Safety Data Sheet
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name: 876-LINE DULUX QUIT RUST SPRAYPAK ENAMEL
Recommended Use: Aerosol spray paint. Packed under pressure.
Supplier: Dulux Australia, a division of DuluxGroup (Australia) Pty Ltd
ABN: 67 000 049 427
Street Address: 1956 Dandenong Road,
Clayton, Victoria
Australia
Telephone Number: +61 3 9263 5678
Facsimile: +61 3 9263 5777
Emergency Telephone: 1 800 033 111 (ALL HOURS)
2. HAZARDS IDENTIFICATION
This material is hazardous according to criteria of Safe Work Australia; HAZARDOUS SUBSTANCE.
Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for Transport by
Road and Rail; DANGEROUS GOODS.
Risk Phrases: Extremely Flammable. Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin. Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Safety Phrases: Keep away from sources of ignition - No Smoking. Do not breathe vapour. Avoid
contact with skin and eyes. Do not empty into drains. Take precautionary measures
against static discharges.
Poisons Schedule: None allocated.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS Number Proportion Risk Phrases
Propellant (propane/butane) - 10-<30% R12
Xylene 1330-20-7 1-<10% R10 R20/21 R38
Ingredients determined not to be hazardous - to 100% -
Cyclohexanone 108-94-1 1-<10% R10 R20
Methyl isobutyl ketone 108-10-1 1-<10% R11 R20 R36/37 R66
n-Butyl alcohol 71-36-3 1-<10% R10 R22 R37/38 R41
R67
Acetone 67-64-1 30-60% R11 R36 R66 R67
Methyl ethyl ketone 78-93-3 1-<10% R11 R36/37 R66 R67
Propylene glycol monomethyl ether acetate 108-65-6 10-<30% R10, R36
Toluene 108-88-3 1-<5% R11 R38 R48/20 R63
R65 R67
Ethyl alcohol 64-17-5 1-<10% R11
Product Name: 876-LINE DULUX QUIT RUST SPRAYPAK Issued: 15/09/2008
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Safety Data Sheet
4. FIRST AID MEASURES
For advice, contact a Poisons Information Centre (e.g. phone Australia 131 126; New Zealand 0800 764 766) or a doctor.
Inhalation:
Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing and loosen remaining
clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. If patient
finds breathing difficult and develops a bluish discolouration of the skin (which suggests a lack of oxygen in the blood -
cyanosis), ensure airways are clear of any obstruction and have a qualified person give oxygen through a face mask.
Apply artificial respiration if patient is not breathing. Seek immediate medical advice. Seek immediate medical advice.
Skin Contact:
If skin or hair contact occurs, immediately remove any contaminated clothing and wash skin and hair thoroughly with
running water. A component of this material can be absorbed through the skin with resultant toxic effects. Seek immediate
medical assistance.
Eye Contact:
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by
a Poisons Information Centre or a doctor, or for at least 15 minutes.
Ingestion:
If swallowed, do NOT induce vomiting. Give a glass of water. Seek immediate medical assistance.
Medical attention and special treatment:
Treat symptomatically.
5. FIRE FIGHTING MEASURES
Hazards from combustion products:
Flammable gas. On burning will emit toxic fumes, including those of oxides of carbon .
Precautions for fire fighters and special protective equipment:
Keep containers cool with water spray. Fire fighters to wear self-contained breathing apparatus and suitable protective
clothing if risk of exposure to vapour or products of combustion.
Suitable Extinguishing Media:
Fine water spray, normal foam, dry agent (carbon dioxide, dry chemical powder).
Hazchem Code: 2YE
6. ACCIDENTAL RELEASE MEASURES
Methods and materials for containment and clean up:
Shut off all possible sources of ignition. In the event of an aerosol can developing a leak, allow to fully discharge in the
open air before disposal.
7. HANDLING AND STORAGE
Conditions for safe storage:
Store in cool place and out of direct sunlight. Store away from oxidising agents. Store away from sources of heat or
ignition. Keep containers closed when not in use - check regularly for leaks.
Product Name: 876-LINE DULUX QUIT RUST SPRAYPAK Issued: 15/09/2008
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Safety Data Sheet
Precautions for safe handling:
Keep out of reach of children. Avoid skin and eye contact. Ensure spray nozzle is always directed away from the user.
