Firestone Specialty Products Company
Material Safety Data Sheet
February 16, 2007 Page: 1
SECTION 1: PRODUCT IDENTIFICATION
Product Name: Spray Adhesive/Primer 7877
Chemical Name / Synonym: None
Chemical Family: Mixture
24-Hour Emergency Phone: (800) 424-9300 CHEMTREC
Manufacturer's Name: Firestone Specialty Products Company
th
Manufacturer's Address: 310 East 96 Street, Indianapolis, IN 46240
NFPA Hazard Rating: Health 3, Flammability 4, Reactivity 1
HMIS Hazard Rating: Health 2, Flammability 4, Reactivity 1
SECTION 2: CHEMICAL COMPOSITION
Chemical Name: Common Name: CAS #: % (by wt) Exposure Limits:
Acetone Methyl Ketone 67-64-1 25 PEL 1000 ppm
TLV 500 ppm
ACGIH STEL 750 ppm
Propane Dimethylmethane 74-98-6 20 PEL 1000 ppm
TLV 1000 ppm
n-Hexane None 110-54-3 20 PEL 500 ppm
TLV 50 ppm
Dimethyl Ether Methyl Ether 115-10-6 15 AIHA WEEL 1000 ppm
Toluene Toluol 108-88-3 5 PEL 200 ppm
OSHA CEILING 300 ppm
TLV 50 ppm (Skin)
C12 ?C14 Isoalkanes None 68551-19-9 5 None Available
Cyclohexane None 110-82-7 10 PEL 300 ppm
TLV 100 ppm
SECTION 3: HAZARD IDENTIFICATION
Primary Route of Exposure: Skin Absorption, Inhalation
Signs and Symptoms of Eye contact may cause severe eye irritation, redness, tearing
Exposure: and blurred vision. Prolonged or repeated skin contact may
cause irritation, dermatitis and drying of the skin. Absorption
through intact skin may contribute to an individual's overall
exposure. Inhalation may cause respiratory system irritation
and central nervous system depression characterized by
headache, dizziness, muscular weakness and fatigue. May
cause unconsciousness if exposure is excessive. Inhalation of
Toluene vapors above 200 ppm may result in impairment of
coordination, increased reaction time and a bad taste in the
mouth. N-Hexane LD50 (rat) of 28.7 kg/kg, n-Hexane LCL0
Firestone Specialty Products Company
Material Safety Data Sheet
February 16, 2007 Page: 2
3
(mouse) of 120 gm/m ; Acetone LC50 (rat) of 16,000 ppm/4hr,
Acetone LD50 (rat) of 9.8 g/kg; Toluene LC50 (rat) of 8,000
ppm/4hr, Toluene LD50 (rat) of 5 g/kg; Dimethyl Ether LC50
3
(rat) of 308 gm/m ; Cyclohexane LD50 (mouse) of 813 mg/kg,
3
Cyclohexane LCL0 (mouse) of 70 gm/m /2 hr.
Medical Conditions Aggravated Exposure to this product may aggravate pre-existing skin and
by Exposure: respiratory diseases. Exposure to Hexane should be avoided
by individuals with neurological diseases.
Chronic Effects: Overexposure to this material (or its components) may cause
kidney, liver, spleen and central nervous system damage.
Based upon animal studies, may cause brain cell and
neuromuscular damage and hearing loss.
Carcinogenicity: None
SECTION 4: FIRST AID MEASURES
First Aid Procedures: If this material contacts the eyes, hold eyelids open and flush
immediately with a gentle stream of water for at least 15
minutes, preferably at an eyewash fountain. Get medical
attention. In case of skin contact, clean with rubbing alcohol,
mineral oil, baby oil or makeup remover first to remove sticky
resin, followed immediately by washing affected area with
soap and water. In case of inhalation, remove to fresh
uncontaminated air. Administer oxygen if breathing is labored.
Give artificial respiration if breathing has stopped. Get
medical attention immediately if oxygen or artificial respiration
is administered. In case of accidental ingestion, do not induce
vomiting. Get medical attention and advise the physician of
the nature of the material.
SECTION 5: FIRE FIGHTING PROCEDURES
Suitable Extinguishing Media: Foam, water spray, (fog), Carbon Dioxide, and dry chemical
type extinguishing agents may all be suitable for extinguishing
fires involving this product. Water may be ineffective, but
should be used to keep fire-exposed containers cool. If a leak
or spill has ignited, use water to disperse the vapors and to
protect men attempting to stop a leak. Water spray may be
used to flush spills away from exposures.
Hazardous Combustion Products: Carbon dioxide, carbon monoxide, various hydrocarbons,
carboxylic acid, acrid smoke and irritating fumes.
