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MATERIAL SAFETY DATA SHEET:DURAHOLD AEROSOL, M/M
DATE OF ISSUE: 11/16/2004 SUPERCEDES: 10/29/2004
SECTION I - GENERAL INFORMATION
Chemical Name & Synonyms: Trade Name & Synonyms:
N/A DURAHOLD AEROSOL, M/M
Chemical Family: Formula Mixture: X
SOLVENT RESIN MIXTURE
Manufacturer's Name:
CHEMSEARCH DIV. OF NCH CORP.
Address:
BOX 152170
IRVING, TX 75015
Prepared By: Product Code Number Emergency Phone Number
L Boynton/Chemist 5587 800-424-9300
SECTION II - HAZARDOUS INGREDIENTS
THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS
Chemical Name (Ingredients) Hazard TLV PEL STEL CAS #
N-HEXANE IRR/FLAM 50 PPM 1 500 PPM 2 N/E 110-54 -3
PETROLEUM HYDROCARBON RESIN IRRITANT N/E 1 N/E 2 N/E 68527 -25-3
STYRENE -ISOPRENE BLOCK COPOLYMER IRRITANT N/E 1 N/E 2 N/E 25038 -32-8
TOLUENE IRR/FLAM 50 PPM 1 200 PPM 2 N/E 108-88 -3
ZINC IRRITANT N/E 1 N/E 2 N/E 7440-66-6
PROPANE FLAM/ASPHY 1000 PPM$1 1000 PPM 2 N/E 74 -98-6
N-BUTANE FLAM/ASPHY 1000 PPM$1 N/E 2 N/E 106-97 -8
$ ALIPHATIC HYDROCARBON GASES VALUES
SECTION III - PHYSICAL DATA
Boiling Point (f): N/E Specific Gravity (H20=1): 0.82
Vapor Pressure (MM HG): 50 PSI Color: GRAY/SILVER
Vapor Density (Air=1): >1 Odor: PETROLEUM
PH @ 100% : N/A Clarity OPAQUE
% Volatile by Volume: 55 Evaporation Rate (BU A/C=1): >1
H20 Solubility: NEGLIGIBLE Viscosity: SEMI-VISCOUS
SECTION IV - FIRE AND EXPLOSION HAZARD
Flash Point: Flammable Limits: LEL: UEL:
<20癋 / C.O.C. PRODUCT MIXTURE 1.0 7.5
Extinguishing Media:
Foam:X Alcohol Foam: CO2:X Dry Chemical:X Water Spray:X Other:
Special Fire Fighting Procedures:
FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL FIRE-
EXPOSED CONTAINERS WITH WATER SPRAY TO PREVENT BURSTING.
Unusual Fire and Explosion Hazards:
VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO DISTANT AND/OR LOW-LYING SOURCES OF IGNITION AND
FLASHBACK. PRODUCT MAY PRODUCE A FLOATING FIRE HAZARD AS LIQUID FLOATS ON WATER. FLAME EXTENSION IS 30
INCHES, BURNBACK IS 0 INCHES.
Aerosol Level (NFPA 30B): 3
NFPA Hazard Rating: (0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme)
Health:2 Flammability:4 Instability:0 Special:
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value:
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NOT ESTABLISHED FOR MIXTURE. SEE SECTION II.
Effects of Overexposure:
-Acute(Short Term Exposure)
EYE CONTACT: CAUSES SEVERE IRRITATION SEEN AS STINGING, TEARING, REDNESS, CORNEAL CLOUDING, AND BLURRED
VISION. SKIN CONTACT: CAUSES IRRITATION SEEN AS ITCHING AND REDNESS. PRODUCT MAY BE ABSORBED THROUGH
THE SKIN IN HARMFUL AMOUNTS. PROLONGED OR REPEATED CONTACT AS FROM CLOTHING WET WITH MATERIAL MAY
CAUSE DRYING, DEFATTING, AND CRACKING OF THE SKIN. INHALATION: MIST OR VAPOR MAY CAUSE RESPIRATORY
IRRITATION SEEN AS COUGHING AND SNEEZING. AT LOW VAPOR CONCENTRATIONS, NO HARMFUL EFFECTS ARE
EXPECTED. AT HIGH VAPOR CONCENTRATIONS, INHALATION MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS SUCH AS
HEADACHE, DIZZINESS, DROWSINESS, WEAKNESS, UNCONCIOUSNESS, POSSIBLE ANESTHETIC EFFECTS FROM CENTRAL
NERVOUS SYSTEM DEPRESSION, AND MAY BE FATAL. INGESTION: MAY CAUSE IRRITATION WITH POSSIBLE NAUSEA,
VOMITING, AND DIARRHEA. INGESTION AND SUBSEQUENT VOMITING OF THIS PRODUCT CAN LEAD TO ASPIRATION OF THE
PRODUCT INTO THE LUNGS WHICH CAN CAUSE DAMAGE AND MAY BE FATAL.
