MATERIAL SAFETY DATA SHEET: PREMALUBE RED AERO (HV)
Section I - General Information
(000000-000000- - 5218)
Date of Issue: Supercedes:
12/7/2006 12:00:00 AM 1/19/2001 12:00:00 AM
Chemical Name & Synonyms: Trade Name & Synonyms:
N/A PREMALUBE RED AERO (HV)
Chemical Family:
Formula is a mixture: []
PETROLEUM MIXTURE
Manufacturer Name:
CERTIFIED LABS, DIV. OF NCH CORP.
Manufacturer Address:
BOX 152170
IRVING, TEXAS 75015
Prepared By: Product Code Number: Emergency Phone Number:
D Hollas/Chemist 5218 800-424-9300
Section II - Hazardous Ingredients
THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS
Chemical Name (Ingredients) Hazard TLV PEL STEL CAS #
HYDROTREATED NAPHTHENIC PETROLEUM DISTILLATE IRRITANT 5 MG/M3 $1 5 MG/M3 $2 10 MG/M3$1 $$
N-HEXANE FLAM/IRR 50 PPM 1 500 PPM 2 N/E 110-54-3
N-HEPTANE FLAM/IRR 400 PPM 1 500 PPM 2 500 PPM 1 142-82-5
CYCLOHEXANE FLAM/IRR 100 PPM 1 300 PPM 2 N/E 110-82-7
PROPANE FLAM/ASPHY 1000 PPM*1 1000 PPM 2 N/E 74-98-6
N-BUTANE FLAM/ASPHY 1000 PPM*1 N/E 2 N/E 106-97-8
ALUMINUM BENZOATE FATTY ACID COMPLEX IRRITANT N/E 1 N/E 2 N/E 82980-54-9
ANTIMONY DIALKYLDITHIOCARBAMATE IRRITANT 0.5MG/M3#1 0.5MG/M3#2 N/E 15890-25-2
$ OIL MIST VALUES
$$ 64742-52-5, 64742-53-6
* ALIPHATIC HYDROCARBON GASES
# ANTIMONY COMPOUNDS
Section III - Physical Data
Specific Gravity (H20=1):0.73
Boiling Point (癋):154?br>
Vapor Pressure (mm Hg):2169 Color:RED
Vapor Density (Air=1):1.7 Odor:PETROLEUM
pH @ 100% :N/A Clarity:OPAQUE
% Volatile by Volume:68 Evaporation Rate (BuAc=1):41
H20 Solubility:NEGLIGIBLE Viscosity:VISCOUS
Section IV - Fire and Explosion Hazard
Flash Point: 73癋 Method Used: SETAFLASH
Flammable Limits: PRODUCT MIXTURE UEL: 50
LEL: 0.7 Aerosol Level (NFPA 30B): 3
Extinguishing Media: NFPA 704 Hazard Rating:
[] Foam [ ] Alcohol Foam [] CO2 4-Extreme Health: 1
3-High
[] Dry Chemical [] Water Spray [ ] Other Flammability: 4
2-Moderate
Instability: 0
1-Slight
Special:
0-Insignificant
Special Fire Fighting Procedures:
FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY TO PREVENT BURSTING.
Unusual Fire and Explosion Hazards:
FLAME EXTENSION IS >30 INCHES. BURNBACK IS 3 INCHES. THIS PRODUCT IS EXTREMELY FLAMMABLE. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO DISTANT AND/OR LOW-
LYING SOURCES OF IGNITION AND FLASHBACK. PRODUCT MAY PRODUCE A FLOATING FIRE HAZARD AS LIQUID FLOATS ON WATER. THE USE OF WATER SPRAY (F0G) WHILE EFFECTIVE,
MAY CAUSE FROTHING AND FOAMING. NEVER USE A WATER JET AS THIS WILL JUST SPREAD THE FIRE. USE CARE AS SPILLS MAY BE SLIPPERY.
Section V - Health and Hazard Data
Threshold Limit Value:
NOT ESTABLISHED FOR MIXTURE. SEE SECTION II.
Effects of Overexposure:
Acute: (Short Term Exposure)
EYE CONTACT: CAUSES IRRITATION SEEN AS STINGING, TEARING, AND REDNESS. SKIN CONTACT: MAY CAUSE IRRITATION SEEN AS ITCHING, REDNESS, AND A BURNING SENSATION.
