REVISION DATE: 12/02/2009
SAFETY DATA SHEET
FLINTS RAPID ONE PACK ETCH PRIMER
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME Flints Rapid One Pack Etch Primer
PAT115 & PAT116
PRODUCT NO.s
Flint Hire & Supply Ltd.
SUPPLIER
Queens Row
London
SE17 2PX
T: 020 7703 9786
F: 020 7703 0616
EMERGENCY TELEPHONE 020 7703 9786
CONTAINER SIZE 5 litre container
2 HAZARDS IDENTIFICATION
Flammable. Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. Toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness.
CLASSIFICATION Xn;R22. Xi;R37/38, R41. N;R51/53. R10, R67.
ENVIRONMENT
The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the aquatic
environment.
PHYSICAL AND CHEMICAL HAZARDS
Heating will generate vapours which may form explosive vapour/air mixtures.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name EC No. CAS-No. Content Classification
1-METHOXY-2-PROPANOL 203-539-1 107-98-2 10-30% R10
BUTANOL-norm 200-751-6 71-36-3 30-60% R10 Xn;R22 Xi;R37/38,R41 R67
PROPAN-2-OL 200-661-7 67-63-0 10-30% F;R11 Xi;R36 R67
TRIZINC BIS(ORTHOPHOSPHATE) 231-944-3 7779-90-0 1-5% N;R50/53
The Full Text for all R-Phrases are Displayed in Section 16
4 FIRST-AID MEASURES
GENERAL INFORMATION
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.
INHALATION
Move the exposed person to fresh air at once. Get medical attention. Provide rest, warmth and fresh air. When breathing is difficult,
properly trained personnel may assist affected person by administering oxygen.
INGESTION
DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! If vomiting occurs, keep head
low so that stomach content doesn't get into the lungs. Drink plenty of water. Get medical attention immediately! Provide rest, warmth and
fresh air.
SKIN CONTACT
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water.
Get medical attention promptly if symptoms occur after washing.
EYE CONTACT
Immediately flush with plenty of water. Remove any contact lenses and open eyes wide apart. Call an ambulance and continue flushing
during transportation to hospital. Bring these instructions. May cause permanent damage if eye is not immediately irrigated.
5 FIRE-FIGHTING MEASURES
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FLINTS RAPID ONE PACK ETCH PRIMER
EXTINGUISHING MEDIA
Fire can be extinguished using: Foam. Dry chemicals, sand, dolomite etc.
SPECIAL FIRE FIGHTING PROCEDURES
Use pressurised air mask if product is involved in a fire. Cool containers exposed to flames with water until well after the fire is out.
UNUSUAL FIRE & EXPLOSION HAZARDS
Fire causes formation of toxic gases.
SPECIFIC HAZARDS
The product is flammable, and heating may generate vapours which may form explosive vapour/air mixtures.
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Avoid discharge into drains, water courses or onto the ground.
SPILL CLEAN UP METHODS
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb spillage with non-combustible, absorbent
material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. Do not contaminate water
sources or sewer.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use
approved respirator if air contamination is above accepted level.
STORAGE PRECAUTIONS
Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and
well-ventilated place. Keep in original container.
STORAGE CLASS
Flammable liquid storage.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Std TWA - 8 hrs STEL - 15 min Notes
Name
WEL 100 375 150 560
1-METHOXY-2-PROPANOL
ppm(Sk) mg/m3(Sk) ppm(Sk) mg/m3(Sk)
WEL 50 ppm(Sk) 154
BUTANOL-norm
mg/m3(Sk)
PROPAN-2-OL WEL 400 ppm 999 mg/m3 500 ppm 1250 mg/m3
WEL = Workplace Exposure Limit.
INGREDIENT COMMENTS
WEL = Workplace Exposure Limits
PROTECTIVE EQUIPMENT
ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
If ventilation is insufficient, suitable respiratory protection must be provided. Wear mask supplied with: Gas cartridge suitable for organic
substances.
