MATERIAL SAFETY DATA SHEET PAGE 1 OF 5
KOP-COAT, INC EMERGENCIES
MARINE GROUP EAST HEALTH/SPILLS......: 800-548-0489
36 PINE STREET CHEMTREC ASSISTANCE: 800-424-9300
ROCKAWAY CHEMTREC OUTSIDE US: 703-527-3887
NJ 07866 CANUTEC............: 613-996-6666
KOP-COAT, INC
PRODUCT INFORMATION: 800-221-4466
OUTSIDE USA........: 973-625-3100
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1 PRODUCT IDENTIFICATION
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PRODUCT NAME: 1381 Ultima SSA Antifouling Paint Green
PRODUCT USE.: Antifouling bottom paint
APPEARANCE..: Green liquid with hydrocarbon odor
CAS NUMBER..: Mixture
SYNONYMS....: None REVISION...: 2
DATE.......: 10/30/08
MSDS NUMBER: 1138106
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2 HAZARDOUS INGREDIENTS
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HAZARDOUS COMPONENT REG AGENCY PPM NOTES MG/M3 NOTES
Ethylbenzene ACGIH STEL 125 543
CAS NUMBER:100-41-4 ACGIH-TWA 100 434
PERCENT BY WGT: <1 NIOSH 100 435
NIOSH STEL 125 545
OSHA STEL 125 545
OSHA TWA 100 435
Zinc oxide (as dust) ACGIH-TWA - 2.0
CAS NUMBER:1314-13-2 OSHA TWA - 15 1
PERCENT BY WGT: 1 TO 5 OSHA-TWA - 5 2
Cuprous oxide (as Cu dust ACGIH-TLV 1.0
and mists) OSHA-TWA 1.0
CAS NUMBER:1317-39-1
PERCENT BY WGT: 35 TO 40
Xylene ACGIH STEL 150 651
CAS NUMBER:1330-20-7 ACGIH-TWA 100
PERCENT BY WGT: 1 TO 5 NIOSH 100 435
NIOSH STEL 150 655
OSHA STEL 150 655
OSHA TWA 100 435
PRODUCT NAME: 1381 Ultima SSA Antifouling Paint Green PAGE 2 OF 5
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2 HAZARDOUS INGREDIENTS
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HAZARDOUS COMPONENT REG AGENCY PPM NOTES MG/M3 NOTES
Copper Naphthenate ACGIH TLV - 1
(as Cu mists) NIOSH - 1
CAS NUMBER:1338-02-9 OSHA TWA - 1
PERCENT BY WGT: <1
Titanium dioxide ACGIH-TWA - 10
CAS NUMBER:13463-67-7 NIOSH - (+) - (+)
PERCENT BY WGT: 5 TO 10 OSHA TWA - 10 1
Tremolite(nonasbestiform) (None established.)
CAS NUMBER:14567-73-8
PERCENT BY WGT: 1 TO 5
Talc (containing no ACGIH TWA - 2 2
asbestos) NIOSH - 2
CAS NUMBER:14807-96-6 OSHA TWA - 2 3
PERCENT BY WGT: 5 TO 10
Petroleum naphtha ACGIH TLV 100 STS
CAS NUMBER:64742-88-7 OSHA TWA 500 STS
PERCENT BY WGT: 1 TO 5
Petroleum distillates ACGIH TLV 100 STS
CAS NUMBER:64742-95-6 OSHA-PEL 500 STS
PERCENT BY WGT: 1 TO 5
Copper (as Cu dusts & ACGIH TWA - 1
mists) NIOSH - 1
CAS NUMBER:7440-50-8 OSHA TWA - 1
PERCENT BY WGT: 1 TO 5
Mineral spirits ACGIH TWA 100 -
CAS NUMBER:8052-41-3 NIOSH - 350
PERCENT BY WGT: 5 TO 10 OSHA TWA 100 -
NOTES:
1) Total dust
2) Respirable fraction
3) Respirable dust
(+)) NIOSH Occupational Carcinogen
STS) Recommend that exposure limits for stoddard solvent be used as a guideline.
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3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW: WARNING! Combustible liquid and vapor. Harmful or fatal if
PRODUCT NAME: 1381 Ultima SSA Antifouling Paint Green PAGE 3 OF 5
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3 HAZARDS IDENTIFICATION
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swallowed or inhaled. May cause eye, skin and respiratory tract irritation.
EYES: May cause moderate eye irritation. Not expected to cause permanent
damage if promptly rinsed from eyes.
