MATERIIAL SAFETY DATA SHEET
M
844-2555 CHROMA-CHEM甎F MED YELLOW
Version 2.271 US
Material no.
Revision date 04/18/2008
Specification 139158
Print Date 04/21/2008
Order Number Page 1 110
,
1. IDENHFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
844-2555 CHROMA-CHEM甎F MED YELLOW
Trade name M
Use of the Substance I Non-aqueous colorant
Preparation
Evonik Degussa Corporation
Company
379 Interpace Parkway
ParsippanY,NJ 07054
USA
973-541-8000
Telephone
Telefax 973-541-8040
us: CHEMTREC EMERGENCY 800-424-9300
NUMBER
CANADA:CANUTEC 613-996-6666
EMERGENCY NUMBER
Product Regulatory Services 973-541-8060
2. HAZARDS IDENTIFICATION
*** EMERGENCY OVERVIEW ***
Form-paste Color-yellow Odor-Sweet ether-like odor.
May cause eye, skin and respiratory tract irritation.
Combustible liquid and vapor.
POTENTIAL HEALTH EFFECTS
Eye contact
Irritati ng.
May cause tearing, reddening and/or swelling.
May injure eye tissue if not removed promptly.
Skin Contact
A moderate skin irritant based on testing of similar CHROMA-CHEM?base mixtures. Prolonged or
repeated contact may cause irritation.
Prolonged skin contact with large amounts of ether acetates may cause drowsiness.
Inhalation
Possibly irritating.
Excessive inhalation of solvent vapors may cause nasal and respiratory irritation and central
nervous system effects including dizziness, weakness, fatigue, nausea, headache, possible
MSDS-US (P511100) / 4/11l12OOB 2:18
MATERI,AL SAFETY DATA SHEET
M
844-2555 CHROMA-CHEM甎F MED YELLOW
2.271 US
Version
Material no.
Revision date 04/18/2008
139158
Specification
04/21/2008
Print Date
Order Number 2/10
Page
unconsciousness and even death.
Ingestion
May cause gastrointestinal irritation, nausea, vomiting, and diarrhea.
Chronic Health Hazard
High vapor concentrations (3000 ppm) of propylene glycol monomethyl ether acetate caused
upper respiratory irritation and liver and kidney effects in subchronic animal testing. The relevance
of these results to humans is not known.
High concentrations of titanium dioxide dust caused microscopic lung tumors in rats in lifetime
inhalation studies. However, DuPont, the primary US manufacturer, based on a review of the test
data and based on an epidemiological study of employees, concludes that titanium dioxide
pigment will not cause chronic respiratory disease in humans at concentrations experienced in the
workplace.
Health studies have shown that many petroleum hydrocarbons pose potential human health risks
which may vary from person to person. As a precaution, exposure to liquids, vapors, mists or
fumes should be minimized.
Because this product is a free-flowing liquid or paste, dust inhalation is not an expected route of
exposure.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Information on ingredients / Hazardous components
2-methoxy-1-methylethyl acetate
Percent 0Nt./ Wt.) 10- 30 %
CAS-No. 108-65-6
Stoddard solvent; Low boiling point naphtha - unspecified
Percent 0Nt./ Wt.)
CAS-No. 8052-41-3 10 - 30 %
Titanium dioxide
Percent 0Nt./ Wt.) 10 - 30 %
CAS-No. 13463-67-7
NJTSR No.56705700001-5053P
Percent 0Nt./ Wt.) 1-5%
CAS-No. Trade Secret
NJTSR NO.56705700001-5057P
Percent 0Nt./ Wt.) 1-5%
CAS-No. Trade Secret
NJTSR NO.56705700001-5056P
Percent 0Nt./ Wt.) 1-5%
CAS-No. Trade Secret
Other information
This material is classified as hazardous under OSHA regulations.
This product contains no lead, cadmium, mercury or hexavalent chromium which have been intentionally
introduced as an element during manufacture or distribution and the sum of the concentration level of
lead, cadmium, mercury, or hexavalent chromium incidentally present in this product shall not exceed
100 parts per million by weight.
MSD5-US (P51/ICO) 14/1812008 2: 18
MATERIAL SAFETY DATA SHEET
844-2555 CHROMA-CHEM甎F MED YELLOW M
2.27/ US
Version
Material no.
04/18/2008
Revision date
139158
Specification
04/21/2008
Print Date
Order Number 3/10
Page
4. FIRST AID MEASURES
Inhalation
If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If unconscious, evaluate the need for
artificial respiration. Get immediate medical attention.
