Material Safety Data Sheet
Vinyl gloss coating
Section 1. Chemical product and company identification
1131064
: HG International b.v.
Manufacturer Code :
2.01
: Damsluisweg 70 1332 EJ Almere MSDS# :
Address
4-1-2008.
: Netherlands Validation date :
Country
4-1-2008.
: +31 (0)36 54 94 700 Print date :
Telephone No.:
P. Stienstra
: +31 (0)36 54 94 744 Responsible name :
Fax
: www..hginternational.com +1.705.726.5445
:
Internet: Telephone No.:
Solstrand Trading +1.705.734.0857
Supplier : Fax :
: 60 Lockhart road Barrie, Ontario L4N 9G8 Canada
Address Country :
: Dirt repellent, glossy, protective and removable coating
Material uses
In Case of Emergency : Chem. Tel Inc. (813) 248 0585 or Toll free (800) 255 3924
Section 2. Composition, Information on Ingredients
CAS # % by weight Exposure limits
Name
Water 7732-18-5 60 - 100 Not available.
Polymer. 15 - 30 Not available.
Ethoxylated alcohol. 5 - 15 Not available.
dipropylene glycol methyl ether 34590-94-8 1-5 Not available.
Watery modified male飊resin. 8050-28-0 1-5 Not available.
phosphoric acid, tris(2-methylpropyl) 126-71-6 0-1 Not available.
ester
1-Methoxy-2-propanol 107-98-2 0-1 Not available.
Tributoxyethyl phosphate 78-51-3 0-1 Not available.
Preservative. 0 - 0.1 Not available.
Mixture of mineral oils and non-ionc mixture <0.1 Not available.
surfactants
Ammonia 1336-21-6 <0.1 Not available.
Nonionics <0.1 Not available.
Section 3. Hazards identification
: Liquid.
Physical State and
Appearance
Emergency overview :
: Dermal contact. Eye contact. Ingestion.
Routes of entry
Potential acute health effects
This product may irritate eyes upon contact.
Eyes :
Can cause irritation.
Skin :
Can cause irritation.
Inhalation :
May be harmful if swallowed. Can cause irritation.
Ingestion :
: CARCINOGENIC EFFECTS: Not available.
Potential chronic health
MUTAGENIC EFFECTS: Not available.
effects
TERATOGENIC EFFECTS: Not available.
: Repeated or prolonged exposure is not known to aggravate medical condition.
Medical conditions
aggravated by
overexposure:
Continued on next page
Page: 2/6
Vinyl gloss coating
: Not available.
Over-exposure
signs/symptoms
See toxicological Information (section 11)
Section 4. First aid measures
: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
Eye Contact
attention if irritation occurs.
: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes.
Skin Contact
Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial
Inhalation
respiration. Get medical attention.
: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
Ingestion
an unconscious person. Get medical attention if symptoms appear.
: Not available.
Notes to Physician
Section 5. Fire fighting measures
May be combustible at high temperature.
Flammability of the product :
Lowest known value: 207癈 (404.6癋) (dipropylene glycol methyl ether).
Auto-ignition Temperature :
Closed cup: Higher than 93.3癈 (200癋).
Flash Points :
Greatest known range: Lower: 1.1% Upper: 14% (dipropylene glycol methyl ether)
Flammable limits :
Decomposition products may include the following materials: carbon oxides (CO, CO2), phosphates.
Products of combustion :
Not available.
Fire hazards in presence of :
various substances
: Not available.
Explosion hazards in
presence of various
substances
: Use an extinguishing agent suitable for surrounding fires.
Fire fighting media and
instructions No specific hazard.
: Fire fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA)
Special protective equipment
with a full facepiece operated in positive pressure mode.
for fire-fighters
: No additional remark.
Special remarks on fire
hazards
Special remarks on explosion : Not available.
hazards
Section 6. Accidental release measures
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective
Personal precautions
equipment (Section 8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Environmental precautions
: If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil
Methods for cleaning up
may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquid-
proof container for disposal. For large spills dike spilled material or otherwise contain material to ensure
runoff does not reach a waterway. Place spilled material in an appropriate container for disposal.
Section 7. Handling and storage
: Wash thoroughly after handling. Do not ingest. Avoid prolonged contact with eyes, skin, and clothing. If
Handling
swallowed, seek medical advice immediately and show this container or label. Keep out of the reach of
children.
: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Continued on next page
Page: 3/6
Vinyl gloss coating
Section 8. Exposure Controls, Personal Protection
: No special ventilation requirements.
Engineering controls
Personal protection
Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates
this is necessary to avoid exposure to liquid splashes, mists or dusts.
Skin : Personal protective equipment for the body should be selected based on the task being performed and the
risks involved and should be approved by a specialist before handling this product.
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary.Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves or gauntlets complying with an approved standard should be worn at
all times when handling chemical products if a risk assessment indicates this is necessary.
Other protection : Not available.
:
Personal protective
equipment (Pictograms)
Personal protection in case : Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult
a specialist BEFORE handling this product.
of a large spill
Consult local authorities for acceptable exposure limits.
Section 9. Physical and chemical properties
: Liquid.
Physical State and
Appearance
White.
Color :
Characteristic.
Odor :
8.8 (Conc. (% w/w): 100) [Basic.]
pH :
1.013 g/cm3 (20癈 / 68癋)
:
Relative density
Dynamic: Highest known value: 1034 cP (Watery modified male飊resin.) Weighted average: 549.79 cP
Viscosity :
Easily soluble in the following materials: diethyl ether.
Solubility :
Partially soluble in the following materials: cold water, hot water, methanol, acetone.
Closed cup: Higher than 93.3癈 (200癋).
:
Flash point
Not available.