PROLONGED OR REPEATED CONTACT AS FROM CLOTHING WET WITH MATERIAL MAY CAUSE DRYING, DEFATTING, AND CRACKING OF THE SKIN. PRODUCT MAY BE ABSORBED THROUGH THE
SKIN IN HARMFUL AMOUNTS. INHALATION: VAPOR OR MIST MAY CAUSE RESPIRATORY IRRITATION SEEN AS COUGHING, SNEEZING, A BURNING SENSATION OF THE NOSE AND THROAT,
AND DIFFICULTY BREATHING. AT LOW VAPOR CONCENTRATIONS, NO HARMFUL EFFECTS ARE EXPECTED. AT HIGH VAPOR CONCENTRATIONS, INHALATION MAY CAUSE CENTRAL NERVOUS
SYSTEM EFFECTS SUCH AS HEADACHE, DIZZINESS, DROWSINESS, WEAKNESS, UNCONCIOUSNESS, POSSIBLE ANESTHETIC EFFECTS FROM CENTRAL NERVOUS SYSTEM DEPRESSION, AND MAY
BE FATAL. INGESTION: MAY CAUSE IRRITATION WITH POSSIBLE NAUSEA, VOMITING, AND DIARRHEA. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS SIMILAR TO INHALATION.
Chronic: (Long Term Exposure)
ON RARE OCCASIONS, PROLONGED AND REPEATED EXPOSURE TO HYDROCARBON OR OIL MIST POSES A RISK OF CHRONIC LUNG INFLAMMATION. THIS CONDITION IS USUALLY
ASYMPTOMATIC AS A RESULT OF REPEATED SMALL ASPIRATIONS. SHORTNESS OF BREATH AND COUGHING ARE THE MOST COMMON SYMPTOMS. ASPIRATION MAY LEAD TO PULMONARY EDEMA
AND HEMORRHAGE AND MAY BE FATAL. SIGNS OF LUNG INVOLVEMENT INCLUDE INCREASED RESPIRATION AND HEART RATES AS WELL AS A BLUISH DISCOLORATION OF THE SKIN.
CHRONIC INHALATION OF SOLVENTS LIKE HEXANE HAVE CAUSED HEARTBEAT IRREGULARITY, HEARTBEAT INCREASE, AND PERMANENT CENTRAL AND PERIPHERAL NERVOUS SYSTEM
DAMAGE, RESULTING IN DECREASED LEARNING ABILITY, LOSS OF MEMORY, PERSONALITY CHANGES, AND DISTURBANCES IN GAIT. A CONDITION KNOWN AS "PAINTER'S SYNDROME" CAN
OCCUR CAUSING A LOSS OF SENSATION IN THE ARMS AND HANDS (PERIPHERAL NEUROPATHY). PROLONGED OR REPEATED EXPOSURE MAY CAUSE CARDIAC SENSITIZATION. CHRONIC SKIN
CONTACT MAY PROMOTE DERMATITIS AND OIL ACNE. IN RARER CASES, AN INCREASED SENSTIVITY TO SUNLIGHT (PHOTOSENSITIVITY) MAY OCCUR. MAY CAUSE SKIN SENSITIZATION
IN SOME INDIVIDUALS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE ARE PRE-EXISTING RESPIRATORY AND SKIN CONDITIONS SUCH AS ASTHMA, EMPHYSEMA, AND DERMATITIS;
PRE-EXISTING REPRODUCTIVE, NEUROLOGICAL, AND CARDIOVASCULAR DISORDERS. TARGET ORGANS: HEART, LIVER, LUNGS, BLOOD-FORMING ORGANS, AND MALE REPRODUCTIVE
SYSTEM.
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MATERIAL SAFETY DATA SHEET: PREMALUBE RED AERO (HV)
Primary Routes of Entry
[] Inhalation [] Ingestion [] Absorption
Emergency First Aid Procedures:
Inhalation:
REMOVE FROM THE AREA TO FRESH AIR. SEEK MEDICAL ATTENTION IF RESPIRATORY IRRITATION DEVELOPS OR IF BREATHING BECOMES DIFFICULT.