Skin contact
Wash contaminated area with lukewarm gently flowing water for at least 20-30 minutes. Remove
contaminated clothing, shoes and leather goods under running water. If symptoms develop or persist,
obtain medical attention. Wash clothing before reuse.
Eye contact
In case of contact, immediately flush eyes with plenty of water for at least 30 minutes, while holding
eyelids apart.
Do not allow contaminated water to contact the unaffected eye or face during irrigation of an affected
eye.
Obtain medical attention immediately.
Ingestion
Do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of
liquid into the lungs. Get medical attention.
If the heart has stopped or breathing has stopped, trained personnel should begin cardiopulmonary
resuscitation or artificial respiration immediately.
5. FIRE-FIGHTING MEASURES
42.22 癈, 108 of
Flash point
Method Setaflash Closed Cup
OSHA Fllammability Classification Combustible Liquid
Suitable extinguishing media
Use water spray or fog, foam, dry chemical or C02.
Specific hazards during fire fighting
Combustible liquid. Vapors can travel to a source of ignition and flash back. Explosive mixtures may
occur at temperatures at or above the flashpoint.
Further information
As in any fire, wear self-contained positive-pressure breathing apparatus, (MSHNNIOSH approved or
equivalent) and full protective gear. Containers can build up pressure if exposed to heat (fire). Cool with
water spray.
MSDS-US (P511100) 14118/2008 2:18
MATERIAL SAFETY DATA SHEET
844-2555 CHROMA-CHEM甎F MED YELLOW M
Version 2.27/ US
Material no.
Revision date 04/18/2008
Specification 139158
Print Date 04/21/2008
Order Number Page 4/10
6. ACCIDENTAL RELEASE MEASURES
Additional advice
Absorb spill with inert material, then place in a chemical waste container. After removal, flush
contaminated area with water and collect for disposal. Clean up spills immediately. Remove sources of
ignition and ventilate area. Use a respirator and other protective equipment as outlined in Section 8.
Obey relevant local, state, provincial and federal laws and regulations. Do not contaminate any lakes,
streams, ponds, groundwater or soil.
7. HANDLING AND STORAGE
Handling
Safe handling advice
Keep away from heat. Keep away from sparks, flames and other sources of ignition. Avoid contact with
eyes, skin and clothing. Avoid breathing vapor or mist. Use with adequate ventilation. The need for
grounding and bonding of containers in accordance with OSHA 29 CFR 1910.106 and NFPA 77 should
be assessed for all product transfers. Follow all MSDS/label precautions even after the container is
emptied because it may retain product residues. Wash thoroughly after handling.
Storage
Requirements for storage areas and containers
Keep in a dry, cool place.
Keep container closed when not in use.
Residual vapors might explode on ignition; do not apply heat, cut, drill, grind or weld on or near this
container.
8. EXPOSURE CONTROLS I PERSONAL PROTECTION
Component occupational exposure guidelines
?Stoddard solvent; Low boiling point naphtha - unspecified
CAS-No. 8052-41-3
Control parameters 100 ppm Time Weighted Average (TWA):(ACGIH)
500 ppm PEL:(OSHA Z1)
2900 mg/m3
100 ppm Time Weighted Average (TWA)
525 mg/m3 Permissible Exposure Limit (PEL):(US CA
OEL)
?Titanium dioxide
CAS-No. 13463-67-7
10 mg/m3 Time Weighted Average (TWA):(ACGIH)
15 mg/m3 PEL:(OSHA Z1)
Total dust.
Other information
Exposure values for mineral spirits (CAS Nr 8052-41-3) are given as Stoddard solvent.
The AIHA WEEL for propylene glycol monomethyl ether acetate is 50 ppm TWA.
MSDS-US (P51/100) 14/18/2008 2:18
MATERIAL SAFETY DATA SKEET
844-2555 CHROMA-CHEM甎F MED YELLOW M
Version 2.27/ US
Material no.
Revision date 04/18/2008
139158
Specification
Print Date 04/21/2008
Order Number Page 5/10
Engineering measures
Use explosion-proof ventilation equipment.
Personal protective equipment
Respiratory protection
A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 or applicable
federal/provincial requirements must be followed whenever workplace conditions warrant respirator use.
NIOSH's "Respirator Decision Logic" may be useful in determining the suitability of various types of
respirators.
