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Revised 1/23/08
Replaces 4/18/07
Printed 1/29/08
MSDS ID: 8055164
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT PART NUMBER: 8055164
DESCRIPTION: 7224 GREY-F
COMPANY: EMERGENCY RESPONSE NUMBERS:
Markem Corporation Transportation:
150 Congress Street United States: (800) 424-9300
Keene, NH 03431 International: (703) 527-3887(collect)
Product Safety and Environmental:
(603) 352-1130
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2. HAZARDOUS INGREDIENTS
COMPONENT CAS # PCT(WT)
Castor oil, hydrogenated 8001-78-3 1-5
Cyclohexane- 1,2-dicarboxylic anhydride 85-42-7 1-5
Iron Oxide Yellow 51274-00-1 1-5
N-butyl alcohol 71-36-3 1-5
Tributyl phosphate 126-73-8 10-30
Copper Chromite Black Spinel 68186-91-4 5-10
2-methyl-1-propanol 78-83-1 0.1-1
Exposure and physical property information is presented in Section 9.
If the total percentage is less than 100, the balance of this product is not
considered to be hazardous as defined in the OSHA Hazard Communication
Standard (29 CFR 1910.1200).
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3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS RATING SYSTEM NFPA RATING SYSTEM
Health: 3 Health: 3
Flammability: 1 Flammability: 1
Reactivity: 1 Reactivity: 1
Protection: B
POTENTIAL HEALTH CONSIDERATIONS
LIKELY ROUTES OF ENTRY:
Inhalation; Contact; Absorption; Ingestion
TARGET ORGANS:
Skin; Nervous System; Respiratory Tract; Eyes; Lungs; Kidneys; Blood;
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3. HAZARDS IDENTIFICATION (Cont.)
Liver; Bladder;
POTENTIAL IMMEDIATE EFFECTS FROM OVEREXPOSURE
EYE CONTACT
Can cause severe eye irritation, tearing and reddening, but not likely to
permanently injure eye tissue. Temporary vision impairment (cloudy or blurred
vision) is possible.
SKIN CONTACT
Corrosive to skin tissue, can cause chemical burns.
Skin Sensitizer! Avoid exposure. If sensitized, repeated exposures will result
in skin irritation, even at very low concentrations.
SKIN ABSORBTION
Toxic if absorbed through the skin causing systemic damage.
INHALATION
Can cause severe respiratory irritation, dizziness, weakness, fatigue, nausea,
headache and possible unconsciousness.
Respiratory Sensitizer! Avoid exposure. If sensitized, repeated exposures
will result in respiratory irritation and shortness of breath, even at very
low concentrations. These asthma-type symptoms may develop immediately or be
delayed up to several hours.
INGESTION
Irritating to mouth, throat, and stomach. Can cause abdominal discomfort,
nausea, vomiting and diarrhea.
Aspiration of material into the lungs can cause chemical pneumonitis which can
be fatal.
POTENTIAL LONG-TERM EFFECTS FROM OVEREXPOSURE:
CANCER INFORMATION
Contains a substance that can cause cancer in laboratory animals at high oral
doses. Not a carcinogen according to NTP, IARC, or OSHA.
No IARC cancer hazard information available.
No ACGIH cancer hazard information available.
No NTP cancer hazard information available.
No OSHA cancer hazard information available.
REPRODUCTIVE SYSTEM INFORMATION
Contains a substance that is a possible reproductive hazard based on tests
with laboratory animals.
ADDITIONAL HEALTH HAZARD INFORMATION
Tributyl phosphate: TBP was found not to be neurotoxic either acutely at 1000
mg/kg or after three months of exposure at up to 325 mg/kg/day. Assuming
similar absorption of TBP by oral and inhalation routes of exposure and a
breathing rate of approximately 170 mL/min, these values are approximately
equivalent to inhalation exposures of 4900 mg/cu m acutely and 1590 mg/cu m
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3. HAZARDS IDENTIFICATION (Cont.)
per day subchronically. The ACGIH TLV (TWA) for TBP is 2.2 mg/cu m. This
indicates that a minimum of a 700-fold safety factor exists for TBP as a
potential neurotoxin(1). Large doses have been reported to cause dyspnea,
weakness, pulmonary edema, and twitching in rats. Chronic inhalation of
large doses can lead to general poisoning with paralysis, urinary bladder
hyperplasia, and increased liver weight.(1) Healy, C.E.; Beyrouty, P.C.;
and Broxup, B.R., Am. Ind. Hyg. Assoc J. 56:349-355 (1995).
