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MATERIAL SAFETY DATA SHEET
Conforms to 2001/58/EC Issued: 21/03/2006
PRODUCT NAME: STARSHINE GLASS & SURFACE CLEANER
I. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME : StarShine Glass & Surface Cleaner Product Number: 313
PRODUCT USE : Water based glass & surface cleaner
MANUFACTURER : Pioneer Eclipse Corp.
P.O.BOX : 909
ADDRESS : 1 Eclipse Road, Sparta NC28675, USA
PHONE : +1 336 372 8080
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/preparation: Preparation
INFORMATION ON HAZARDOUS INGREDIENTS
Chemical Name Einecs No. Weight % CAS No. Symbol R phrases
1-Methoxy-2-Propanol 203-539-1 60-70 107-98-2 F (flammable) R10
Xi (irritant)
2-Propanol 200-661-7 10-20 67-63-0 Xi (irritant) R11
F (flammable) R36, R67
Amines, C12-18- 273-281-2 2-5 68955-55-5 Xi (irritant) R38, R41,
alkyldimethyl, N-oxides N (Dangerous R50
for the
Environment)
*See section 16 for the full text of relevant R phrases
3. HAZARDS IDENTIFICATION
Physical/chemical hazards: Flammable
Human health hazards: Flammable and irritating to skin and eyes.
Environmental hazards: On the basis of available information this material/preparation is not
expected to produce any significant adverse environmental effects when
used as directed.
4. FIRST AID MEASURES
EFFECTS AND SYMPTOMS
Inhalation: None known
Ingestion: None known
Skin contact: May be mildly irritating
Eye contact: May be mildly irritating
FIRST AID MEASURES
Inhalation: No specific measures required
Ingestion: No specific measures required
Skin contact: Immediately wash off with plenty of water. If irritation develops, get medical
attention.
Eye contact: Immediately wash out with water. If irritation develops, get medical attention.
5. FIRE FIGHTING MEASURES
Extinguishing media: Dry chemical, water spray, foam, carbon dioxide
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MATERIAL SAFETY DATA SHEET
Conforms to 2001/58/EC Issued: 21/03/2006
PRODUCT NAME: STARSHINE GLASS & SURFACE CLEANER
Hazardous combustion products: None
Unusual fire and explosion hazards: Materials can splatter above 100癈/212癋.
Special fire fighting procedures: None
6. ACCIDENTAL RELEASE MEASURES
Small spills: Absorb spill on inert material (e.g. sand, earth) and dispose of as waste material in
accordance with national and regional provisions.
Large spills: Keep spectators away. Floors may be slippery; use care to avoid falling. Dike and contain spill
with inert material (e.g. sand, earth). Transfer liquid to containers for recovery or disposal and
solid diking material to separate containers for disposal. Keep spills and cleaning runoff out of
sewers and open bodies of water.
7. HANDLING AND STORAGE
Handling: Avoid contact with skin and eyes
Storage: Storage temperature (Max. 60癈/140癋) (Min. 1癈/34癋). Keep from freezing, product may
coagulate. Keep container sealed when not in use. Keep out of reach of children.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
Exposure limit values:
Component Name:: Source / Date Value / Units Type Carcinogenic
Listing*
1-Methoxy-2- US (ACGIH)/2005 100 ppm 8 HRS / TWA. N/L
propanol 369 mg/m3
1-Methoxy-2- US (ACGIH)/2005 150 ppm 15 MIN / STEL.
propanol 553 mg/m3
2-Propanol US (ACGIH)/2005 200 ppm 8 HRS / TWA. N/L
491 mg/m3
2-Propanol US (ACGIH)/2005 400 ppm 15 MIN / STEL.
983 mg/m3
*1 = OSHA, 2 = IARC, 3 = NTP, 4 = Others, N/L = Not Listed
Exposure controls: No special ventilation requirements. Ensure adequate general ventilation.
OCCUPATIONAL EXPOSURE CONTROLS
Respiratory protection: No specific personal protection is required.
Hand protection: Rubber gloves recommended
Eye protection: Safety glasses recommended
Skin protection: If major exposure is possible, wear suitable protective clothing such as rubber
boots, apron, etc.
Environmental exposure controls: No specific environmental exposure controls required.
9. PHYSICAL AND CHEMICAL PROPERTIES
GENERAL INFORMATION
Appearance: Clear blue liquid Odour: Slight solvent odour
IMPORTANT HEALTH, SAFETY AND ENVIRONMENTAL INFORMATION
pH: 8.50 to 9.50 Boiling point/boiling range: 100癈
Flash point: 53癈 Explosive properties: None
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MATERIAL SAFETY DATA SHEET
Conforms to 2001/58/EC Issued: 21/03/2006
PRODUCT NAME: STARSHINE GLASS & SURFACE CLEANER
Oxidizing properties: Not an oxidizer Vapour pressure: Less than water
Relative density: 1.00 kg/l @ 20癈 Solubility: 100% soluble in water
Partition coefficient (n-octanol/water): Not determined Viscosity: less than 10 CPS @ 20癈
Vapour density: Greater than air Evaporation rate: Less than water
10. STABILITY AND REACTIVITY
Conditions to avoid: None known
Materials to avoid: None known
Hazardous decomposition products: None known
11. TOXICOLOGICAL INFORMATION
COMPONENT SUMMARY
1-METHOXY-2-Propanol
LD50: (Oral) Rat 5660 mg/kg
Potential Health Effects
Eye: Moderately irritating to eyes.
Skin: May cause moderate irritation to skin.
Ingestion: Causes irritation to gastrointestinal tract.