Eye Contact:
RINSE THE EYES WITH WATER. REMOVE ANY CONTACT LENSES AND CONTINUE FLUSHING WITH PLENTY OF WATER FOR SEVERAL MINUTES. SEEK MEDICAL ATTENTION IF IRRITATION
DEVELOPS.
Skin Contact:
WIPE AWAY MATERIAL WITH A CLOTH. WASH WITH SOAP AND WATER. SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS. CLEAN CLOTHING AND SHOES.
Ingestion:
GIVE 3 TO 4 GLASSES OF WATER, BUT DO NOT INDUCE VOMITING. IF VOMITING OCCURS, GIVE FLUIDS AGAIN. SEEK MEDICAL ATTENTION IF DISCOMFORT OCCURS.
Notes to Physician:
THERE IS NO SPECIFIC ANTIDOTE. TREAT THE PATIENT SYMPTOMATICALLY.
Section VI - Toxicity Information
Product Contains Chemicals Listed as Carcinogen or Potential Carcinogen By:
[ ] IARC [ ] NTP [ ] OSHA [ ] ACGIH [ ] Other
VOC CONTENT: 57.5% BY WEIGHT; 66.9% BY VOLUME; 420 G/L.
HYDROTREATED NAPHTHENIC PETROLEUM DISTILLATE (<3% DMSO EXTRACTABLE MATERIAL)
ORL-RAT LD50: >5 GM/KG 4.
SKN-RBT LD50: >2 GM/KG 4.
SKN-RBT SDT: 500 MG SEVERE 4.
MINERAL OIL AND HYDROCARBON MISTS DERIVED FROM HIGHLY REFINED OILS AND PETROLEUM DISTILLATES ARE REPORTED TO HAVE LOW ACUTE AND SUB-ACUTE TOXICITIES IN
ANIMALS. EFFECTS FROM SINGLE AND SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG
INFLAMMATORY REACTION, LIPOID GRANULOMA FORMATION, AND LIPOID PNEUMONIA. IN ACUTE AND SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS AT OR
NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED NO SIGNIFICANT TOXICOLOGICAL EFFECTS. IN LONG TERM STUDIES (UP TO TWO YEARS) NO CARCINOGENIC EFFECTS HAVE
BEEN REPORTED IN ANY ANIMAL SPECIES TESTED. THESE PETROLEUM DISTILLATES ARE SEVERELY HYDROTREATED, SEVERELY SOLVENT EXTRACTED, AND/OR PROCESSED BY MILD
HYDROTREATMENT AND EXTRACTION. FOR THIS REASON, THEY ARE NOT CLASSIFIED AS CANCER HAZARDS. 3.
N-HEXANE
ORL-RAT LD50: 25 GM/KG 4.
IHL-HMN TCLo: 190 PPM/8W 4.
EYE-RBT-SDT: 10 MG MILD 4.
THIS MATERIAL MAY ADVERSELY AFFECT THE MALE REPRODUCTIVE SYSTEM (DECREASED SPERM COUNTS AND DEGENERATIVE CHANGES IN THE TESTES) BASED ON TESTING IN
LABORATORY ANIMALS. 3.
KIDNEY EFFECTS IN MALE RATS WERE OBSERVED IN LABORATORY ANIMALS EXPOSED TO A SIMILAR MATERIAL. EFFECTS WERE CONSISTENT WITH MALE RATS HYALINE DROPLET
NEPHROPATHY WHICH IS OF QUESTIONABLE SIGNIFICANCE TO HUMAN HEALTH. IN ANIMALS, REPEATED EXPOSURE TO HIGH CONCENTRATIONS OF A SIMILAR SOLVENT HAS CAUSED A
DECREASE IN THE RED BLOOD CELL COUNT. 3.
CAUSES FETOTOXICITY IN ANIMALS AT DOSES WHICH ARE MATERNALLY TOXIC. 3.
N-HEPTANE
IHL-RAT LC50: 103 G/M3/4H 4.
ORL-RAT TDL0: 60 G/KG/3W-1 4.
CYCLOHEXANE
ORL-RAT LD50: 12705 MG/KG 4.
SKN-RBT LD: >180 GM/KG 4.
SKN-RBT-SDT: 1548 MG/2D (INTERMITTENT) 4.
