MATERIAL SAFETY DATA SHEET
For Coatings Resins and Related Materials
MSDS NUMBER ISSUE DATE SUPERCEDES: PREPARED BY:
MSDS FTR-SL1 3/11/96 All Previous N/A
Section I - Product & Company Identification
PRODUCT IDENTITY (as used on label and list): FTR-SL1 Sealant
Manufacturer / Distributor EMERGENCY PHONE NUMBER(S)
NAME: Seaman Corporation DAY: 330-262-1111
ADDRESS: 1000 Venture Blvd. NIGHT (CHEMTREC): 800-424-9300
ADDRESS: Wooster, OH 44691 INFORMATION: 330-262-1111
Trade Names or Synonyms: Pourable Sealer HMIS Hazard Codes: none: extreme
CAS Number: None/Mixture 0 4
D.O.T. Hazard Class: Hazard Class 3 Health: 2
Proper Shipping Name: Adhesives Fire: 2
Packing group III Reactivity: 0
Personal Protection: G
Section II - Hazardous Ingredients
Ingredients Percent C.A.S.
Material Description by Weight Registry Number LEL VP
Titanium dioxide 3 to 5 13463-67-7 N/A N/A
Calcium oxide (lime) 1 to 3 1305-78-8 None None
Talc (hydrous magnesium silicate) 3 to 5 14807-96-6 None None
Silicone dioxide (quartz) < 0.1 14808-60-7 None None
Amorphous silica (fumed) 3 to 7 112945-52-5 None None
2, 4-Toluene diisocyanate* < 0.1 584-84-9 1 <1
Mineral spirits (Stoddard type) 5 to 10 8052-41-3 1 2
Section III - Physical Data
Boiling Range: 240-450?F Freezing Point: No Data
Vapor Pressure: < 4mm Hg at 77?F Vapor Density: Heavier than air
Evap. Rate Relative to n-butyl acetate: Slower Water Soluble: Slight (<0.1%)
% Volatile by Volume: 8 to 10
Spec. Gravity: 1.1 Odor Threshold: No data
Appearance: Smooth pigmented viscous liquid. Typical paint thinner odor
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Section IV - Fire and Explosion Hazard Data
Flash Point: 145?F OSHA Flammability Classification: Combustible Class III A
Autoignition Temp: No Data LEL: 0.9
Explosive Limits: (%V in air) UEL: 7.0
EXTINGUISHING MEDIA
Water spray (fog), foam, dry chemical or carbon dioxide.
SPECIAL FIREFIGHTING PROCEDURES
Firefighters must wear self contained breathing apparatus or air masks. Containers exposed to fire should be kept
cool with water spray. A water stream directed into the fire may cause frothing with subsequent spread of fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode due to build up of pressure when exposed to heat. Thermal decomposition or
combustion of product may generate irritating and/or toxic gases. Vapor is heavier than air and may travel along
the ground or floor and be ignited at locations distant from the source.
Section V - Toxicological Information
Ingredient LD50 (mg/kg) LC50 (ppm)
Material Description PEL TLV STEL TLV (twa) Rat Rabbit Rat
(mg/m3) (mg/m3) (mg/m3) ppm (oral) (dermal) inhal
Titanium dioxide 10* N/A 10* N/A N/A N/A N/A
Calcium oxide (lime) 5* Not Given 2* N/A N/A N/A N/A
Talc (hydrous magnesium silicate) 2* Not Given 2* N/A N/A N/A N/A
Silicon dioxide (quartz) 0.1** Not Listed 0.1** N/A N/A N/A N/A
Amorphous silica (fumed) 10* Not Listed 6* N/L 3160 N/A N/A
2,4-toluene diisocyanate* 0.005 ppm 0.02 ppm N/L 0.005 >5800 >1600 No Data
Mineral spirits (Stoddard type) 100 ppm Not Listed N/L 100 >5000 N/L No Data
*Total Dust **Respirable Dust
Section VI - Health Hazard Data
Threshold Limit Values: See Section V
Acute Overexposure Information:
Inhalation: Regard this product as a severe irritant. The product may contain trace amounts of an isocyanate.
Exposure to a concentration of airborne isocyanates above TLV may produce irritation of the
respiratory tract, coughing, chest discomfort, and shortness of breath. Individuals with a history of
exposure to isocyanates can develop more severe symptoms, such as bronchitis, bronchial spasms,
and pulmonary edema (fluid in the lungs). For most individuals these effects are reversible.