Isobutyl alcohol: Administration by subcutaneous injection or by gavage has
been reported to cause an increased incidence of benign and malignant tumors
in rats. No human findings are available.
MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY OVEREXPOSURE
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4. FIRST AID MEASURES
EYE CONTACT
Immediately flush eyes with plenty of water for at least 20 minutes retracting
eyelids often. Get immediate medical attention.
SKIN CONTACT
Wash with soap and water. Remove contaminated clothing and launder. Get
medical attention if irritation develops or persists.
INHALATION
Remove to fresh air. If not breathing, perform rescue breathing and, if
available, have a trained person administer oxygen.
Get medical attention immediately.
INGESTION
Emergency personnel should be contacted immediately and be provided with
this MSDS. For ingestion of small quantities of chemicals, the risk
associated with inducing vomiting usually exceeds the poisoning risk.
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5. FIRE FIGHTING MEASURES
FLAMMABILITY DATA
FLASH POINT: 241 F, 116 C
EXPLOSIVE/FLAMMABILITY LIMITS ESTIMATED FROM INGREDIENTS:
LOWER LIMIT: 1.4 %
UPPER LIMIT: 20.0 %
AUTOIGNITION TEMPERATURE ESTIMATED FROM INGREDIENTS:
670 F, 354 C
GENERAL HAZARDS
Vapors may be ignited by heat, sparks, flames or other sources of ignition
giving rise to a Class B fire. Vapors are heavier than air and may travel to a
source of ignition and flash back. Container may explode in heat of fire.
Empty container may still contain residual material that can ignite and/or
result in an explosion. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty container to heat, flame, sparks, static electricity,
or other sources of ignition.
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5. FIRE FIGHTING MEASURES (Cont.)
EXTINGUISHING MEDIA
Use alcohol foam, carbon dioxide (CO2) or dry chemical. Water may not be
effective to extinguish fire. Use water spray to cool fire-exposed containers
and to protect personnel.
FIRE FIGHTING INSTRUCTIONS
Do not enter fire area without proper protection including self-contained
breathing apparatus and full protective equipment. Fight fire from a
safe distance and a protected location. Heat may build pressure and rupture
closed containers, spreading fire and increasing risk of burns or injuries.
Use water spray/fog for cooling. Even if material is water soluble, it may
not be practical to extinguish fire by water dilution. Notify authorities if
liquid enters sewers or other public waters.
HAZARDOUS COMBUSTION PRODUCTS
carbon dioxide; carbon monoxide; phosphorus compounds
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6. ACCIDENTAL RELEASE MEASURES
SPILL CLEAN-UP PROCEDURES
Shut off ignition sources; smoking, flames or other sources of ignition
must not be permitted in the area. Small Spills: Take up with sand or other
noncombustible absorbent material and put into properly labeled containers for
disposal. Large Spills: Dike ahead of liquid spill area to minimize migration
and vapor generation. Ventilate the area. Get professional help from outside
contractors, the fire department or your trained spill brigade.
HEALTH CONSIDERATIONS AND PROTECTIVE EQUIPMENT
Information on the selection and use of personal protective equipment is found
in Section 8 of this MSDS. Personal protective equipment needs must be
evaluated based on information provided on this sheet and the special
circumstances created by the spill including; material spilled, quantity, the
area in which it occurred and the expertise of employees in the area
responding to the spill. Never exceed any occupational exposure limits and
consider that the evaporation of volatile solvents can lead to the
displacement of air creating an environment that can cause asphxyiation.
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7. HANDLING AND STORAGE
HANDLING
Avoid contact with material, avoid breathing vapors, use only in a well
ventilated area, use bonding and grounding when transferring this material.
STORAGE
Store in a cool dry ventilated location, away from oxidizers, heat, flame or
other incompatible conditions. Keep container(s) closed if possible.
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8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
ENGINEERING CONTROLS
Local exhaust ventilation or other engineering controls are normally required
when handling or using this product to keep exposure to airborne contaminants
below the TLV, PEL, or other recommended exposure limit and/or maintain
operator comfort.
RESPIRATORY PROTECTION
If air monitoring indicates airborne concentrations at or above the limits,
or symptoms of inhalation over-exposure occur, a respiratory protection
program may be required. Engineering controls to reduce the exposure below
acceptable limits are usually preferable to a respirator program.
EYE PROTECTION
Chemically resistant safety glasses with side shields must be worn when
handling this product. Further eye protection such as chemical splash goggles
and/or face shield must be worn when the possibility exists for eye contact
due to splashing or spraying liquid or airborne particles. Contact lenses
should not be worn. An eye wash station should be available.
