resistant clothing and footwear.
evolution of particulate matter, which can cause polymer fume fever see HUMAN
HEALTH EFFECTS). Trace amounts of hydrogen fluoride, carbonyl fluoride, and Eye/Face Protection: Wear safety glasses. Wear coverall chemical splash goggles and
perfluoroisobutylene may be evolved at about 380 C (716 F), with larger amounts at face shield when possibility exists for eye and face contact due to splashing or spraying of
higher temperatures. molten material.
Other Protection: Avoid contamination of cigarettes or tobacco with dust from this
SECTION VII ?SPILL OR LEAK PROCEDURE
material. Do not use a torch to clean this material from equipment without local exhaust,
ventilation and respirator
Steps to be taken in case material is released or spilled
Review Fire and Explosion Data Section IV before proceeding with clean up. Use
SECTION IX ?SPECIAL PRECAUTIONS
appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Sweep up to
avoid slipping hazard.
Storage: Keep containers closed to avoid contamination.
Ecotoxicological Information Medical Use: CAUTION: Do not use in medical applications involving permanent
implantation in the human body.
Aquatic Toxicity
No information is available. Toxicity is expected to be low based on insolubility in water. TRANSPORTATION INFORMATION: Shipping Information:
DOT Proper Shipping Name: Not regulated.
Waste Disposal
STATE RIGHT-TO-KNOW LAWS
Preferred options for disposal are (1) recycling and (2) landfill. Incinerate only if
incinerator is capable of scrubbing out hydrogen fluoride and other acidic combustion
No substances on the state hazardous substances list, for the states indicated below, are
products. Treatment, storage, transportation, and disposal must be in accordance with
used in the manufacture of products on this Material Safety Data Sheet with the exceptions
applicable federal, state/provincial and local regulations. indicated:
SUBSTANCES ON THE PENNSYLVANIA HAZARDOUS SUBSTANCES LIST
SECTION VIII ?SPECIAL PROTECTION INFORMATION PRESENT AT A CONCENTRATION OF 1% OR MORE (0.01%) FOR SPECIAL
HAZARDOUS SUBSTANCES): None known
Ventilation: Use local exhaust to completely remove vapors and fumes liberated during WARNING: SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
hot processing from the work area. CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: Cadmium
compound
Respiratory Protection: A respirator is not required if local exhaust ventilation is
SUBSTANCES ON THE NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE
adequate. At processing temperatures less than 400 C (750 F) a NIOSH/MSHA
LIST PRESENT AT A CONCENTRATION OF 1% OR MORE (0.1% FOR
approved air purifying respirator with dust/mist cartridge or canister may provide
SUBSTANCES IDENTIFIED AS CARCINOGENS, MUTAGENS OR TERATOGENS):
protection from airborne particulates which cause polymer fume fever. At higher
Cadmium compound
processing temperatures if ventilation is inadequate to maintain hydrogen fluoride and
carbonyl fluoride concentrations below exposure limits, use a positive pressure air
U.S. FEDERAL REGULATIONS:
supplied respirator. Air purifying respirators may not provide adequate protection.
TSCA Inventory Status: Listed
Protective Clothing: If there is potential contact with
CORPORATE HEADQUARTERS PHONE: (714) 899-8100
Page 3 of 4
FAX: (714) 899-8179
5700 Skylab Road
Internet: http://www.airtechintl.com
Huntington Beach, CA 92647
e-mail: airtech@airtechintl.com
MATERIAL SAFETY DATA SHEET
Dahlar 9000 ?Issue Date: September 12, 2008
ADVANCED MATERIALS GROUP
USER'S RESPONSIBILITY
This bulletin cannot cover all possible situations which the user may experience during
processing. Each aspect of your operation should be examined to determine if, or where,
additional precautions may be necessary. All health and safety information contained in
this bulletin should be provided to your employees or customers. It is your responsibility
to use this information to develop appropriate work practice guidelines and employee
instructional programs for your operation.
DISCLAIMER OF LIABILITY
As the conditions or methods of use are beyond our control, we do not assume any
responsibility and expressly disclaim any liability for any use of this material.
Information contained herein is believed to be true and accurate but all statements or
suggestions are made without warranty, express or implied, regarding accuracy of the
information, the hazards connected with the use of the material or the results to be
obtained from the se thereof. Compliance with all applicable federal, state and local laws
and regulations remains the responsibility of the user.
CORPORATE HEADQUARTERS PHONE: (714) 899-8100
Page 4 of 4
FAX: (714) 899-8179
5700 Skylab Road
Internet: http://www.airtechintl.com
Huntington Beach, CA 92647
e-mail: airtech@airtechintl.com
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