Page : 1
MATERIAL SAFETY DATA SHEET Revised edition no : 1
According to 2001/58EC Date : 23/3/2006
Supersedes : 0/0/0
Floreal Fresh CODE: 32102066
1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY
: Floreal Fresh
Trade name
: Liquid.
Type of product
: For professional use only.
Use
: Ecover Belgium NV
Company identification
Industrieweg 3
2390 Malle Belgium
: +32 (0)3 309 25 00
Phone
: +32 (0)3 311 72 70
Fax
: +32 (0)70 245 245
Emergency phone nr
: See address above.
Responsible for placing on the
market
2 COMPOSITION / INFORMATION ON INGREDIENTS
: Preparation.
Substance / Preparation
: This product contains hazardous components (Directive 67/548/EEC).
Components
: Regulation (CE) No. 648/2004 of 31 March 2004 on detergents:
Composition
< 5% : - Anionic surfactants
5% - 15% : - Nonionic surfactants
Perfumes - Preservatives
TRIS (HYDROXYMETHYL) NITROMETHANE, 2-BROMO-2-NITROPROPANE-1,3-
DIOL.
LINALOOL, LIMONENE.
Substance name Contents CAS No EC No Index No Classification
: > 10 % 69227-22-1 ----- ----- Xn; R22
Alkyl polyglycol ether C10-16 with PO
Xi; R41
and EO
: > 1 <= 10 % ----- ----- ----- R10
Perfume
Xn; R65
N; R51-53
: > 1 <= 10 % 68585-47-7 271-557-7 ----- Xi; R38-41
Sodiumalkyl(C10-16)sulfate
: > 0.01 <= 0.1 % 78-70-6 201-134-4 -----
Linalool
: > 0.01 <= 0.1 % 5989-27-5 227-813-5 601-029-00-7 R10
Limonene (D-)
Xi; R38
R43
N; R50-53
: > 0.01 <= 0.1 % 126-11-4 204-769-5 ----- Xn; R22
Trishydroxymethylnitromethane
: < 0.01 % 52-51-7 200-143-0 603-085-00-8 Xn; R21/22
Bronopol (INN)
Xi; R37/38-41
N; R50
: Alkyl polyglycol ether C10-16 with PO and EO
INCI
PARFUM
SODIUM LAURYLSULFATE
LINALOOL
LIMONENE
TRIS (HYDROXYMETHYL) NITROMETHANE
2-BROMO-2-NITROPROPANE-1,3-DIOL
3 HAZARDS IDENTIFICATION
: Not classified as dangerous product.
Hazards identification
Symptoms relating to use
: None under normal conditions.
- Inhalation
: Prolonged or repeated contact may cause skin to become dry.
- Skin contact
: Irritation to eyes.
- Eye contact
: Nausea.
- Ingestion
Diarrhea.
Ecover Belgium NV In case of emergency : +32 (0)70 245 245
Industrieweg 3 2390 Malle Belgium
Page : 2
MATERIAL SAFETY DATA SHEET Revised edition no : 1
According to 2001/58EC Date : 23/3/2006
Supersedes : 0/0/0
Floreal Fresh CODE: 32102066
3 HAZARDS IDENTIFICATION (continued)
Vomiting.
Abdominal pain.
4 FIRST AID MEASURES
First aid measures
: Not relevant.
- Inhalation
: Rinse affected area thoroughly with water to remove concentrated product.
- Skin contact
Remove contaminated clothing.
: Rinse immediately and for at least 15 minutes with copious amounts of water (also
- Eye contact
assure adequate flushing under the eyelids and if possible after having removed
contact lenses). Bring the victim to an ophthalmist.
: Wash out mouth and do not induce vomiting! Let the victim drink 2 glasses of water
- Ingestion
on his own.
Seek medical advice.
: No specific recommendations.
Note to physician
: No specific recommendations.
Workplace equipment
5 FIRE-FIGHTING MEASURES
: None.
Specific hazards
Extinguishing media
: All extinguishing media can be used.
- Suitable extinguishing media
: None.
- Unsuitable extinguishing media
: Exercise caution when fighting any chemical fire.
Protection against fire
See Heading 8.
6 ACCIDENTAL RELEASE MEASURES
: Spill area may be slippery.
Personal precautions
Avoid contact with eyes.
Equip cleanup crew with proper protection.
See Heading 8.
: Avoid release to the environment.
Environmental precautions
: Recover spilled material as much as possible in a clean container for reuse. Spilled
Clean up methods
product must be collected with sand or an inert absorbent material and dispose of
as chemical waste. Rinse away remainder with water.
7 HANDLING AND STORAGE
: Not expected to be a fire/explosion hazard under normal conditions of use.
Protection against fire
: Store in a cool and frost-free place in a closed packaging.
Storage
: Avoid contact with eyes.
Handling
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection
: Wear waterproof gloves when taking up intensively material which is accidentally
- Skin protection
released. Persons with a sensitive skin are also recommended to wear waterproof
gloves.
: Wear safety goggles when clearing accidentally released material and if there is a
- Eye protection
risk of splashing.
: Ensure there is adequate ventilation.
