Product name: SKYDROL?LD4 Fire resistant hydraulic fluid Page 1 / 8
Solutia Inc. Material Safety Data Sheet Date: 11/10/2005
Reference Number: 000000000183 Version 6.2/E
Solutia Inc.
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: SKYDROL?LD4 Fire resistant hydraulic fluid
Reference Number: 000000000183 Date: 11/10/2005
Company Information:
United States: Canada:
Solutia Inc. Solutia Canada Inc.
575 Maryville Center Drive, P.O. Box 66760 6800 St. Patrick Street
St. Louis, MO 63166-6760 LaSalle, PQ H8N 2H3
Emergency telephone: Chemtrec: 1-800-424-9300 Emergency telephone: CANUTEC: 1-613-996-6666
Non-Emergency telephone: 1-314-674-6661 Non-Emergency telephone: 1-314-674-6661
Mexico: Brazil:
Solutia MEXICO, S. DE R.L. DE C.V. Solutia Brazil Ltd.
Paseo de la Reforma No. 2654 Piso 3-A Avenue Carlos Marcondes, 1200
Col. Lomas Altas CEP: 12241-420-S鉶 Jos?dos Campos/SP-Brazil
C.P. 11950 Mexico D.F. Emergency telephone: 55 12 3932 7100 (PABX)
Emergency telephone: SETIQ: (in Mexico) 01-800-002-1400 Non-Emergency telephone: 55 11 3365 1800 (PABX)
Non-Emergency telephone: (in Mexico) 01-55-5259-6800
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Form: oily, liquid
Colour: clear to purple
Odour: odourless
WARNING STATEMENTS
WARNING!
Causes eye irritation
Causes skin irritation
Causes respiratory tract irritation
Contains material which may cause urinary bladder damage based on animal data
Limited evidence of a carcinogenic effect.
POTENTIAL HEALTH EFFECTS
Likely routes of exposure: eye and skin contact
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Solutia Inc. Material Safety Data Sheet Date: 11/10/2005
Reference Number: 000000000183 Version 6.2/E
inhalation
Eye contact: Highly irritating to eyes.
Skin contact: Highly irritating to skin.
No more than slightly toxic if absorbed.
Repeated contact may cause a drying, solvent like action on the skin.
Inhalation: Severely irritating if inhaled.
No more than slightly toxic if inhaled.
Significant adverse health effects are not expected to develop under normal
conditions of exposure.
Ingestion: No more than slightly toxic if swallowed.
Significant adverse health effects are not expected to develop if only small
amounts (less than a mouthful) are swallowed.
Signs and symptoms of coughing
overexposure: sneezing
headache
nausea/vomiting
Target organs/systems: Contains material which may cause urinary bladder damage based on animal
data
Refer to Section 11 for toxicological information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS No. Average Concentration Units
concentration range
tributyl phosphate 126-73-8 58.2 %
dibutyl phenyl phosphate 2528-36-1 20.0 - 30.0 %
butyl diphenyl phosphate 2752-95-6 5.0 - 10.0 %
2-ethylhexyl 7-oxabicyclo[4.1.0] heptane- 62256-00-2 <=10.0 %
3-carboxylate
2,6-di-tert-butyl-p-cresol 128-37-0 1.0 - 5.0 %
4. FIRST AID MEASURES
If in eyes: Immediately flush with plenty of water for at least 15 minutes.
If easy to do, remove any contact lenses.
Get medical attention.
Remove material from skin and clothing.
If on skin: Immediately flush the area with plenty of water.
Remove contaminated clothing.
Wash skin gently with soap as soon as it is available.
Get medical attention.
Wash clothing before reuse.
If inhaled: Remove patient to fresh air.
If not breathing, give artificial respiration.
If breathing is difficult give oxygen.
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Solutia Inc. Material Safety Data Sheet Date: 11/10/2005
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Remove material from eyes, skin and clothing.
If swallowed: Immediate first aid is not likely to be required.
A physician or Poison Control Center can be contacted for advice.