May form flammable vapour mixtures with air. All potential sources of ignition (open flames, pilot lights, furnaces, spark
producing switches and electrical equipment etc) must be eliminated both in and near the work area. Do NOT smoke.
Flameproof equipment is necessary in all areas where this chemical is being used. Nearby equipment must be earthed.
Vapour may travel a considerable distance to source of ignition and flash back.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits: No value assigned for this specific material by the National Occupational Health and
Safety Commission. However, Exposure Standard(s) for constituent(s):
Acetone: 8hr TWA = 1185 mg/m3 (500 ppm), 15 min STEL = 2375 mg/m3 (1000 ppm)
Butane: 8hr TWA = 1900 mg/m3 (800 ppm)
n-Butyl alcohol: Peak Limitation = 152 mg/m3 (50 ppm), Sk
Cyclohexanone: 8hr TWA = 100 mg/m3 (25 ppm), Sk
Ethyl alcohol: 8hr TWA = 1880 mg/m3 (1000 ppm)
1-Methoxy-2-propanol acetate: 8hr TWA = 274 mg/m3 (50 ppm), 15 min STEL = 548 mg/m3 (100 ppm), Sk
Methyl ethyl ketone (MEK): 8hr TWA = 445 mg/m3 (150 ppm), 15 min STEL = 890 mg/m3 (300 ppm)
Methyl isobutyl ketone: 8hr TWA = 205 mg/m3 (50 ppm), 15 min STEL = 307 mg/m3 (75 ppm)
Propane: Asphyxiant
Toluene: 8hr TWA = 191 mg/m3 (50 ppm), 15 min STEL = 574 mg/m3 (150 ppm), Sk
Xylene (o-, m-, p- isomers): 8hr TWA = 350 mg/m3 (80 ppm), 15 min STEL = 655 mg/m3 (150 ppm)
As published by the National Occupational Health and Safety Commission.
TWA - The time-weighted average airborne concentration over an eight-hour working day, for a five-day working week
over an entire working life.
STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should not be
exceeded at any time during a normal eight hour work day. According to current knowledge this concentration should
neither impair the health of, nor cause undue discomfort to, nearly all workers.
Peak Limitation - a ceiling concentration which should not be exceeded over a measurement period which should be as
short as possible but not exceeding 15 minutes.
Asphyxiant - gases which can lead to reduction of oxygen concentration by displacement or dilution. The minimum
oxygen content in air should be 18% by volume under normal atmospheric pressure.
`Sk' Notice - absorption through the skin may be a significant source of exposure. The exposure standard is invalidated if
such contact should occur.
These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These exposure standards should not be used as fine
dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity.
Product Name: 876-LINE DULUX QUIT RUST SPRAYPAK Issued: 15/09/2008
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Substance No: 000000022007 Version: 1
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Safety Data Sheet
Engineering controls:
Use in well ventilated areas. Vapour heavier than air - prevent concentration in hollows or sumps. DO NOT enter
confined spaces where vapour may have collected. Keep containers closed when not in use.
Personal Protective Equipment:
Orica Personal Protection Guide No.1,1998: NOT IN USE
No special personal protective equipment required. Always wash hands before smoking, eating, drinking or using the
toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Aerosol
Colour: Coloured
Odour: Solvent
Solubility: Soluble in organic solvents. Insoluble in water.
Specific Gravity: 0.8-0.9 approx.
Relative Vapour Density (air=1): >1
Vapour Pressure (20 癈): N Av
Flash Point (癈): -104 (propane)
Flammability Limits (%): 2.4-9.5 (propane)
Autoignition Temperature (癈): N Av
% Volatile by Volume: N Av
Solubility in water (g/L): Insoluble
Melting Point/Range (癈): N App
Boiling Point/Range (癈): N Av
Decomposition Point (癈): N Av
pH: N App
Viscosity: N Av
Evaporation Rate: N Av
10. STABILITY AND REACTIVITY
Chemical stability: Stable under normal conditions of use.
Conditions to avoid: Avoid exposure to heat, sources of ignition, and open flame. Avoid exposure to direct
sunlight.
Incompatible materials: Incompatible with oxidising agents.
