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SUPERSEDES: NEW
MATERIAL SAFETY DATA SHEET
STANDARD TOP COAT - EPOXY
IDENTIFICATION AND EMERGENCY INFORMATION
Product Name: Devran 224HS (N Formula)
Supplier - Pulsafeeder Inc., 2883 Brighton-Henrietta Town Line Road, Rochester, NY 14623,
(585)292-8000
Emergency Telephone - (800) 545-2643
HAZARDS IDENTIFICATION (ANSI Section 3)
Primary route(s) of exposure: Inhalation, skin contact, eye contact, ingestion.
Effects of overexposure:
Inhalation: Irritation of respiratory tract. Prolonged inhalation may lead to
mucous membrane irritation, fatigue, drowsiness, dizziness and/or
lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, gastro-intestinal
disturbances, abdominal pain, chest pain, blurred vision, coughing, choking, difficulty with
speech, apathy, central nervous system depression, intoxication, tightness of chest,
metallic taste, anesthetic effect or narcosis, difficulty of breathing, allergic response, fever
and chills, dehydration, tremors, abnormal blood pressure, liver damage, kidney damage,
pulmonary edema, pneumoconiosis, loss of consciousness, cyanosis, respiratory failure,
asphyxiation, death. Possible sensitization to respiratory tract.
Skin contact: Irritation of skin. Prolonged or repeated contact can cause dermatitis,
defatting, blistering, allergic response, severe skin irritation, or burns. Possible
sensitization to skin.
Eye contact: Irritation of eyes. Prolonged or repeated contact can cause conjunctivitis,
blurred vision, tearing of eyes, severe eye irritation, severe eye irritation or burns,
corneal injury.
Ingestion: Ingestion may cause lung inflammation and damage due to aspiration of
material into lungs, mouth and throat irritation, mucous membrane irritation, drowsiness
and/or lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, gastro-
intestinal disturbances, abdominal pain, visual disturbances, apathy, central nervous
system depression, intoxication, anesthetic effect or narcosis, difficulty of breathing,
burns of the mouth, throat, stomach, liver damage, pulmonary edema, convulsions, loss
of consciousness, respiratory failure, death.
Medical conditions aggravated by exposure: Eye, skin, respiratory disorders
FIRST-AID MEASURES (ANSI Section 4)
Inhalation: Remove to fresh air. Restore and support continued breathing. Get
emergency medical attention. Have trained person give oxygen if necessary. Get medical
help for any breathing difficulty. Remove to fresh air if inhalation causes eye watering,
headaches, dizziness, or other discomfort.
Skin contact: Wash thoroughly with soap and water. If any products remain, gently rub
petroleum jelly, vegetable or mineral/baby oil onto skin. Repeated applications may be
needed. Remove contaminated clothing. Wash contaminated clothing before re-use.
Dispose of contaminated leather items, such as shoes and belts. If irritation occurs,
consult a physician.
Eye contact: Flush immediately with large amounts of water, especially under lids for at
least 15 minutes. If irritation or other effects persist, obtain medical treatment.
Ingestion: If swallowed, obtain medical treatment immediately.
FIRE-FIGHTING MEASURES (ANSI Section 5)
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SUPERSEDES: NEW
Fire extinguishing media: Dry chemical or foam water fog. Carbon dioxide. Closed
containers may exploded when exposed to extreme heat or fire. Vapors are heavier than
air and may travel long distances to a source of ignition and flash back. Vapors can form
explosive mixtures in air at elevated temperatures. Closed containers may burst if
exposed to extreme heat or fire. May decompose under fire conditions emitting irritant
and/or toxic gases.
Fire fighting procedures: Water may be used to cool and protect exposed containers.
Firefighters should use full protective clothing, eye protection, and self-contained
breathing apparatus. Self-contained breathing apparatus recommended.
Hazardous decomposition or combustion product: Carbon monoxide, carbon dioxide,
oxides of nitrogen, acrid fumes, oxides of sulfur, aldehydes, toxic gases, barium
compounds, smoke and soot. Cyanides.
ACCIDENTAL RELEASE MEASURES (ANSI Section 6)
Steps to be taken in case material is released or spilled: Comply with all applicable
health and environmental regulations. Eliminate all sources of ignition. Ventilate area.
Ventilate area with explosion-proof equipment. Spills may be collected with absorbent
materials. Evacuate unnecessary personnel. Place collected material in proper container.
Complete personal protective equipment must be used during cleanup. Large spills-shut
off leak if safe to do so. Dike and contain spill. Pump to storage or salvage vessels. Use
absorbent to pick up excess residue. Keep salvageable material and rinse water out of
sewers and water courses. Small spills-use absorbent to pick up residue and dispose of
properly.