- Respiratory protection
Ecover Belgium NV In case of emergency : +32 (0)70 245 245
Industrieweg 3 2390 Malle Belgium
Page : 3
MATERIAL SAFETY DATA SHEET Revised edition no : 1
According to 2001/58EC Date : 23/3/2006
Supersedes : 0/0/0
Floreal Fresh CODE: 32102066
8 EXPOSURE CONTROLS / PERSONAL PROTECTION (continued)
Environment protection see ?6
9 PHYSICAL AND CHEMICAL PROPERTIES
: Liquid.
Physical state at 20 癈
: Orange.
Colour
: Flower aroma.
Odour
: 8
pH value (concentrated product)
: 1,00 kg/l
Density
: < 50 mPa.s
Viscosity at 25癈 [mPa.s] (Brookfield
LVT)
: Complete.
Solubility in water
: > 100
Flash point [癈]
: 2.99
Volatile Organic Compounds (%)
: None.
Explosion limits
: None.
Oxidising properties
10 STABILITY AND REACTIVITY
: No decomposition under normal conditions of storage and use.
Stability and reactivity
: Do not store <0癈 and >40癈.
Conditions to avoid
: Do not mix with other cleaning products.
Materials to avoid
Acids.
: None under normal conditions.
Hazardous decomposition products
11 TOXICOLOGICAL INFORMATION
Skin irritation (RBC test: Denaturation : 322 Slight irritant.
Index) (ppm)
Evaluation of the security for the
human health
: Not or only slightly irritant due to the composition.
- Dermal
: Irritation due to the composition.
- Ocular
: Hardly toxic (LD 50 rat-orl-theo 500-5000 ppm).
- Ingestion
: This product contains sensitizing fragrance components > 100 ppm: see ?2 and
Sensitization
15.
: All Techno Green products contain only ELINCS or EINECS registred raw materials
Note
and do not contain any ingredients known to be mutagenic, carcinogenic,
teratogenic or reproduction toxic (R45,46,47,49,60,61,63,64, EU 97/C234, 67/548/
EEC, 88/379/EEC, OSHA, NTP, IARC (cat 1-3))
12 ECOLOGICAL INFORMATION
Ecological effects information
: 56 Partially biodegradable.
Biodegradation [%] Sapromat
respirometry test (OECD 301 F)
: 142 Hardly toxic.
EC50 72h Algae (Selenastrum
capricornutum) [ppm] (OECD 201)
: 33 Slightly toxic
48 Hour EC50 Daphnia magna [ppm]
(OECD 202)
: Techno Green products do not contain any bioaccumulating raw materials and no
Remarks
PCM or nitromusk perfume components.
Ecover Belgium NV In case of emergency : +32 (0)70 245 245
Industrieweg 3 2390 Malle Belgium
Page : 4
MATERIAL SAFETY DATA SHEET Revised edition no : 1
According to 2001/58EC Date : 23/3/2006
Supersedes : 0/0/0
Floreal Fresh CODE: 32102066
13 DISPOSAL CONSIDERATIONS
: Dispose in a safe manner in accordance with local/national regulations.
General
: Waste of this product is considered chemical waste. The legislation concerning
Product
disposal of waste can differ from one country/state to another. The disposal should
therefore be done according to national or local waste legislation. If in doubt, ask
the local waste management authority for advice (also see ?6 and ?8 when
disposing of).
: The empty packaging of this product is not subject to ADR. Cleaned empty
Packaging
packaging (including labels and caps) is fully recycable (HDPE + PP); they may be
collected selectively for recycling according to national or local waste legislation.
Uncleaned packaging should be disposed of as chemical waste.
14 TRANSPORT INFORMATION
: Not classified.
General information
15 REGULATORY INFORMATION
: None.
R Phrase(s)
: None.
S Phrase(s)
: < 5% : - Anionic surfactants
EEC Composition of detergents
5% - 15% : - Nonionic surfactants
Perfumes - Preservatives
LINALOOL, LIMONENE.
TRIS (HYDROXYMETHYL) NITROMETHANE, 2-BROMO-2-NITROPROPANE-1,3-
DIOL.
16 OTHER INFORMATION
: For correct use of this product: see Technical Data Sheet.
Training advice
List of relevant R phrases (heading 2) : R10 : Flammable.
R21/22 : Harmful in contact with skin and if swallowed.
R22 : Harmful if swallowed.
R37/38 : Irritating to respiratory system and skin.
R38 : Irritating to skin.
R41 : Risk of serious damage to eyes.
R43 : May cause sensitization by skin contact.
R50 : Very toxic to aquatic organisms.
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 : Harmful : may cause lung damage if swallowed.
: MSDS and additional literature data of the respective suppliers.
Sources of key data used
: First version of this MSDS in this new format.
Revision
: 23/3/2006
Print date
The contents and format of this SDS are in accordance with EEC Commission Directive 2001/58EC.
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other
reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way
connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this
product. If the product is used as a component in another product, this MSDS information may not be applicable.
End of document
Ecover Belgium NV In case of emergency : +32 (0)70 245 245
Industrieweg 3 2390 Malle Belgium
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