EC Material Safety Data Sheet
Manufacturer/Supplier: Vandex Isoliermittel-Gesellschaft mbH, D-21493 Schwarzenbek
Product number: 191
Trade name: VANDEX POLYCEM LIQUID / VANDEX POLYCEM LIQUID M
Printing date: 15.05.2006 Reviewed on: 15.05.2006 Page: 1/8
01. Identification of preparation and company
Trade name
VANDEX POLYCEM LIQUID / VANDEX POLYCEM LIQUID M
* Use of preparation
Mixing liquid for VANDEX POLYCEM and VANDEX POLYCEM MORTAR
Manufacturer/Supplier
Vandex Isoliermittel-Gesellschaft m.b.H.
Industriestrasse 19?3
D-21493 Schwarzenbek
Phone: +49 4151 89 15-0
Fax: +49 4151 89 15 50
* General Information
Phone: +49 41 51 89 15 31 (Laboratory, Vandex Isoliermittel GmbH, Germany)
Phone: +41 32 626 36 36 (Technical Department, Vandex International AG, Switzerland)
* Emergency telephone
GIZ Nord Poisons Centre, Germany
Phone: +49 551 19240
02. Composition/Information on ingredients
* Chemical characterization
Water-borne plasticizer-free copolymerisate dispersion based on styrene/acrylic acid ester.
* Hazardous ingredients
Components CAS No. EC no. Classification Percent %
Triisobutyl phospat 126-71-6 204-798-3 Xi, R 43, R 52/53 <1%
03. Hazards identification
* Statements of hazard
The product does not require a hazard warning label in accordance with EC Directives. Frequent contact can lead to skin and eye irritation,
especially if product is allowed to dry out. Observe the usual precautions when handling chemicals.
04. First aid measures
*General Information
Remove contaminated, soaked clothing immediately and dispose of safely.
* Inhalation
Move to fresh air. If symptoms persist, call a physician.
*Skin contact
Wash off with soap and water. If symptoms persist, call a physician.
* Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately.
*Ingestion
If swallowed, seek medical advice immediately and show this container or label. If conscious, drink plenty of water. Do not induce vomiting
without medical advice.
* Notes to physician
Main symptoms: None known.
Treatment: Treat symptomatically.
05. Fire-fighting measures
* Suitable extinguishing media
foam. dry powder. carbon dioxide (CO2). water spray.
* Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
*Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases
Under conditions giving incomplete combustion, hazardous gases produced may consist of carbon monoxide carbon dioxide (CO2).
Combustion gases of organic materials must in principle be graded as inhalation poisons.
*Special protective equipment for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
*Environmental precautions
Dike and collect water used to fight fire.
*Other Information
This is a water-based product and presents no particular fire or explosion hazard.
EC Material Safety Data Sheet
Manufacturer/Supplier: Vandex Isoliermittel-Gesellschaft mbH, D-21493 Schwarzenbek
Product number: 191
Trade name: VANDEX POLYCEM LIQUID / VANDEX POLYCEM LIQUID M
Printing date: 15.05.2006 Reviewed on: 15.05.2006 Page: 2/8
06. Accidental release measures
* Personal precautions
Contaminated surfaces will be extremely slippery. Avoid contact with the skin and the eyes.
Environmental precautions
Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system.
Methods for cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable and closed containers
for disposal. Contaminated equipment (brushes, rags) must be cleaned immediately with water. Dispose of in accordance with local
regulations.
07. Handling and storage
* Handling
* Advice on safe handling
Product may contain hazardous volatile ingredients which could accumulate in the unvented headspace of drums or containers.
Open/use containers in ventilated area. Do not breathe vapour.
* Protection ?fire and explosion
No special protective measures against fire required.
* Storage
* Material Storage
Protect from frost. To maintain product quality, do not store in heat or direct sunlight. Keep at temperatures between 5 and 25 癈 (40 and
77 F)
* Technical measures/Storage conditions
Keep tightly closed in a dry and cool place. No special technical protective measures required.
* Incompatible products
No special restrictions on storage with other products.
* German storage class
12: Non-combustible liquids
08. Exposure controls and personal protection
* National occupational exposure limits (Germany)
Components AGW
Triisobutyl phosphate 50 mg/m? listed
* ACGIH Exposure Limits
No exposure limits established.
