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MATERIAL SAFETY DATA SHEET
I. IDENTIFICATION .
MANUFACTURED BY: Old Masters REVISED: 08/16/2007
1900 Albany Place SE PRINTED: 08/21/2007
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General Information:
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PRODUCT LINE: Brushing Lacquer Clear
927 Clear Wood Finish Gloss
928 Clear Wood Finish Semi-Gloss
929 Clear Wood Finish Satin
II. HAZARDOUS INGREDIENTS .
CAS #97-85-8 Isobutyl Isobutyrate (IBIB) WT %: 5-20
ACGIH TLV: ACGIH STEL:
OSHA PEL: OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: LEL%:
CAS #110-43-0 Methyl Amyl Ketone WT %: 5-20 Footnote: (1)
ACGIH TLV: 50 PPM TWA ACGIH STEL:
OSHA PEL: 100 ppm TWA OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: 2.14 mm LEL%: 1.1
CAS #108-10-1 Methyl Isobutyl Ketone WT %: 5-20 Footnote: (1)
ACGIH TLV: 50 ppm TWA ACGIH STEL: 75 ppm
OSHA PEL: 100 ppm TWA OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: 15mm Hg20C LEL%: 1.2
CAS #71-36-3 n-Butanol WT %: 5-20 Footnote: (1)
ACGIH TLV: 50 ppm SKIN ACGIH STEL: 150 ppm SKIN
OSHA PEL: 100 ppm TWA OSHA CEILING: 150 mg/m3 SKIN OSHA PEAK:
VAPOR PRESSURE: 4.4 mm LEL%: 1.45
CAS #1330-20-7 Xylene WT %: 5-20 Footnote: (1)
ACGIH TLV: 100 ppm TWA ACGIH STEL: 150 ppm
OSHA PEL: 100 ppm TWA OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: 6.6mmHg@20C LEL%: 1.0%
CAS #100-41-4 Ethyl Benzene WT %: 1-5
ACGIH TLV: 100 ppm TWA ACGIH STEL: 125 ppm
OSHA PEL: 100 ppm TWA OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: LEL%:
CAS #112-34-5 Diethylene Glycol Butyl Ether WT %: 1-5 Footnote: (1)
ACGIH TLV: N.E. ACGIH STEL:
OSHA PEL: OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: .02mmHg@20c LEL%: .9 %
CAS #78-93-3 Methyl Ethyl Ketone WT %: 1-5 Footnote: (1)
ACGIH TLV: 200 ppm TWA ACGIH STEL: 300 ppm
OSHA PEL: 200 ppm TWA OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: 83mm Hg75F LEL%: 1.8
CAS #67-63-0 Isopropyl Alcohol WT %: 1-5 Footnote: (1)
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ACGIH TLV: 400 ppm TWA ACGIH STEL: 500 ppm TWA
OSHA PEL: 400 ppm TWA OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: 33 mm LEL%: 2.0
WARNING MESSAGES:
(1) Reports have associated repeated and prolonged occupational overexposure to solvents
with permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal. Chronic exposure may
cause damage to the central nervous system, respiratory system, lung, eye, skin, liver,
gastrointestinal tract, spleen, kidneys, and blood.
(2) See Section IX for reportable Hazardous Air Pollutants.
III. PHYSICAL DATA .
BOILING RANGE: 174-308?F
EVAPORATION RATE: * slower than ether *
PERCENT VOLATILE BY VOLUME: 81.76-82.35% WEIGHT PER GALLON: 7.76-7.80 LBS
VAPOR DENSITY: * heavier than air *
ACTUAL VOC (lb/gal): 5.67-5.71
EPA VOC (lb/gal): 5.67-5.71 EPA VOC (g/L): 679.49-684.29
IV. FIRE AND EXPLOSION HAZARD DATA .
FLASH POINT: 10?C 50?F LEL: Refer to Section II
FLAMMABILITY CLASSIFICATION: CLASS 1B
HAZARD CLASSIFICATION: *Flammable Liquid
EXTINGUISHING MEDIA: *carbon dioxide, dry chemical, or fire foam*
UNUSUAL FIRE AND EXPLOSION HAZARDS: keep away from heat, sparks, and flame.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing aparatus and
protective clothing. USE WATER WITH CAUTION.