Hand protection
Use impermeable gloves.
Eye protection
Chemical resistant goggles must be worn.
Skin and body protection
A safety shower and eye wash fountain should be readily available.
To identify additional Personal Protective Equipment (PPE) requirements, it is recommended that a
hazard assessment in accordance with the OSHA PPE Standard (29CFR 1910.132) be conducted before
using this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form paste
Color yellow
Sweet ether-like odor.
Odor
Safety data
> 143 DC
Boiling point/range
42.22 DC
Flash point
Method Setaflash Closed Cup
Relative density 1.1
Solubility/qualitative Solubility in water: Negligible.
65 - 85 KU (25 DC)
Viscosity, dynamic
Solvents and Volatiles Data
% VOC (gm/!) 461.81
Evaporation rate Slower than butyl acetate
10: STABILITY AND REACTIVITY
Conditions to avoid Avoid high temperatures and sources of ignition.
MSDS-US (P51/100) 14/18/20082.18
MATERIAL SAFETY DATA SHEET
M
844-2555 CHROMA-CHEM甎F MED YELLOW
2.27/ US
Version
Material no.
04/18/2008
Revision date
139158
Specification
04/21/2008
Print Date
Order Number 6/10
Page
Materials to avoid oxidizing substances
11. TOXICOLOGICAL INFORMATION
Component Acute oral toxicity 2-methoxy-1-methylethyl acetate
108-65-6
LD50 Rat: 8532 mg/kg
Stoddard solvent; Low boiling point naphtha - unspecified
8052-41-3
LD50 Rat: > 5000 mg/kg
Titanium dioxide
13463-67-7
LD50 Rat: > 24000 mg/kg
NJTSR NO.56705700001-5053P
Trade Secret
LD50 Rat: 4150 mg/kg
NJTSR NO.56705700001-5057P
Trade Secret
LD50 Rat: 4450 mg/kg
Component Acute inhalation LC50 (rat) > 4345 ppm, 6 hours, vapor
toxicity 2-methoxy-1-methylethyl acetate
related to substance
Stoddard solvent; Low boiling point naphtha - unspecified
8052-41-3
LC50 Rat: > 5500 mg/m3 14 h
Titanium dioxide
13463-67-7
LC50 Rat: > 6820 mg/m3 14 h
Component Acute dermal toxicity 2-methoxy-1-methylethyl acetate
108-65-6
LD50 Rabbit: > 19000 mg/kg
(calculated)
(literature value)
Stoddard solvent; Low boiling point naphtha - unspecified
8052-41-3
LD50 Rabbit: > 3000 mg/kg
Titanium dioxide
13463-67-7
LD50 Rabbit: > 10000 mg/kg
Component Repeated dose Titanium dioxide
MSDS-US (P5111C0) /4/18/20082: 18
MATERIAL SAFETY DATA SHEET
M
844-2555 CHROMA-CHEM甎F MED YELLOW
Version 2.27/ US
Material no.
Revision date 04/18/2008
139158
Specification
04/21/2008
Print Date
Order Number 7/10
Page
13463-67-7
toxicity 1
High concentrations of titanium dioxide dust caused microscopic lung
tumors in rats lin lifetime inhalation studies. However, DuPont, the primary
US manufacturer, based on a review of the test data and based on an
epidemiological study of employees, concludes that titanium dioxide
pigment will not cause chronic respiratory disease in humans at
concentrations experienced in the workplace.
Component carcinogenicity Titanium dioxide
assessment 13463-67-7
Contains a component which is classified as an IARC 2B carcinogen
(possibly carcinogenic to humans).
Component General Toxicity 2-methoxy-1-methylethyl acetate
Information 108-65-6
High vapor concentrations (3000 ppm) of propylene glycol monomethyl
ether acetate caused upper respiratory irritation and liver and kidney
effects in subchronic animal testing. The relevance of these results to
humans is not known.
12. ECOLOGICAL INFORMATION
General Ecological Information No ecotoxicological studies are available.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL
Advice on disposal Waste must be disposed of in accordance with federal, state, provincial
and local regulations. CONTAINER DISPOSAL: Empty containers by
removing the top and inverting to allow all free-flowing product to drain. To
meet regulatory criteria, the container is considered empty when less than
3% remains in the container. Additional special handling is not typically
required and the empty container can be discarded with other non
hazardous trash. Note: Local disposal regulations may be more stringent
and require additional restrictions or precautions. Customers should
check with their local disposal company, municipal or state authority.
