Page 1/5
Material Safety Data Sheet
According to 2001/58/EC
Printing date 15.09.2006 Reviewed on 20.06.2006
* 1 Identification of substance:
?Product details:
?Trade name: Baker CLkTM-888
?Article number: 5108-05, 5118-05, 5138-T6
?Manufacturer/Supplier:
Mallinckrodt Baker B.V. Tel:(+31) (0)570 - 687500
P.O.Box 1 Fax:(+31) (0)570 - 687574
7400 AA Deventer
The Netherlands
?Informing department: Mallinckrodt Baker Sales Office Tel.: (31) (0) 570 687500
* 2 Composition/Data on components:
?Chemical characterization
?Description: Mixture consisting of the following components.
?Dangerous components:
Ingredient CAS No Percent Hazardous
Sulfolan 126-33-0 30-80% Yes Xn R22
Alkylammonium hydroxide N/A <5% Yes T R25-34-52/53
?Additional information For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
?Hazard designation:
Xn Harmful
?Information pertaining to particular dangers for man and environment
R 22 Harmful if swallowed.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature
and by information furnished by supplier companies.
* 4 First aid measures
?General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
?After inhalation Supply fresh air; consult doctor in case of symptoms.
?After skin contact If skin irritation continues, consult a doctor.
?After eye contact Rinse opened eye for several minutes under running water.
?After swallowing
Rinse out mouth and then drink plenty of water.
Instantly call for doctor.
GB
(Contd. on page 2)
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Page 2/5
Material Safety Data Sheet
According to 2001/58/EC
Printing date 15.09.2006 Reviewed on 20.06.2006
Trade name: Baker CLkTM-888
(Contd. of page 1)
* 5 Fire fighting measures
?Suitable extinguishing agents Use fire fighting measures that suit the environment.
?Protective equipment: Wear self-contained breathing apparatus.
* 6 Accidental release measures
?Person-related safety precautions: Not required.
?Measures for environmental protection: No special measures required.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
* 7 Handling and storage
?Handling
?Information for safe handling:
Work only in fume cupboard.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about protection against explosions and fires: no special requirements
?Storage
?Requirements to be met by storerooms and containers: No special requirements.
?Information about storage in one common storage facility:
Store away from flammable substances.
Store away from oxidizing agents.
?Further information about storage conditions: Protect from frost.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with critical values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
?Breathing equipment:
Not necessary if room is well-ventilated.
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure
use breathing apparatus that is independent of circulating air.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
(Contd. on page 3)
GB
DR
Page 3/5
Material Safety Data Sheet
According to 2001/58/EC
Printing date 15.09.2006 Reviewed on 20.06.2006
Trade name: Baker CLkTM-888
(Contd. of page 2)
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection: Safety glasses recommended during refilling.
?Body protection: Protective work clothing.
* 9 Physical and chemical properties:
?General Information
Fluid
Form:
Colourless
Colour:
Amine-like
Smell:
?Change in condition
Melting point/Melting range: -10癈
Boiling point/Boiling range: Not determined
165癈
?Flash point:
Product is not selfigniting.
?Self-inflammability:
Product is not explosive.
?Danger of explosion:
23 hPa
?Steam pressure at 20癈:
1.190 g/cm?br>
?Density at 20癈
?Solubility in / Miscibility with
Fully miscible
Water:
?Solvent content:
0.0 %
Organic solvents:
23.3 %
Water:
* 10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: Heat,boiling teperatures.
?Materials to be avoided:
?Dangerous reactions No dangerous reactions known
?Dangerous products of composition:
Nitrous vitriol gases
Ammonia
Carbon monooxide
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
126-33-0 Sulfolan
Oral LD50 1941 mg/kg (rat)
Irritation of skin LD50 4009 mg/kg (rabbit)
?Primary irritant effect:
?on the skin: No irritant effect.
(Contd. on page 4)
GB
DR
Page 4/5
Material Safety Data Sheet
According to 2001/58/EC
Printing date 15.09.2006 Reviewed on 20.06.2006
Trade name: Baker CLkTM-888
(Contd. of page 3)
?on the eye: No irritant effect.
?Sensitization: No sensitizing effect known.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC Classification
Guidelines for Preparations as issued in the latest version:
Harmful
* 12 Ecological information:
?General notes:
Water hazard class 2 (Self-assessment): hazardous for water.
Do not allow product to reach ground water, water bodies or sewage system.
Danger to drinking water if even small quantities leak into soil.
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
?Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
?ADR/RID-GGVS/E Class: 8 (C7) Corrosive substances.
3267
?UN-Number:
II
?Packaging group:
8
?Label
3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
?Designation of goods:
?Maritime transport IMDG/GGVSea:
8
?IMDG/GGVSea Class:
3267
?UN Number:
8
?Label
II
?Packaging group:
F-A;S-B
?EMS Number:
No
?Marine pollutant:
(Contd. on page 5)
GB
DR
Page 5/5
Material Safety Data Sheet
According to 2001/58/EC
Printing date 15.09.2006 Reviewed on 20.06.2006
Trade name: Baker CLkTM-888
(Contd. of page 4)
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
?Correct technical name:
?Air transport ICAO-TI and IATA-DGR:
8
?ICAO/IATA Class:
3267
?UN/ID Number:
8
?Label
II
?Packaging group:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
?Correct technical name:
* 15 Regulatory information
?Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous
Materials (GefStoffV)
?Code letter and hazard designation of product:
Xn Harmful
?Hazard-determining components of labelling:
Sulfolan
?Risk phrases:
22 Harmful if swallowed.
?Safety phrases:
23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
25 Avoid contact with eyes.
36 Wear suitable protective clothing.
60 This material and its container must be disposed of as hazardous waste.
?National regulations
Class Share in %
I 5.0
?Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.
* 16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
?Relevant R phrases
22 Harmful if swallowed.
25 Toxic if swallowed.
34 Causes burns.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Department issuing data specification sheet: Quality Assurance Department
?Contact: Mallinckrodt Baker B.V. Deventer Holland Tel. (+31) 570 - 687500
GB
DR
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