HANDLING AND STORAGE (ANSI Section 7)
Handling and storage: Store below 100f (38c). Keep away from heat, sparks and open
flame.
Other precautions: Use only with adequate ventilation. Do not take internally. Keep out
of reach of children. Avoid contact with skin and eyes, and breathing of vapors. Wash
hands thoroughly after handling, especially before eating or smoking. Keep containers
tightly closed and upright when not in use. Avoid conditions which result in formation of
inhalable particles such as spraying or abrading (sanding) painted surfaces. If such
conditions cannot be avoided, use appropriate respiratory protection as directed under
exposure controls/personal protection. Empty containers may contain hazardous
residues. Ground equipment when transferring to prevent accumulation of static charge.
EXPOSURE CONTROLS/PERSONAL PROTECTION (ANSI Section 8)
Respiratory protection: Control environmental concentrations, below applicable
exposure standards when using this material. When respiratory protection is determined
to be necessary, use a NIOSH/MSHA (Canadian z94.4). Approved elastomeric sealing-
surface facepiece respirator outfitted with organic vapor cartridges and paint spray
(dust/mist) prefilters. Determine the proper level of protection by conducting appropriate
air monitoring. Consult 29CFR1910.134 for selection of respirators (Canadian z94.4).
Ventilation: Provide dilution ventilation or local exhaust to prevent build-up of vapors.
Use explosion proof equipment.
Personal protective equipment: Eye wash, safety shower, safety glasses or goggles.
Impervious gloves, impervious clothing, face shield, apron, boots.
STABILITY AND REACTIVITY (ANSI Section 10)
Under normal conditions: Stable see section 5 fire fighting measures
Material to avoid: Oxidizers, acids, reducing agents, bases, aldehydes, amines, nitric
acid, phosphorous, lewis acids, mineral acids.
Conditions to avoid: Elevated temperatures, contact with oxidizing agent, storage near
acids, sparks, open flame, ignition sources.
Hazardous polymerization: Will not occur may polymerize in presence of aliphatic
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SUPERSEDES: NEW
amines.
TOXICOLOGICAL INFORMATION (ANSI Section 11)
Supplemental health information: Contains a chemical that is moderately toxic by
ingestion. Contains a chemical that is readily absorbed through skin. Contains a chemical
that may be absorbed through skin. Notice- reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal. Other effects of overexposure may include toxicity to
liver, kidney, central nervous system, blood.
Carcinogenicity: Inhalation of non-asbestiform cosmetic grade talc for 2 years at 6 and
18 mg/m3 produced clear evidence of carcinogenicity in female rats (lung and adrenal
tumors) and some evidence of carcinogenicity in male rats (adrenal tumors). No evidence
of carcinogenicity was demonstrated in male and female mice under the same conditions.
Microscopic examination of the lungs of rats and mice exposed to talc revealed additional
exposure related effects primarily associated with the inflammatory response. Contains
crystalline silica which is considered a hazard by inhalation. IARC has classified
crystalline silica as carcinogenic to humans (group 1).Crystalline silica is also a known
cause of silicosis as a known human carcinogen. The international agency for research
on cancer (IARC) has classified carbon black as possibly carcinogenic to humans
(groups 2b) based on sufficient evidence in animals and inadequate evidence in humans.
The international agency for research on cancer (IARC) has evaluated ethylbenzene and
classified it as a possible human carcinogen (group 2b) based on sufficient evidence for
carcinogenicity in experimental animals, but inadequate evidence for cancer exposed
humans. In a 2 year inhalation study conducted by the national toxicology program
(NTP), ethylbenzene vapor at 750 ppm produced kidney and testicular tumors in rats and
lung and liver tumors in mice. Genetic toxicity studies showed no genotoxic effects. The
relevance of these results to humans is not known.
Reproductive effects: High exposures to xylene in some animal studies, often at
maternally toxic levels, have affected embryo/fetal development. The significance of this
finding is not known.
Mutagenicity: No mutagenicity effects are anticipated
Teratogenicity: No teratogenic effects are anticipated
ECOLOGICAL INFORMATION (ANSI Section 12)
No ecological testing has been done by ICI paints on this product as a whole.
DISPOSAL CONSIDERATIONS (ANSI Section 13)
Waste disposal: Dispose in accordance with all applicable regulations. Avoid discharge
to natural waters.