* Exposer controls
* Engineering measures
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general
extraction.
* Personal protective equipment
* General advice
Avoid contact with skin and eyes.
* Hygienic measures
Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke. Take off all contaminated clothing
immediately. Wash contaminated clothing before re-use.
* Eye protection
safety glasses.
* Hand protection
* Chemicals resistant gloves
Suitable material: rubber gloves
Type: These types of protective gloves are offered by various manufacturers. Please note the manufacturers' detailed statements,
especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under
which the gloves are being used.
EC Material Safety Data Sheet
Manufacturer/Supplier: Vandex Isoliermittel-Gesellschaft mbH, D-21493 Schwarzenbek
Product number: 191
Trade name: VANDEX POLYCEM LIQUID / VANDEX POLYCEM LIQUID M
Printing date: 15.05.2006 Reviewed on: 15.05.2006 Page: 3/8
09. *Physical and chemical properties
* General Information
Form: liquid
Colour: white
Odour: of acrylic monomers
* Relevant safety data
Boiling point: approx. 100 癈 (water)
Flashpoint not applicable
Vapour pressure (20 癈) approx. 24 hPa
Density (20 癈) 1,0 g/cm?br>
method: ISO 8962
Solubility in water (20 癈) miscible
pH-value (20 癈) 7?
method: ISO 1148
10. Stability and reactivity
*Stability
Stable under recommended storage conditions.
* Conditions to avoid
Do not freeze
* Materials to avoid
materials that react with water.
* Thermal decomposition
No decomposition if stored and applied as directed.
* Hazardous reactions
No hazards to be especially mentioned.
11. Toxicological information
LD50/oral/rat: > 5000 mg/kg
EEC 84/449, B.1
Skin irritation: non-irritant
EEC 84/449, B.4
Species: rabbit
Eye irritation: non-irritant
EEC 84/449, B.5
Species: rabbit eye
Toxicological data given are determined by analogy.
12. Ecological information
Biodegradation: > 80%
Zahn-Wellens-Test
Toxicity to bacteria: ECO: approx. 1000 mg/l
OECD 209
Chemical Oxygen Demand: approx. 1300 mg/g
Acute fish toxicity: LC50: > 500 mg/l
Durations (hours): 96 h
OECD 203
Species: zebra fish
Ecological data are determined by analogy.
13. Disposal considerations
*Product information
Disposal required in compliance with all waste management related state and local regulations. The choice of the appropriate method of
disposal depends on the product composition by the time of disposal as well as the local statutes and possibilities for disposal. Diluted
solution may be introduced into a biological purification plant, with permission of the responsible authorities.
*Uncleaned empty packaging
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse. Regulations
concerning reuse or disposal of used packaging materials must be observed.
*European Waste Catalogue
Allocation of a waste code number, according to the European Waste Catalogue (EWC), should be carried out in agreement with the
regional waste disposal company.
EC Material Safety Data Sheet
Manufacturer/Supplier: Vandex Isoliermittel-Gesellschaft mbH, D-21493 Schwarzenbek
Product number: 191
Trade name: VANDEX POLYCEM LIQUID / VANDEX POLYCEM LIQUID M
Printing date: 15.05.2006 Reviewed on: 15.05.2006 Page: 4/8
14. Transport information
Not a dangerous good according to the transport regulations.
15. Regulatory information
*Labelling in accordance with EC directives
The product does not require a hazard warning label in accordance with EC directives/the relevant national laws.
*Special regulations on certain preparations
Contains triisobutyl phosphate. May cause allergic reactions.
*Water hazard Class (WGK)
WGK class: 1
WGK source: classification based on addendum 4 (VwVwS)
16. Other information
* R-phrase(s):
R43 ?May cause sensitization by skin contact.
R52/53 ?Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
* For further information, see:
For more information, consult the Technical Data Sheet.
* Other Information:
Traces of residual monomers can be found in the product: Butylacrylate. Styrene.
