Material Safety Data Sheet
Product name : Titebond Solvent Based FRP Adhesive
1. Product and company identification
CAS # : Mixture
Address : Franklin International
2020 Bruck Street
Columbus OH 43207
Contact person : Franklin Technical Services
Telephone : (800) 877-4583
Emergency phone: : Franklin Security
(614) 445-1300
Reference number : 3103
: 3227
Product code
Date of revision : 3/15/2010.
Print date : 3/16/2010.
Chemtrec (24 Hour) : (800) 424 - 9300
Chemtrec International : (703) 527 - 3887
Product use : Adhesive
: Solvent Based
Product type
2. Hazards identification
Physical state : Liquid. [Paste.]
Odor : Solvent(s) [Slight]
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Emergency overview : DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY
CAUSE FLASH FIRE. HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT,
EYE AND SKIN IRRITATION. MAY BE HARMFUL IF SWALLOWED. PROLONGED
OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS
MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE.
Extremely flammable liquid. Harmful by inhalation. May be harmful if swallowed.
Severely irritating to eyes. Irritating to respiratory system and skin. Defatting to the skin.
Keep away from heat, sparks and flame. Do not breathe vapor or mist. Do not ingest.
Do not get in eyes. Avoid contact with skin and clothing. Contains material that may
cause target organ damage. Use only with adequate ventilation. Keep container tightly
closed and sealed until ready for use. Wash thoroughly after handling.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Inhalation : Toxic by inhalation. Irritating to respiratory system.
Ingestion : Harmful if swallowed.
Skin : Irritating to skin.
Eyes : Severely irritating to eyes. Risk of serious damage to eyes.
Potential chronic health effects
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2. Hazards identification
Chronic effects : Contains material that may cause target organ damage. Prolonged or repeated contact
can defat the skin and lead to irritation, cracking and/or dermatitis.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Target organs : Contains material which may cause damage to the following organs: peripheral nervous
system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
Over-exposure signs/symptoms
Inhalation : High vapor concentrations can cause headaches, dizziness, drowsiness and nausea and
may lead to unconsciousness.
Adverse symptoms may include the following:
respiratory tract irritation
coughing
Ingestion : No specific data.
Skin : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Eyes : Adverse symptoms may include the following:
pain or irritation
watering
redness
Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
aggravated by over-
exposure
See toxicological information (section 11)
3. Composition/information on ingredients
United States
Name CAS number %
n-hexane 110-54-3 10 - 25
Canada
Name CAS number %
n-hexane 110-54-3 10 - 25
Mexico Classification
Name CAS number UN number % IDLH H F R Special
n-hexane 110-54-3 UN1993 10 - 25 1100 ppm 0 3 0
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in
this section.
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4. First aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
5. Fire-fighting measures
Flammability of the product : Extremely flammable liquid. In a fire or if heated, a pressure increase will occur and the
container may burst, with the risk of a subsequent explosion.
Extinguishing media
Suitable : Use dry chemical, CO2, water spray (fog) or foam.
Not suitable : Do not use water jet.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
6. Accidental release measures
Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Absorb
with an inert material.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see section 13). Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilled product. Note: see section 1 for emergency
contact information and section 13 for waste disposal.
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7. Handling and storage
Handling : Put on appropriate personal protective equipment (see section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from heat,
sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use non-sparking tools. Take
precautionary measures against electrostatic discharges. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Storage : Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination.
8. Exposure controls/personal protection
United States
Ingredient Exposure limits
n-hexane OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hour(s).
TWA: 180 mg/m?8 hour(s).
NIOSH REL (United States, 6/2008).
TWA: 50 ppm 10 hour(s).
TWA: 180 mg/m?10 hour(s).
ACGIH TLV (United States, 1/2008). Absorbed through skin.
TWA: 50 ppm 8 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 500 ppm 8 hour(s).
TWA: 1800 mg/m?8 hour(s).
Canada
Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling
Ingredient List name ppm mg/m?Other ppm mg/m?Other ppm mg/m?Other Notations
n-hexane US ACGIH 1/2008 50 - - - - - - - - [1]
AB 6/2008 50 176 - - - - - - - [1]
BC 6/2008 20 - - - - - - - - [1]
ON 6/2008 50 176 - - - - - - -
QC 6/2008 50 176 - - - - - - - [1]
[1]Absorbed through skin.