REGULATORY INFORMATION (ANSI Section 14)
As of the date of this MSDS, all of the components in this product are listed (or
are otherwise exempt from listing) on the TSCA inventory. This product has been
classified in accordance with the hazard criteria of the CPR (controlled products
regulations) and the MSDS contains all the information required by the CPR.
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SUPERSEDES: NEW
Physical Data (ANSI Sections 1,9, and 14)
Product Description Wt./ VOC % Volatile Flas Boiling HMIS Dot, proper
Code Gal. Gr./ltr. by Volume h Point shipping name
Point
224FN253 Devran 224hs high build 12.74 244.23 29.25 100f 241- *220 Paint,
1 epoxy coating-in gray 355 combustible
base liquid, UN 1263,
PGIII
224FN253 Devran 224hs high build 12.76 243.51 29.18 100f 241- *220 Paint,
4 epoxy coating-medium 355 combustible
gray base liquid, UN 1263,
PGIII
224FN290 Devran 224hs high build 12.75 244.59 29.30 100f 241- *220 Paint,
4 epoxy coating-haze gray 355 combustible
base liquid, UN 1263,
PGIII
224FN350 Devran 224hs high build 13.07 247.82 29.72 100f 241- *220 Paint,
1 epoxy coating-white base 355 combustible
liquid, UN1263
PGIII
224FN950 Devran 224hs high build 11.86 264.60 31.73 100f 241- *320 Paint,
1 epoxy coating deep tint 415 combustible
base liquid, UN1263,
PGIII
224FN950 Devran 224hs high build 10.85 272.39 32.67 100f 241- *320 Paint,
2 epoxy coating neutral tint 415 combustible
base liquid, UN1263,
PGIII
224GN090 Devran 224hs high build 11.70 241.35 28.03 100f 277- *320 Paint,
8 epoxy coating-converter 415 combustible
liquid, UN1263.
PGIII
Ingredients Product Codes with % by Weight (ANSI Section 2)
Chemical Common CAS. 224FN25 224FN25 224FN29 224FN35 224FN95 224FN95 224GN09
Name Name No. 31 34 04 01 01 02 08
Benzene, Ethylbenze 100- .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0
ethyl- ne 41-4
2- Methyl 108- 1-5 1-5 1-5 1-5 5-10 5-10
pentanone, isobutyl 10-1
4-methyl ketone
1,3,5- 1,3,5- 108- .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 1-5 .1-1.0
trimethylbe trimethylbe 67-8
zene zene
1,2,ethana Triethylene 112- 1-5
diamine,n,n tetramine 24-3
'-bis(2-
aminoethyl)
-
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Chemical Common CAS. 224FN25 224FN25 224FN29 224FN35 224FN95 224FN95 224GN09
Name Name No. 31 34 04 01 01 02 08
Antigorite Antigorite 1213 1-5 1-5 1-5 1-5 1-5 1-5 1-5
5-86-
3
Benzene, Xylene 1330 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 1-5 1-5
dimethyl -20-7
Carbon Carbon 1333 .1-1.0 .1-1.0
black black -86-4
Titanium Titanium 1346 5-10 5-10 5-10 10-20 10-20
oxide oxide 3-67-
7
Tremolite, Tremolite 1456 5-10 5-10 5-10 5-10 5-10 5-10 5-10
nonasbestif 7-73-
orm 8
Talc Talc 1480 5-10 5-10 5-10 1-5 1-5 1-5 1-5
7-96-
6
Quartz Quartz 1480 10-20 10-20 10-20 10-20 10-20 10-20 5-10
8-60-
7
Oxirane,2,2 Diglycidyl 1675 10-20 10-20 10-20 10-20 10-20 20-30
'-(((1- ether of -54-3
methylethyl bisphenol a
idene) bis
(4,1-
phenyleneo
xymethylen
e)))bis-
Anthophyllit Anthophyllit 1706 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0
e, e 8-78-
nonasbestif 9
orm
Aluminum 21645-51-2 1-5 1-5
hydroxide
Phenol,4,4' Epoxy 2503 10-20 10-20 10-20 10-20 10-20 20-30
-(1- resin 6-25-
methylethyl 3
idene)bis-
,polymer
with 2,2'-
((1-
methylethyl
idene)bis(4
,1-
phenyleneo
xymethylen
e))bis(oxira
ine)
Solvent Light 6474 1-5 1-5 1-5 1-5 1-5 1-5 5-10
naphtha aromatic 2-95-
solvent 6
naphtha
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Chemical Common CAS. 224FN25 224FN25 224FN29 224FN35 224FN95 224FN95 224GN09
Name Name No. 31 34 04 01 01 02 08
Fatty acids, Polyamide 6841 20-30
c18- resin 0-23-
unsatd.,dim 1
mers,
reaction
products
with
polyethylen
epolyamine
s
Silica Barium 7663 1-5 1-5 1-5 1-5
sulfate 1-86-
9
Sulfuric Barium 7727 20-30
acid, sulfate -43-7
barium salt
Benzene,1, Pseudocu 95- 1-5 1-5 1-5 1-5 1-5 1-5 5-10
2,4- mene 63-6
trimethyl-
Castor oil Rheologivc Sup. 1-5
dericative al additive Conf.
