MATERIAL SAFETY DATA SHEET
PRODUCT IDENTIFICATION
PRODUCT NAME: SPRAY ADHESIVE (NFPA RATINGS)
PART #: N4820 HEALTH: 2
FIRE: 3
REACTIVITY: 0
HMIS PROTECTIVE EQUIPMENT: X See your supervisor
PRODUCT INFORMATION MEDICAL EMERGENCY
(800) 262-0012 (856) 455-4555
TRANSPORTATION EMERGENCY DISTRIBUTOR / MANUFACTURER
CHEMTREC (800) 424-9300 NATIONAL REFRIGERANTS, INC.
661 KENYON AVE. ROSENHAYN, NJ
HAZARDOUS INGREDIENTS
OSHA Hazardous Components (29 CFR 1910.1200) EXPOSURE LIMITS: 8 HR. TWA
OSHA PEL ACGIH TLV
Hexane (110-54-3) 800 800
Acetone (67-64-1) 50 50
Propane (74-98-6) 1000 1000
HAZARDS IDENTIFICATIONS
EMERGENCY OVERVIEW:
DANGER! Flammable. Harmful or fatal if swallowed. Vapor harmful. Aerosol, contents under pressure.
Irritating to eyes, skin, mucous membranes, and respiratory tract.
POTENTIAL HEALTH EFFECTS:
INHALATION: Excessive inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness, nausea,
headache, possible unconsciousness or asphyxiation.
EYE CONTACT: Irritation.
SKIN CONTACT: Irritation due to defatting of skin.
INGESTION: Possible chemical pneumonitis if aspirated into lungs.
CHRONIC Effects: (Effects due to excessive exposure to the raw materials of this mixture) Excessive inhalation of
hexane may cause nerve damage.
CARCINOGENICITY: LISTED IN NTP? No IARC? No OSHA Regulated? No
FIRST AID MEASURES
INHALATION: Remove to fresh air. If not breathing, apply artificial respiration and administer oxygen. Keep victim warm.
Seek medical advice.
EYE CONTACT: Flush with large amounts of running water for 15 minutes occasionally lifting lower and upper eyelids.
Seek medical advice.
SKIN CONTACT: Wash exposed area with soap and water. Remove contaminated clothing. Seek medical advice if
symptoms develop.
INGESTION: Give water. Do NOT induce vomiting. Aspiration into lungs may cause chemical pneumonia. Seek
immediate medical attention. Do not give anything by mouth to an unconscious person. If spontaneous
vomiting occurs, keep head below hips.
N4820 SPRAY ADHESIVE Page 1 of 3
FIRE FIGHTING MEASURES
FLASHPOINT (TEST METHOD): < 113 Degrees F
FLAMMABLE LIMITS: LOWER: N/E UPPER: N/E
AUTOIGNITION TEMPERATURE (non-aerosol i.e. base stock): N/E.
GENERAL HAZARD: WARNING! Product under pressure, may explode from excessive heat. Water may be ineffective to fight
fire. Toxic gases may be produced in fire.
FIRE FIGHTING INSTRUCTIONS: Do not enter without full bunker of equipment including self contained breathing apparatus.
Stay upwind, keep all personnel away. Cool fire exposed containers with water.
EXTINGUISHING MEDIA: Use carbon dioxide, dry chemical or foam.
HAZARDOUS COMBUSTION PRODUCTS: Smoke, fumes and oxides of carbon.
ACCIDENTAL RELEASE MEASURES
Ventilate and isolate hazard area. Remove all sources of ignition. Keep unnecessary and unprotected personnel away. Clean up
spills and leaks immediately to prevent soil and water contamination.
LAND SPILL: Absorb spill with inert, non-combustible material, then place in a chemical waste container.
WATER SPILL: Do not flush to sewer. Collect and store in a chemical waste container.
HANDLING AND STORAGE
HANDLING: Use with adequate ventilation. Avoid skin/eye contact and breathing vapors. Do not smoke while spraying.
DO NOT CUT, WELD, BRAZE, SOLDER, DRILL, OR EXPOSE TO HEAT, FLAME, SPARKS AND/OR
STATIC ELECTRICITY. Intentional misuse by deliberately concentrating vapors and inhaling contents can
be harmful or fatal.
STORAGE: Store in a cool, dry place away from heat (< 120oF.), ignition sources, oxidizers, and strong acids and bases.
EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Adequate ventilation to control vapor accumulation.
PERSONAL PROTECTION: If TLV exceeded, NIOSH approved respirator. Wear safety glasses or chemical goggles or full face
shield and chemical impervious apron to protect from splashing. Wear chemical impervious gloves.
Wash clothing before reuse.
PHYSICAL AND CHEMICAL PROPERTIES
VAPOR PRESSURE: psig @ 70of (aerosols): 32-42 VAPOR DENSITY (Air=1) : N/E
SPECIFIC GRAVITY: 0.863 EVAPORATION RATE (ETHER=1): N/E
SOLUBILITY IN WATER: Partial pH: NA
FREEZING POINT: Not Applicable BOILING POINT: Not Applicable
APPEARANCE & ODOR: Straw colored with ketone solvent odor. AEROSOL - % VOC (W/W): 95
STABILITY AND REACTIVITY
STABILITY: Stable
CONDITIONS TO AVOID: Avoid excessive heat, ignition sources, and flames. Isolate from oxidizers and strong acids and bases.
MATERIALS TO AVOID: None known. Test on surface before using.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide.
HAZARDOUS POLYMERIZATION: Will not occur.
N4820 SPRAY ADHESIVE Page 2 of 3
TOXICOLOGICAL INFORMATION
Isobutane LC50: 57 pph/15M (inh - rat)
1041 g/m3/2H
LCLo: (inh - mouse)
Acetone LDLo: 8 g/kg (oral - dog)
TCLo: 12,000 ppm/4h (inh - human) CNS, GIT
TCLo: 500 ppm (inh - human) EYE
LD50: 5800 mg/kg (oral - rat)
50,100 mg/m3/8H
LC50: (inh - rat)
Hexane LD50: 28,710 mg/kg (oral - rat)
TCLo: 190 ppm / 8W (inh - human) PNS
ECOLOGICAL INFORMATION
No data available.
DISPOSAL CONSIDERATIONS
Classification of waste required before disposal. Do not puncture or incinerate. Follow all local, state and federal
regulations. Aerosol cans when vented to atmosphere pressure through normal use pose no disposal hazard. Full or
partially filled containers are considered hazardous waste.
TRANSPORTATION INFORMATION
PROPER SHIPPING NAME: Consumer commodity, ORM-D
HAZARD CLASS: Not applicable
IDENTIFICATION NUMBER: Not applicable
DOT Emergency Guide #: 126
Reportable Quantity (RQ): Not Applicable
International: Aerosols, flammable, (each not exceeding 1 L capacity), 2.1, UN 1950, LTD QTY
REGULATORY INFORMATION
TSCA (Toxic Substance Control Act): Components of this product are listed on the TSCA Inventory.
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act): NAP
SARA TITLE III (Superfund Amendments and Reauthorization Act): NAP
CALIFORNIA PROPOSITION 65: Not listed
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National Refrigerants, Inc. believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR
IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be valid where such product is used in
combination with any other methods of use of the product and of the information referred to herein are beyond the
control of National Refrigerants. National Refrigerants expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
10/09
DATE OF LATEST REVISION/REVIEW:
Ray Madariaga
PERSON RESPONSIBLE FOR MSDS:
N4820 SPRAY ADHESIVE Page 3 of 3
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