MATERIAL SAFETY DATA SHEET PAGE 1 OF 6
KOP-COAT, INC EMERGENCIES
MARINE GROUP EAST HEALTH/SPILLS......: 800-548-0489
36 PINE STREET CHEMTREC ASSISTANCE: 800-424-9300
ROCKAWAY CHEMTREC OUTSIDE US: 703-527-3887
NJ 07866 CANUTEC............: 613-996-6666
KOP-COAT, INC
PRODUCT INFORMATION: 800-221-4466
OUTSIDE USA........: 973-625-3100
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1 PRODUCT IDENTIFICATION
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PRODUCT NAME: Bottom Prep 6998 Skip Sand Primer
PRODUCT USE.: Bottom prep system
APPEARANCE..: Clear liquid with hydrocarbon odor
CAS NUMBER..: Mixture
SYNONYMS....: None REVISION...: 2
DATE.......: 11/19/08
MSDS NUMBER: 1699800
HMIS HEALTH RATING....: 2 NFPA HEALTH RATING....: 2
HMIS FLAMMABLE RATING.: 3 NFPA FLAMMABLE RATING.: 3
HMIS REACTIVITY RATING: 1 NFPA REACTIVITY RATING: 1
HMIS PERSONAL PROTECT.: X
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2 HAZARDOUS INGREDIENTS
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HAZARDOUS COMPONENT REG AGENCY PPM NOTES MG/M3 NOTES
Ethylbenzene ACGIH STEL 125 543
CAS NUMBER:100-41-4 ACGIH-TWA 100 434
PERCENT BY WGT: <1 NIOSH 100 435
NIOSH STEL 125 545
OSHA STEL 125 545
OSHA TWA 100 435
Propylene glycol mono- ACGIH STEL 150 553
methyl ether ACGIH-TWA 100 369
CAS NUMBER:107-98-2
PERCENT BY WGT: 5 TO 10
PM Acetate (None established.)
CAS NUMBER:108-65-6
PERCENT BY WGT: 30 TO 35
Toluene (skin) ACGIH-TWA 50 188
CAS NUMBER:108-88-3 NIOSH 100
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2 HAZARDOUS INGREDIENTS
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HAZARDOUS COMPONENT REG AGENCY PPM NOTES MG/M3 NOTES
PERCENT BY WGT: 5 TO 10 NIOSH STEL 150
OSHA C 300
OSHA TWA 200
Methyl n-amyl ketone ACGIH-TWA 50 233
CAS NUMBER:110-43-0 NIOSH 100 465
PERCENT BY WGT: 10 TO 15 OSHA TWA 100 465
Butyl cellosolve acetate ACGIH TLV 20
CAS NUMBER:112-07-2
PERCENT BY WGT: 1 TO 5
Epoxy Resin (None established.)
CAS NUMBER:25068-38-6
PERCENT BY WGT: 10 TO 15
Formaldehyde ACGIH CEIL 0.3 0.37
CAS NUMBER:50-00-0 NIOSH 0.016 (+) - (+)
PERCENT BY WGT: <1 NIOSH CEIL 0.1 4 -
OSHA CEIL 5 -
OSHA STEL 2 -
OSHA TWA 0.75 -
n-Butyl alcohol (skin) ACGIH TLV 20
CAS NUMBER:71-36-3 NIOSH CEIL 50 150
PERCENT BY WGT: 1 TO 5 OSHA CEIL 50 150
Aluminum (as metal dust) ACGIH TWA - 10
CAS NUMBER:7429-90-5 OSHA TWA - 15 1
PERCENT BY WGT: 5 TO 10 OSHA-TWA - 5 2
Mineral spirits ACGIH TWA 100 -
CAS NUMBER:8052-41-3 NIOSH - 350
PERCENT BY WGT: 1 TO 5 OSHA TWA 100 -
NOTES:
1) Total dust
2) Respirable fraction
4) The short term exposure limit (STEL) is a 15-minute TWA that should not be
exceeded at any time during a workday.
(+)) NIOSH Occupational Carcinogen
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3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW: DANGER! Flammable liquid and vapor. Harmful or fatal if
swallowed or inhaled. May cause eye, skin and respiratory tract irritation.
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3 HAZARDS IDENTIFICATION
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EYES: May cause severe eye irritation. May cause eye burns without immediate
first aid treatment.
SKIN: May cause moderate skin irritation. Prolonged and/or repeated skin
contact may cause irritation characterized by redness, cracking and blistering.
One or more of the components of this product are known to cause an allergic
skin reaction (sensitization) in susceptible individuals. May be absorbed in
toxic amounts through the skin and cause systemic effects.