Wash heavily contaminated clothing before reuse.
Notes to physicians: After flushing eyes for at least 15 minutes, opthalmic preparations of sterile
mineral or castor oil may be instilled one time in the exposed eye for relief of
pain.
5. FIRE FIGHTING MEASURES
Fire point: 176 C ASTM D-2155
Hazardous products of combustion: None known;
Extinguishing media: Water spray, foam, dry chemical, or carbon dioxide
Unusual fire and explosion hazards: None known
Fire fighting equipment: Firefighters, and others exposed, wear self-contained breathing apparatus.
Equipment should be thoroughly decontaminated after use.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Use personal protection recommended in section 8.
Environmental Keep out of drains and water courses.
precautions:
Methods for cleaning up: Contain large spills with dikes and transfer the material to appropriate containers for
reclamation or disposal. Absorb remaining material or small spills with an inert material
and then place in a chemical waste container. Flush spill area with water.
Refer to Section 13 for disposal information and Sections 14 and 15 for reportable quantity information.
7. HANDLING AND STORAGE
Handling
Avoid breathing vapour or mist.
Avoid contact with eyes, skin and clothing.
Use with adequate ventilation.
Keep container closed.
Wash thoroughly after handling.
Emptied containers retain vapour and product residue. Observe all recommended safety precautions until container
is cleaned, reconditioned or destroyed. Do not reuse this container.
Storage
General: Stable under normal conditions of handling and storage.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Airborne exposure limits: (ml/m3 = ppm)
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Solutia Inc. Material Safety Data Sheet Date: 11/10/2005
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SKYDROL?LD4 No specific occupational exposure limit has been established.
tributyl phosphate ACGIH TLV: 0.2 ml/m3 ; 2.2 mg/m3 ; ; 8-hr TWA
OSHA PEL: 5 mg/m3 ; ; 8-hr TWA
Mexican OEL: 0.2 ml/m3 ; 2.5 mg/m3 ; ; 8-hr TWA
Mexican OEL: 0.4 ml/m3 ; 5 mg/m3 ; ; 15-min STEL
dibutyl phenyl phosphate ACGIH TLV: 0.3 ml/m3 ; 3.5 mg/m3 ; skin * ; 8-hr TWA
* skin absorption of this material may add to the overall exposure.
2,6-di-tert-butyl-p-cresol ACGIH TLV: 2 mg/m3 ; ; 8-hr TWA
OSHA PEL: 5 mg/m3 ; ; 8-hr TWA
Mexican OEL: 10 mg/m3 ; ; 8-hr TWA
Mexican OEL: 20 mg/m3 ; ; 15-min STEL
Eye protection: Wear chemical goggles.
Have eye flushing equipment available.
Hand protection: Wear chemical resistant gloves.
Consult the glove/clothing manufacturer to determine the appropriate type
glove/clothing for a given application.
Body protection: Wear suitable protective clothing.
Wear full protective clothing if exposed to splashes.
Consult the glove/clothing manufacturer to determine the appropriate type
glove/clothing for a given application.
Wash contaminated skin promptly.
Launder contaminated clothing and clean protective equipment before reuse.
Have safety shower available at locations where skin contact can occur.
Wash thoroughly after handling.
Respiratory protection: Avoid breathing vapour or mist.
Use approved respiratory protection equipment (full facepiece recommended) when
airborne exposure limits are exceeded.
If used, full facepiece replaces the need for face shield and/or chemical goggles.
Consult the respirator manufacturer to determine the appropriate type of equipment for
a given application.
Observe respirator use limitations specified by the manufacturer.
Ventilation: Provide natural or mechanical ventilation to control exposure levels below airborne
exposure limits.
If practical, use local mechanical exhaust ventilation at sources of air contamination
such as processing equipment.