Mexico
Ingredient Exposure limits
n-hexane NOM-010-STPS (Mexico, 9/2000).
LMPE-PPT: 50 ppm 8 hour(s).
LMPE-PPT: 176 mg/m?8 hour(s).
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere
or biological monitoring may be required to determine the effectiveness of the ventilation
procedures
or other control measures and/or the necessity to use respiratory protective equipment.
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8. Exposure controls/personal protection
Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor
or dust concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
Personal protection
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation.
controls
9. Physical and chemical properties
Physical state : Liquid. [Paste.]
Flash point : Closed cup: <-17.778癈 (<-0.0004癋) [Setaflash.]
Flammable limits : Lower: 1.2%
Upper: 7.5%
Color : Beige.
Odor : Solvent(s) [Slight]
Boiling/condensation point : 61.667癈 (143癋)
Relative density : 1.26
Volatility : 20.39% (w/w)
VOC (less water, less : 247 g/l
exempt solvents)
Solubility : Insoluble in the following materials: cold water and hot water.
10 . Stability and reactivity
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Materials to avoid : Highly reactive or incompatible with the following materials:
oxidizing materials
Incompatibility : Reactive or incompatible with the following materials: oxidizing materials, acids and
alkalis.
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10 . Stability and reactivity
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
products
Conditions of reactivity : Highly flammable in the presence of the following materials or conditions: open flames,
sparks and static discharge.
11 . Toxicological information
United States
Acute toxicity
Product/ingredient name Result Species Dose Exposure
n-hexane LD50 Oral Rat 25 gm/kg -
LDLo Rat 9100 mg/kg -
Intraperitoneal
TDLo Oral Rat 20000 mg/kg -
LC50 Inhalation Rat 627000 mg/m3 3 minutes
Vapor
LC50 Inhalation Rat 48000 ppm 4 hours
Gas.
Chronic toxicity
No known significant effects or critical hazards.
Irritation/Corrosion
Conclusion/Summary
Skin : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
Eyes : Severely irritating to eyes.
Respiratory : High vapor concentrations can cause headaches, dizziness, drowsiness and nausea and
may lead to unconsciousness.
Sensitizer
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
Canada
Acute toxicity
Product/ingredient name Result Species Dose Exposure
n-hexane LD50 Oral Rat 25 gm/kg -
LDLo Rat 9100 mg/kg -
Intraperitoneal
TDLo Oral Rat 20000 mg/kg -
LC50 Inhalation Rat 627000 mg/m3 3 minutes
Vapor
LC50 Inhalation Rat 48000 ppm 4 hours
Gas.
Chronic toxicity
No known significant effects or critical hazards.
Irritation/Corrosion
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11 . Toxicological information
Conclusion/Summary
Skin : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
Eyes : Severely irritating to eyes.
Respiratory : High vapor concentrations can cause headaches, dizziness, drowsiness and nausea and
may lead to unconsciousness.
Sensitizer
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
Mexico
Acute toxicity
Product/ingredient name Result Species Dose Exposure
n-hexane LD50 Oral Rat 25 gm/kg -
LDLo Rat 9100 mg/kg -
Intraperitoneal
TDLo Oral Rat 20000 mg/kg -
LC50 Inhalation Rat 627000 mg/m3 3 minutes
Vapor
LC50 Inhalation Rat 48000 ppm 4 hours
Gas.
Chronic toxicity
No known significant effects or critical hazards.
Irritation/Corrosion
Conclusion/Summary
Skin : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
Eyes : Severely irritating to eyes.
Respiratory : High vapor concentrations can cause headaches, dizziness, drowsiness and nausea and
may lead to unconsciousness.
Sensitizer
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
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12 . Ecological information
Environmental effects : No known significant effects or critical hazards.
United States
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
n-hexane - Acute LC50 113000 ug/L Fish - Mozambique tilapia - 96 hours
Fresh water Tilapia mossambica - 99
mm - 10 g
- Acute LC50 2500 to 2980 Fish - Fathead minnow - 96 hours
ug/L Fresh water Pimephales promelas - 31
days - 20.4 mm - 0.123 g
Biodegradability
No known significant effects or critical hazards.
