Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II
SAFETY DATA SHEET
1. Identification of the preparation and of the company
Product name and/or code: SYNTEKO CLASSIC 1636/1637/1646
Chemical/technical name: Lacquer
Manufacturer: ES SADOLIN AS
TOBIASE 8
TALLINN 10147
Estonia
Tel.+ 372 6 30 52 99
Fax: +372 6 305256
es@sadolin.ee
Poison centre: 6269390, direct number 16662
Emergency telephone number: 112
Intended use: For decorative and protective treatment
2. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification: F; R11, R53
Legend: R11- Highly flammable
R53 - May cause long-term adverse effects in the aquatic environment
3. Composition/information on ingredients
Description: Mixture of substances listed below with nonhazardous additions.
Ingredient name CAS number EC number Concentration % Classification
Melamine-formaldehyde polymer 68002-25-5 -- 5-10 R53
Urea RPW formaldehyde, butylated 68002-19-7 -- 10-25 R53
Ethanol 64-17-5 200-578-6 10-25 F; R11
1-methoxypropan-2-ol 107-98-2 203-539-1 5-10 R10
1-ethoxypropan-2-ol 1569-02-4 216-374-5 1-5 R10
Formaldehyde 50-00-0 200-001-8 <0,15 Carc.Cat.3; R40
T; R23/24/25
C; R34-43
See section 16 for the full text of the R-phrases declared above.
Occupational exposure limits, if available, are listed in section 8.
See section 11 for more detailed information on health effects and symptoms.
4. First-aid measures
General: In all cases of doubt, or when symptoms persist, seek medical attention. Never
give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing
is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Give nothing by mouth. If unconscious, place in recovery
position and seek medical advice.
Ingestion: If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do not induce vomiting.
PAGE: 1/5
SAFETY DATA SHEET
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do not use solvents or thinners.
Eye contact: Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open.
5. Fire-fighting measures
SMALL FIRE: Use dry chemical powder.
Suitable:
LARGE FIRE: Use water spray or fog. Cool containers with water jet in order
to prevent pressure build-up, auto-ignition or explosion.
These products are carbon oxides (CO, CO2).
Hazardous thermal decomposition
products:
Not to be used: Water may be ineffective in extinguishing large fires.
Special protective equipment for Fire-fighters should wear appropriate protective equipment and self-contained
fire-fighters: breathing apparatus (SCBA).
Special risks: Fire will produce dense black smoke. Exposure to decomposition products may
cause a health hazard. Appropriate breathing apparatus may be required. Cool
closed containers exposed to fire with water. Do not release runoff from fire to
sewers or waterways.
6. Accidental release measures
Personal precautions: Admissibly the danger of fire. Use only in well-ventilated areas. Depending on
the size of the waste; Wear suitable protective clothing. To prevent skin
contact protective gloves should be used during the work. Splash goggles.
Environmental precautions: Keep away from heat. Keep away from sources of ignition. Stop leak if without
risk. Absorb with dry earth, sand or other non-combustible material. Prevent
entry into sewers, basements or confined areas. Dike if necessary.
Methods for cleaning up: Contain and collect spillage with non-combustible absorbent materials, e.g.
sand, earth, vermiculite, diatomaceous earth and place in container for
disposal according to local regulations (see section 13). Do not allow to enter
drains or watercourses.
7. Handling and storage
Handling Directions for Safe Handling: Avoid breathing vapour. Avoid contact with eyes,
skin, and clothing. Avoid prolonged or repeated exposure.
Electrically bond and ground metal containers to prevent static discharge when
transferring liquid.
Storage Store in accordance with current regulations for flammable goods.
Observe label precautions. Store between 0 and 25癈 in a dry, well ventilated
place away from sources of heat and open flame. Keep away from sources
ignition. Keep away from oxidizing agents, from strongly alkaline and strongly
acid materials.
No smoking. Containers which are opened must be carefully resealed and kept
upright to prevent leakage.
Do not empty into drains.
Special requirements: Post signs in storage areas to prevent smoking or striking of matches or lighters.
Do not store containers near oxidizing agents.
Recommended: Use original container. Keep container tightly closed.
8. Exposure controls/personal protection
Recommended monitoring Provide adequate ventilation. Where reasonably practicable, this should be
procedures achieved by the use of local exhaust ventilation and good general extraction. If
these are not sufficient to maintain concentrations of particulates and solvent
vapours below the OEL, suitable respiratory protection must be worn.
Exposure controls
Page: 2/5
SAFETY DATA SHEET
Occupational exposure controls: Use process enclosures, local exhaust ventilation or other engineering controls to
keep airborne levels below recommended exposure limits.
Respiratory protection: Wear appropriate respirator when ventilation is inadequate.