Explosive properties :
Greatest known range: Lower: 1.1% Upper: 14% (dipropylene glycol methyl ether)
Explosion Limits :
Not applicable
Oxidizing properties :
Not available.
Physical chemical comments :
Section 10. Stability and reactivity
: The product is stable.
Stability and Reactivity
: Stable under recommended storage and handling conditions (see section 7).
Conditions of instability
: Reactive with oxidizing agents.
Incompatibility with various
substances
: carbon oxides (CO, CO2)
Hazardous Decomposition
Products
: Yes.
Hazardous polymerization
Continued on next page
Page: 4/6
Vinyl gloss coating
Section 11. Toxicological information
dipropylene glycol methyl ether LD50 5135 mg/kg Oral Rat
LD50 9500 mg/kg Dermal Rat
LD50 9500 mg/kg Dermal Rabbit
Tributoxyethyl phosphate LD50 6200 mg/kg Oral Rat
LD50 >2000 mg/kg Dermal Rabbit
1-Methoxy-2-propanol LD50 5700 mg/kg Oral Rabbit
LD50 11700 mg/kg Oral Mouse
LD50 13500 mg/kg Dermal Rabbit
LDLo 3739 mg/kg Oral Rat
LC50 7000 (6 hour(s)) Inhalation Rat
LC50 10000 (5 hour(s)) Inhalation Rat
phosphoric acid, tris(2-methylpropyl) LD50 4180 mg/kg Oral Rat
ester LD50 >5000 mg/kg Dermal Rabbit
Nonionics LD50 13792 mg/kg Oral Rat
Watery modified male飊resin. LD50 >2000 mg/kg Oral Rat
Ethoxylated alcohol. LD50 >5000 mg/kg Oral Rat
Ammonia LD50 350 mg/kg Oral Rat
LDLo 43 mg/kg Oral human
LDLo 750 mg/kg Oral Cat.
:
: Contains material which causes damage to the following organs: upper respiratory tract, central nervous
Chronic effects on humans
system (CNS), eye, lens or cornea.
: Not considered to be toxic for humans.
Other toxic effects on
humans
: Not available.
Special remarks on toxicity
to animals
: Not available.
Special remarks on chronic
effects on humans
: Not available.
Special remarks on other
toxic effects on humans
Specific effects
: No known significant effects or critical hazards.
Carcinogenic effects
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Reproduction toxicity
Section 12. Ecological information
dipropylene glycol methyl ether PIMEPHALES PROMELAS 48 hour(s) >10000 mg/l
(LC50)
Tributoxyethyl phosphate Pimephales promelas (LC50) 96 hour(s) 11.2 mg/l
Daphnia (LC50) 48 hour(s) 10 to 100 mg/l
1-Methoxy-2-propanol Bacteria (EC50) 48 hour(s) >1000 mg/l
Fish (LC50) 96 hour(s) >1000 mg/l
phosphoric acid, tris(2-methylpropyl) ester Daphnia (EC50) 48 hour(s) 11 mg/l
LEUCISCUS IDUS (LC50) 96 hour(s) 10 to 100 mg/l
Algae (EC50) 72 hour(s) 33 mg/l
Nonionics FATHEAD MINNOWS (LC50) 96 hour(s) 61.7 to 71.7 mg/l
Not available.
BOD and COD :
Inherently biodegradable.
Biodegradable/OECD :
Not available.
Mobility :
Decomposition products may include the following materials: carbon oxides (CO, CO2) and water,
Products of degradation :
phosphates.
: The product itself and its products of degradation are not toxic.
Toxicity of the products of
biodegradation
: Not available.
Special remarks on the
products of biodegradation
Continued on next page
Page: 5/6
Vinyl gloss coating
Section 13. Disposal considerations
: The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilled
Waste information
material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions
and any by-products should at all times comply with the requirements of environmental protection and
waste disposal legislation and any regional local authority requirements.
: Not available.
Waste stream
Consult your local or regional authorities.
Section 14. Transport information
Regulatory UN Proper shipping name Class Packing group Label Additional information
Information number
Not - - - Remarks
DOT
regulated. Keep in frostfree area
Classification
Not - - - Remarks
TDG
regulated. Keep in frostfree area
Classification
- - -
Not Remarks
ADR/RID
regulated.
Class Keep in frostfree area
- - -
Not Remarks
IMDG Class
regulated. Keep in frostfree area
Not - - - RemarksKeep in
IATA-DGR
regulated.
Class frostfree area
Section 15. Regulatory information
: Not controlled under WHMIS (Canada).
WHMIS (Canada)
CEPA DSL: Water; dipropylene glycol methyl ether; Tributoxyethyl phosphate; 1-Methoxy-2-propanol;
phosphoric acid, tris(2-methylpropyl) ester; Watery modified male飊resin.; poly(oxy-1,2-ethanediyl),
.alpha.-isodecyl-.omega.-hydroxy-; Ammonia; Styrene; poly(oxy-1,2-ethanediyl), .alpha.-hydro-.omega.-
hydroxy-, ether with .alpha.-fluoro-.omega.-(2-hydroxyethyl)poly(difluoromethylene) (1:1); propan-2-ol;
1,4-dioxane
International regulations
EINECS : Not available.
DSCL (EEC) : This product is not classified according to the EU regulations.
International lists :
Section 16. Other information
Label Requirements :
Hazardous Material 1 National Fire
Health Flammability
0
Information System Protection
0
Fire hazard
Health Instability
1 0
(U.S.A.) Association
0
Reactivity
(U.S.A.) Special
C
Personal protection
: Not available.
References
Other special considerations : Not available.
4-1-2008.
Date of printing :
4-1-2008.
:
Date of issue
No previous validation.
Date of previous issue :
2.01
Version :
Notice to reader
Continued on next page
Page: 6/6
Vinyl gloss coating
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
|