-Chronic (Long Term Exposure)
CHRONIC SKIN CONTACT MAY PROMOTE DERMATITIS. PROLONGED OR REPEATED OVEREXPOSURE MAY CAUSE AN
ENLARGED LIVER, KIDNEY EFFECTS AND CARDIAC SENSITIZATION. CHRONIC INHALATION OF SOLVENTS LIKE TOLUENE
HAVE CAUSED PERMANENT CENTRAL AND PERIPHERAL NERVOUS SYSTEM DAMAGE RESULTING IN DECREASED LEARNING
ABILITY. A CONDITION KNOWN AS "PAINTER'S SYNDROME" CAN OCCUR CAUSING A LOSS OF SENSATION IN THE ARMS AND
LEGS (PERIPHERAL NEUROPATHY). MEDICAL CONDITIONS AGGRAVATED: PRE -EXISTING LIVER AND KIDNEY DISEASES AND
PRE -EXISTING RESPIRATORY AND SKIN CONDITIONS SUCH AS ASTHMA, EMPHYSEMA, AND DERMATITIS. TARGET ORGANS:
AUDITORY SYSTEM, BLOOD-FORMING ORGANS, CENTRAL AND PERIPHERAL NERVOUS SYSTEMS, HEART, LIVER, KIDNEYS.
THE PRIMARY ROUTES OF EXPOSURE ARE SKIN AND EYE CONTACT.
Primary Routes of Entry: Inhalation:X Ingestion: Absorption:X
Emergency and First Aid Procedures:
-Inhalation:
REMOVE FROM THE AREA TO FRESH AIR. SEEK MEDICAL ATTENTION IF RESPIRATORY IRRITATION DEVELOPS OR IF
BREATHING BECOMES DIFFICULT.
-Eye Contact:
IMMEDIATELY RINSE THE EYES WITH WATER. REMOVE ANY CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15
MINUTES. HOLD THE EYELIDS APART TO ENSURE RINSING OF THE ENTIRE SURFACE OF THE EYES AND LIDS WITH WATER.
GET IMMEDIATE MEDICAL ATTENTION.
-Skin Contact:
WASH AFFECTED AREAS WITH LARGE AMOUNTS OF SOAP AND WATER FOR 15 MINUTES. REMOVE CONTAMINATED
CLOTHING AND SHOES. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. WASH CLOTHING AND CLEAN SHOES BEFORE
REUSE.
-Ingestion:
GIVE 3 TO 4 GLASSES OF WATER, BUT DO NOT INDUCE VOMITING. IF VOMITING OCCURS, GIVE FLUIDS AGAIN. GET
IMMEDIATE MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING PERSON.
-Notes to Physician:
INGESTION AND SUBSEQUENT VOMITING OF THIS PRODUCT CAN LEAD TO ASPIRATION OF THE PRODUCT INTO THE LUNGS
WHICH CAN CAUSE DAMAGE AND MAY BE FATAL. DEPENDING ON THE AMOUNT INGESTED AND RETAINED AS WELL AS THE
TOXICITY OF THE PRODUCT, GASTRIC LAVAGE SHOULD BE CONSIDERED. KEEP PATIENT'S HEAD BELOW HIPS TO PREVENT
PULMONARY ASPIRATION. IF COMATOSE, A CUFFED ENDOTRACHAEL TUBE WILL PREVENT ASPIRATION.
SECTION VI - TOXICITY INFORMATION
Product Contains Chemicals Listed as Carcinogen or Potential Carcinogen By:
IARC: No NTP: No OSHA: No ACGIH: No OTHER: No
VOC CONTENT: 55% BY WEIGHT, 451 G/L
N-HEXANE
ORL-RAT LD50: 25 GM/KG 4.
IHL-HMN TCLo: 190 PPM/8W 4.
EYE-RBT SDT: 10 MG MILD 4.
THIS MATERIAL MAY ADVERSELY AFFECT THE MALE REPRODUCTIVE SYSTEM BASED ON TESTING IN LABORATORY
ANIMALS. 3.
PETROLEUM HYDROCARBON RESIN
NO TOXICITY DATA AVAILABLE
STYRENE -ISOPRENE BLOCK COPOLYMER
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NO TOXICITY DATA AVAILABLE
TOLUENE
EYE-RBT SDT: 870 UG MILD 4.