Hand protection: Gloves
Eye protection: Safety glasses
Skin protection: Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working
period. Ensure that eyewash stations and safety showers are close to the
workstation location.
Occupational exposure limits 18.09.2001 nr 293 (RT I 2001, 77, 460) Estonia
Substance Name CAS number Long term exposure limit Short term exposure limit (STEL) 15 minute
8 hour TWA
(ppm) (mg/m3) (ppm) (mg/m3)
Ethanol 64-17-5 500 1000 1000 1900
1-methoxypropan-2-ol 107-98-2 100 375 150 568
9. Physical and chemical properties
General information
Appearance: Liquid
Colour: Colourless
Odour: Organic solvents
Important health, safety and environmental information
pH: n.a.
Flash point ( 癈 ): 15癈
Boiling point ( 癈 ): n.a.
Explosion limits (v/v): Lower: 1% Upper: 19%
Density (kg/l): 1636, 1637: 0,98 / 1646: 0,97
VOC (g/l) 438 A+B
10. Stability and reactivity
Stability: Stable under recommended storage and handling conditions (see section 7).
Condition to avoid Keep away from heat, flames, ignition sources and incompatibles.
Materials to Avoid: Strong oxidants, alkali metals, ammonia, oxidizing agents, peroxides.
Hazardous decomposition Carbon dioxide (CO2) and carbon monoxide (CO).
products:
11. Toxicological information
There are no data available on the preparation itself. The preparation has been assessed following the conventional
method of the Danggerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See
Sections 2 and 15 for details.
Eye contact: Can cause irritation. Splashes may cause temporary pain and blurred vision.
Ingestion: Causes headaches, gastritis, intoxication, blindness and, in acute cases, death.
Inhalation: Excessive inhalation is irritating to the eyes and upper respiratory tract and can cause symptoms of
intoxication.
Prolonged exposure to high concentrations may cause drowsiness, loss of appetite and inability to concentrate.
Skin contact: Removes natural oils and fats from skin causing redness, a mild burning sensation, and irritation,
cracking or flaking.
Persons with pre-existing asthma and other respiratory conditions, skin disorders and eye problems or impaired liver
and kidney functions may be more susceptible to the effects of the substance.
Chronic exposure: Prolonged skin contact causes drying and cracking of skin. May affect liver, kidneys, gastrointestinal
Page: 3/5
SAFETY DATA SHEET
tract, blood, CNS, reproductive system and cardiovascular system.
Ethanol has been linked to birth defects in human.
12. Ecological information
There are no data available on the preparation itself.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and classified as dangerous for the enviroment: May cause long-term adverse effects in the aquatic
environment.
Additional information: This product contains 438 g/l VOC (A+B).
13. Disposal considerations
Methods of disposal: The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements.
Waste classification: 08 01 11 15.01.02 plastic packaging
(European Waste Catalogue) waste paint and varnish containing organic solvents or other dangerous
substances
15.01.02 plastic packaging
14. Transport information
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
International transport regulations
Regulatory UN number Proper Class PG* Label Additional
information shipping name information
1263 Paint product 3 II Limited quantity:
ADR/RID Class
LQ 7
EmS No: F-E, S-E
1263 Paint product 3 II
ADN Class
1263 Paint product 3 II
IMDG Class
1263 Paint product 3 II
IATA-DGR Class
PG* : Packing group
15. Regulatory information
Hazard symbol/symbols:
HIGHLY FLAMMABLE
Page: 4/5
SAFETY DATA SHEET
Risk phrases: R11 Highly flammable
R53 May cause long-term adverse effects in the aquatic environment
Safety phrases: S2 Keep out of reach of children
S16 Keep away from sources of ignition - no smoking
S23 Do not breathe vapour and spray mist
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice
S46 If swallowed, seek medical advice immediately and show this container or
label
S51 Use only in well ventilated areas
S61 Avoid release to the environment. Refer to special instructions/Safery data
sheets
Contains formaldehyde. May produce allergic reaction.
Tactile warning: Yes
16. Other information
Full text of R-phrases referred to R10 Flammable.
in sections 2 and 3: R11 Highly flammable
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R34 Causes burns
R40 Limited evidence of a carcinogenic effect
R43 May cause sensitization by skin contact
R53 May cause long-term adverse effects in the aquatic environment
Full text of classifications referred T Toxic
to in sections 2 and C Corrosive
3: F Very flammable
Version: 5
Date of issue: 01.02.2010
Date of previous issue 12.02.2009
Updated: Complement in chapter 3
Notice to reader
The information in this SDS is based on the present state of our knowledge and on current laws. The product is not to be
used for purposes other than those specified under section 1 without first obtaining written handling instructions. It is
always the responsibility of the user to take all necessary steps to fulfil the demands set out in the local rules and
legislation. The information in this SDS is meant to be a description of the safety requirements for our product. It is not to
be considered a guarantee of the product's properties.
