Page : 1
MATERIAL SAFETY DATA SHEET Revised edition no : 2
According to Regulation (EC) 1907/ Date : 10 / 3 / 2008
2006 Supersedes : 8 / 3 / 2006
Techno Gloss 32104391
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY
: Techno Gloss
Trade name
: Liquid.
Type of product
: For professional use only.
Use
: Ecover Belgium NV
Company identification
Industrieweg 3
2390 Malle Belgium
: sds@ecover.com
e-mail:
: +32 (0)3 309 25 00
Phone
: +32 (0)3 311 72 70
Fax
: +32 (0)70 245 245 (Antipoison Centre Belgium)
Emergency phone nr
: See address above.
Responsible for placing on the
market
2. HAZARDS IDENTIFICATION
: Not classified as dangerous product.
Hazards identification
Symptoms relating to use
: None under normal conditions.
- Inhalation
Irritation of the bronchial tract, narcotic effects, dizziness and headaches may occur
with high vapour concentrations.
: Prolonged or repeated skin contact with the material may remove natural oils.
- Skin contact
: Slight eye irritant.
- Eye contact
: Abdominal pain.
- Ingestion
Diarrhea.
Headache.
Vomiting.
3. COMPOSITION / INFORMATION ON INGREDIENTS
: Preparation.
Substance / Preparation
: This product is not hazardous but contains hazardous components.
Components
: Regulation (CE) No. 648/2004 of 31 March 2004 on detergents:
Composition
Preservatives
2-BROMO-2-NITROPROPANE-1,3-DIOL, TRIS (HYDROXYMETHYL)
NITROMETHANE.
Substance name Contents CAS No EC No Index No Classification
Dipropyleneglycol Methylether : Between 1 and 10 % 34590-94-8 252-104-2 ----- R10
Tributhoxy Ethyl Phosphate : Between 1 and 10 % 78-51-3 201-122-9 ----- R52-53
2-bromo-2-nitropropane-1,3-diol : < 0.1 % 52-51-7 200-143-0 603-085-00-8 Xn; R21/22
Xi; R37/38-41
N; R50
Trishydroxymethylnitromethane : < 0.1 % 126-11-4 204-769-5 ----- Xn; R22
: PPG-2 METHYL ETHER
INCI
Tributhoxyethylphosphate
2-BROMO-2-NITROPROPANE-1,3-DIOL
TRIS (HYDROXYMETHYL) NITROMETHANE
4. FIRST AID MEASURES
First aid measures
: Assure fresh air breathing.
- Inhalation
Allow the victim to rest.
Seek medical attention if ill effect or irritation develops.
Ecover Belgium NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgium
Page : 2
MATERIAL SAFETY DATA SHEET Revised edition no : 2
According to Regulation (EC) 1907/ Date : 10 / 3 / 2008
2006 Supersedes : 8 / 3 / 2006
Techno Gloss 32104391
4. FIRST AID MEASURES (continued)
: Rinse affected area thoroughly with water to remove concentrated product.
- Skin contact
Remove contaminated clothing.
: Rinse immediately and for at least 15 minutes with copious amounts of water (also
- Eye contact
assure adequate flushing under the eyelids and if possible after having removed
contact lenses). Bring the victim to an ophthalmist.
: Wash out mouth and do not induce vomiting! Let the victim drink 2 glasses of water
- Ingestion
on his own.
Seek medical advice.
: No specific recommendations.
Note to physician
: No specific recommendations.
Workplace equipment
5. FIRE-FIGHTING MEASURES
: None.
Specific hazards
Extinguishing media
: All extinguishing media can be used.
- Suitable extinguishing media
: None.
- Unsuitable extinguishing media
: Exercise caution when fighting any chemical fire.
Protection against fire
See Heading 8.
6. ACCIDENTAL RELEASE MEASURES
: Spill area may be slippery.
Personal precautions
Avoid contact with skin and eyes.
Equip cleanup crew with proper protection.
See Heading 8.
: Avoid release to the environment.
Environmental precautions
: Recover spilled material as much as possible in a clean container for reuse. Spilled
Clean up methods
product must be collected with sand or an inert absorbent material and dispose of
as chemical waste. Rinse away remainder with water.
7. HANDLING AND STORAGE
: Not expected to be a fire/explosion hazard under normal conditions of use.
Protection against fire
: Store in a cool, dark and frost-free place in a closed packaging.
Storage
Keep only in the original container.
: Avoid contact with skin and eyes.
Handling
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection
: Wear waterproof gloves (preferably PVC or butylrubber) in case of intensive use or
- Skin protection
*
contact with undiluted product.
Wear suitable protective clothing.
: Wear safety goggles when clearing accidentally released material and if there is a
- Eye protection
risk of splashing.
