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SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: FLEXANE FL-10 PRIMER
HMIS
15980
Stock No.:
Manufacturer Name: ITW Devcon
Address: 30 Endicott Street
Health Hazard 2*
Danvers, MA 01923
Fire Hazard 3
MSDS Revision Date: 10/10/2006
REACTIVITY 1
Emergency telephone number (800) 424-9300
Personal
X
Protection
* Chronic Health
Effects:
In the US, call CHEMTREC: (800) 424-9300
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SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS#
Phenolic Resin 9003-35-4 5 - 10 by Weight
Methyl Isobutyl Ketone 108-10-1 30 - 60 by Weight
Ethanol 64-17-5 1 - 5 by Weight
Toluene 108-88-3 10 - 30 by Weight
Isopropanol 67-63-0 10 - 30 by Weight
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SECTION 3: HAZARDS IDENTIFICATION
Emergency Overview: WARNING! Flammable. Irritant.
Primary Routes of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye Contact: Can cause moderate irritation, burning sensation, tearing, redness, and swelling.
Overexposure may cause lacrimation, conjunctivitis, corneal damage and
permanent injury.
Skin Contact: Can cause skin irritation; itching, redness, rashes, hives, burning, and swelling.
Inhalation: Respiratory tract irritant. High concentration may cause dizziness, headache, and
anesthetic effects.
Ingestion: Causes irritation, a burning sensation of the mouth, throat and gastrointestinal
tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe reddening,
swelling, and possible tissue destruction
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs: Eyes. Skin. Respiratory system. Digestive system. Kidney Central nervous
system.
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Conditions: sensitization may be more susceptible to the effects of this product.
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SECTION 4: FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure
adequate flushing of the eyes by separating the eyelids with fingers. Get
immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while
removing contaminated clothing and shoes. Get medical attention if irritation
develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give
oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.
Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested.
Provide a glass of water to dilute the material in the stomach. If vomiting occurs
naturally, have the person lean forward to reduce the risk of aspiration.
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SECTION 5: FIRE FIGHTING MEASURES
Flammable Properties : Flammable.
Auto Ignition Temp : Not determined.
Flash Point: 55癋 (12.7癈)
Flash Point Method: Tag closed cup (TCC)
Lower Explosive Limit (LEL) 1.3%
Upper Explosive Limit (UEL) 8.0%
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire space
without full protective gear. If possible, contain fire run-off water.
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SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering
the spill area.
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical
waste container. Provide ventilation. Collect spill with a non-sparking tool. Place
into a suitable container for disposal. Clean up spills immediately observing
precautions in the protective equipment section. After removal, flush spill area
with soap and water to remove trace residue.
Flammable, eliminate ignition sources. Vapors can form an ignitable mixture with
air. Vapors can flow along surfaces to distant ignition sources and flash back.
Ventilate area. Use proper personal protective equipment as listed in section 8.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Other Precautions: Pump or shovel to storage/salvage vessels.
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SECTION 7: HANDLING AND STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Material
will accumulate static charges which may cause an electrical spark (ignition
source). Use proper grounding procedures. Do not reuse containers without
proper cleaning or reconditioning.
Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible
materials, direct sunlight, and incompatible substances. Keep container tightly
closed when not in use.
Hygiene Practices: Wash thoroughly after handling.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
products (see Section 10) during welding/flame cutting operations and to protect
against dust during sanding/grinding of cured product. Hazardous liquid or vapor
residue may remain in emptied container. Do not reuse, heat, burn, pressurize,
cut, weld, braze, solder, drill, grind, expose to sparks, flame, or ignition sources
of empty containers without proper commercial cleaning or reconditioning.
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SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Good general ventilation should be sufficient to
control airborne levels. Where such systems are not effective wear suitable
personal protective equipment, which performs satisfactorily and meets OSHA or
other recognized standards. Consult with local procedures for selection, training,
inspection and maintenance of the personal protective equipment.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin
contact. Consult manufacturer's data for permeability data.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR
1910.133, OSHA eye and face protection regulation, or the European standard
EN 166.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by
air purifying respirators is limited. Use a positive pressure air supplied respirator
if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators may not
provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash
and a deluge shower safety station.
