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64-17-5 67-63-0 108-10-1

File Name: 64-17-5_67-63-0_108-10-1.asp

                                                                     Material Safety Data Sheet 1
Thermoplastic Comfort Systems, Inc
TCS Cement

Section 1 ?General Information

Date of MSDS: December 3, 2004

Product Identification: TCS Cement HMIS Rating
Company Name: Thermoplastic Comfort Systems, Inc HEALTH: 1
Company Address: 2075 E. 27th Street FLAMMABILITY: 3
Signal Hill, CA 90755 REACTIVITY: 0
United States of America
General Information Telephone: (562)-426-2970
Emergency Telephone: Not required by regulations.

Section 2 ?Hazardous Ingredients

Hazardous Component CAS# OSHA PEL ACGIH
TLV

Ethyl Alcohol 64-17-5 1000 ppm 1000 ppm
Isopropyl Alcohol 67-63-0 400 ppm 200 ppm
Methy1 Isobutyl Ketone 108-10-1 100 ppm 50 ppm

Section 3 ?Hazard Identification

Emergency Overview: This material is cloudy beige colored liquid coating used to secure teeth
in denture model. It has an alcohol type order and flashpoint of 60deg
F.
Primary Routes of Exposure: Inhalation
Potential Acute Health Effects:
Eye: May cause eye irritation
Skin: May cause skin irritation
Ingestion: May be harmful if swallowed
Inhalation: Vapors may be irritating to eyes and respiratory tract. May cause CNS
depression.
Potential Chronic Health Effects:
Signs and Symptoms: Chronic exposures may result in irritation to mucous membranes,
headache, drowsiness, CNS depression, and /or liver damage.

Section 4 ?First Air Measures

Eye Contact: Flush eyes with water for at least 15 minutes
Skin Contact: Wash with soap and water
Ingestion: If the person is conscious and able to swallow have them drink water to
dilute. Call a poison control center, physician, or emergency room.
Inhalation: If exposed to excessive levels of vapor or mist, remove to fresh air. Seek
medical attention if cough or other symptoms develop.


Section 5 璅ire Fighting Measures


Flash Point(method): 60 deg. F
Extinguishing Media: Use dry chemicals, "alcohol resistant" foam, or carbon dioxide.
Water may be ineffective but water applied as a spray can absorb
some of the fire's heat and should be used to keep fire-exposed
containers cool.

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Distributor: Imperial Trading Ltd. (800) 733-7490 www.imperialdental.net
Material Safety Data Sheet 2
Thermoplastic Comfort Systems, Inc
TCS Cement
Protection of Firefighters: As in any fire, wear self-contained breathing apparatus pressure
demand, NIOSH and full protective gear. Evacuate area and fight
fire from safe distance.
Fire and Explosion Hazards: Vapors may form explosive mixture with air


Section 6 ?Accidental Release Measures

Personal Precautions: Avoid skin contact. Avoid breathing vapors. Wash hands before eating.

Clean Up Methods: Keep unnecessary people away. Remove all sources of ignition. Dike and
contain spill with inert material (sand, earth, etc.) and transfer liquid to containers for recovery
or disposal. Keep spill out of sewer and open bodies of water. Floors may be slippery: care
should be exercised to avoid falls. Avoid runoff into storm sewers and ditches that lead to
waterways.


Section 7 ?Handling and Storage

Handling: Keep away from heat, spark and flame. Keep operating temperatures below
ignition temperatures at all times. Use with adequate ventilation. Avoid contact with eyes, skin
and clothing.

Storage: Store away from heat. Keep away from heat, sparks and flame. Keep containers
tightly closed and upright when not in use. Protect against physical damage.

Section 8 ?Exposure Controls / Personal Protection

Engineering Controls: Use general room dilution ventilation, process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below recommended
exposure limits.

Personal Protective Equipment (PPE):
Eye Protection: Where contact is likely, wear chemical slash goggles and/or full-face
shield.

Skin Protections: Where contact is likely, wear chemical resistant gloves and protective
clothing to prevent skin contact.

Respiratory Protection: Where vapor levels exceed allowable exposure limits, wear a
NIOSH approved air purifying respirator with an organic vapor cartridge.

General Hygiene Practices: Avoid eye and skin contact. Avoid breathing vapors. Wash hands
before eating and drinking. Do not smoke while using this material.

Section 9 ?Physical Data

Appearance: Cloudy beige liquid Odor: Alcohol type odor
Physical State:Liquid pH: 4.5 - 5.5
Boiling Point: 173 deg F* Melting/Freezing Point: N/A
Vapor Pressure: 40mm/Hg* Vapor Density: 1.59
Odor Threshold: N/D Viscosity: 25 ?300 cps
Specific Gravity (water=1) .89 Autoignition Temp: 685 deg F*
*based on pure ethyl alcohol.