SKIN PROTECTION
Prevent skin contact by wearing gloves and other protective equipment.
Inspect gloves for chemical break-through and replace if detected. Clean
protective equipment thoroughly after each use. Do not remove from workplace.
An emergency shower in the area is recommended.
Appropriate gloves to be used for MARKEM products that are mixtures have not
been determined. Glove type(s) for ingredients present at 10% or more
(if known) are:
Butyl rubber, Polyethylene,
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9. PHYSICAL AND CHEMICAL PROPERTIES - PRODUCT
APPEARANCE: Liquid
COLOR: Grey
ODOR: Characteristic
SPECIFIC GRAVITY(g/ml): 1.54
PERCENT VOLATILE: 24
VOC CONTENT(lb/gl): Not determined
VAPOR PRESSURE (Pa): Not determined
BOILING PT OR RANGE(F): ND
pH: NA
VISCOSITY: ND
VAPOR DENSITY: Heavier than air
FREEZING POINT(F): ND
EVAPORATION RATE: 0.5-2 (n-Butyl acetate = 1)
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9.1 EXPOSURE, PHYSICAL AND CHEMICAL PROPERTIES FOR COMPONENTS
COMPONENT ACGIH OSHA
TWA\CEIL STEL TWA CEIL
8001-78-3 NE NE NE NE
85-42-7 NE NE NE NE
51274-00-1 NE NE NE NE
71-36-3 50 ppm C sk NE 100 ppm NE
126-73-8 0.2 ppm NE 0.2 ppm NE
68186-91-4 NE NE NE NE
78-83-1 50 ppm NE 50 ppm NE
SPECIFIC EVAP RATE WATER VAPOR
GRAVITY N-BUTYL SOLUBILITY PRESSURE
COMPONENT CAS NUMBER ACETATE=1 Weight % mmHg at F
8001-78-3 1.000 ND ND ND
85-42-7 1.190 ND Negligible;1.1mmHg @
100 C
51274-00-1 1.000 ND ND ND
71-36-3 0.808 0.1-0.5 Minimal; 1-4.4 mmHg
126-73-8 0.980 <0.01 Negligible;7.3@302F
68186-91-4 5.200 ND ND ND
78-83-1 0.803 0.5-2 Minimal; 1-8.8 mmHG
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10. STABILITY AND REACTIVITY
STABILITY
Stable under normal conditions.
CONDITIONS TO AVOID
Heat, sparks, open flame, other ignition sources, oxidizing conditions, and
elevated temperatures.
INCOMPATIBILITY
acids; caustics (bases); strong oxidizing agents;
HAZARDOUS DECOMPOSITION PRODUCTS
carbon dioxide; carbon monoxide; phosphorus compounds
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11. TOXICOLOGICAL INFORMATION
Castor oil, hydrogenated:
LD50 (oral, rat): > 10,000 mg/kg
Skin irritation(rabbit): 500 mg/24hr (mild irritant)
Eye irritation(rabbit): 100 mg/24hr (mild irritant)
N-Butyl alcohol:
Acute toxicity:
LD50 (oral, rat): 800-4400 mg/kg.
LD50 (oral, rabbit): 1600-3500 mg/kg.
LD50 (dermal, rabbit): 4200-5300 mg/kg.
LC50 (ihl,rat): Greater than 8000 ppm (4-hr exposure).
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11. TOXICOLOGICAL INFORMATION (Cont.)
Tributyl phosphate:
Acute toxicity:
Oral LD50 rat: 1390 mg/kg, Effect: kidney, ureter, bladder (changes in
(tubules)
Inhalation LC50 rat: 28 gm/m3/1H
Eye rabbit: 500 mg, Effect: Severe
C.I. Pigment Black 28:
Contains chromium (III). It is an inorganic mixture of copper oxide(II) and
chromium (III) oxide which are homogenously and ionically interdiffused to
form a crystalline matrix of spinel. It is insoluble in water.
LD50 (oral, rat) >5,000 mg/kg
Isobutyl alcohol:
LD50 (rat, oral): 2460 mg/kg
LD50 (rabbit, oral): 3400 mg/kg
LD50 (rabbit, dermal): 4240 mg/kg
LCLO (rat, inhalation): 8000 ppm/4 hours
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12. ECOLOGICAL INFORMATION
N-butyl alcohol:
LC50 Pimephales promelas (fathead minnow) 1730 mg/l/96 hr.
Release of n-butanol to soil will result in volatilization from the soil
surface and biodegradation. n-Butanol should not bind strongly to soil and
so is expected to leach into groundwater.