Methyl Isobutyl Ketone:
Guideline ACGIH : ACGIH TLV-STEL 75 ppm
Guideline OSHA : OSHA PEL-TWA 100 ppm
Ethanol:
Guideline ACGIH : ACGIH TLV-TWA 1000 ppm
Guideline OSHA : OSHA PEL-TWA 1000 ppm
Toluene:
Guideline ACGIH : ACGIH TLV-TWA 50 ppm
Guideline OSHA : OSHA PEL-TWA 200 ppm
Isopropanol:
Guideline ACGIH : ACGIH TLV-TWA 200 ppm
Guideline OSHA : OSHA PEL-TWA 400 ppm
Notes : Only established PEL and TLV values for the ingredients are listed below.
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical State/Appearance: Liquid.
Color: blue
Odor: Solvent.
Boiling Point: 195癋 (90.5癈)
Melting / Freezing Point : Not determined.
Solubility: Approximately. 35%
Specific Gravity: 0.87
pH: Approximately 7 @ 5 Percent Solution
Vapor Density: >1 (air = 1)
Vapor Pressure: 13 mmHg @68癋
Molecular Formula: Mixture
Molecular Weight: Mixture
Percent Volatile: 80
VOC Data : 640 g/L
Percent Solids by Weight 20
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SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions. Heating resin above 300 F in the presence of air may cause
slow oxidative decomposition.
Incompatibilities with Other Oxidizing agents. Strong acids and alkalis.
Materials:
Hazardous Polymerization: Not reported.
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SECTION 11: TOXICOLOGICAL INFORMATION
Phenolic Resin:
Skin Effects: Skin - Rat LD50: >2 gm/kg - [Details of toxic effects not reported other than
lethal dose value ](RTECS)
Skin - Human TCLo - Lowest published toxic concentration: 1 pph - [Skin and
Appendages - dermatitis, allergic (after topical exposure) ](RTECS)
Ingestion Effects: Oral - Rat LD50: >5 gm/kg - [Details of toxic effects not reported other than
lethal dose value ] (RTECS)
Methyl Isobutyl Ketone:
Eye Effect: Eye - Rabbit Standard Draize Test : 100 uL/24H - [Moderate ](RTECS)
Skin Effects: Skin - Rabbit Standard Draize Test : 500 mg/24H - [mild](RTECS)
Skin - Rabbit LD - Lethal dose: >3 gm/kg - [Details of toxic effects not reported
other than lethal dose value ](RTECS)
Inhalation Effects: Inhalation - Rat LC50: 100 gm/m3 - [Details of toxic effects not reported other
than lethal dose value] (RTECS)
Inhalation - Mouse LC50: 23300 mg/m3 - [Details of toxic effects not reported
other than lethal dose value] (RTECS)
Inhalation - Mouse LC50: 23300 mg/m3 - [Brain and Coverings - increased
intracranial pressure Lungs, Thorax, or Respiration - other changes Liver - fatty
liver degeneration ] (RTECS)
Ingestion Effects: Oral - Rat LD50: 4600 mg/kg - [Brain and Coverings - increased intracranial
pressure Liver - fatty liver rat Blood - changes in spleen ] (RTECS)
Oral - Mouse LD50: 1900 mg/kg - [Details of toxic effects not reported other
than lethal dose value ] (RTECS)
Oral - Mouse LD50: 2850 mg/kg - [Brain and Coverings - increased intracranial
pressure Liver - fatty liver rat Blood - changes in spleen ] (RTECS)
Ethanol:
Eye Effect: Eye - Rabbit Rinsed with water : 100 mg/4S - [Moderate ](RTECS)
Skin Effects: Skin - Rabbit Standard Draize Test : 20 mg/24H - [Moderate](RTECS)
Skin - Rabbit LDLo: 20 gm/kg - [Details of toxic effects not reported other than
lethal dose value ](RTECS)
Inhalation Effects: Inhalation - Rat LC50: 20000 ppm/10H - [Details of toxic effects not reported
other than lethal dose value] (RTECS)
Inhalation - Mouse LC50: 39 gm/m3/4H - [Details of toxic effects not reported
other than lethal dose value] (RTECS)
Ingestion Effects: Oral - Rat LD50: 7 gm/kg - [Details of toxic effects not reported other than lethal
dose value ] (RTECS)
Oral - Mouse LD50: 3450 mg/kg - [Details of toxic effects not reported other
than lethal dose value ] (RTECS)
Toluene:
Eye Effect: Eye - Human Standard Draize Test : 300 ppm(RTECS)
Skin Effects: Skin - Rabbit Standard Draize Test : 20 mg/24H - [Moderate](RTECS)