Components referred to herein may be regulated by specific Canadian provincial legislation. Please refer to exposure
limits legislated for the province in which the substance will be used.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point: 160 C Cleveland Open Cup
Autoignition temperature: 398 C ASTM D-2155
Specific gravity: 1.004 - 1.014 @ 25 C
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Solutia Inc. Material Safety Data Sheet Date: 11/10/2005
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Kinematic viscosity: 10.8 - 11.6 cSt @ 38 C
NOTE: These physical data are typical values based on material tested but may vary from sample to sample.
Typical values should not be construed as a guaranteed analysis of any specific lot or as specifications for the
product.
10. STABILITY AND REACTIVITY
Conditions to avoid: Elevated temperatures
Materials to avoid: Contact with strong oxidizing agents.
Hazardous reactions: Hazardous polymerization does not occur.
Hazardous decomposition phosphorus oxides (PxOy); carbon monoxide (CO); carbon dioxide
products:
11. TOXICOLOGICAL INFORMATION
This product has been tested for toxicity. Results from Solutia sponsored studies or from the available public
literature are described below.
Acute animal toxicity data
Oral: LD50 , rat, 2,100 mg/kg , Slightly toxic following oral administration.
Dermal: LD50 , rabbit, > 3,160 mg/kg , Practically nontoxic after skin application in animal
studies.
Inhalation: LC50 , rat, > 5.8 mg/l , , No mortality or signs of toxicity at the highest level
achievable.
Eye irritation: rabbit , Slightly irritating to eyes (rabbit)., 24 h
Skin irritation: rabbit , Moderately irritating to skin., 24 h
Skin sensitization: Human experience , Predictive patch testing on human volunteers did not produce
dermal sensitization.
Repeat dose toxicity: rat, , inhalation, 28 days, , Repeated exposure produced eye irritation in animal
models. Repeated exposure produced respiratory tract irritation in animal models.
Produced effects on body weight, serum enzymes and/or organ weights in repeat
dose studies.
Neurotoxicity: chicken, gavage, acute, Brain cholinesterase inhibition.
Mutagenicity: No genetic effects were observed in standard tests using bacterial and animal cells.
Components
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Solutia Inc. Material Safety Data Sheet Date: 11/10/2005
Reference Number: 000000000183 Version 6.2/E
Data from Solutia studies and/or the available scientific literature on the components of this material which have
been identified as hazardous chemicals under the criteria of the OSHA Hazard Communication Standard (29 CFR
1910.1200) or the Canadian Hazardous Products Act are discussed below.
tributyl phosphate Slightly toxic following oral administration.
Practically nontoxic after skin application in animal studies.
Slightly irritating to eyes (rabbit).
Highly irritating to skin (rabbit).
Produced no dermal sensitization (guinea pigs).
Repeated oral administration produced multiple systemic effects.
No delayed neurotoxicity was observed in animal models.
This material produced tumours in laboratory animals at dose levels that exceed the
maximum tolerated dose.
The weight of the evidence indicates that this material is not mutagenic in in-vitro
assays.
dibutyl phenyl phosphate Slightly toxic following oral administration.
Practically nontoxic after skin application in animal studies.
Practically non irritating to eyes (rabbit).
Practically non irritating to skin (rabbit).
Produced no dermal sensitization (guinea pigs).
Repeated skin exposure produced irritation in animal studies.
Produced effects on body weight, serum enzymes and/or organ weights in repeat dose
studies.
Repeated oral administration produced multiple organ effects.
No delayed neurotoxicity was observed in animal models.
No birth defects were noted in rats given the active ingredient orally during pregnancy.
This material had no effect on reproduction or fertility.
Produced developmental toxicity.
The weight of the evidence indicates that this material is not mutagenic in in-vitro
assays.
2,6-di-tert-butyl-p-cresol Slightly irritating to skin, eyes and respiratory system in animal models.
Produced effects on body weight, serum enzymes and/or organ weights in repeat dose
studies.
Both positive and negative responses observed in standard tests for genetic changes.
2-ethylhexyl 7- Slightly toxic following oral administration.
oxabicyclo[4.1.0] Practically nontoxic after skin application in animal studies.
heptane-3-carboxylate Practically non irritating to eyes (rabbit).
Slightly irritating to skin (rabbit).