IHL-RAT TCLo: 300 PPM/6H/2W-I 4.
PROPANE
IHL-LC50: >40% BY VOLUME 3.
N-BUTANE
IHL-RAT LC50: 658 G/M3/4H 4.
ALUMINUM BENZOATE FATTY ACID COMPLEX
NO TOXICITY DATA AVAILABLE
ANTIMONY DIALKYLDITHIOCARBAMATE
ORL-RAT LD50: 16400 MG/KG 4.
SKN-RBT LD50: 16000 MG/KG 4.
Section VII - Reactivity Data
Stability Hazardous Polymerization
[] Stable [ ] Unstable [] Will not occur [ ] May occur
Conditions to Avoid: Conditions to Avoid:
AVOID HEAT, HOT SURFACES, SPARKS, AND OPEN FLAMES. N/A
Incompatibility (Materials to Avoid):
STRONG OXIDIZING AGENTS SUCH AS CHLORINE BLEACH, CONCENTRATED HYDROGEN PEROXIDE, CHROMIC ACID, AND BROMINE; ACIDS AND ALKALIS.
Hazardous Decomposition Products:
OXIDES OF ALUMINUM, ANTIMONY, CARBON, NITROGEN, AND SULFUR; ALDEHYDES; AMINES; CARBON DISULFIDE; HYDROGEN SULFIDE GAS; KETONES; SMOKE AND FUMES; VARIOUS
OTHER HYDROCARBONS.
Section VIII - Spill Or Leak Procedures
Steps to be Taken if Material is Released or Spilled:
DUE TO THE NATURE OF THE AEROSOL PACKAGING, A LARGE SPILL IS UNLIKELY. FOR A SMALL SPILL, WEAR APPROPRIATE PROTECTIVE CLOTHING, ELIMINATE IGNITION SOURCES OF
ELECTRICAL, STATIC, OR FRICTIONAL SPARKS, VENTILATE THE AREA, ABSORB WITH AN INERT MATERIAL AND TRANSFER ALL MATERIAL INTO A PROPERLY LABELED CONTAINER FOR
DISPOSAL. USE CARE AS SPILLS MAY BE SLIPPERY.
Waste Disposal Method(s):
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MATERIAL SAFETY DATA SHEET: PREMALUBE RED AERO (HV)
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. TYPICAL DISPOSAL IS TO WRAP THE EMPTY AEROSOL CONTAINER IN SERVERAL LAYERS OF
NEWSPAPER AND DISPOSE OF IN THE TRASH. AEROSOL RECYCLING PROGRAMS ARE AVAILABLE IN MANY AREAS. DO NOT PUNCTURE OR INCINERATE THIS CONTAINER.
Neutralizing Agent:
N/A
Section IX - Special Protection Information
Required Ventilation:
LOCAL VENTILATION IS RECOMMENDED TO CONTROL EXPOSURE FROM OPERATIONS THAT CAN GENERATE EXCESSIVE LEVELS OF MISTS OR VAPORS. LOCAL VENTILATION IS PREFERRED,
BECAUSE IT PREVENTS DISPERSION INTO WORK AREAS BY CONTROLLING IT AT ITS SOURCE.
Respiratory Protection:
RESPIRATORS SHOULD BE SELECTED BY AND USED UNDER THE DIRECTION OF A TRAINED HEALTH AND SAFETY PROFESSIONAL FOLLOWING REQUIREMENTS FOUND IN OSHA'S RESPIRATOR
STANDARD (29 CFR 1910.134) AND ANSI'S STANDARD FOR RESPIRATORY PROTECTION (Z88.2-1992). FOR CONCENTRATIONS ABOVE THE TLV AND/OR PEL BUT LESS THAN 10 TIMES
THESE LIMITS, A NIOSH APPROVED HALF-FACEPIECE RESPIRATOR EQUIPPED WITH APPROPRIATE CHEMICAL CARTRIDGES MAY BE USED. FOR CONCENTRATIONS GREATER THAN 10 TIMES
THE TLV AND/OR PEL, CONSULT THE NIOSH RESPIRATOR DECISION LOGIC FOUND IN PUBLICATION NO. 87-116 OR ANSI Z88.2-1992.