Eyes: Moderate irritant. May cause tearing, reddening of the eyes and reversible corneal injury.
Skin: Regard this product as a severe irritant. The product may contain trace amounts of an isocyanate,
a class of compounds generally regarded as primary skin irritants. Contact with the product may
cause dermatitis, allergic responses, and in sensitive individuals, redness, swelling, and blisters.
Ingestion: May cause irritation if swallowed.
Note: Pre-existing respiratory or skin condition(s) may be aggravated by exposure.
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Section VI - Health Hazard Data (Continued)
Chronic Overexposure information:
1.This product does not contain dust as produced and does not generate dust in normal use. Dust generated
by abnormal activities, such as sanding or grinding, could contain a small amount (<0.1%) of respirable
silicone dioxide (quartz) dust. NTP and IARC have listed free respirable silica as a suspect human carcinogen.
Prolonged and/or repeated overexposure to free respirable silica may cause silicosis or other delayed and serious
lung injury. The dust could also contain particles of titanium dioxide, calcium oxide, talc, aluminum sulfate, and/or
calcium carbonate. Chronic overexposure to dusts of these substances may cause delayed and serious lung injury.
2. This product may contain a small amount (< 0.1%) of toluene diisocyanate. NIOSH, NTP and IARC list
toluene diisocyanate as a suspected carcinogen. Note also that prolonged or repeated exposure to
isocyanates can lead to skin sensitization. For persons so sensitized, even brief exposures to the isocyanates
can produce reddening, swelling, rash, or blisters. Similarly, prolonged and repeated exposures to
isocyanates at levels well below the TLV can produce chemical asthma, and nonspecific asthmatic conditions.
3. No other known components of this product are listed as known or suspected carcinogens per NTP, IARC, or OSHA.
4. This product contains solvents. Reports have associated repeated and prolonged occupational over-exposure to
solvents with permanent brain and nervous system damage. Solvents are also reported to cause liver damage,
kidney damage, mucous membrane irritation. Be warned that intentional misuse by deliberately inhaling the
contents (a process often called "sniffing") may be harmful or fatal.
Medical Conditions Generally Aggravated by Exposure: Any pre-existing respiratory or skin condition.
Emergency and First Aid Procedures:
Inhalation: Move the victim into fresh air. If the victim has difficulty breathing, administer oxygen.
Administer artificial respiration if the victim is not breathing. Obtain immediate medical attention.
Skin: Remove contaminated clothing and shoes. Wash affected area(s) thoroughly with soap and water.
Wipe or flush affected skin with isopropyl alcohol (rubbing alcohol). Wash again thoroughly with soap
and water. If irritation persists, seek medical attention.
Eyes: Flush the eyes with plenty of water for at least 15 minutes. If necessary, gently hold the eyelids open
during the flush. Obtain immediate medical attention.
Ingestion: Obtain immediate medical medical attention. Do not induce vomiting. Should vomiting occur,
be sure to keep victim's head below hips to avoid aspiration of vomitus into the lungs.
Section VII - Reactivity Data
Stability: K Unstable K Stable
X
Hazardous Polymerization: K May occur K Will not occur
X
This product contains an isocyanate. Contact with moisture or other materials that react with isocyanates may
cause polymerization.
Incompatibility: Water, alcohols, amines, strong oxidants, strong bases and acids.
Conditions to Avoid: Contact with water vapor. Sources of ignition. Long term
exposure to elevated temperatures.
Hazardous Decomposition Products: Oxides of carbon and nitrogen, hydrogen cyanide gas,
other acids and toxic fumes.
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Section VIII - Spill or Leak Procedures
Steps to Be Taken in Case Material is Released or Spilled:
Ventilate the area and remove all sources of ignition. Evacuate unnecessary personnel. Wipe up small spills with
rags or towels. Put spent rags in loosely covered containers in a well ventilated area. Large spills should be handled
carefully. Put on respiratory protection. Dike or impound spilled liquid. Cover the spill with absorbent compound
(eg., vermiculite, clay or sand). Use non-sparking tools to sweep or shovel into containers. Cover loosely and
remove to a well-ventilated waste area. Repeat sorbent/sweep cycle until the spill has dried up. Rinse the spill area
thoroughly with water. Flush the rinsings to the sanitary sewer or soak them up with absorbent material. Do not
discharge undiluted product to the sanitary sewer or discharge the product or cleanup wastes to lakes, streams,
ponds or sewer. Avoid contact with eyes and skin.