SKN-RBT SDT: 20 MG/24H MODERATE 4.
SKN-RBT LD50: 12.2 G/KG 4.
ORL-HMN LDLo: 50 MG/KG 4.
ORL-RAT LD50: 636 MG/KG 4.
IHL-RAT LC50: 49 G/M3/4H 4.
ANIMAL STUDIES HAVE SHOWN THAT REPEATED INHALATION OF HIGH LEVELS PRODUCED HISTOLOGICAL CHANGES IN
THE BRAIN, DEGENERATION OF THE HEART TISSUE, CARDIAC SENSITIZATION AND POSSIBLE IMMUNE SYSTEM
SUPPRESSION. INTENTIONAL ABUSE OF TOLUENE VAPORS HAS BEEN LINKED TO DAMAGE OF THE BRAIN, KIDNEY, AND
LIVER. 3.
MANY CASE STUDIES INVOLVING ABUSE DURING PREGNANCY INDICATE THAT TOLUENE CAN CAUSE BIRTH DEFECTS,
GROWTH RETARDATION AND LEARNING DIFFICULTIES. 3.
ZINC
SKN-HMN SDT: 300 UG/3D INTERMITTENT MILD 4.
IHL-HMN TCLo: 124 MG/M3/50M 4.
PROPANE
NO TOXICOLOGICAL DATA ARE AVAILABLE
N-BUTANE
IHL-RAT LC50: 658 G/M3/4H 4.
IHL-MUS LC50: 680 G/M3/4H 4.
HUMAN VOLUNTEERS EXPOSED REPEATEDLY TO GASES OF SIMILAR HYDROCARON MIXTURES RANGING FROM 250 TO
1000 PPM EXHIBITED NO CARDIAC OR PULMONARY FUNCTION ABNORMALITIES. 3.
SECTION VII - REACTIVITY DATA
Stability: Stable:X Unstable:
Conditions to Avoid: AVOID HEAT, HOT
SURFACES, SPARKS, AND OPEN
FLAMES.
Incompatibility (Materials to Avoid):
STRONG OXIDIZING AGENTS SUCH AS CHLORINE BLEACH AND CONCENTRATED HYDROGEN PEROXIDE, SOME RUBBER AND
PLASTICS.
Hazardous Decomposition Products:
OXIDES OF CARBON.
Hazardous Polymerization: May Occur: Will Not Occur:X
Conditions to Avoid: N/A
SECTION VIII - SPILL OR LEAK PROCEDURES
Steps to be Taken if Material is Released or Spilled:
DUE TO THE NATURE OF THE AEROSOL PACKAGING, A LARGE SPILL IS UNLIKELY. FOR A SMALL SPILL, WEAR APPROPRIATE
PROTECTIVE CLOTHING, ELIMINATE ALL SOURCES OF IGNITION, VENTILATE THE AREA, ABSORB WITH AN INERT MATERIAL
AND TRANSFER ALL MATERIAL INTO A PROPERLY LABELED CONTAINER FOR DISPOSAL. USE CARE AS SPILLS MAY BE
SLIPPERY.
Waste Disposal Method(s):
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. TYPICAL DISPOSAL IS TO WRAP THE
EMPTY AEROSOL CONTAINER IN SEVERAL LAYERS OF NEWSPAPER AND DISPOSE OF IN THE TRASH. AEROSOL RECYCLING
PROGRAMS ARE AVAILABLE IN MANY AREAS. DO NOT PUNCTURE OR INCINERATE THIS CONTAINER.
Neutralizing Agent:
N/A
SECTION IX - SPECIAL PROTECTION INFORMATION
Required Ventilation:
LOCAL VENTILATION IS RECOMMENDED TO CONTROL EXPOSURE FROM OPERATIONS THAT CAN GENERATE EXCESSIVE
LEVELS OF VAPORS OR MISTS. LOCAL VENTILATION IS PREFERRED, BECAUSE IT PREVENTS DISPERSION INTO WORK
AREAS BY CONTROLLING IT AT ITS SOURCE.
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Respiratory Protection:
RESPIRATORS SHOULD BE SELECTED BY AND USED UNDER THE DIRECTION OF A TRAINED HEALTH AND SAFETY
PROFESSIONAL FOLLOWING REQUIREMENTS FOUND IN OSHA'S RESPIRATOR STANDARD (29 CFR 1910.134) AND ANSI'S
STANDARD FOR RESPIRATORY PROTECTION (Z88.2-1992). FOR CONCENTRATIONS ABOVE THE TLV AND/OR PEL BUT LESS
THAN 10 TIMES THESE LIMITS, A NIOSH APPROVED HALF-FACEPIECE RESPIRATOR EQUIPPED WITH APPROPRIATE
CHEMICAL CARTRIDGES MAY BE USED. FOR CONCENTRATIONS GREATER THAN 10 TIMES THE TLV AND/OR PEL, CONSULT
THE NIOSH RESPIRATOR DECISION LOGIC FOUND IN PUBLICATION NO. 87-116 OR ANSI Z88.2-1992.