: Ensure sufficient ventilation. When exposed to high vapor concentrations wear a
- Respiratory protection
*
respirator for organic vapors (type A).
Environment protection see ?6
: Dipropyleneglycol Methylether : MAC [mg/m砞 : 300
Occupational Exposure Limits
Dipropyleneglycol Methylether : MAC [ppm] : 50
Ecover Belgium NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgium
Page : 3
MATERIAL SAFETY DATA SHEET Revised edition no : 2
According to Regulation (EC) 1907/ Date : 10 / 3 / 2008
2006 Supersedes : 8 / 3 / 2006
Techno Gloss 32104391
9. PHYSICAL AND CHEMICAL PROPERTIES
: Emulsion.
Physical state at 20 癈
: White.
Colour
: Solvent.
Odour
: 8
pH value (concentrated product)
: 1,03 kg/l
Density
: 13.2 cP
Viscosity
: Forms emulsion in presence of water.
Solubility in water
: > 100
Flash point [癈]
: 5.3
Volatile Organic Compounds (%)
: None.
Explosion limits
: None.
Oxidising properties
10. STABILITY AND REACTIVITY
: Store away from freezing (avoid freezing during storage).
Stability and reactivity
: Extremely high or low temperatures.
Conditions to avoid
: Acids.
Materials to avoid
Oxidizing agent.
Do not mix with other cleaning products.
: DPM may form peroxides.
Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
: 3300 (not irritating).
Skin irritation (Invittox n?9) (ppm)
Evaluation of the security for the
human health
: Not or only slightly irritant due to the composition.
- Dermal
: Not or only slightly irritant due to the composition.
- Ocular
: Hardly toxic (LD 50 rat-oral-theoretic 500-5000 ppm).
- Ingestion
: To the best of our knowledge, this product contains no sensitizing raw materials.
Sensitization
Prolonged or repeated skin contact with the material may remove natural oils.
: All Techno Green products contain only ELINCS or EINECS registred raw materials
Note
and do not contain any ingredients known to be mutagenic, carcinogenic,
teratogenic or reproduction toxic (R45,46,47,49,60,61,63,64, EU 97/C234, 67/548/
EEC, 88/379/EEC, OSHA, NTP, IARC (cat 1-3))
12. ECOLOGICAL INFORMATION
Ecological effects information
: No data available.
Biodegradation [%] Sapromat
respirometry test (OECD 301 F)
: > 1000 Not toxic.
EC50 72h Algae (Selenastrum
capricornutum) [ppm] (OECD 201)
: > 1000 Not toxic.
48 Hour EC50 Daphnia magna [ppm]
(OECD 202)
: Techno Green products do not contain any bioaccumulating raw materials and no
Remarks
PCM or nitromusk perfume components.
Ecover Belgium NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgium
Page : 4
MATERIAL SAFETY DATA SHEET Revised edition no : 2
According to Regulation (EC) 1907/ Date : 10 / 3 / 2008
2006 Supersedes : 8 / 3 / 2006
Techno Gloss 32104391
13. DISPOSAL CONSIDERATIONS
: Waste of this product is considered chemical waste. The legislation concerning
Product
disposal of waste can differ from one country/state to another. The disposal should
therefore be done according to national or local waste legislation. If in doubt, ask
the local waste management authority for advice (also see ?6 and ?8 when
disposing of).
: The empty packaging of this product is not subject to ADR. Cleaned empty
Packaging
packaging (including labels and caps) is fully recycable (HDPE + PP); they may be
collected selectively for recycling according to national or local waste legislation.
Uncleaned packaging should be disposed of as non-chemical waste.
14. TRANSPORT INFORMATION
: Not classified.
General information
15. REGULATORY INFORMATION
: None.
R Phrase(s)
: None.
S Phrase(s)
: Preservatives
EEC Composition of detergents
2-BROMO-2-NITROPROPANE-1,3-DIOL, TRIS (HYDROXYMETHYL)
NITROMETHANE.
16. OTHER INFORMATION
: For correct use of this product: see Technical Data Sheet.
Training advice
List of relevant R phrases (heading 3) : R10 : Flammable.
R21/22 : Harmful in contact with skin and if swallowed.
R22 : Harmful if swallowed.
R37/38 : Irritating to respiratory system and skin.
R41 : Risk of serious damage to eyes.
R50 : Very toxic to aquatic organisms.
R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
: MSDS and additional literature data of the respective suppliers.
Sources of key data used
Chemiekaarten, 21th edition, 2006, ed. MIA, VMCI, Samson.
: First version of this MSDS in this new format.
Revision
: 8 / 8 / 2008
Print date
The contents and format of this SDS are in accordance with Regulation (EC) No 1907/2006
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other
reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way
connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this
product. If the product is used as a component in another product, this MSDS information may not be applicable.
End of document
Ecover Belgium NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgium
|