Material Safety Data Sheet
Klenzmax TFC Green II
Section 1. Chemical product and company identification
: Klenzmax TFC Green II
Trade name
: Cleaning product
Product use
: Ecolab Food and Beverage
Supplier
5105 Tomken Road
Mississauga ON L4W 2X5
1-800-352-5326
: 933069-02
Code
Date of issue 06-November-2008
EMERGENCY HEALTH INFORMATION: 1-800-328-0026
Outside United States and Canada CALL 1-651-222-5352 (in USA)
Section 2. Composition, information on ingredients
Name CAS number % by weight
sodium hydroxide 1310-73-2 7 - 13
ethanol, 2,2'-iminobis-, n-tallow alkyl derivs., n-oxides 61791-46-6 3-7
xylenesulfonic acid, sodium salt 1300-72-7 3-7
dipropylene glycol methyl ether 34590-94-8 1-5
ethanol, 2-(2-ethoxyethoxy)- 111-90-0 1-5
1-methoxy-2-propanol 107-98-2 1-5
poly(oxy-1,2-ethanediyl), .alpha.-sulfo-.omega.-hydroxy-, c12-14-alkyl ethers, sodium 68891-38-3 1-5
salts
amines, coco alkyldimethyl, n-oxides 61788-90-7 0.5 - 1.5
Section 3. Hazards identification
Physical state : Liquid. [Liquid.]
Emergency : DANGER !
overview
CAUSES RESPIRATORY TRACT, DIGESTIVE TRACT, EYE AND SKIN BURNS.
Do not ingest. Do not get in eyes, on skin or on clothing. Do not breathe vapour or spray.
Use only with adequate ventilation. Keep container closed. Wash thoroughly after handling.
: Skin contact, Eye contact, Inhalation, Ingestion
Routes of entry
Potential acute health effects
Eyes : Corrosive to eyes.
Skin : Corrosive to the skin.
: Corrosive to the respiratory system.
Inhalation
: Causes burns to mouth, throat and stomach.
Ingestion
See toxicological information (section 11)
Section 4. First-aid measures
Eye contact : In case of contact, immediately flush eyes with cool running water. Remove contact lenses and
continue flushing with plenty of water for at least 15 minutes. Get medical attention
immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
Skin contact :
removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Inhalation : If inhaled, remove to fresh air. If exposed person is not breathing, give artificial respiration or
oxygen applied by trained personnel. Get medical attention immediately.
Ingestion : If material has been swallowed and the exposed person is conscious, give small quantities of
water to drink. Do not induce vomiting. Never give anything by mouth to an unconscious
person. Get medical attention immediately.
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Klenzmax TFC Green II
Section 5. Fire-fighting measures
:
Auto-ignition temperature Not available.
:
Flash point 97.7778 癈 (Closed cup)
:
Flammable limits Not available.
Hazardous thermal : Decomposition products may include the following materials:
carbon dioxide
decomposition products
carbon monoxide
sulfur oxides
metal oxide/oxides
: Use an extinguishing agent suitable for the surrounding fire.
Fire-fighting media and
Dyke area of fire to prevent runoff.
instructions
In a fire or if heated, a pressure increase will occur and the container may
burst.
Special protective equipment for : Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
fire-fighters
mode.
Risk of explosion of the product in the presence of mechanical impact: Not available.
Risk of explosion of the product in the presence of static discharge: Not available.
Section 6. Accidental release measures
Personal : Immediately contact emergency personnel. Stop leak if without risk. Use suitable protective
equipment. Keep unnecessary personnel away. Do not touch or walk through spilt material.
precautions
Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers,
precautions
waterways, soil or air).
Methods for : If emergency personnel are unavailable, contain spilt material. For small spills, add absorbent
(soil may be used in the absence of other suitable materials), scoop up material and place in a
cleaning up
sealable, liquid-proof container for disposal. For large spills, dyke spilt material or otherwise
contain it to ensure runoff does not reach a waterway. Place spilt material in an appropriate
container for disposal.
Section 7. Handling and storage
Handling : Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe vapour or spray.
Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling.
Storage : Keep out of reach of children. Keep container in a cool, well-ventilated area. Keep container
tightly closed.
Store between the following temperatures: -10 and 40癈
Section 8. Exposure controls/personal protection
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. Provide suitable facilities for quick drenching or flushing of the eyes and body in
case of contact or splash hazard.
Personal protection :
Eyes : Use chemical splash goggles. For continued or severe exposure wear a face shield over the
goggles.
Hands : Use chemical-resistant, impervious gloves.