Recycle of plastic or metal containers may require clean rather than empty
containers. In this case the containers can be rinsed with mineral spirits
until the containers are considered generally product free.
14. TRANSPORT INFORMATION
Sea transport IMDG-Code
o
3
Class
UN-No 1263
III
Packaging group
MSOS-US (P51/1CO) 14/1B/2DOB 2:1B
MATERIAL SAFETY DATA SHEET
844-2555 CHROMA-CHEM甎F MED YELLOW M
Version 2.27/ US
Material no.
Revision date 04/18/2008
Specification 139158
Print Date 04/211/2008
Order Number Page 8/10
F-E, S-E
EmS
Proper technical name (Proper shipping name)
PAINT RELATED MATERIAL
Air transport ICAO-TI/IATA-DGR
Class 3
L1t\I-No 1263
Packaging group III
Proper technical name (Proper shipping name)
Paint related material
Loading instructions/Remarks
lATA C ERG-Code 3L
lATA P ERG-Code 3L
CFR INWTR In the U.S. this material may be classified as combustible liquid.
Combustible liquids are not regulated in packages 450 liters or less.
This applies for shipments by road and rail only.
CFR RAIL In the U.S. this material may be classified as combustible liquid.
Combustible liquids are not regulated in packages 450 liters or less.
This applies for shipments by road and rail only.
CFR ROAD In the U.S. this material may be classified as combustible liquid.
Combustible liquids are not regulated in packages 450 liters or less.
This applies for shipments by road and rail only.
15. REGULATORY INFORMATION
Information on ingredients / Non-hazardous components
This product contains the following non-hazardous components
NJTSR NO.56705700001-5659P
rNt.! WL) 5 -10 %
CAS-No. Trade Secret Percent
NJTSR NO.56705700001-6864P
rNt.! Wt.) 10 - 30 %
CAS-No. Trade Secret Percent
NJTSR NO.56705700001-5790P
rNt.! Wt.)
CAS-No. Trade Secret Percent 10 - 30 %
US Federal Regulations
OSHA
If listed below, chemical specific standards apply to the product or components:
? None listed
Clean Air Act Section (112)
If listed below, components present at or above the de minimus level are hazardous air pollutants:
? None listed
MSO&-US (P51/100) 14118/2008 2:18
MATERIAL SAFETY DATA SHEET
844-2555 CHROMA-CHEM甎F MED YELLOW M
2.27/ US
Version
Material no.
04/18/2008
Revision date
139158
Specification
04/21/2008
Print Date
Order Number 9/10
Page
CERCLA Reportable Quantities
If listed below, a reportable quantity (RQ) applies to the product based on the percent of the named
component:
? None listed
SARA Title III Section 311/312 Hazard Categories
The product meets the criteria only for the listed hazard classes:
? Acute Health Hazard
? Chronic Health Hazard
? Fire Hazard
SARA Title III Section 313 Reportable Substances
If listed below, components are subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
? None listed
Toxic Substances Control Act (TSCA)
If listed below, non-proprietary substances are subject to export notification under Section 12 (b) of
TSCA:
? None listed
State Regulations
California Proposition 65
A warning under the California Drinking Water Act is required only if listed below:
? None listed
MSDS-US (P5111CO) 1411e,2C88 2:18
MATERIAL SAFETY DATA SHEET
844-2555 CHROMA-CHEM甎F MED YELLOW M
2.27/ US
Version
Material no.
04/18/2008
Revision date
139158
Specification
04/21/2008
Print Date
Order Number 10/10
Page
International Chemical Inventory Status
Unless otherwise noted, this product is in compliance with the inventory listing of the countries shown
below. For information on listing for countries not shown, contact Evonik Degussa Corporation
Product Regulatory Services Department:
? Listedlregistered
Europe (EINECS/ELINCS)
? Listed/registered
USA (TSCA)
? Listed/registered
Canada (DSl)
? Listed/reg istered
Australia (AICS)
? Not listed/Not registered
Japan (MITI)
? Listed/registered
Korea (TCCl)
? Not listed/Not registered
Philippines (PICCS)
? Listed/registered
China
16. OTHER INFORMATION
HMIS Ratings
Health: 2*
Flammability: 2
a
Physical Hazard:
Further information
Changes since the last version are highlighted in the margin. This version replaces all previous versions.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text.
MSDS-US (P5111CO) 14/1812008 2:18
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