HAND PROTECTION
Use protective gloves.
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FLINTS RAPID ONE PACK ETCH PRIMER
EYE PROTECTION
Wear approved safety goggles.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. Provide eyewash station.
HYGIENE MEASURES
DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove
any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. Use appropriate skin cream to
prevent drying of skin. When using do not eat, drink or smoke.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Liquid
ODOUR Odour of alcohol
SOLUBILITY Slightly soluble in water.
BOILING POINT (癈) 82 - 119 @ 760 mm Hg RELATIVE DENSITY 0.84 - 0.96 @ 20癱
VAPOUR DENSITY (air=1) >1 VOLATILE BY VOL. (%) 88
VISCOSITY 100 - 150 cps @ 25癱 FLASH POINT (癈) 24 CC (Closed cup).
FLAMMABILITY LIMIT - LOWER(%) 0.8 VOLATILE ORGANIC COMPOUND <700 g/litre
(VOC)
10 STABILITY AND REACTIVITY
STABILITY
Stable under normal temperature conditions.
CONDITIONS TO AVOID
Avoid exposing to heat and contact with strong oxidising substances.
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
11 TOXICOLOGICAL INFORMATION
INHALATION
Vapours irritate the respiratory system, and may cause coughing and difficulties in breathing. In high concentrations, vapours are narcotic
and may cause headache, fatigue, dizziness and nausea.
INGESTION
Harmful if swallowed. May cause nausea, headache, dizziness and intoxication.
SKIN CONTACT
Prolonged or repeated exposure may cause severe irritation.
EYE CONTACT
Extreme irritation of eyes and mucous membranes, including burning and tearing. Risk of serious damage to eyes.
TARGET ORGANS
Skin. Eyes. Respiratory system, lungs.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the aquatic
environment.
13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION
Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
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FLINTS RAPID ONE PACK ETCH PRIMER
UK ROAD CLASS 3
PROPER SHIPPING NAME PAINT (TRIZINC BIS(ORTHOPHOSPHATE)*2-4H2O)
UN NO. ROAD 1263 UK ROAD PACK GR. III
ADR CLASS NO. 3 ADR CLASS Class 3: Flammable liquids.
ADR PACK GROUP III TUNNEL RESTRICTION CODE (D/E)
HAZARD No. (ADR) 30 ADR LABEL NO. 3
HAZCHEM CODE 3YE CEFIC TEC(R) NO. 30GF1-III, 30GF1-sp
RID CLASS NO. 3 RID PACK GROUP III
UN NO. SEA 1263 IMDG CLASS 3
IMDG PACK GR. III EMS F-E, S-E
MFAG See Guide UN NO. AIR 1263
AIR CLASS 3 AIR PACK GR. III
15 REGULATORY INFORMATION
LABELLING
Harmful Dangerous for the
environment
CONTAINS BUTANOL-norm
RISK PHRASES
R10 Flammable.
R22 Harmful if swallowed.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R67 Vapours may cause drowsiness and dizziness.
SAFETY PHRASES
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S37/39 Wear suitable gloves and eye/face protection.
S51 Use only in well-ventilated areas.
S57 Use appropriate containment to avoid environmental contamination.
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
EU DIRECTIVES
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
APPROVED CODE OF PRACTICE
Classification and Labelling of Substances and Preparations Dangerous for Supply.
GUIDANCE NOTES
Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108).
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FLINTS RAPID ONE PACK ETCH PRIMER
NATIONAL REGULATIONS
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689. Control of Substances Hazardous to Health
Regulations 2002 (as amended)
16 OTHER INFORMATION
ISSUED BY
HS&E Manager.
REVISION DATE 12/02/2009
REV. NO./REPL. SDS GENERATED 3
SDS NO. 10187
SAFETY DATA SHEET STATUS
Approved.
DATE 04/03/2008
RISK PHRASES IN FULL
R10 Flammable.
R11 Highly flammable.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R67 Vapours may cause drowsiness and dizziness.
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
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