SKIN: May cause skin irritation. Prolonged and/or repeated skin contact may
cause irritation characterized by redness, cracking and blistering. May be
absorbed in toxic amounts through the skin and cause systemic effects.
INHALATION: May cause respiratory tract irritation. Exposure to high
concentrations may cause central nervous system effects, including headache,
drowsiness, nausea, and dizziness. Continued inhlation may result in
unconsciousness or death.
INGESTION: May cause gastrointestinal disturbances such as nausea, vomiting,
diarrhea, and effects similar to those described in INHALATION. Aspiration of
this product into the lungs during ingestion or vomiting may cause mild to
severe pulmonary injury, possibly progressing to death.
CHRONIC: Reports have associated repeated or prolonged occupational exposure
to solvents with permanent brain or nervous system damage, liver and kidney
damage or may cause cardiac arrhythmia.
CARCINOGENS: Ethylbenzene and titanium dioxide are classified by IARC as
possibly carcinogenic to humans (2B) based on inadequate evidence in humans and
sufficient evidence of carcinogenicity in laboratory animals.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin, eyes, respiratory tract,
liver, kidneys.
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4 FIRST AID MEASURES
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EYE CONTACT: Hold eye open and rinse slowly and gently with water for 15-20
minutes. Remove contact lenses, if present, after the first five minutes, then
continue rinsing the eye. Contact a poison control center for treatment advice.
SKIN CONTACT: Take off contaminated clothing. Rinse skin immediately with
plenty of water for 15-20 minutes. Call a poison control center or doctor for
treatment advice. Wash contaminated clothing before reuse.
INHALATION: Move person to fresh air. If person is not breathing, call 911 or
an ambulance, then give artifical respiration, preferably mouth-to-mouth. Call
a poison control center or doctor for further treatment advice.
INGESTION: Immediately call a poison control center or doctor. Do not induce
vomiting unless told to do so by a poison control center or doctor. Do not give
any liquid to the person. Do not give anything by mouth to an unconscious
person.
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4 FIRST AID MEASURES
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NOTE TO PHYSICIAN: There is no specific antidote for effects from overexposure
to this material. Treatment should be directed at the control of symptoms and
the clinical condition.
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5 FIRE FIGHTING MEASURES
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FLASH POINT: 105 F/41C
EXTINGUISHING MEDIA: Use dry chemical, carbon dioxide, water spray or foam.
FIRE FIGHTING PROCEDURES: As in any fire, wear complete fire service protective
equipment, including full-face MSHA/NIOSH approved or equivalent self-contained
breathing apparatus. Use water to cool fire-exposed container/structure/protect
personnel.
FIRE AND EXPLOSION HAZARDS: Can release vapors that form explosive mixtures.
Vapors can travel to a source of ignition and flash back. Closed containers may
explode when exposed to extreme heat (fire). Toxic vapors may be given off in a
fire.
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6 SPILL AND LEAK PROCEDURES
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Stop spill/leak if no risk involved. Avoid breathing vapors. Eliminate ALL
sources of ignition such as flares, flames (including pilot lights), and
electrical sparks. Ventilate area. Take up carefully to avoid heat and sparks.
Use an inert absorbent to complete a clean-up. This material reacts with
oxidizing materials. Dispose of contaminated absorbent, container and unused
contents in accordance with local, state and federal regulations.
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7 HANDLING AND STORAGE
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HANDLING: Avoid breathing of vapors, mists or fumes. Do not get on skin, in
eyes or on clothing. Spray paint in accordance with OSHA 29 CFR 1910.107. Use
with adequate ventilation. Wash thoroughly after handling.
STORAGE: Store in areas/buildings designed to comply with OSHA 1910.106. Keep
in a closed, labeled container within a cool (well-shaded), dry, ventilated
area. Protect from physical damage. Keep containers closed when material is
not in use. Maintain good housekeeping.
OTHER: Keep away from heat and open flame. If post application/use processing
of this product generates dust or if spray application is made, " Exposure
Limits " in Section 2 apply. Do not use until manufacturer's precautions have
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7 HANDLING AND STORAGE
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been read/understood. Containers of this material may be hazardous when
empty. Since emptied containers retain product residues (vapor, liquid), all
hazard precautions given in the data sheet must be observed. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME
SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY CAN EXPLODE AND
CAUSE INJURY OR DEATH. All five gallon pails and larger containers, should be
grounded and/or bonded when material is transferred.
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8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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ENGINEERING CONTROLS: Ventilation is normally required when handling or using
this product to keep exposure to airborne contaminants below the exposure limit.