\\\DC - 99852/0001 - 1653977 v1

Distributor: Imperial Trading Ltd. (800) 733-7490 www.imperialdental.net
Material Safety Data Sheet 3
Thermoplastic Comfort Systems, Inc
TCS Cement
Section 10 璖tability and Reactivity

Stability: Stable, non-reatictive
Hazardous Polymerization: Will not occur
Hazardous Decomposition Products: Carbon monoxide during incomplete combustion.
Conditions to Avoid: Heat, sparks, flames.
Imcompatibility: Oxidizing agents

Section 11 ?Toxicological Information


Carcinocenicity: This material is not considered a carcinogen by IARC or NTP and is not
regulated as a carcinogen by OSHA.


Section 12 ?Ecological information


Chemical Fate and Effects: No data available


Section 13 ?Disposal Considerations


RCRA Hazardous Waste: This material, when discarded or disposed of, could be a hazardous
waste according to federal regulations (40 CFR 261) due to the characteristics of ignitability
(D001). The transportation, storage, treatment, and disposal of this waste must be conducted
in compliance with 40 CFR 262,263,264,268 and 270. Disposal can only occur in properly
permitted facilities. Check state and local regulations for any additional requirements as these
may be more restrictive than federal laws and regulations. Chemical additions, processing or
otherwise altering this material may make the waste management information presented in
this MDSD incomplete, inaccurate, or otherwise inappropriate.

Section 14 ?Transportation Information

Regulated by the US DOT: Yes
DOT Proper Shipping Name: Paint
UN/NA Number: UN 1263

Section 15 ?Transportation Information

CERCLA:
The Comprehensive Environmental Response Compensation and Liability Act of 1980
(CERCLA) requires notification to the National Center for releases of quantities of Hazardous
Substances equal or greater than the reportable quantities (RQs) in 40 CFR 302.4 (for CERCLA
102).

Components present in this product at a level which could require reporting under the statute
are:
Chemical Name CAS# Maximum Concentration (Wt.%)
None N/A N/A

SARA Title III, section 311/312:
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
emergency planning based on Threshold Planning Quanitities (TPQs) and release reporting
based on Reportable Quantities (RQs) in 40 CFR 355 (used for SARA 302,604,311 and 312)
\\\DC - 99852/0001 - 1653977 v1

Distributor: Imperial Trading Ltd. (800) 733-7490 www.imperialdental.net
Material Safety Data Sheet 4
Thermoplastic Comfort Systems, Inc
TCS Cement

Components present in this product at a level which could require reporting under the statute
are:
Chemical Name CAS# Maximum Concentration (Wt.%)
None N/A N/A

SARA Title III, section 313:
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA
313).

Components present in this product at a level which could require reporting under the statute
are:
Chemical Name CAS# Maximum Concentration (Wt.%)
Methy1 Isobutyl 108-10-1 1%

TSCA:
The components of this mixture are listed in the Yoxic Substance Control Act Inventory of
Chemical Substances.

This Product contains the following chemicals which export notification under section 12(b) of
the TSCA regulation.

Chemical Name CAS# TSCA Section
Isopropanol 67-63-0 Sec 4
Methy1 isobutyl ketone 108-10-1 Sec 4

Section 16 ?Other Information

Legend: N/A: Not Applicable
N/D: Not Determined
N/E Not Established
STEL: Short Term Exposure Limit
Cps: Centipoise
Mppcf: million particles per cubic foot or air.
PPB: Parts per Billion
TLV: Threshold Limit Value
ACGIH: American Conference of Governmental Industrial Hygienists
CPSC: Consumer Product Safety Commission
DOT: US Dept. of Transportation
FHSA: Federal Hazardous Substance Act
OSHA: Occupational Safety and Health Administration (US dept. of Labor)
RCRA: Resource Conservation and Recovery Act
SARA: Superfund Amendment and Reauthorization Act
Skin: This substance has the potential to be absorbed systemically through the
skin.
TSCA: Toxic Substance Control Act


NOTICE
All information, recommendations and suggestions appearing herein concerning this product
are based upon data obtained from the manufacturer and/or recognized technical sources;
however, Thermoplastic Comfort System, Inc. makes no warranty, representation or guarantee
as to the accuracy, sufficiency, or completeness of the material set forth herein. It is the user's
responsibility to determine the safety, toxicity and suitability of his/her own use, handling and
disposal of the product. Since actual use by others is beyond our control, no warranty,
\\\DC - 99852/0001 - 1653977 v1

Distributor: Imperial Trading Ltd. (800) 733-7490 www.imperialdental.net
Material Safety Data Sheet 5
Thermoplastic Comfort Systems, Inc
TCS Cement
expressed or implied, is made by Thermoplastic Comfort System, Inc. as to the effects of such
use. Thermoplastic Comfort System, Inc. does not assume any liability arising out of use by
others of the product referred to herein. The data in this Material Safety Data Sheet relate only
to the specific material designated herein and does not relate to use in combination with any
other material.




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Distributor: Imperial Trading Ltd. (800) 733-7490 www.imperialdental.net

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