Hazardous decomposition Oxides of carbon.
products:
Hazardous reactions: None known.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product
label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
Product Name: 876-LINE DULUX QUIT RUST SPRAYPAK Issued: 15/09/2008
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Safety Data Sheet
Ingestion: Swallowing can result in nausea, vomiting and central nervous system depression. If
the victim is showing signs of central system depression (like those of drunkeness)
there is greater likelihood of the patient breathing in vomit and causing damage to
the lungs. Breathing in vomit may lead to aspiration pneumonia (inflammation of the
lung).
Eye contact: An eye irritant.
Skin contact: Contact with skin will result in irritation. Will have a degreasing action on the skin.
Repeated or prolonged skin contact may lead to irritant contact dermatitis.
Component/s of this material can be absorbed through the skin with resultant toxic
effects.
Inhalation: Material may be irritant to the mucous membranes of the respiratory tract (airways).
Breathing in vapour can result in headaches, dizziness, drowsiness, and possible
nausea. Breathing in high concentrations can produce central nervous system
depression, which can lead to loss of co-ordination, impaired judgement and if
exposure is prolonged, unconsciousness. Intentional misuse by deliberately
concentrating and breathing the contents can be harmful or fatal.
Long Term Effects:
No information available for the product. However, for the solvent component (toluene) (1): Evidence indicates that
repeated or prolonged exposure to this chemical could result in central nervous system disorders.
Toxicological Data: No LD50 data available for the product. For the constituent Toluene (1):
Oral LD50 (rat): 636 mg/kg
Dermal LD50 (rabbit): 14100 uL/kg
12. ECOLOGICAL INFORMATION
Ecotoxicity Avoid contaminating waterways.
13. DISPOSAL CONSIDERATIONS
Disposal methods:
Do not puncture or burn can when empty; contents are under pressure. If aerosol can develops a leak, allow to fully
discharge before disposal. Normally suitable for disposal at approved land waste site.
14. TRANSPORT INFORMATION
Road and Rail Transport
Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for Transport by
Road and Rail; DANGEROUS GOODS.
FLAMMABLE
GAS
2
UN No: 1950
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Safety Data Sheet
Class-primary 2.1 Flammable Gas
Proper Shipping Name: AEROSOLS
Hazchem Code: 2YE
Marine Transport
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for
transport by sea; DANGEROUS GOODS.
FLAMMABLE
GAS
2
UN No: 1950
Class-primary: 2.1 Flammable Gas
Proper Shipping Name: AEROSOLS
Air Transport
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods
Regulations for transport by air; DANGEROUS GOODS.
FLAMMABLE
GAS
2
UN No: 1950
Class-primary: 2.1 Flammable Gas
Proper Shipping Name: AEROSOLS, FLAMMABLE
15. REGULATORY INFORMATION
Classification: This material is hazardous according to criteria of Safe Work Australia;
HAZARDOUS SUBSTANCE.
Hazard Category: Xn: Harmful
Xi: Irritant
Risk Phrase(s): R12: Extremely Flammable.
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
R36/38: Irritating to eyes and skin.
R66: Repeated exposure may cause skin dryness or cracking.
R67: Vapours may cause drowsiness and dizziness.
Safety Phrase(s): S16: Keep away from sources of ignition - No smoking.
S23: Do not breathe vapour/mist/aerosol.
S24/25: Avoid contact with skin and eyes.
S29: Do not empty into drains.
S33: Take precautionary measures against static discharges.
Product Name: 876-LINE DULUX QUIT RUST SPRAYPAK Issued: 15/09/2008
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Substance No: 000000022007 Version: 1
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Safety Data Sheet
Poisons Schedule: None allocated.
All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION
(1) Material Safety Data Sheet; 07/ 2004.
Reason(s) for Issue:
First Issue Primary MSDS
This safety data sheet has been prepared by SH&E Shared Services.
This SDS summarises to our best knowledge at the date of issue, the chemical health and safety hazards of the material
and general guidance on how to safely handle the material in the workplace. Since DuluxGroup Limited cannot anticipate
or control the conditions under which the product may be used, each user must, prior to usage, assess and control the
risks arising from its use of the material.
If clarification or further information is needed, the user should contact their DuluxGroup representative or DuluxGroup
Limited at the contact details on page 1.
DuluxGroup Limited's responsibility for the material as sold is subject to the terms and conditions of sale, a copy of which
is available upon request.
Product Name: 876-LINE DULUX QUIT RUST SPRAYPAK Issued: 15/09/2008
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Substance No: 000000022007 Version: 1
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