Alterations/supplements to the previous version are marked with *
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
EC Material Safety Data Sheet
Manufacturer/Supplier: Vandex Isoliermittel-Gesellschaft mbH, D-21493 Schwarzenbek
Product number: 192
Trade name: VANDEX POLYCEM
Printing date: 01. 04. 2006 Reviewed on: 01. 04. 2006 Page: 5/8
01. Identification of preparation and company
Trade name
VANDEX POLYCEM
* Use of preparation
mixed with VANDEX POLYCEM LIQUID protective coating for sewage treatment facilities
Manufacturer/Supplier
Vandex Isoliermittel-Gesellschaft m.b.H.
Industriestrasse 19?3
D-21493 Schwarzenbek
Phone: +49 4151 89 15-0
Fax: +49 4151 89 15 50
* General Information
Phone: +49 41 51 89 15 31 (Laboratory, Vandex Isoliermittel GmbH, Germany)
Phone: +41 32 626 36 36 (Technical Department, Vandex International AG, Switzerland)
* Emergency telephone
GIZ Nord Poisons Centre, Germany
Phone: +49 551 19240
02. Composition/Information on ingredients
* Chemical characterization
Preparation of cement, silica sands and additives
* Hazardous ingredients
Ingredients CAS no. EINECS no. Concentration Hazard symbols R-phrases
Cement 65997-15-1 266-043-4 25?0% Xi, irritant R 38, 41
( 2 ppm CrVI)
14808-60-7 238-878-4 1?% Xn R 48/20
Silica SiO
03. Hazards identification
* Classification
Xi irritant
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
* Particular information pertaining specific risk for humans and environment
Prolonged contact with the product may cause skin disorders / chemicals burns
* Further information
The content of hexavalent chromium in the cement is reduced to 2 ppm. The chromate reduction is effective within the shelf life and when
properly stored. Please refer to chapter 7.
04. First aid measures
* Inhalation
Remove person from exposure. In case of irritation of respiratory system seek medical advice.
Skin contact
After contact with skin wash immediately with plenty of water. If irritation persists seek medical advice.
* Eye contact
In case of contact with the eyes rinse immediately with plenty of water (eye lid wide open) for at least 10 minutes and seek medical advice
urgently.
Ingestion
Drink plenty of water. Seek medical advice.
05. Fire-fighting measures
* Suitable extinguishing media
Adapt to surrounding fire; product is not combustible.
* Special exposure hazards arising from the preparation itself, combustion products, resulting gases
Avoid extinguishing water entering into water courses, drains or ground water.
In contact with extinguishing water an alkaline solution ?which can cause irritation ?is produced.
* Special protective equipment for fire-fighters
Use self-contained breathing apparatus
EC Material Safety Data Sheet
Manufacturer/Supplier: Vandex Isoliermittel-Gesellschaft mbH, D-21493 Schwarzenbek
Product number: 192
Trade name: VANDEX POLYCEM
Printing date: 01. 04. 2006 Reviewed on: 01. 04. 2006 Page: 6/8
06. Accidental release measures
* Personal precautions
Avoid contact with skin and eyes. Do not breathe dust. Refer to chapter 8.
Environmental precautions
Avoid uncontrolled contact with water. Avoid uncontrolled discharge into environment after contact with water. Do not allow to enter into
water courses, drains or ground water.
Methods for cleaning up/collecting
Clean up dry. Avoid dust formation.
07. Handling and storage
* Information for safe handling
Keep out of the reach of children.
Avoid dust formation and dust deposit.
Avoid contact with skin and eyes.
Do not breathe dust.
Refer to chapter 8 ?Personal protective equipment
Information about protection against explosions and fires
Not applicable.
* Requirements to be met by storerooms and containers
Store protected from humidity in unopened, undamaged original packaging. Shelf life: 12 months
* Information about separation of incompatible products
Keep away from food, drink and animal feedingstuffs.
08. Exposure controls and personal protection
* Exposure limit values (Great Britain)
65997-15-1 Portland cement
inhalable dust EH40 / 2005: OEL 8-hour TWA 10 mg/m?br>
respirable dust EH40 / 2005: OEL 8-hour TWA 4 mg/m?br>
14808-60-7 Silica SiO
EH40 / 2005: OEL 8-hour TWA 0.3 mg/m?br>
Respirable crystalline
OEL = Occupational Exposure Limit; TWA = Time Weighted Average; Observe country specific occupational exposure limits
* Occupational exposure controls
Avoid dust formation. Avoid creating dust. Provide appropriate ventilation or local exhaust ventilation. If it is not possible to reduce exposure
levels to below exposure limit values with ventilation use appropriate respirator according to national regulations.
