The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification
Product ID: 451.0020488.076
Product Name: 020488 VOLVO GRAY 6U
Product Use: Paint product.
Print date 09/Feb/2006
Revision Date 04/Feb/2006
Company Identification
The Valspar Corporation - Architectural Coatings Division
1000 Lake Road
Medina, OH 44256
Manufacturer's Phone: 1-330-725-4511
24-Hour Medical Emergency 1-888-345-5732
Phone:
2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Product ID: 451.0020488.076
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Common Name Approx. Chemical name
CAS-No. Weight %
DIMETHYL KETONE 40 - 45 ACETONE
67-64-1
PROPANE 10 - 15 Propane
74-98-6
BUTANE 5 - 10 Butane
106-97-8
METHYL ETHYL KETONE 1-5 Methyl ethyl ketone
78-93-3
METHYL ISOBUTYL 1-5 Methylisobutyl ketone
KETONE
108-10-1
TOLUENE 1-5 Toluene
108-88-3
PROPRIETARY PIGMENT 1-5 PROPRIETARY PIGMENT
XYLENE 1-5 Xylenes (o-, m-, p- isomers)
1330-20-7
ETHYL 3- 1-5 Ethyl 3-ethoxypropionate
ETHOXYPROPIONATE
763-69-9
ACETIC ACID ESTER 1-5 Hexanol, acetate, branched and linear
88230-35-7
PROPRIETARY RESIN 1-5 PROPRIETARY RESIN
BUTYLBENZYL 1-5 Butyl benzyl phthalate
PHTHALATE
85-68-7
ISOPROPYL ALCOHOL 1-5 Isopropyl alcohol
67-63-0
ETHYLBENZENE .1 - 1 Ethyl benzene
100-41-4
If this section is blank there are no hazardous components per OSHA guidelines.
3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache,
nausea or respiratory irritation.
Eye Contact:
Corneal Injury/eye damage. Causes eye irritation.
Skin Contact:
May cause moderate skin irritation.
Product ID: 451.0020488.076
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Acute Ingestion:
May be harmful if swallowed.
Other Effects:
May cause central nervous system depression. May cause kidney damage. May cause liver damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be
harmful or fatal. May cause eye damage and pain. Prolonged and/or repeated contact can result in skin irritation.
May cause skin drying with prolonged exposure. Possible birth defects hazard. Contains ingredients which may
cause birth defects based on animal data. May cause liver damage. May cause kidney damage.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.
4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean
contaminated shoes.
Ingestion:
If swallowed, contact medical personnel immediately to determine best course of action.
Medical conditions aggravated by exposure: Any respiratory or skin condition.
5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit): -31?F ( -35?C) TCC/PM
Lower explosive limit: 1%
Upper explosive limit: 16 %
Autoignition temperature: Not available. ?F ( ?C)
Sensitivity to impact: No.
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding
and grounding information in Section 7.
Hazardous combustion products: See Section 10.
Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire. Firefighters should be equipped with self-
contained breathing apparatus and turn out gear.
Product ID: 451.0020488.076
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6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5,
"Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition.
Remove with inert absorbent and non sparking tools. Avoid contact with eyes.
7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees
F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with
OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue,
including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must
be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above
the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing
or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected
equipment are properly bonded and grounded at all times.
8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all
exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an
air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature
to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's
instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate
ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Product ID: 451.0020488.076
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Common Name Approx. TWA (final) Ceilings limits (final) Skin designations
CAS-No. Weight %
DIMETHYL KETONE 40 - 45 2400 mg/m?1000 ppm
67-64-1
PROPANE 10 - 15 1800 mg/m?1000 ppm
74-98-6
METHYL ETHYL KETONE 1-5 590 mg/m?200 ppm
78-93-3
METHYL ISOBUTYL 1-5 410 mg/m?100 ppm
KETONE
108-10-1
TOLUENE 1-5 200 ppm 300 ppm
108-88-3
PROPRIETARY PIGMENT 1-5 15 mg/m? Total dust.
XYLENE 1-5 435 mg/m?100 ppm
1330-20-7
ISOPROPYL ALCOHOL 1-5 980 mg/m?400 ppm
67-63-0
ETHYLBENZENE .1 - 1 435 mg/m?100 ppm
100-41-4
ACGIH Threshold Limit Value (TLV's)
Common Name Approx. TWA STEL Ceiling limits Skin
CAS-No. Weight % designations
DIMETHYL KETONE 40 - 45 500 ppm 750 ppm
67-64-1
PROPANE 10 - 15 1000 ppm
74-98-6
BUTANE 5 - 10 1000 ppm
106-97-8
METHYL ETHYL KETONE 1-5 200 ppm 300 ppm
78-93-3
METHYL ISOBUTYL 1-5 50 ppm 75 ppm
KETONE
108-10-1
TOLUENE 1-5 50 ppm Can be absorbed
108-88-3 through the skin.
PROPRIETARY PIGMENT 1-5 10 mg/m?br>
XYLENE 1-5 100 ppm 150 ppm
1330-20-7
ISOPROPYL ALCOHOL 1-5 200 ppm 400 ppm
67-63-0
ETHYLBENZENE .1 - 1 100 ppm 125 ppm
100-41-4
If this section is blank, no information is available.
9. PHYSICAL PROPERTIES
Odor: Normal for this product type.
Physical State: Liquid
pH: Not determined.