Skin : Use synthetic apron, other protective equipment as necessary to prevent skin contact.
Respiratory : Wear appropriate respirator when ventilation is inadequate and occupational exposure limits
are exceeded.
Name Exposure limits
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Klenzmax TFC Green II
sodium hydroxide CA Alberta Provincial (Canada, 10/2006).
C: 2 mg/m?15 minute(s).
CA British Columbia Provincial (Canada, 7/2007).
STEL: 2 mg/m?15 minute(s).
CA Ontario Provincial (Canada, 3/2007).
CEV: 2 mg/m?br>
CA Quebec Provincial (Canada, 12/2006).
STEV: 2 mg/m?15 minute(s).
ACGIH TLV (United States, 1/2008).
C: 2 mg/m?br>
dipropylene glycol methyl ether CA Alberta Provincial (Canada, 10/2006). Absorbed through skin.
STEL: 909 mg/m?15 minute(s).
STEL: 150 ppm 15 minute(s).
STEL: 606 mg/m?8 hour(s).
TWA: 100 ppm 8 hour(s).
CA British Columbia Provincial (Canada, 7/2007). Absorbed through skin.
STEL: 150 ppm 15 minute(s).
TWA: 100 ppm 8 hour(s).
CA Ontario Provincial (Canada, 3/2007).
STEV: 910 mg/m?15 minute(s).
STEV: 150 ppm 15 minute(s).
TWAEV: 605 mg/m?8 hour(s).
TWAEV: 100 ppm 8 hour(s).
CA Quebec Provincial (Canada, 12/2006). Absorbed through skin.
STEV: 909 mg/m?15 minute(s).
STEV: 150 ppm 15 minute(s).
TWAEV: 606 mg/m?8 hour(s).
TWAEV: 100 ppm 8 hour(s).
ACGIH TLV (United States, 1/2008). Absorbed through skin.
STEL: 909 mg/m?15 minute(s).
STEL: 150 ppm 15 minute(s).
TWA: 606 mg/m?8 hour(s).
TWA: 100 ppm 8 hour(s).
ethanol, 2-(2-ethoxyethoxy)- CA Ontario Provincial (Canada, 3/2007). Absorbed through skin.
TWAEV: 2 mg/m?8 hour(s).
TWAEV: 0.5 ppm 8 hour(s).
1-methoxy-2-propanol CA Alberta Provincial (Canada, 10/2006).
15 min OEL: 553 mg/m?15 minute(s).
15 min OEL: 150 ppm 15 minute(s).
8 hrs OEL: 369 mg/m?8 hour(s).
8 hrs OEL: 100 ppm 8 hour(s).
CA British Columbia Provincial (Canada, 7/2007).
STEL: 75 ppm 15 minute(s).
TWA: 50 ppm 8 hour(s).
CA Ontario Provincial (Canada, 3/2007).
STEV: 550 mg/m?15 minute(s).
STEV: 150 ppm 15 minute(s).
TWAEV: 365 mg/m?8 hour(s).
TWAEV: 100 ppm 8 hour(s).
CA Quebec Provincial (Canada, 12/2006).
STEV: 553 mg/m?15 minute(s).
STEV: 150 ppm 15 minute(s).
TWAEV: 369 mg/m?8 hour(s).
TWAEV: 100 ppm 8 hour(s).
ACGIH TLV (United States, 1/2008).
STEL: 553 mg/m?15 minute(s).
STEL: 150 ppm 15 minute(s).
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Klenzmax TFC Green II
TWA: 369 mg/m?8 hour(s).
TWA: 100 ppm 8 hour(s).
Section 9. Physical and chemical properties
: Liquid. [Liquid.]
Physical state
: Green.
Colour
: Faint odour.
Odour
: 13.6 to 14 [Conc. (% w/w): 100%]
pH
: Not available.
Boiling/condensation point
: Not available.
Melting/freezing point
Relative density : 1.13 to 1.15
: Not available.
Vapour pressure
: Not available.
Vapour density
: Not available.
Odour threshold
: Not available.
Evaporation rate
Viscosity : Dynamic: 10 cP
LogKow : Not available.
: Easily soluble in the following materials: cold water and hot water.
Solubility
Section 10. Stability and reactivity
: The product is stable. Under normal conditions of storage and use, hazardous
Stability
polymerisation will not occur.
: Not available.
Conditions of instability
: Extremely reactive or incompatible with the following materials: acids.
Reactivity
Reactive or incompatible with the following materials: metals.
Slightly reactive or incompatible with the following materials: moisture.