* Personal protective equipment
General protective and hygiene measures
Do not eat or drink during work ?no smoking. Wash hands before breaks and after work. Use appropriate skin protection products.
* Respiratory protection
Use approved dust mask/respirator
* Hand protection
Use suitable impervious protective gloves
Eye protection
Use tightly fitting safety glasses.
* Skin protection
To avoid skin contact use suitable protective clothing.
* Environmental exposure controls
Do not allow to enter into water courses, drains or ground water.
09. Physical and chemical properties
* General information
Appearance: grey powder
Odour: odourless
* Important health, safety and environmental information
Boiling point: not applicable
Flashpoint: not applicable
Ignition temperature: not applicable
Explosive limits:
Lower/Upper: not applicable
EC Material Safety Data Sheet
Manufacturer/Supplier: Vandex Isoliermittel-Gesellschaft mbH, D-21493 Schwarzenbek
Product number: 192
Trade name: VANDEX POLYCEM
Printing date: 01. 04. 2006 Reviewed on: 01. 04. 2006 Page: 7/8
Vapour pressure: not applicable
Bulk density: approx. 1.5 kg/l
Solubility in water: (20 癈) up to 1.5 g/l
pH-value: 11 ?13.5
10. Stability and reactivity
Conditions to avoid
Avoid contact with humidity.
* Materials to avoid
Acid
* Hazardous decomposition products
Not applicable.
11. Toxicological information
* Irritant/Corrosive effects
Irritating to skin and mucous membranes. Risk of serious damage to eyes. Prolonged contact with the product may cause skin disorders /
chemicals burns.
* Sensitization
As long as material is used within shelf life sensitization is not to be expected. Refer to chapter 3+7.
12. Ecological information
* Ecotoxicity
Eco-toxicological effect only possible in case of unintended release of big quantities in contact with water due to increased pH value.
Product is slightly water pollutant (self assessment). Do not allow to enter into water courses, drains or ground water.
* Mobility
Refer to ecotoxicity
* Persistence and degradability
No data available for the preparation
* Bioaccumulative potential
No data available for the preparation
* Other adverse effects
No data available for the preparation
13. Disposal considerations
Product/Preparation
Recommendation
Clean up dry, not contaminated material can be re-used. Hardens after contact with water, hardened material can be disposed of as
construction and demolition waste ?concrete (EWC-Code 170101). The listed waste number according to the European Waste Code
(EWC) is a recommendation. The final classification has to be done together with the local waste disposal company / authority.
Contaminated packaging
Recommendation
Contaminated packaging must be emptied of all residues and can be recycled following appropriate cleaning. Avoid dust formation.
Uncleaned packaging must be disposed of in accordance with official local regulations (EWC-Code 150105 composite packaging
(Paper/PE-foil)).
14. Transport information
Not a dangerous good according to the transport regulations.
15. Regulatory information
Classification according to EEC directives
Danger symbol and danger designation
Xi irritant
Hazard-determining components of labelling
Cement
* Risk-phrases
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes
EC Material Safety Data Sheet
Manufacturer/Supplier: Vandex Isoliermittel-Gesellschaft mbH, D-21493 Schwarzenbek
Product number: 192
Trade name: VANDEX POLYCEM
Printing date: 01. 04. 2006 Reviewed on: 01. 04. 2006 Page: 8/8
* Safety-phrases
S2 Keep out of the reach of children.
S 22 Do not breathe dust
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection
16. Other information
* Sources of key data used to compile the data sheet:
EC Directive 67/548/EC resp. 99/45/EC as amended in each case
EC Directive 91/155/EC as amended in each case
EC Directive 2001/58/EC as amended in each case
EC Directive 2000/39/EC as amended in each case
Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.
* Relevant R-phrases (chapter 2):
R 48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes
Alterations/supplements to the previous version are marked with *
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
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