Chemical Hazard Data (ANSI Section 2, 8, 11, and 15)
Common CAS. 8-Hour STE C S 8- STE C S S. S S C H M N I O
Name No. TWA L Hour L R. 2 3 C
TWA Std
.
Ethylbenze 100- 100 125 NA NA 100 NA NA NA NA N Y Y Y N N Y N
ne 41-4 ppm ppm ppm
Methyl 108- 50 ppm 75 NA NA 100 NA NA NA NA N Y Y Y N N N N
isobutyl 10-1 ppm ppm
ketone
1,3,5 108- 25 ppm 35 NA NA NA NA NA NA NA N N N N N N N N
Triethylben 67-8 ppm
zene
Triethylene 112- NA NA NA NA NA NA NA NA NA N N N N N N N N
tetramine 24-3
Antigorite 12135- NA NA NA NA NA NA NA NA NA N N N N N N N N
86-3
Xylene 1330- 100 150 NA NA 100 NA NA NA NA N Y Y Y N N N N
20-7 ppm ppm ppm
Carbon 133- 3.5 NA NA NA 3.5 NA NA NA NA N N N N N N Y N
Black 86-4 mg/m3 mg/m
3
Titanium 13463- 10 NA NA NA 10 NA NA NA NA N N N N N N N N
dioxide 67-7 mg/m3 mg/m
3
Tremolite 14567- NA NA NA NA NA NA NA NA NA N N N N N N N N
73-8
Talc 14807- 2 NA NA NA NA NA NA NA NA N N N N N N N N
96-6 mg/m3
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Quartz 14808- .05 NA NA NA .01 NA NA NA NA N N N N N Y Y N
60-7 mg/m3 mg/m
3
Diglycidyl 1675- NA NA NA NA NA NA NA NA NA N N N N N N N N
ether of 54-3
bisphnol a
Anthophyllit 17068- NA NA NA NA NA NA NA NA NA N N N N N N N N
e 78-9
Aluminum 21645- 10 NA NA NA 5 NA NA NA NA N N N N N N N N
hydroxide 51-2 mg/m3 mg/m
3
Epoxy 25036- NA NA NA NA NA NA NA NA NA N N N N N N N N
resin 25-3
Light 64742- NA NA NA 50 NA NA NA NA NA N N N N N N N N
aromatic 95-6 0x
solvent pp
naphtha m
Polyamide 68410- NA NA NA NA NA NA NA NA NA N N N N N N N N
resin 23-1
n-butanol 71-36- 20 ppm NA NA NA 100 NA NA NA NA N Y Y N N N N N
3 mg/m
3
Amorphous 7631- 10 NA NA NA 6 NA NA NA NA N N N N N N N N
silica 86-9 mg/m3 mg/m
3
Barium 7727- 10 NA NA NA 5 NA NA NA NA N N N N N N N N
sulfate 43-7 mg/m3 mg/m
3
4- 84852- NA NA NA NA NA NA NA NA NA N N N N N N N N
nonylpheno 15-3
l, branched
Pseudocu 95-63- 25 ppm NA NA NA NA NA NA NA NA N Y N N N N N N
mene 6
Rheologica Sup.Co NA N NA NA NA NA NA NA NA N N N N N N N N
l additive nf.
Footnotes:
C=ceiling-Concentration that should not be exceeded, even instantaneously.
S= Skin-Additional exposure, over and above airborn exposure, may result from skin
absorption.
N/a=not applicable
NA = not established
CC= CERCLA Chemical
PPM= parts per million
Mg/m3=milligrams per cubic meter
Sup Conf= supplier Confidential
S2=Sara Section 302 EHS
S3= Sara Section 313 Chemical
S. R. Std.=Supplier Recommended Standard
H=Hazardous Air Pollutant
M=Marine Pollutant
P=Pollutant
S=Severe Pollutant
Carcinogenicity Listed By:
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N=NTP, I=IARC, O=OSHA, Y=YES, N=NO
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