: Under normal conditions of storage and use, hazardous decomposition products
Hazardous decomposition
should not be produced.
products
: Under normal conditions of storage and use, hazardous polymerisation will not
Hazardous polymerisation
occur.
Section 11. Toxicological information
Potential acute health effects
: Corrosive to eyes.
Eyes
: Corrosive to the skin.
Skin
: Corrosive to the respiratory system.
Inhalation
: Causes burns to mouth, throat and stomach.
Ingestion
Potential chronic health effects
Carcinogenic effects : No known significant effects or critical hazards.
NTP
Ingredient name ACGIH IARC OSHA
Not applicable.
:
Mutagenic effects No known significant effects or critical hazards.
Teratogenic effects : No known significant effects or critical hazards.
Reproductive effects : No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Sensitization to Product
Synergistic products : Not available.
(toxicologically)
Toxicity data
Ingredient name Test Route Result Species
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Klenzmax TFC Green II
dipropylene glycol methyl ether LD50 Dermal 10 mL/kg Rabbit
LD50 Oral 5.5 ml/kg Rat
ethanol, 2,2'-iminobis-, n-tallow alkyl LD50 Oral 2394 mg/kg Rat
derivs., n-oxides
sodium hydroxide LD50 Dermal >2000 mg/kg Rabbit
LD50 Dermal 1350 mg/kg Rabbit
LD50 Oral 500 mg/kg Rabbit
LD50 Oral 300 to 500 Rat
mg/kg
LDLo Oral 500 mg/kg Rabbit
1-methoxy-2-propanol LD50 Dermal 13 gm/kg Rabbit
LD50 Oral 5 gm/kg Dog
LD50 Oral 11700 mg/kg Mouse
LD50 Oral 6600 mg/kg Rat
LD50 Oral 5700 mg/kg Rabbit
LDLo Oral 3739 mg/kg Rat
LC50 Inhalation 10000 ppm Rat
ethanol, 2-(2-ethoxyethoxy)- LD50 Dermal >32 gm/kg Guinea pig
LD50 Oral 7500 mg/kg Rat
LD50 Oral 7250 mg/kg Mouse
LC50 Inhalation >5240 mg/m3 Rat
amines, coco alkyldimethyl, n-oxides LD50 Oral >2000 mg/kg Rat
: Contains material which may cause damage to the following organs: lungs, upper
Target organs
respiratory tract, central nervous system (CNS).
Section 12. Ecological information
Ecotoxicity
Ingredient name Species Period Result
ethanol, 2,2'-iminobis-, n-tallow alkyl Daphnia 48 hours Acute EC50 0.94 mg/L
derivs., n-oxides
Algae 72 hours Acute IC50 <1 mg/L
Fish 96 hours Acute LC50 1.9 mg/L
sodium hydroxide Daphnia 48 hours Acute EC50 156 mg/L
Daphnia 48 hours Acute EC50 45.4 mg/L
Daphnia 48 hours Acute EC50 40 mg/L
Fish 96 hours Acute LC50 189 mg/L
Fish 96 hours Acute LC50 72 mg/L
ethanol, 2-(2-ethoxyethoxy)- Fish 96 hours Acute LC50 26500
mg/L
Fish 96 hours Acute LC50 21400
mg/L
Fish 96 hours Acute LC50 13900
mg/L
Fish 96 hours Acute LC50 13400
mg/L
Fish 96 hours Acute LC50 >10000
mg/L
Fish 96 hours Acute LC50 9650 mg/L
amines, coco alkyldimethyl, n-oxides Daphnia 48 hours Acute EC50 8 mg/L
Daphnia 48 hours Acute EC50 4.4 mg/L
Algae 72 hours Acute EC50 <1 mg/L
Algae 72 hours Acute EC50 0.8 mg/L
Fish 96 hours Acute LC50 14 mg/L
Fish 96 hours Acute LC50 10 to 100
mg/L
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Klenzmax TFC Green II
Section 13. Disposal considerations
Waste disposal : The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements.
Consult your local or regional authorities.
Section 14. Transport information
Certain shipping modes or package sizes may have exceptions from the transport
regulations. The classification provided may not reflect those exceptions and
may not apply to all shipping modes or package sizes.
UN Classification
UN1824
UN number
SODIUM HYDROXIDE SOLUTION
Proper shipping name
8
Class
Not
applicable. Packing group II
See shipping documents for specific transportation information.
Section 15. Regulatory information
WHMIS : Class E: Corrosive material
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
Section 16. Other information
Date of issue : 06-November-2008.
Responsible name : Regulatory Affairs
1-800-352-5326
Date of previous issue : 10-October-2008.
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product
in the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.
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