Glove Protection:
NEOPRENE OR NITRILE RUBBER GLOVES IF REPEATED OR PROLONGED SKIN CONTACT IS LIKELY. ENSURE COMPLIANCE
WITH OSHA'S PERSONAL PROTECTIVE EQUIPMENT (PPE) STANDARD FOR HAND PROTECTION, 29 CFR 1910.138.
Eye Protection:
CHEMICAL GOGGLES SHOULD BE WORN WHEN HANDLING. ENSURE COMPLIANCE WITH OSHA'S PERSONAL PROTECTIVE
EQUIPMENT (PPE) STANDARD FOR EYE AND FACE PROTECTION, 29 CFR 1910.133.
Other Protection:
WEAR GENERAL-DUTY WORK CLOTHES AND SHOES. REMOVE SOAKED CLOTHING AND SHOES. WASH CLOTHING AND
CLEAN SHOES BEFORE REUSE. A SAFETY SHOWER AND AN EYEWASH STATION SHOULD BE AVAILABLE.
SECTION X - STORAGE AND HANDLING INFORMATION
Storage Temperature: Indoors:X Outdoors: Heated: Refrigerated:
Minimum Temperature:35癋 Maximum Temperature:120癋
Precautions to be taken in Handling and Storing:
USE WITH CAUTION AROUND HEAT, SPARKS, PILOT LIGHTS, STATIC ELECTRICITY, AND OPEN FLAME.
Other Precautions:
KEEP OUT OF REACH OF CHILDREN. READ THE ENTIRE LABEL BEFORE USING THE PRODUCT. FOLLOW THE LABEL
DIRECTIONS.
SECTION XI - REGULATORY INFORMATION
Chemical Name CAS Number Upper % Limit
TOLUENE 108-88-3 10
N-HEXANE 110-54-3 25
Those Ingredients listed above are subject to the reporting requirements of 313 of Title III& of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR part 372.
PLEASE CALL 1-800-527-9919 FOR ADDITIONAL INFORMATION IF YOU ARE A CALIFORNIA CUSTOMER.
THIS MSDS IS NOT INTENDED FOR USERS IN THE STATE OF CALIFORNIA
SECTION XII - REFERENCES
1. THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL
AGENTS AND BIOLOGICAL EXPOSURE INDICES, ACGIH, 2004.
2. OSHA PEL.
3. VENDOR'S MSDS.
4. REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES, CCINFOWeb, 2004.
ALL THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE TOXIC SUBSTANCES CONTROL ACT (TSCA) AND
ARE EITHER LISTED ON THE TSCA INVENTORY OR OTHERWISE EXEMPTED FROM LISTING. -------------------------------------------------
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IRR:IRRITANT, FLAM/FLAMM:FLAMMABLE, COMB:COMBUSTIBLE, CORR:CORROSIVE CARC:CARCINOGENIC, TOX:TOXIC,
N/A:NOT APPLICABLE, N/E:NOT ESTABLISHED, COC:CLEVELAND OPEN CUP, PMCC:PENSKY-MARTIN CLOSED CUP,
TCC:TAGLIABUE CLOSED CUP, LEL:LOWER EXPLOSION LIMIT, UEL:UPPER EXPLOSION LIMIT, NFPA:NATIONAL FIRE
PROTECTION ASSOCIATION, IARC:INTERNATIONAL AGENCY FOR THE RESEARCH ON CANCER, NTP:NATIONAL
TOXICOLOGY PROGRAM, OSHA:OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION, ACGIH:AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS, TLV:THRESHOLD LIMIT VALUE, PEL:PERMISSIBLE EXPOSURE LIMIT,
STEL:SHORT-TERM EXPOSURE LIMIT, MLD:MILD, MOD:MODERATE, SEV:SEVERE, MUT:MUTAGENIC, ASPHYX:ASPHYXIANT,
PNOS:PARTICLES (INSOLUBLE) NOT OTHERWISE SPECIFIED, SDT:STANDARD DRAIZE TEST, ORL:ORAL, IHL:INHALATION,
HMN:HUMAN
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT
FORMULATION.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE
RESULTS TO BE OBTAINED FROM THE USE THEREOF.
CHEMSEARCH DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or
disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended
use,storage or disposal of the product."
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