Page: 5/5
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II
SAFETY DATA SHEET
1. Identification of the preparation and of the company
Product name and/or code: SYNTEKO HARDENER 1647
Chemical/technical name: Hardener
Manufacturer: ES SADOLIN AS
TOBIASE 8
TALLINN 10147
Estonia
Tel.+ 372 6 30 52 99
Fax: +372 6 305256
es@sadolin.ee
Poison centre: 6269390, direct number 16662
Emergency telephone number: 112
Intended use: Hardener
2. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification: F; R11
Xi; R36
Legend: R11- Highly flammable
R36- Irritating to eyes
3. Composition/information on ingredients
Substance/preparation: Preparation
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive
67/548/EEC:
CAS
Ingredient name EC number Concentration % Classification
number
Ethyl acetate 141-78-6 205-500-4 1-5 F; R11, Xi; R36, R66, R67
Ethanol 64-17-5 200-578-6 50-60 F; R11
p-Toluene sulphonic acid 104-15-4 203-180-0 10-20 Xi; R36/37/38
1-methoxypropan-2-ol 107-98-2 203-539-1 20-30 R10
1-methoxypropanol 1589-47-5 216-455-5 0,1-0,5 R10 Repr. Cat. 2;
R61 Xi; R37/38-41
See section 16 for the full text of the R-phrases declared above.
Occupational exposure limits, if available, are listed in section 8.
See section 11 for more detailed information on health effects and symptoms.
4. First-aid measures
, In all cases of doubt, or when symptoms persist, seek medical attention. Never
give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing
is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen
by trained personnel. Give nothing by mouth. If unconscious, place in recovery
position and seek medical advice.
PAGE: 1/5
SAFETY DATA SHEET
Ingestion: If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do not induce vomiting.
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do not use solvents or thinners.
Eye contact: Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open.
5. Fire-fighting measures
SMALL FIRE: Use dry chemical powder.
Suitable:
LARGE FIRE: Use water spray or fog. Cool containers with water jet in order
to prevent pressure build-up, auto-ignition or explosion.
These products are carbon oxides (CO, CO2).
Hazardous thermal decomposition
products:
Not to be used: Water may be ineffective in extinguishing large fires.
Special protective equipment for Fire-fighters should wear appropriate protective equipment and self-contained
fire-fighters: breathing apparatus (SCBA).
Special risks: Fire will produce dense black smoke. Exposure to decomposition products may
cause a health hazard. Appropriate breathing apparatus may be required. Cool
closed containers exposed to fire with water. Do not release runoff from fire to
sewers or waterways.
6. Accidental release measures
Personal precautions: Admissibly the danger of fire. Use only in well-ventilated areas. Depending
on the size of the waste; Wear suitable protective clothing. To prevent skin
contact protective gloves should be used during the work. Splash goggles.
Environmental precautions: Keep away from heat. Keep away from sources of ignition. Stop leak if
without risk. Absorb with dry earth, sand or other non-combustible material.
Prevent entry into sewers, basements or confined areas. Dike if necessary.
Methods for cleaning up: Contain and collect spillage with non-combustible absorbent materials, e.g.
sand, earth, vermiculite, diatomaceous earth and place in container for
disposal according to local regulations (see section 13). Do not allow to enter
drains or watercourses.
7. Handling and storage
Handling: Directions for Safe Handling: Avoid breathing vapour. Avoid contact with eyes,
skin, and clothing. Avoid prolonged or repeated exposure.
Electrically bond and ground metal containers to prevent static discharge when
transferring liquid.
Storage: Store in accordance with current regulations for flammable goods.
Observe label precautions. Store between 0 and 25癈 in a dry, well ventilated
place away from sources of heat and open flame. Keep away from sources
ignition. Keep away from oxidizing agents, from strongly alkaline and strongly
acid materials.
No smoking. Containers which are opened must be carefully resealed and kept
upright to prevent leakage.
Do not empty into drains.
Special requirements: Post signs in storage areas to prevent smoking or striking of matches or lighters.
Do not store containers near oxidizing agents.
Recommended: Use original container. Keep container tightly closed.
8. Exposure controls/personal protection
Recommended monitoring Provide adequate ventilation. Where reasonably practicable, this should be
procedures achieved by the use of local exhaust ventilation and good general extraction. If
these are not sufficient to maintain concentrations of particulates and solvent
vapours below the OEL, suitable respiratory protection must be worn.
Page: 2/5
SAFETY DATA SHEET
Exposure controls
Occupational exposure controls: Use process enclosures, local exhaust ventilation or other engineering controls
to keep airborne levels below recommended exposure limits.