Facilities storing or utilizing this product should be equipped with an eyewash
station and shower.
RESPIRATORS: Ensure fresh air entry during application and drying. If
engineering controls do not maintain airborne concentrations to a level which is
adequate to protect worker health, or if air monitoring demonstrates vapor level
is above applicable limits, wear an appropriate, properly fitted respirator
(NIOSH/MSHA approved or equivalent) during and after application. Respirator
selection, use and maintenance should be in accordance with the requirements in
29 CFR 1910.134 and NIOSH 42 CFR 84,whenever workplace conditions warrant a
respirator's use.
PERSONAL PROTECTIVE EQUIPMENT: Industrial safety glasses at a minimum. As
necessary for work area conditions: use side shields, goggles, or faceshield.
As required, chemical resistant flexible-type gloves (heavy duty neoprene or
equal). Wear industrial-type work clothing and safety footwear. Depending on
working conditions, i.e., contact potential, wear resistant protective garments
such as head/neck cover, aprons, jackets, pants, coveralls, boots, etc.
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9 PHYSICAL AND CHEMICAL PROPERTIES
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Weight Per Gallon (lbs): 15.030 % VOL by Weight.: 18
Vapor Density.: (Air=1)>1 Boiling Point...: Not determined
Vapor Pressure: Not determined Evaporation Rate: (ether=1)<1
pH............: Not determined Specific Gravity: 1.804
Solubility In Water: Negligible Viscosity.......: Not determined
VOC Content................: 330 g/L
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10 STABILITY AND REACTIVITY DATA
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STABILITY: This material is stable.
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10 STABILITY AND REACTIVITY DATA
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HAZARDOUS POLYMERIZATION: None
INCOMPATIBILITY: Avoid acids, reducing agents, oxidizing agents, chlorates,
bromates, potassium nitrate, hydrogen peroxide, heat, sparks and open flame.
HAZARDOUS DECOMPOSITION PRODUCT(S): Carbon monoxide, carbon dioxide, noxious
copper compounds, and irritating vapors of acetic acid and other toxic organic
compounds during fires.
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11 TOXICOLOGICAL INFORMATION
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Titanium Dioxide: Rats exposed to titanium dioxide dust at 250 mg/m3 developed
lung cancer, however, such exposure levels are not attainable in the workplace.
Xylene: Laboratory animals exposed to high levels of xylene showed evidence of
effects on the liver, kidneys, lungs, spleen, and caused hearing loss. Rats
exposed during pregnancy to xylene showed fetotoxic effects.
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12 ECOLOGICAL INFORMATION
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Product has not been tested for ecotoxicity.
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13 DISPOSAL CONSIDERATIONS
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Dispose of unusable product in accordance with local, state and federal
regulations.
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14 TRANSPORTATION INFORMATION
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DEPARTMENT OF TRANSPORTATION REPORTABLE QUANTITIES
REPORTABLE QTY (LBS) HAZARDOUS SUBSTANCE
100 Xylene
Shipment by Ground-Domestic:
Combustible liquid - Exempt from DOT Regulations in non-bulk (< 119 gallons)
containers.
Shipment by Air:
DOT PROPER SHIPPING NAME: Paint
DOT HAZARD CLASS: 3 Packing Group III
LABEL: Flammable liquid
DOT IDENTIFICATION NUMBER: UN 1263
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15 REGULATORY INFORMATION
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PRODUCT NAME: 1381 Ultima SSA Antifouling Paint Green PAGE 7 OF 5
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15 REGULATORY INFORMATION
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SARA TITLE III SECTION 313 CHEMICALS
Ethylbenzene
Zinc oxide (as dust)
Cuprous oxide (as Cu dust and mists)
Xylene
Copper (as Cu dusts & mists)
WARNING: THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER.
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
EPA Registration Number 60061-71.
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16 OTHER INFORMATION
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Ethylbenzene is considered a Group 2B carcinogen (possibly carcinogenic to
humans). This category generally includes agents for which there is limited
evidence in humans in the absence of sufficient evidence in experimental
animals.
NOTICE: This document is generated for the purpose of distributing health,
safety and environmental data. The information on this MSDS was obtained from
sources which we believe are reliable. However, the information is provided
without any warranty, expressed or implied, regarding its correctness. Some
information presented and conclusions drawn herein are from sources other than
direct test data on the substance itself. Kop-Coat makes no warranty with
respect thereto and disclaims all liability from reliance thereon.
PREPARED BY: Manager of Health, Safety and Environmental Affairs
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