Waste Disposal Method:
Review all local, state, and federal regulations concerning health and pollution for appropriate disposal
procedures. Do not incinerate closed containers.
Section IX - Special Protection Information
Respiratory Protection: Wear NIOSH/MSHA approved respiratory protection when the product is
mixed or applied in a poorly ventilated area or if workplace levels of
ingredients exceed the TLV. Follow applicable federal, state, and local
regulations.
Ventilation: Use local exhaust (e.g., open windows, fans) as needed to keep vapor/dust
levels below recommended limits.
Protective Equipment: Wear gloves (Natural or butyl rubber, supported PVA, or nitrile. Avoid
neoprene.), eye goggles and clean protective clothing to cover arms and
legs and keep exposure to a minimum.
Section X - Special Precautions
Precautions to be Taken in Handling and Storage:
DO NOT BREATHE VAPORS DO NOT TAKE INTERNALLY
AVOID CONTACT WITH EYES, CLOTHING, AND SKIN WEAR PROTECTIVE CLOTHING AT ALL TIMES
KEEP CONTAINER CLOSED WHEN NOT IN USE WASH THOROUGHLY AFTER USING
KEEP OUT OF REACH OF CHILDREN USE ONLY WITH ADEQUATE VENTILATION
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Section XI - Regulatory Data
VOC CONTENT: 75.2 g/L excluding water and exempt compounds.
CALIFORNIA PROPOSITION 65:
This product contains less than 0.1% free silicon dioxide (quartz) which is listed by the State of California
as known to cause cancer. This product also contains less than 0.1% toluene diisocyanate which is also listed by the
state of California as known to cause cancer.
TRANSPORTATION: DOT UN
HAZARD CLASS: Combustible liquid Not Regulated
UN/NA NUMBER: NA1993 Not Regulated
SHIPPING NAME: Combustible liquid Not Regulated
nos (contains mineral spirits)
PLACARD AT: N/A N/A
CLASS NUMBER: 3 Air: N/A Marine: N/A
SUBSID RISK: N/A Air: N/A Marine: N/A
PACKING GROUP: III Air: N/A Marine: N/A
REPORTING
CERCLA REPORTABLE QUANTITY: 1,000,000 lbs.
WASTE: None
SARA SECTION 304 EMERGENCY RESPONSE REPORTABLE QUANTITY: None
SARA SECTION 311/312 INVENTORY REPORTING (Y/N): Y
SARA SECTION 311/312 HAZARD CLASS (ES): Acute and chronic health hazard. Fire hazard.
SARA SECTION 313 ROUTINE RELEASE REPORTING CHEMICALS: Toluene diisocyanate. 0.1%
COMPONENTS ON TSCA INVENTORY (Y/N): Y
DISPOSAL
EPA RCRA WASTE CLASS: Not Regulated
EPA RCRA WASTE NUMBER: Not Regulated
CALIFORNIA LIST LAND BAN (Y/N): Not Regulated
Section XII - Abbreviations Used
N/A= Information or Data Not Available. OSHA= Occupational Safety and Health Administration
NTP= National Toxicology Program PEL= Permissible Exposure Limit (8-hr. TWA) (OSHA)
IARC= International Agency for Research on Cancer TLV= Threshold Limit Value (8-hr. TWA) (ACGIH)
NIOSH= National Institute of Occupational Safety and Health STEL= Short Term Exposure Limit (15-min TWA) (OSHA)
ACGIH= American Conference of Governmental Industrial Hygienists C= Ceiling Value
Disclaimer
This information is furnished without warranty, representation, or license of any kind, except that this information
is accurate to the best of Seaman Corporation's knowledge, or is obtained from sources believed by Seaman
Corporation to be accurate. No warranty is expressed or implied regarding the accuracy of this information or the
results to be obtained from its use thereof. Seaman Corporation assumes no responsibility for injuries proximately
caused by use of the material if reasonable safety procedures are not followed as stipulated in this Data Sheet.
Additionally, Seaman Corporation assumes no responsibility for injuries proximately caused by abnormal use of
the Material even if reasonable safety procedures are followed. Buyer assumes the risk in its use of the material.
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