Inhalation: Slightly irritating to respiratory tract.
Chronic: May damage liver and kidneys.
CARCINOGENICITY: Not expected to occur.
2-Propanol
LD50: (Oral) Rat 5045 mg/kg
Potential Health Effects
Eye: Causes eye irritation, reddening and burns.
Skin: Causes skin irritation and burns.
Ingestion: Can cause drowsiness, unconsciousness and death.
Inhalation: Causes severe irritation to upper respiratory tract and can lead to death.
Chronic: May cause skin effects.
CARCINOGENICITY: Not expected to occur
Amines, C12-18-alkyldimethyl, N-oxides
Potential Health Effects
Eye: Severely irritating to eyes. May cause permanent damage.
Skin: Irritating to skin.
Ingestion: May cause gastrointestinal irritation including nausea and diarrhea.
Inhalation: May be irritating to respiratory system.
Chronic: None known.
CARCINOGENICITY: Not expected to occur.
PREPARATION SUMMARY
Acute Toxicity:
LD50 estimated to be greater than 5000 mg/kg.
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MATERIAL SAFETY DATA SHEET
Conforms to 2001/58/EC Issued: 21/03/2006
PRODUCT NAME: STARSHINE GLASS & SURFACE CLEANER
LOCAL EFFECTS
Skin contact: Irritating to skin upon repeated or prolonged contact.
Eye contact: Slightly irritating
Sensitization: None known
Chronic effects: None known
SPECIFIC EFFECTS
Carcinogenicity: None known
Reproductive effects: None known
Teratogenicity: None known
Mutagenicity: None known
12. ECOLOGICAL INFORMATION
Component Summary
2-Propanol
Fish low toxicity: LC/EC/IC50 > 100 mg/l
1-METHOXY-2-Propanol
Fish low toxicity: LC/EC/IC50 > 1000 mg/l
Amines, C12-18-alkyldimethyl, N-oxides
Aquatic Toxicity: fish, CL50: <1 mg/l
Also poisonous for fish and plankton in water bodies.
PREPARATION SUMMARY
Ecotoxicity: This preparation is highly soluble in water. Limited toxicity tests and models indicate
this preparation should exhibit low toxicity to aquatic organisms.
Environmental Fate: This preparation will biodegrade relatively rapidly in both soil and water, and will not
persist in the environment. Due care should be taken to avoid accidental releases to
aquatic or terrestrial systems.
Bioaccumulation: Because of this preparation's high solubility and rapid biodegradability, it is unlikely
that bioaccumulation will occur in aquatic or terrestrial systems. Models estimate
that this material will preferentially partition to water versus air or soil.
Based on available information, this preparation is not expected to produce any
significant adverse environmental effects, when used as directed.
13. DISPOSAL
Disposal of this material should be in accordance with local, regional and national regulations.
14. TRANSPORT INFORMATION
INTERNATIONAL TRANSPORTATION REGULATIONS:
UN number: UN1993
Packing group: III
LAND-ROAD/RAILWAY
Proper shipping name: Flammable, n.o.s. mixture contains isopropyl alcohol and
1-methoxy-2-propanol
ADR/RID class: 3
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MATERIAL SAFETY DATA SHEET
Conforms to 2001/58/EC Issued: 21/03/2006
PRODUCT NAME: STARSHINE GLASS & SURFACE CLEANER
30oc
ADR/RID item number:
SEA
Proper shipping name: Flammable, n.o.s. mixture contains isopropyl alcohol and
1-methoxy-2-propanol
IMDG class: 3
Medical First Aid Guide (MFAG): 330
Emergency Schedules (EmS): Fire F-E, Spillage S-E
Marine Pollutant: none
15. REGULATORY INFORMATION
NATIONAL REGULATIONS: No additional national regulations are known to the supplier.
EU REGULATIONS
Hazard Symbol:
EU Classification: Classified as Flammable according to current legislation (67/548/EEC,
1999/45/EC).
Risk phrases: See section 16.
Safety phrases: S2-Keep out of reach of children.
S7-Keep container tightly closed.
S16-Keep away from sources of ignition-No smoking.
S24/25-Avoid contact with eyes and skin.
S26-In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S28a-After contact with skin, wash immediately with plenty of water.
S37/39- Wear suitable gloves and eye/face protection.
S61-Avoid release to the environment.
EINECS Status: All ingredients are included in the EINECS inventories.
CANADA CPR Status: This product has been classified in accordance with the hazard criteria of
the Controlled Products Regulations and the MSDS contains all the
information required by the Controlled Products Regulations.
Other Data
The surfactant contained in this preparation complies with the biodegradability criteria laid down in
Regulation (EC) No. 648/2004 on detergents. Data to support this assertion are held at the disposal of the
competent authorities of the Member states and will be made available to them, at their direct request or at
the request of the detergent manufacturer.
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MATERIAL SAFETY DATA SHEET
Conforms to 2001/58/EC Issued: 21/03/2006
PRODUCT NAME: STARSHINE GLASS & SURFACE CLEANER
16. OTHER INFORMATION
Relevant R phrases
R10-Flammable.
R11-Highly flammable.
R36- Irritating to eyes.
R38-irritating to skin.
R41-Risk of serious damage to eyes.
R50-Very toxic to aquatic organisms.
R67-Vapors may cause drowsiness and dizziness.
Detergent/Cleaner labeling (89/542/EEC):
(0.2<5%) Nonionic surfactants and (<5%) Perfume.
Issued by:
Genie G Bost, Regulatory Affairs Manager
Revision Information:
21/03/2006, revision conforming to 648/2004/EC
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