Recommended Fire Fighting Wear impermeable protective clothing and self-contained
Procedures: breathing apparatus. Toxic fumes and vapors may be
evolved. Minimize the breathing of gases, vapors, fumes or
decomposition products. Use supplied-air breathing
equipment for enclosed or confined spaces or as otherwise
needed.
Unusual Fire and Explosion This product is volatile and gives off invisible vapors. Either
Hazards: the liquid or vapor may settle in low areas or travel some
distance along the ground or surface to ignition sources where
they may ignite or explode.
Firestone Specialty Products Company
Material Safety Data Sheet
February 16, 2007 Page: 3
SECTION 6: PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to Be Taken in Case Shut off and eliminate all ignition sources. Keep people away.
Material is Released or Spilled: Recover free product. Add sand, earth or other suitable
absorbent to spill area. Minimize breathing vapors. Minimize
skin contact. Ventilate confined spaces. Open all windows
and doors. Keep product clear of sewers, water, or extensive
land areas. Assure conformity with applicable government
regulations. Continue to observe precautions for volatile,
flammable vapors from absorbed material.
Precautions to Be Taken in Do not store above 120?F. Do not store in direct sunlight.
Handling and Storing: Keep away from heat, sparks, and open flames. Keep
containers closed. Vapors of this material are heavier than air
and will collect in low or confined areas. Containers, even
those that have been emptied, can contain explosive vapors.
Do not cut, drill, grind, weld or perform similar operations near
containers. Static electricity may accumulate and create a fire
hazard. Ground fixed equipment. Bond and ground all
transfer containers and equipment.
SECTION 7: EXPOSURE CONTROLS / PERSONAL PROTECTION
Ventilation: Use with ventilation sufficient to prevent exceeding
recommended exposure limits or build up of explosive
concentrations of vapor in air.
Respiratory Protection: If personal exposure concentrations cannot be maintained below
the appropriate exposure limits using engineering controls, a
NIOSH approved respirator may be appropriate based on
employer-determined exposure levels.
Eye Protection: Safety glasses with side shields are recommended when
pouring or applying this product.
Skin Protection: Wear polyvinyl alcohol, nitrile rubber, or neoprene glove when
handling this product to avoid prolonged skin contact.
Other: Not required.
Work / Hygienic Practices: Wash exposed skin prior to eating, drinking or smoking and at
the end of each shift. Wash contaminated clothing prior to
reuse.
SECTION 8: PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor: Clear amber liquid with mint odor
Flash Point: - 156?F Lower Explosive Limit: 1.0%
Method Used: Pensky-Martens CC Upper Explosive Limit: 18%
Evaporation Rate: >1 (Butyl Acetate=1) Boiling Point: Unknown
pH (undiluted product): Unknown Melting Point: Not Applicable
Solubility in Water: Negligible Specific Gravity: 0.68 (Water=1)
Vapor Density: Heavier than air Percent Volatile: 79%(by weight)
84% (by vol.)
Vapor Pressure: Unknown
Firestone Specialty Products Company
Material Safety Data Sheet
February 16, 2007 Page: 4
SECTION 9: STABILITY AND REACTIVITY
Thermal Stability: Stable
Hazardous Polymerization: Will not occur
Conditions to Avoid: Avoid flames, sparks or other sources of ignition.
Incompatible with acids, oxidizers, aldehydes, reducing
agents.
SECTION 10: TRANSPORTATION
Regulatory Agency: DOT
Proper Shipping Name: Aerosols
Hazard Classification: 2.1
Identification Number: UN1950
Labels Required: Flammable Gas
Other Requirements: ICAO/IATA - UN1950, Aerosols, 2.1.
IMDG - UN1950, Aerosols, Class 2.1, EMS F-D, S-U.
SECTION 11: MISCELLANEOUS INFORMATION
Additional Comments: None
Date of Previous MSDS: July 31, 2006
Changes Since Previous MSDS: Company name change.
Telephone Number for Additional (317) 575-7190
Information:
DISCLAIMER
The information contained herein is based on data considered accurate which has been obtained from
other companies and organizations. However, no warranty or representation is expressed or implied that
the information, is accurate, complete or representative. Firestone Specialty Products Company, a
subsidiary of Bridgestone Americas Holding, Inc. assumes no responsibility for injury to the buyer, the
buyer's employees, or any third persons, if reasonable safety procedures are not followed. Additionally,
Firestone Specialty Products Company assumes no responsibility for injury to buyer, the buyer's
employees, or any third persons caused by abnormal use of this material, even if reasonable safety
procedures are followed.
|