Vapor pressure: NOT DETERMINED mmHG @ 68?F ( 20?C)
Product ID: 451.0020488.076
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Vapor density (air = 1.0): 5
Boiling point: -42?F ( -41?C)
Solubility in water: Not determined.
Coefficient of water/oil distribution: Not determined.
Density (lbs per US gallon): 6.54
Specific Gravity .78
Evaporation rate (butyl acetate = 1.0): 5.6
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid: None known.
Incompatibility: Strong oxidizers.
Hazardous Polymerization: None anticipated.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide.
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding
and grounding information in Section 7.
11. TOXICOLOGICAL INFORMATION
Mutagens:
Common Name Approx. Calif- Prop. 65. Developmental California Prop 65 - reproductive
CAS-No. Weight % Toxicity male
TOLUENE 1-5 Listed: January 1, 1991
108-88-3 Developmental toxin.
Teratogens:
Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient
evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name Approx. IARC Group 1 - Human IARC Group 2A - limited IARC Group 2b -
CAS-No. Weight % Evidence human data sufficient animal data
ETHYLBENZENE .1 - 1 Monograph 77, 2000
100-41-4
Product ID: 451.0020488.076
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Common Name Approx. NTP Known NTP Suspect NTP Evidence of
CAS-No. Weight % carcinogens carcinogens carcinogenicity
TOLUENE 1-5 MALE RAT - NO
108-88-3 EVIDENCE; FEMALE
RAT - NO EVIDENCE;
MALE MICE - NO
EVIDENCE; FEMALE
MICE - NO EVIDENCE.
BUTYLBENZYL 1-5 (PB83-118398: male
PHTHALATE rat-inadequate; female
85-68-7 rat-positive; male mice-
negative; female mice-
negative); (PB98-
131089: male rat-some
evidence; female rat-
equivocal evidence)
ETHYLBENZENE .1 - 1 male rat-clear evidence;
100-41-4 female rat-some
evidence; male mice-
some evidence; female
mice-some evidence
Common Name Approx. OSHA Select OSHA Possible select ACGIH Carcinogens
CAS-No. Weight % carcinogens carcinogens
ETHYLBENZENE .1 - 1 Group A3 Confirmed
100-41-4 animal carcinogen with
unknown relevance to
humans.
If this section is blank, no information is available.
12. ECOLOGICAL DATA
Not available at this time.
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name: CONSUMER COMMODITY ORM-D
UN ID Number: CONCOM
49 CFR Hazardous Material Regulations Parts 100-180
The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain
combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to
determine if the use of these exceptions applies to your shipments when re-shipping our products.
International Air Transport Association:
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1
UN ID Number: UN1950
International Maritime Organization:
Product ID: 451.0020488.076
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Proper Shipping Name: AEROSOLS
Hazard Class: 2
UN ID Number: UN1950
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
Common Name Approx. SARA 302 SARA 313 CERCLA RQ IN LBS.
CAS-No. Weight %
DIMETHYL KETONE 40 - 45 5000
67-64-1
METHYL ETHYL KETONE 1 - 5 5000
78-93-3
METHYL ISOBUTYL 1-5 form R reporting required 5000
KETONE for 1.0% de minimis
108-10-1 concentration
TOLUENE 1-5 form R reporting required 1000
108-88-3 for 1.0% de minimis
concentration
XYLENE 1-5 form R reporting required 100
1330-20-7 for 1.0% de minimis
concentration
BUTYLBENZYL 1-5 100
PHTHALATE
85-68-7
ETHYLBENZENE .1 - 1 form R reporting required 1000
100-41-4 for 1.0% de minimis
concentration
SARA 311/312 Hazard Class:
Acute: Yes
Chronic: Yes
Flammability: Yes
Reactivity: No
Sudden Pressure: Yes
U.S. STATE REGULATIONS:
Pennsylvania Right To Know:
PROPANE 74-98-6
ISOPROPYL ALCOHOL 67-63-0
DIMETHYL KETONE 67-64-1
METHYL ETHYL KETONE 78-93-3
BUTYLBENZYL PHTHALATE 85-68-7
ACETIC ACID ESTER 88230-35-7
PROPRIETARY RESIN Trade Secret
ETHYL 3-ETHOXYPROPIONATE 763-69-9
BUTANE 106-97-8
METHYL ISOBUTYL KETONE 108-10-1
TOLUENE 108-88-3
XYLENE 1330-20-7
PROPRIETARY PIGMENT Trade Secret
Additional Non-Hazardous Materials
SUPPLIER TRADE SECRET Trade Secret
Product ID: 451.0020488.076
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California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or
other reproductive harm.
Rule 66 status of product Not photochemically reactive.
INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory: All components of this product are in compliance with U.S.
TSCA Chemical Substance Inventory Requirements.
Canada Domestic Substances List: Not all components in this product are listed on the
Domestic Substances List.
16. OTHER INFORMATION
HMIS Codes
Health: 2
Flammability: 4
Reactivity: 1
PPE: X - See Section 8 for Personal Protective Equipment (PPE).
Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer,
NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH -
American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management
District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International
Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established,
N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams
per liter, MM - Millimeters, MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per
thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time
Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance,
this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this
information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES,
EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT.
VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only
remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at
our option. This MSDS contains additional information required by the state of Pennsylvania.
Product ID: 451.0020488.076
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