The Laminex Group
90 - 94 Tram Road
DONCASTER VIC 3108
Telephone: 03 9848 4811
Facsimile: 03 9848 8158
Date last updated: 22/07/2003
MATERIAL SAFETY DATA SHEET NO. 502
STATEMENT OF HAZARDOUS NATURE: This material is classified as a hazardous
substance according to the criteria of NOHSC and a Dangerous Good by the criteria of the
ADG Code.
TRADE ESSENTIALS - BRUSHABLE CONTACT ADHESIVE - 440T
IMPORTANT NOTICE: This Material Safety Data Sheet (MSDS) is issued by The Laminex
Group in accordance with NOHSC Guidelines. As such, the information contained herein
must not be altered, deleted or added to. The Laminex Group will issue a new MSDS when
there is a change in product specifications and/or NOHSC guidelines / regulations. The
Laminex Group will not accept any responsibility for any changes made to its MSDS in
content by any other person.
COMPOSITION & INFORMATION ON INGREDIENTS
Chemical Entity CAS No. Proportion R phrase
Hazardous constituents
Acetone 67-64-1 10 - 30% R11, R36
n-Hexane 110-54-3 <5% R11, R20, R48, R65, R67
Hexane mixed isomers 30-60% R11, R38
Toluene 108-88-3 10-30% R11, R20, R65,
Non hazardous materials up to 100%
No other hazardous materials are present in this product at concentrations above the cut off
levels as Noted in the List of Designated Hazardous Substances, [NOHSC: 10005 (1999)] or
as defined in the Approved Criteria for Classifying Hazardous Substances [NOHSC: 10008
(1999)].
AICS status: All components of the finished product are listed on the AICS
HAZARDS IDENTIFICATION
Emergency Overview: Highly flammable, harmful by inhalation, ingestion and by skin
and eye contact.
Acute:
Swallowed: Moderately toxic. Tends to break up into a foam if the patient
vomits. Upon aspiration into the lungs, chemical pneumonitis
may develop.
Eye: Irritating to the eye
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Skin: Mildly irritating to the skin. Frequent or prolonged contact can
cause skin complaints such as dermatitis
Inhalation: Irritating to the respiratory system. Prolonged exposure to
vapours may cause headaches, impairment of judgement,
central nervous system depression which in extreme cases
may lead to unconsciousness or death.
Chronic:
Reports exist related to chronic toluene poisoning which indicate bone marrow and liver
damage.
FIRST AID MEASURES
Swallowed: Do not induce vomiting. Give 1 - 2 glasses of water and obtain
medical assistance. Should the patient vomit, maintain a clear
airway until medical assistance is obtained
Eye: Flush with water for 15 minutes. It is advisable to obtain medical
advice concerning any eye injury.
Skin: Hose down with water before removing clothes due to possibility
of static discharging igniting vapour. Wash affected areas with
soap and water thoroughly. Allow clothing to thoroughly air dry
then launder before re-use. If symptoms persist, seek medical
advice.
Inhaled: Carefully remove persons to fresh air, avoid becoming affected
yourself. If the patient is severely affected obtain medical
assistance. If the person stops breathing apply artificial
respiration and other first aid techniques as required until medical
assistance arrives
Advice to Doctor
Oral: Gastrointestinal irritation, nausea, vomiting and cramping. CNS
depression ranging from mild headache to anaesthesia and
coma. Pulmonary irritation secondary to exhalation of solvent.
Lavage with cuffed tube if a large quantity is ingested. Aspiration
is the main danger. Enforce bed rest and observe carefully.
Observe for 24 hours for chemical pneumonitis. Longer term
medical surveillance may be necessary. Maintain airway and vital
functions
Inhalation: CNS depression characterised by headache and dizziness which
in extreme cases can lead to unconsciousness and death.
FIRE FIGHTING MEASURES
Fire / Explosion Hazard: Product is flammable and does represent a fire and explosion
hazard. Excessively heated sealed containers may rupture
explosively.
Sources of Ignition
Advice: Isolate from of sources of heat, naked flames and sparks,
including static discharges. Prevent build up of flammable
vapours. Vapour and air mixture may ignite explosively
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Dangerous
Decomposition: Carbon Dioxide, carbon monoxide and other unidentified thermal
decomposition products
Fire Fighting
Recommendations: Use foam, carbon dioxide or dry chemical
ACCIDENTAL RELEASE MEASURES
Wear rubber gloves and goggles in addition to respiratory protection for protection against
splashes and vapours. Extinguish all ignition sources. Dam and recover. Prevent entry into
drainage systems, rivers, waterways etc. Collect with absorbent materials such as sand, earth
or appropriate commercial absorbent. Shovel up with non-sparking tools. Place into suitable
containers. Empty containers may contain product residue. Follow safety procedures until
container has been cleaned
HANDLING AND STORAGE
Store on wooden pallet. Store between 0o and 30oC. Should recommended maximum storage
temperature be exceeded, cool sealed container under running water for 30 minutes before
use. Excessively heated sealed drums may rupture explosively.