Canada
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
n-hexane - Acute LC50 113000 ug/L Fish - Mozambique tilapia - 96 hours
Fresh water Tilapia mossambica - 99
mm - 10 g
- Acute LC50 2500 to 2980 Fish - Fathead minnow - 96 hours
ug/L Fresh water Pimephales promelas - 31
days - 20.4 mm - 0.123 g
Biodegradability
No known significant effects or critical hazards.
Mexico
Aquatic ecotoxicity
Result Species
Product/ingredient name Test Exposure
n-hexane - Acute LC50 113000 ug/L Fish - Mozambique tilapia - 96 hours
Fresh water Tilapia mossambica - 99
mm - 10 g
- Acute LC50 2500 to 2980 Fish - Fathead minnow - 96 hours
ug/L Fresh water Pimephales promelas - 31
days - 20.4 mm - 0.123 g
Biodegradability
No known significant effects or critical hazards.
Other adverse effects : No known significant effects or critical hazards.
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Empty
containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
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14 . Transport information
Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
DOT Classification 1133 ADHESIVES, 3 II -
containing flammable
liquid
TDG Classification 1133 ADHESIVES, 3 II -
containing flammable
liquid
Mexico 1133 ADHESIVES, 3 II -
containing flammable
Classification
liquid
ADR/RID Class 1133 ADHESIVES, 3 II -
containing flammable
liquid
IMDG Class 1133 ADHESIVES, 3 II -
containing flammable
liquid
IATA-DGR Class 1133 ADHESIVES, 3 II -
containing flammable
liquid
PG* : Packing group
15 . Regulatory information
United States
HCS Classification : Flammable liquid
Toxic material
Irritating material
Target organ effects
U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted.
TSCA precursor chemical list: 2-diethylaminoethanol
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: n-hexane; Benzene, ethenyl-, polymer
with 1,3-butadiene
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
Titebond Solvent Based FRP Adhesive: Fire hazard, Immediate (acute) health hazard,
Delayed (chronic) health hazard
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 313
Product name CAS number Concentration
Form R - Reporting : n-hexane 110-54-3 10 - 25
requirements
Supplier notification : n-hexane 110-54-3 10 - 25
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15 . Regulatory information
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State regulations : Massachusetts Spill: None of the components are listed.
Massachusetts Substances: The following components are listed: HEXANE
New Jersey Hazardous Substances: The following components are listed: n-HEXANE
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
Pennsylvania RTK Hazardous Substances: The following components are listed:
HEXANE
Canada
WHMIS (Canada) : Class B-2: Flammable liquid
Class D-2A: Material causing other toxic effects (Very toxic).
Canadian lists : CEPA Toxic substances: None of the components are listed.
Canadian ARET: None of the components are listed.
Canadian NPRI: The following components are listed: n-Hexane
Alberta Designated Substances: None of the components are listed.
Ontario Designated Substances: None of the components are listed.
Quebec Designated Substances: None of the components are listed.
Canada inventory : Not determined.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
Mexico
Classification :
3 Flammability
Health 2 0 Reactivity
Special
International regulations
International lists : Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Chemical Weapons : Not listed
Convention List Schedule I
Chemicals
Chemical Weapons : Not listed
Convention List Schedule
II Chemicals
Chemical Weapons : Not listed
Convention List Schedule
III Chemicals
16 . Other information
Label requirements : EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY
CAUSE FLASH FIRE. HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT,
EYE AND SKIN IRRITATION. MAY BE HARMFUL IF SWALLOWED. PROLONGED
OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS
MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE.
Hazardous Material :
Information System (U.S.A.)
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16 . Other information
* 2
Health
3
Flammability
0
Physical hazards
Caution: HMIS?ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS?ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS?ratings are to be used with a fully implemented
HMIS?program. HMIS?is a registered mark of the National Paint & Coatings Association (NPCA). HMIS?br>
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of printing : 3/16/2010.
: 3/15/2010.
Date of issue
Date of previous issue : 3/11/2010.
Version :1
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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