INHALATION: May cause respiratory tract irritation. Exposure to high
concentrations may cause central nervous system effects, including headache,
drowsiness, nausea, and dizziness. Continued inhlation may result in
unconsciousness or death.
INGESTION: May cause gastrointestinal disturbances such as nausea, vomiting,
diarrhea, and effects similar to those described in INHALATION. Aspiration of
this product into the lungs during ingestion or vomiting may cause mild to
severe pulmonary injury, possibly progressing to death.
CHRONIC: Reports have associated repeated or prolonged occupational exposure
to solvents with permanent brain or nervous system damage, liver and kidney
damage or may cause cardiac arrhythmia.
CARCINOGENICITY: Formaldehyde is classified as a human carcinogen and
ethylbenzene is classified as possibly carcinogenic to humans (2B) by IARC.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing
disease in or a history of ailments involving the nervous system, liver, kidney,
respiratory system or eyes are at a greater risk of developing adverse effects
when exposed to this material.
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4 FIRST AID MEASURES
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EYE CONTACT: Hold eye open and rinse slowly and gently with water for 15-20
minutes. Remove contact lenses, if present, after the first five minutes, then
continue rinsing the eye. Contact a poison control center for treatment advice.
SKIN CONTACT: Take off contaminated clothing. Rinse skin immediately with
plenty of water for 15-20 minutes. Call a poison control center or doctor for
treatment advice. Wash contaminated clothing before reuse.
INHALATION: Move person to fresh air. If person is not breathing, call 911 or
an ambulance, then give artifical respiration, preferably mouth-to-mouth. Call
a poison control center or doctor for further treatment advice.
INGESTION: Immediately call a poison control center or doctor. Do not induce
vomiting unless told to do so by a poison control center or doctor. Do not give
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4 FIRST AID MEASURES
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any liquid to the person. Do not give anything by mouth to an unconscious
person.
NOTE TO PHYSICIAN: There is no specific antidote for effects from overexposure
to this material. Treatment should be directed at the control of symptoms and
the clinical condition.
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5 FIRE FIGHTING MEASURES
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FLASH POINT: 45 F / 7 C
EXTINGUISHING MEDIA: Use dry chemical, carbon dioxide, water spray or foam.
FIRE FIGHTING PROCEDURES: As in any fire, wear complete fire service protective
equipment, including full-face MSHA/NIOSH approved or equivalent self-contained
breathing apparatus. Use water to cool fire-exposed container/structure/protect
personnel.
FIRE AND EXPLOSION HAZARDS: Can release vapors that form explosive mixtures.
Vapors can travel to a source of ignition and flash back. Closed containers may
explode when exposed to extreme heat (fire). Toxic vapors may be given off in a
fire.
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6 SPILL AND LEAK PROCEDURES
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Stop spill/leak if no risk involved. Avoid breathing vapors. Eliminate ALL
sources of ignition such as flares, flames (including pilot lights), and
electrical sparks. Ventilate area. Take up carefully to avoid heat and sparks.
Use an inert absorbent to complete a clean-up. This material reacts with
oxidizing materials. Dispose of contaminated absorbent, container and unused
contents in accordance with local, state and federal regulations.
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7 HANDLING AND STORAGE
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HANDLING: Avoid prolonged or repeated breathing of vapors or mists. Do not
get on skin, in eyes or on clothing. Spray paint in accordance with OSHA 29 C
FR 1910.107. Use with adequate ventilation. Wash thoroughly after handling.
STORAGE: Store in areas/buildings designed to comply with OSHA 1910.106. Keep
in a closed, labeled container within a cool (well-shaded), dry, ventilated
area. Protect from physical damage. Keep containers closed when material is
not in use. Maintain good housekeeping.
OTHER: Keep away from heat and open flame. If post application/use processing
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7 HANDLING AND STORAGE
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of this product generates dust or if spray application is made, " Exposure
Limits " in Section 2 apply. Do not use until manufacturer's precautions have
been read/understood. Containers of this material may be hazardous when
empty. Since emptied containers retain product residues (vapor, liquid), all
hazard precautions given in the data sheet must be observed. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME
SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY CAN EXPLODE AND
CAUSE INJURY OR DEATH. All five gallon pails and larger containers, should be
grounded and/or bonded when material is transferred.
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8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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ENGINEERING CONTROLS: Ventilation is normally required when handling or using
this product to keep exposure to airborne contaminants below the exposure limit.
Facilities storing or utilizing this product should be equipped with an eyewash
station and shower.
RESPIRATORS: Ensure fresh air entry during application and drying. If
engineering controls do not maintain airborne concentrations to a level which is
adequate to protect worker health, or if air monitoring demonstrates vapor level
is above applicable limits, wear an appropriate, properly fitted respirator
(NIOSH/MSHA approved or equivalent) during and after application. Respirator
selection, use and maintenance should be in accordance with the requirements in
29 CFR 1910.134 and NIOSH 42 CFR 84,whenever workplace conditions warrant a
respirator's use.