Glove Protection:
NEOPRENE OR NITRILE RUBBER GLOVES IF REPEATED OR PROLONGED SKIN CONTACT IS LIKELY. ENSURE COMPLIANCE WITH OSHA'S PERSONAL PROTECTIVE EQUIPMENT (PPE) STANDARD
FOR HAND PROTECTION, 29 CFR 1910.138.
Eye Protection:
SAFETY GLASSES WITH SIDE SHIELDS IF THE METHOD OF APPLICATION PRESENTS THE LIKELIHOOD OF EYE CONTACT. ENSURE COMPLIANCE WITH OSHA'S PERSONAL PROTECTIVE
EQUIPMENT (PPE) STANDARD FOR EYE AND FACE PROTECTION, 29 CFR 1910.133.
Other Protection:
WEAR GENERAL-DUTY WORK CLOTHES AND SHOES. A SAFETY SHOWER AND AN EYEWASH STATION SHOULD BE AVAILABLE. REMOVE OIL SOAKED CLOTHING AND SHOES. WASH CLOTHING AND
CLEAN SHOES BEFORE REUSE.
Section X - Storage and Handling Information
Storage Temperature Storage Conditions
Max: 120癋 Min: 35癋 [] Indoors [ ] Outdoors [ ] Heated [ ] Refrigerated
Precautions to be Taken in Handling and Storing:
USE WITH CAUTION AROUND HEAT, SPARKS, PILOT LIGHTS, STATIC ELECTRICITY, AND OPEN FLAME.
Other Precautions:
KEEP OUT OF REACH OF CHILDREN. READ THE ENTIRE LABEL BEFORE USING THE PRODUCT. FOLLOW THE LABEL DIRECTIONS.
Section XI - Regulatory Information
Chemical Name CAS Number Upper % Limit
HEXANE 110-54-3 30
ANTIMONY COMPOUNDS N/A 5
CYCLOHEXANE 110-82-7 10
Those Ingredients listed above are subject to the reporting requirements of 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40
CFR part 372.
Please call 1-800-527-9919 for additional information if you are a California customer. This MSDS is not intended for users in the state of California.
Section XII - References
1. THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS AND BIOLOGICAL EXPOSURE INDICES, ACGIH, 2006.
2. OSHA PEL.
3. VENDOR'S MSDS.
4. REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES, CCINFOWeb, 2006.
ALL THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE TOXIC SUBSTANCES CONTROL ACT (TSCA) AND ARE EITHER LISTED ON THE TSCA INVENTORY OR OTHERWISE
EXEMPTED FROM LISTING.
IRR:IRRITANT, FLAM/FLAMM:FLAMMABLE, TOX:TOXIC, IHL:INHALATION, COMB:COMBUSTIBLE, CORR:CORROSIVE, CARC:CARCINOGENIC, N/A:NOT APPLICABLE, N/E:NOT ESTABLISHED,
COC:CLEVELAND OPEN CUP, PMCC:PENSKY-MARTIN CLOSED CUP, TCC:TAGLIABUE CLOSED CUP, LEL:LOWER EXPLOSION LIMIT, UEL:UPPER EXPLOSION LIMIT, HMN:HUMAN,
IARC:INTERNATIONAL AGENCY FOR THE RESEARCH ON CANCER, NFPA:NATIONAL FIRE PROTECTION ASSOCIATION, ORL:ORAL, NTP:NATIONAL TOXICOLOGY PROGRAM, OSHA:OCCUPATIONAL
SAFETY & HEALTH ADMINISTRATION, ACGIH:AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS, TLV:THRESHOLD LIMIT VALUE, PEL:PERMISSIBLE EXPOSURE LIMIT,
STEL:SHORT-TERM EXPOSURE LIMIT, MLD:MILD, MOD:MODERATE, SEV:SEVERE, MUT:MUTAGENIC, ASPHYX:ASPHYXIANT, PNOC:PARTICULATES NOT OTHERWISE CLASSIFIED,
PNOR:PARTICULATES NOT OTHERWISE REGULATED, PNOS:PARTICLES (INSOLUBLE) NOT OTHERWISE SPECIFIED, SDT:STANDARD DRAIZE TEST
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING
THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
CERTIFIED LABS, DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a
manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage, or disposal of the product.
?008 NCH Corporation All rights reserved.
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