Page : 1
SAFETY DATA SHEET Revised edition no : 2
Date : 7 / 11 / 2007
Supersedes : 23 / 2 / 2006
PERBIO CHOC RTU I3030
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N
N : Dangerous for
the environment
1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
: PERBIO CHOC RTU
Trade name
: Insecticide.
Type of product
Responsible for placing on the market : LODI
Parc d'Activit閟 des Quatre Routes
35390 GRAND FOUGERAY France
Email contact: regulatory@lodi.fr
: NPIS 0121 5078 4123 BIRMINGHAM CENTRE
Emergency phone nr
BNPC 00 33 3 83 32 36 36 NANCY FRANCE
2 HAZARDS IDENTIFICATION
: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
Dangerous product
environment.
: Not expected to present a significant inhalation hazard under anticipated conditions
- Inhalation
of normal use.
: Repeated exposure to this material can result in absorption through skin.
- Skin contact
: Must not come into contact with food or be consumed.
- Ingestion
3 COMPOSITION / INFORMATION ON INGREDIENTS
: This product is hazardous.
Components / Impurities
Substance name Contents CAS No EC No Index No Classification
: 5 g/l 7696-12-0 231-711-6 ----- N; R50-53
Tetram閠hrine
: 5 g/l 52645-53-1 258-067-9 613-058-00-2 Xn; R20/22
permethrin
R43
N; R50-53
: < 40 g/l 51-03-6 ----- ----- N; R50-53
Piperonyl butoxide
: < 1.5 % 107-98-2 203-539-1 603-064-00-3 R10
1-Methoxy-2-propanol
: < 0.5 % 1589-47-5 216-455-5 603-106-00-0 R10
2-methoxypropanol
Repr. Cat. 2; R61
Xi; R37/38-41
4 FIRST AID MEASURES
: Assure fresh air breathing.
- Inhalation
: Wash skin with mild soap and water.
- Skin contact
: Rinse with water.
- Eye contact
: Rinse mouth. Seek medical advice (show the label where possible).
- Ingestion
5 FIRE-FIGHTING MEASURES
: All extinguishing media can be used.
Extinguishing media
: Use water spray or fog for cooling exposed containers.
Surrounding fires
: Do not enter fire area without proper protective equipment, including respiratory
Protection against fire
protection.
: Avoid (reject) fire-fighting water to enter environment.
Special procedures
LODI
Parc d'Activit閟 des Quatre Routes 35390 GRAND FOUGERAY France
Email contact: regulatory@lodi.fr
Page : 2
SAFETY DATA SHEET Revised edition no : 2
Date : 7 / 11 / 2007
Supersedes : 23 / 2 / 2006
PERBIO CHOC RTU I3030
5 FIRE-FIGHTING MEASURES (continued)
Exercise caution when fighting any chemical fire.
6 ACCIDENTAL RELEASE MEASURES
: Equip cleanup crew with proper protection.
Personal precautions
: Notify authorities if product enters sewers or public waters. Prevent entry to sewers
Environmental precautions
and public waters. Toxic to aquatic life.
: Sweep or shovel spills into appropriate container for disposal. Use suitable disposal
Clean up methods
containers.
7 HANDLING AND STORAGE
: Avoid all unnecessary exposure.
General
: Store in dry, well-ventilated area.
Storage
: Wash hands and other exposed areas with mild soap and water before eat, drink or
Handling
smoke and when leaving work.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection
: No special respiratory protection equipment is recommended under normal
- Respiratory protection
conditions of use with adequate ventilation.
: In case of repeated or prolonged contact wear gloves.
- Hand protection
: No special clothing/skin protection equipment is recommended under normal
- Skin protection
conditions of use.
: Not required.
- Eye protection
: When using, do not eat, drink or smoke.
- Ingestion
: 1-Methoxy-2-propanol : OEL (UK)-LTEL [ppm] : 100
Occupational Exposure Limits
1-Methoxy-2-propanol : OEL (UK)-STEL [ppm] : 150
: This product contains hazardous components for the aquatic environment. Avoid
Exposure controls
release to the environment.