Material will float and may ignite on surface of
water. Use water spray to keep fire exposed
containers cool. Water may be ineffective in
fighting the fire.
V. HEALTH HAZARD DATA .
THRESHOLD LIMIT VALUE: See Section II.
EFFECTS OF OVEREXPOSURE:
Acute- High vapor concentrations are irritating to the eyes and the
respiratory tract, and may cause headaches, dizziness,
anesthesia, drowsiness, unconsciousness, and other central
nervous system effects, including death. Product has a low
order of acute oral and dermal toxicity, but minute amounts
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aspirated into the lungs during ingestion or vomiting may cause
mild to severe pulmonary injury and possibly death.
Chronic- Xylene contains ethylbenzene which has been classified as a
possible carcinogen to humans, Group 2B, by the International
Agency for Research on Cancer(IARC), based on sufficient
evidence in laboratory animals but inadequate evidence for
cancer in humans. Prolonged or repeated overexposure to
ethylbenzene may cause the following: kidney effects, liver
effects, lung effects, thyroid effects, testicular effects,
pituitary effects.
MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: consult physician
PRIMARY ROUTE(S) OF ENTRY: Skin and Inhalation
EMERGENCY AND FIRST AID PROCEDURES:
INHALATION: Remove to fresh air. Restore breathing. Treat
symptomatically. Consult a physician.
EYES: Flush immediately with large amounts of water for at least
15 minutes. Talk to a physician for medical treatment.
SKIN: Wipe off with towel. Wash with soap and water. Remove
contaminated clothing.
INGESTION: If swallowed, call a physician immediately. Remove
stomach contents by gastric suction or induce vomiting only
as directed by a medical personnel. Never give anything by
mouth to an unconscious person.
VI. REACTIVITY DATA .
STABILITY: *stable* HAZARDOUS POLYMERIZATION: *will not occur*
INCOMPATIBILITY: Material can react violently with strong oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS: Fire, burning and welding may generate
carbon monoxide.
CONDITIONS TO AVOID: Fire, burning, and welding.
VII. SPILL OR LEAK PROCEDURES .
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Remove all sources of ignition (flames, hot surfaces and
electrical, static or frictional sparks). Avoid breathing
vapors. Ventilate area. Use non-sparking tools. Remove with
inert absorbant.
WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and
federal regulations.
VIII. SPECIAL PROTECTION INFORMATION .
RESPIRATORY PROTECTION: In confined areas of poor ventilation, use chemical
cartridge respirator or self-contained breathing
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apparatus.
VENTILATION: Provide general dilution or local exhaust ventilation in
volume and pattern to keep TLV and LEL of most hazardous
ingredient in Section II, below acceptable limit.
PROTECTIVE GLOVES: None required except for prolonged contact.
EYE PROTECTION:
Splash proof eye goggles. In emergency situations, use eye
goggles with a full face shield.
OTHER PROTECTIVE EQUIPMENT: *none*
HYGIENIC PRACTICES: See Section V
IX. SPECIAL PRECAUTIONS .
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Do not store near heat, sparks, or flame.
OTHER PRECAUTIONS: * none *
LIST OF HAZARDOUS AIR POLLUTANTS SUBJECT TO THE PROVISIONS OF THE CLEAN AIR
ACT, TITLE I SECTION 112 'National Emission Standards for Hazardous Air
Pollutants':
Wt% of HAPS Pounds HAPS/
Ingredient CAS # in product Gal product
------------------------------ ------------ ----------- ----------
Xylene 1330-20-7 14.2 % 1.1
Methyl Isobutyl Ketone 108-10-1 11.7 % 0.9
Diethylene Glycol Butyl Ether 112-34-5 4.9 % 0.4
Ethyl Benzene 100-41-4 1.1 % 0.1
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