Release of n-butanol to water is expected to result in biodegradation and in
volatilization from the water surface.
Vapor phase n-butanol in the atmosphere is expected to react with
photochemically generated hydroxyl radicals with a half-life of 1.2
(experimental)-2.3 (estimated) days.
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13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with all federal, state, local or provincial
regulations.
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14. TRANSPORT INFORMATION, DOT and IATA:
DOT & IATA: NOT RESTRICTED
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15. REGULATORY INFORMATION
Those ingredients appearing on the following list that do not appear
in Section 2 are present at <0.1% for carcinogens, <1% for other hazardous
substances, or are not considered hazardous in this product.
UNITED STATES OF AMERICA
FEDERAL REGULATIONS
CERCLA: The following components have CERCLA reportable quantities:
CASRN DESCRIPTION CERCLA RQ WEIGHT%
71-36-3 N-BUTYL ALCOHOL 5000 lb final RQ; 3
2270 kg final RQ
78-83-1 ISOBUTYL ALCOHOL 5000 lb final RQ; 0
2270 kg final RQ
RCRA: The following components are subject to RCRA land disposal restrictions:
CASRN DESCRIPTION
71-36-3 N-BUTYL ALCOHOL
78-83-1 ISOBUTYL ALCOHOL
SARA TITLE III
SECTION 302 Extremely Hazardous Substances (EHS)
CASRN DESCRIPTION
None
SECTION 311/312 Community Right to Know
CASRN DESCRIPTION
71-36-3 N-BUTYL ALCOHOL
SARA HAZARD CATEGORY INFORMATION
FIRE: NO
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE: NO
IMMEDIATE (ACUTE) HEALTH HAZARD: NO
DELAYED (CHRONIC) HEALTH HAZARD: NO
SECTION 313 Toxic Chemical Release Inventory Reporting (TRI)
CASRN DESCRIPTION
71-36-3 N-BUTYL ALCOHOL 3
TSCA
SECTION 8(b) Inventory: All chemicals in this product appear in the inventory
or are exempt from the listing requirements.
SECTION 12(b) Export: The following chemicals are subject to export reporting
CASRN DESCRIPTION
71-36-3 N-BUTYL ALCOHOL
126-73-8 TRIBUTYL PHOSPHATE
78-83-1 ISOBUTYL ALCOHOL
STATE REGULATIONS
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65)
The following chemical(s) in this product are known to the State of
California to cause cancer:
CASRN DESCRIPTION WGT%
71-43-2 BENZENE 0.001-0
50-00-0 FORMALDEHYDE 0.01-0.
The benzene content of this material is <80 ppm. The bisphenol A and
epichlorohydrin content is <1 ppm.
The following chemical(s) in this product are known to the State of
California to be hazards to reproductive health: WGT%
CASRN DESCRIPTION 0.001-0
71-43-2 BENZENE
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15. REGULATORY INFORMATION (Cont.)
MASSACHUSETTS Right to Know Law
CASRN DESCRIPTION %
71-36-3 N-BUTYL ALCOHOL 1-5
126-73-8 TRIBUTYL PHOSPHATE 10-30
78-83-1 ISOBUTYL ALCOHOL 0.1-1
NEW JERSEY Right to Know Law
CASRN DESCRIPTION %
85-42-7 HYDROHEXAPHTHALIC ANHYDRIDE 1-5
71-36-3 N-BUTYL ALCOHOL 1-5
126-73-8 TRIBUTYL PHOSPHATE 10-30
78-83-1 ISOBUTYL ALCOHOL 0.1-1
PENNSYLVANIA Right to Know Law
CASRN DESCRIPTION %
71-36-3 1-BUTANOL 1-5
126-73-8 TRIBUTYL PHOSPHATE 10-30
78-83-1 1-PROPANOL, 2-METHYL- 0.1-1
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16. OTHER INFORMATION
Copper Chromite Black Spinel: This pigment is a crystalline compound, not a
mixture. It contains the following SARA III, 313 reportable chemicals:
Chromium (III), 42%; Copper, 26%; Manganese, 2%.
Note: A CAS number in the form TSXXXX-XX-X is a trade secret.
NA= Not applicable
ND= Not determined
TS= Trade secret
MSDS prepared by Richard C. Berry
This information is offered in good faith as typical values and not as product
specifications. No warranty, either expressed or implied, is made. The
recommended industrial hygiene and safe handling practices are believed to be
generally applicable, however each user must review the recommendations and
determine the suitablity for their intended use.
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