Respiratory protection: Wear appropriate respirator when ventilation is inadequate.
Hand protection: Gloves
Eye protection: Safety glasses
Skin protection: Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working
period. Ensure that eyewash stations and safety showers are close to the
workstation location.
Occupational exposure limits 18.09.2001 nr 293 (RT I 2001, 77, 460) Estonia
Substance Name CAS number Long term exposure Short term exposure limit 15 minute
limit STEL
8 hour TWA
(ppm) (mg/m3) (ppm) (mg/m3)
Ethanol 64-17-5 500 1000 1000 1900
1-methoxypropan-2-ol 107-98-2 100 375 150 568
9. Physical and chemical properties
General information
Appearance: Liquid
Colour: Colourless
Odour: Characteristic
Important health, safety and environmental information
pH: n.a.
Flash point ( 癈 ): 15癈
Boiling point ( 癈 ): n.a.
Explosion limits (v/v): 1-14
Density (kg/l): 0.9
10. Stability and reactivity
Stability: Stable under recommended storage and handling conditions (see section 7).
Condition to avoid Keep away from heat, flames, ignition sources and incompatibles.
Materials to Avoid: Strong oxidants, alkali metals, ammonia, oxidizing agents, peroxides.
Hazardous decomposition Carbon Dioxide (CO2) and Carbon Monoxide (CO).
products:
11. Toxicological information
There are no data available on the preparation itself. The preparation has been assessed following the conventional
method of the Danggerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly.
See Sections 2 and 15 for details.
Eye contact: Can cause irritation. Splashes may cause temporary pain and blurred vision.
Ingestion: Causes headaches, gastritis, intoxication, blindness and, in acute cases, death.
Inhalation: Excessive inhalation is irritating to the eyes and upper respiratory tract and can cause symptoms of
intoxication.
Prolonged exposure to high concentrations may cause drowsiness, loss of appetite and inability to concentrate.
Skin contact: Removes natural oils and fats from skin causing redness, a mild burning sensation, and irritation,
cracking or flaking.
Persons with pre-existing asthma and other respiratory conditions, skin disorders and eye problems or impaired liver
and kidney functions may be more susceptible to the effects of the substance.
Page: 3/5
SAFETY DATA SHEET
Chronic exposure: Prolonged skin contact causes drying and cracking of skin. May affect liver, kidneys,
gastrointestinal tract, blood, CNS, reproductive system and cardiovascular system.
Ethanol has been linked to birth defects in human.
12. Ecological information
There are no data available on the preparation itself.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is not classified as dangerous for the enviroment.
13. Disposal considerations
Methods of disposal: The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste
disposal legislation and any regional local authority requirements.
Waste classification: 08 01 11* (European Waste Catalogue)
14. Transport information
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
International transport regulations
Regulatory UN number Proper shipping Class PG* EmS No Additional
information name information
1263 Paint product 3 II Hazard
ADR/RID Class
identification
number
30
Limited quantity:
LQ 7
EmS No: F-E, S-E
1263 Paint product 3 II
ADN Class
1263 Paint product 3 II
IMDG Class
1263 Paint product 3 II
IATA-DGR Class
PG* : Packing group
15. Regulatory information
EU regulations
Hazard symbol/symbols:
IRRITANT HIGHLY FLAMMABLE
Page: 4/5
SAFETY DATA SHEET
Risk phrases: R11: Highly flammable
R36: Irritating to eyes.
Safety phrases: S2: Keep out of reach of children.
S7/9: Keep container tightly closed and in a well-ventilated place.
S16: Keep away from sources of ignition - no smoking.
S23: Do not breathe vapour and spray mist.
S46: If swallowed, seek medical advice immediately and show this container or
label.
S51: Use only in well ventilated areas.
16. Other information
Full text of R-phrases referred to R10 Flammable.
in sections 2 and 3 - Europe R11 Highly flammable
R20 Harmful by inhalation.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R61 May cause harm to the unborn child.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
Full text of classifications referred Xn HARMFUL
to in sections 2 and Xi IRRITATING
3 - Europe F VERY FLAMMABLE
T TOXIC
Version: 3
UPDATE: Correction p. 1, 2
Date of issue: 2009-02-19
Date of previous issue 2008-03-26
Notice to reader
The information in this SDS is based on the present state of our knowledge and on current laws. The product is not to be used for purposes
other than those specified under section 1 without first obtaining written handling instructions. It is always the responsibility of the user to take
all necessary steps to fulfil the demands set out in the local rules and legislation. The information in this SDS is meant to be a description of the
safety requirements for our product. It is not to be considered a guarantee of the product's properties.
Page: 5/5
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