Skin - Rabbit LD50: 14100 uL/kg - [Details of toxic effects not reported other
than lethal dose value ](RTECS)
Inhalation Effects: Inhalation - Rat LC50: 49 gm/m3/4H - [Details of toxic effects not reported other
than lethal dose value] (RTECS)
Inhalation - Mouse LC50: 400 ppm/24H - [Details of toxic effects not reported
other than lethal dose value] (RTECS)
Inhalation - Mouse LC50: 30000 mg/m3/2H - [Details of toxic effects not
reported other than lethal dose value] (RTECS)
Inhalation - Mouse LC50: 19900 mg/m3/7H - [Details of toxic effects not
reported other than lethal dose value] (RTECS)
Inhalation - Mouse LC50: 10000 mg/m3 - [Behavioral - somnolence (general
depressed activity) ] (RTECS)
Ingestion Effects: Oral - Rat LD50: 636 mg/kg - [Details of toxic effects not reported other than
lethal dose value ] (RTECS)
Isopropanol:
Eye Effect: Eye - Rabbit Standard Draize Test : 100 mg/24H - [Moderate](RTECS)
Skin Effects: Skin - Rabbit Standard Draize Test : 500 mg - [mild ](RTECS)
Skin - Rabbit LD50: 12800 mg/kg - [Details of toxic effects not reported other
than lethal dose value ](RTECS)
Inhalation Effects: Inhalation - Rat LC50: 72600 mg/m3 - [Behavioral - general anesthetic Lungs,
Thorax, or Respiration - other changes ] (RTECS)
Inhalation - Mouse LC50: 53000 mg/m3 - [Behavioral - general anesthetic
Lungs, Thorax, or Respiration - other changes ] (RTECS)
Ingestion Effects: Oral - Rat LD50: 5000 mg/kg - [oral - general anesthetic ] (RTECS)
Oral - Mouse LD50: 3600 mg/kg - [oral - altered sleep time (including change in
righting reflex) oral - somnolence (general depressed activity) ] (RTECS)
Oral - Mouse LD50: 3600 mg/kg - [oral - general anesthetic ] (RTECS)
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SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
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SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
RCRA Number : D001
Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may
spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool or
waste in a sealed, water-filled, metal con
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SECTION 14: TRANSPORT INFORMATION
DOT Shipping Name: Flammable liquids, n.o.s.
DOT UN Number: 1993
DOT Hazard Class: 3
DOT Packing Group: II
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SECTION 15: REGULATORY INFORMATION
WHMIS Pictograms
Methyl Isobutyl Ketone:
TSCA Inventory Status Listed
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 606-004-00-4
Ethanol:
TSCA Inventory Status Listed
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 603-002-00-5
Toluene:
TSCA Inventory Status Listed
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 601-021-00-3
Isopropanol:
TSCA Inventory Status Listed
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 603-003-00-0
Canadian Regulations. WHMIS Hazard Class(es): B2; D2B; D2A
All components of this product are on the Canadian Domestic Substances List.
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SECTION 16: ADDITIONAL INFORMATION
HMIS Health Hazard: 2*
HMIS Fire Hazard: 3
HMIS Reactivity: 1
HMIS Personal Protection: X
MSDS Revision Date: 10/10/2006
Disclaimer: "This Health and Safety Information is correct to the best of our knowledge and
belief at the date of its publication but we cannot accept liability for any loss,
injury or damage which may result from its use. The information given in the
Data Sheet is designed only as a guidance for safe handling, storage and the use
of the substance. It is not a specification nor does it guarantee any specific
properties. All chemicals should be handled only by competent personnel, within
a controlled environment."
Copyright?1996-2007 Actio Software Corporation. All Rights Reserved.
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