Keep away from heat, naked flames or sparks including static discharges. Use appropriate
earthing techniques when transferring liquids from one container to another.
Store away from oxidising agents. Keep containers closed at all times when not in use
DANGEROUS GOODS CLASS / SUBSIDIARY RISK: Class 3 Flammable Liquid Packaging
Group II.
EXPOSURE CONTROLS AND PERSONAL PROTECTION
Exposure
This material contains the following materials for which exposure limits have been set by
NOHSC Australia as listed in the "National Exposure Standards {NOHSC: 3008 (1995)" and
Amendments to Adopted National "Exposure Standards for Atmospheric Contaminants in the
Occupational Environment (Source A Updates Batch 1) 2001 and (Source A Updates Batch
2) 2002 as follows:
Acetone 67-64-1 TWA 500 ppm
STEL 1000 ppm
Toluene 108-88-3 TWA 50 ppm
STEL 150 ppm
n-hexane 110-54-3 TWA 20 ppm
STEL Not noted
Other isomers of hexane TWA 500 ppm
STEL 1000 ppm
Ventilation: Provide explosion proof ventilation sufficient to maintain
exposure levels below the listed exposure limits
Personal Protection:
Respiratory type
(AS1716): Organic vapour mask if exposed to mist or vapours at up to
10 times the exposure limit. Above this level use air supplied
or self contained breathing apparatus.
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Glove Type: Impervious gloves should be worn to prevent skin contact.
Consult industrial glove supplier for a suitable glove
Eye: Goggles or face shields to avoid splashes
Clothing: Sufficient to avoid skin contact.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Yellow to amber liquid
Boiling point, oC: approx. 55
Vapour Pressure@ 760 mm Hg at 25 oC: Not known
Solubility in Water, g/l: Immiscible
Specific Gravity: kg /litre Approx. 0.82
Flash Point, oC: -26
Flammability Limits, % Upper: 7.4% v/v
Lower 1.1% v/v
Evaporation Rate (BuAc = 1): Not Determined
Other Data: None noted
Major recommended usage: Specialised applications including solvent based adhesive
Method of application: Mechanical or hand tool
STABILITY AND REACTIVITY
Reactivity: Stable at normal temperature and pressures
TOXICOLOGICAL INFORMATION
Toluene:-
Oral Rat LD50 5000 mg / kg
Skin Rabbit LD50 12,124 mg / kg
Acetone:-
Oral Rat LD50 5,800 mg / kg
Skin Rabbit, adult LD50 20 g / kg
n-hexane:-
Oral rat LD50 28,710 mg / kg
Inhalation Human TCLo 190ppm / 8W: Peripheral nervous system effects
ECOLOGICAL INFORMATION
No data available for the product. Do not allow to enter the environment. Waste material
should be collected and disposed of according to the relevant Local / State or Federal
regulations.
DISPOSAL
Refer to Land Waste Management Authority
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TRANSPORT INFORMATION
This material is a Class 3 Flammable Liquid according to the Australian Code for the
Transport of Dangerous Goods by Road and Rail
Proper Shipping Name: Adhesive containing Flammable Liquid (i) immiscible in water
UN Number: 1133
Dangerous Goods Class 3.1
Subsidiary Risk: Not Applicable
HAZCHEM Code: 3[Y]E
Poisons Schedule: 5
REGULATORY INFORMATION
Hazard Classification: Harmful Xn
Risk Phrases R11 Highly flammable
R20 Harmful by inhalation
R36 Irritating to eyes
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed
R67 Vapours may cause drowsiness and dizziness
Safety Phrases S9 Keep container in well ventilated place
S16 Keep away from sources of ignition. No smoking
S24 Avoid contact with skin
S25 Avoid contact with eyes
S29 Do not empty into drains
S33 Take precautionary measures against static discharge
S51 Use only in well ventilated areas
OTHER INFORMATION
Contact Point: National Starch and Chemical Pty Ltd
Stanton Road,
SEVEN HILLS. NSW. 2147
TITLE: SHE Manager
TELEPHONE: 02 9624 6022
PREPARED BY: Margaret Teleki
TITLE: SHE Support
TELEPHONE: 02 9624 6022
Whilst the information contained in this document is based on data which, to the best of our knowledge, was accurate
and reliable at the time of preparation, no responsibility can be accepted by us for errors and omissions. The
provision of this information should not be construed as a recommendation to use any of our products in violation of
any patent rights or in breach of any statute or regulation. Users are advised to make their own determination as to
the suitability of this information in relation to their particular purposes and specific circumstances. Since the
information contained in this document may be applied under conditions beyond our control, no responsibility can be
accepted by us for any loss or damage caused by any person acting or refraining from action as a result of this
information.
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