9 PHYSICAL AND CHEMICAL PROPERTIES
: Liquid.
Physical state at 20 癈
: Slightly yellow.
Colour
: Characteristic.
Odour
: 0.795
Density
: 8.75mm2/sec (40?C)
Viscosity
: Partial.
Solubility in water [vol/vol]
: >62癈
Flash point [癈]
10 STABILITY AND REACTIVITY
: None under normal conditions.
Hazardous reactions
: None under normal conditions.
Hazardous properties
LODI
Parc d'Activit閟 des Quatre Routes 35390 GRAND FOUGERAY France
Email contact: regulatory@lodi.fr
Page : 3
SAFETY DATA SHEET Revised edition no : 2
Date : 7 / 11 / 2007
Supersedes : 23 / 2 / 2006
PERBIO CHOC RTU I3030
11 TOXICOLOGICAL INFORMATION
: None under normal conditions.
- Inhalation
: Not regulated under the criteria of Directive 67/548/EEC.
- Dermal
: Not irritating under the criteria of Directive 67/548/EEC.
- Other
: On active ingredients:
Rat oral LD50 [mg/kg]
- Permethrin: 430mg/Kg
- Tetramethrin: > 5000mg/Kg
12 ECOLOGICAL INFORMATION
: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
Ecological effects information
environment. Avoid release to the environment.
: Tetramethrin: 0.0037mg/L
96 H-LC50 - Rainbow trout [mg/l]
: Permethrin: 0.0006mg/L
48 H-LC50 - Daphnia magna [mg/l]
13 DISPOSAL CONSIDERATIONS
: Dispose of this material and its container at hazardous or special waste collection
General
point. Dispose in a safe manner in accordance with local/national regulations. Avoid
release to the environment.
14 TRANSPORT INFORMATION
: UN3082 MATI萊E DANGEREUSE DU POINT DE VUE DE L'ENVIRONNEMENT,
Shipping name
LIQUIDE, N.S.A., 9, III (permethrin)
: LQ 7
ADR/RID
Combination packagings - Inner packaging : Maximum : 5 l
Combination packagings - Package : Maximum : 30 kg
Inner packagings placed in shrink-wrapped or stretch-wrapped trays - Inner
packaging : Maximum contents : 5 l
Inner packagings placed in shrink-wrapped or stretch-wrapped trays - Package
Maximum : 20 kg
15 REGULATORY INFORMATION
: N : Dangerous for the environment
- Symbol(s)
: R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in
- R Phrase(s)
the aquatic environment.
: S23 : Do not breathe spray.
- S Phrase(s)
S35 : This material and its container must be disposed of in a safe way.
S51 : Use only in well-ventilated areas.
S61 : Avoid release to the environment. Refer to special instructions/Safety data
sheets.
: Contains : - permethrin . May produce an allergic reaction.
Further Phrases
16 OTHER INFORMATION
Recommended uses and restrictions : See product bulletin for detailed information.
List of relevant R phrases (heading 2) : R10 : Flammable.
R20/22 : Harmful by inhalation and if swallowed.
R37/38 : Irritating to respiratory system and skin.
R41 : Risk of serious damage to eyes.
R43 : May cause sensitization by skin contact.
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
LODI
Parc d'Activit閟 des Quatre Routes 35390 GRAND FOUGERAY France
Email contact: regulatory@lodi.fr
Page : 4
SAFETY DATA SHEET Revised edition no : 2
Date : 7 / 11 / 2007
Supersedes : 23 / 2 / 2006
PERBIO CHOC RTU I3030
16 OTHER INFORMATION (continued)
R61 : May cause harm to the unborn child.
: Revision - See : *
Revision
: 7 / 11 / 2007
Print date
: None.
Further information
The contents and format of this SDS are in accordance with EEC Commission Directive 2001/58EC.
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling,
storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with
the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may not be applicable.
End of document
LODI
Parc d'Activit閟 des Quatre Routes 35390 GRAND FOUGERAY France
Email contact: regulatory@lodi.fr