PERSONAL PROTECTIVE EQUIPMENT: Industrial safety glasses at a minimum. As
necessary for work area conditions: use side shields, goggles, or faceshield.
As required, chemical resistant flexible-type gloves (heavy duty neoprene or
equal). Wear industrial-type work clothing and safety footwear. Depending on
working conditions, i.e., contact potential, wear resistant protective garments
such as head/neck cover, aprons, jackets, pants, coveralls, boots, etc.
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9 PHYSICAL AND CHEMICAL PROPERTIES
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Weight Per Gallon (lbs): 8.300 % VOL by Weight.: 70.6%
Vapor Density.: (Air=1)>1 Boiling Point...: Not determined
Vapor Pressure: Not determined Evaporation Rate: (ether=1)<1
pH............: Not determined Specific Gravity: 0.996
Solubility In Water: Negligible Viscosity.......: Not determined
VOC Content................: 703 g/L
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10 STABILITY AND REACTIVITY DATA
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10 STABILITY AND REACTIVITY DATA
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STABILITY: Stable
HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILITY: Avoid oxidizing agents, heat, sparks and open flames.
HAZARDOUS DECOMPOSITION PRODUCT(S): Carbon monoxide, carbon dioxide, oxides of
nitrogen and other toxic organic compounds.
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11 TOXICOLOGICAL INFORMATION
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Butyl alcohol: Long-term exposure to excessive levels of butyl alcohol has been
reported to cause hearing loss. The ACGIH TLV of 50 ppm is set to protect from
this potential adverse health effect.
Toluene: Prolonged intentional toluene abuse may lead to damage to many organ
systems, having effects on: central and peripheral nervous systems, vision,
hearing, liver, kidneys, heart and blood. Comparable central nervous system
effects have not been shown to result from occupational exposure to toluene.
Toluene may be harmful to the human fetus based on positive test results with
laboratory animals. Case studies show that prolonged intentional abuse of
toluene during pregnancy can cause birth defects.
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12 ECOLOGICAL INFORMATION
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Product has not been tested for ecotoxicity.
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13 DISPOSAL CONSIDERATIONS
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Dispose of unusable product in accordance with local, state and federal
regulations.
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14 TRANSPORTATION INFORMATION
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DEPARTMENT OF TRANSPORTATION REPORTABLE QUANTITIES
REPORTABLE QTY (LBS) HAZARDOUS SUBSTANCE
1000 Toluene (skin)
100 Xylene
100 Formaldehyde
DOT Information for Air Transport and Ground Transport in Containers > 1.2 qt:
DOT Proper Shipping Name & ID Number: UN1263, Paint
DOT CLASS: 3 (Flammable liquid)
Packing Group: II
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14 TRANSPORTATION INFORMATION
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DOT INFORMATION FOR GROUND TRANSPORT IN CONTAINERS LESS THAN 1.2 QUARTS (1 L):
DOT Proper Shipping Name: ORM-D
Label: None
Marking: ORM-D
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15 REGULATORY INFORMATION
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SARA TITLE III SECTION 313 CHEMICALS
Ethylbenzene
Toluene (skin)
Formaldehyde
n-Butyl alcohol (skin)
Aluminum (as metal dust)
WARNING: THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER.
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
No additional information available.
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16 OTHER INFORMATION
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Ethylbenzene is considered a Group 2B carcinogen (possibly carcinogenic to
humans). This category generally includes agents for which there is limited
evidence in humans in the absence of sufficient evidence in experimental
animals.
Inhalation of high concentrations of formaldehyde (>7 ppm) for the major portion
of their lifetime has caused cancer in laboratory animals.
IARC Monograph Volume 29 states that formaldehyde gas is carcinogenic in rats.
The National Toxicology Program (NTP) Annual Report states that there is
sufficient evidence for the carcinogenicity of formaldehyde in experimental
animals.
ACGIH categorizes Formaldehyde as a Group A2: Suspected Human Carcinogen.
NOTICE: This document is generated for the purpose of distributing health,
safety and environmental data. The information on this MSDS was obtained from
sources which we believe are reliable. However, the information is provided
without any warranty, expressed or implied, regarding its correctness. Some
information presented and conclusions drawn herein are from sources other than
direct test data on the substance itself. Kop-Coat makes no warranty with
PRODUCT NAME: Bottom Prep 6998 Skip Sand Primer PAGE 8 OF 6
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16 OTHER INFORMATION
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respect thereto and disclaims all liability from reliance thereon.
PREPARED BY: Manager of Health, Safety and Environmental Affairs
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