No mortality or signs of toxicity at the highest level tested.
Produced dermal sensitization (guinea pigs).
The weight of the evidence indicates that this material is not mutagenic in in-vitro
assays.
The weight of the evidence indicates that this material is mutagenic in in vivo assays.
12. ECOLOGICAL INFORMATION
Environmental Toxicity
Invertebrates 48 h, EC50 Water flea (Daphnia magna) 5.8 mg/l
Fish: 96 h, EC50 Rainbow trout (Oncorhynchus mykiss) 5.2 mg/l
96 h, EC50 Fathead minnow (Pimephales promelas) 4.8 mg/l
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Solutia Inc. Material Safety Data Sheet Date: 11/10/2005
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Algae: 96 h, EC50 Algae (Selenastrum capricornutum) 10 mg/l
Environmental fate
Biodegradation
Readily biodegradable.
13. DISPOSAL CONSIDERATIONS
US EPA RCRA Status: This material when discarded is not a hazardous waste as that term is defined by the
Resource, Conservation and Recovery Act (RCRA), 40 CFR 261.
Disposal considerations: Incineration
Recycle
Miscellaneous advice: This product meets the criteria for a synthetic used oil under the U.S. EPA Standards for
the Management of Used Oil (40 CFR 279). Those standards govern recycling and
disposal in lieu of 40 CFR 260 -272 of the Federal hazardous waste program in states
that have adopted these used oil regulations. Consult your attorney or appropriate
regulatory official to be sure these standards have been adopted in your state. Recycle or
burn in accordance with the applicable standards.
Local, state, provincial, and national disposal regulations may be more or less stringent.
This product should not be dumped, spilled, rinsed or washed into sewers or public
waterways.
14. TRANSPORT INFORMATION
The data provided in this section is for information only. Please apply the appropriate regulations to properly
classify your shipment for transportation.
US DOT
Other: Not regulated for transport.
Canadian TDG
Other: Not regulated for transport.
ICAO/IATA Class
Other: Not regulated for transport.
15. REGULATORY INFORMATION
All components are in compliance with U.S. TSCA, EU EINECS, Canadian DSL, Australian AICS, Korean,
the following inventories: Japanese ENCS, Chinese
Canadian WHMIS classification: D2(B) - Materials Causing Other Toxic Effects
SARA Hazard Notification:
Hazard Categories Under Title III Immediate
Rules (40 CFR 370): Delayed
Section 302 Extremely Hazardous Not applicable
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Solutia Inc. Material Safety Data Sheet Date: 11/10/2005
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Substances:
Section 313 Toxic Chemical(s): Not applicable
CERCLA Reportable Quantity:
Not applicable
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation and the MSDS contains all the information required by the Canadian Controlled Products Regulation.
Refer to Section 11 for OSHA/HPA Hazardous Chemical(s) and Section 13 for RCRA classification.
Safety data sheet also created in accordance with Brazilian law NBR 14725
16. OTHER INFORMATION
Product use: Hydraulic fluids and additives
Reason for revision: Significant changes to the following section(s):, Section 3
Health Fire Reactivity Additional Information
Suggested NFPA Rating 2 1 0
Suggested HMIS Rating: 2 1 0 G
Prepared by the Solutia Hazard Communication Group. Please consult Solutia @ 314-674-6661 if further
information is needed.
TM, ?is a registered trademark of Solutia Inc.
SOLUTIA is a trademark of Solutia Inc.
Responsible Care?is a registered trademark of the American Chemistry Council.
Although the information and recommendations set forth herein (hereinafter "Information") are presented
in good faith and believed to be correct as of the date hereof, Solutia Inc. makes no representations as to
the completeness or accuracy thereof. Information is supplied upon the condition that the persons
receiving same will make their own determination as to its suitability for their purposes prior to use. In no
event will Solutia Inc. be responsible for damages of any nature whatsoever resulting from the use of or
reliance upon Information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR
IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY
OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE
PRODUCT TO WHICH INFORMATION REFERS.
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