MATERIAL SAFETY DATA SHEET
U-MARK, Inc. Date: December 28, 2009
PRODUCT NAME: METALHEAD PAINT MARKER AND METALHEAD PAINT
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Product Identifier: Metalhead Refillable Paint Marker and Metalhead Paint
General Use: Marking on Most Surfaces
Product Color: Black, Blue, Green, White, Yellow, Orange
U-Mark, Inc., 102 Iowa Avenue, Belleville, IL 62220 USA tel. 618-235-7500
24-hour Emergency Phone: Infotrac 1-800-535-5053 (within USA & Canada),
1-352-323-3500 (International)
2. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient CAS No. % by Wt. Exposure Limits (ppm)
Less than OSHA ACGIH
TWA TWA
Denatured Alcohol 64-17-5 30 1000 1000
Propylene Glycol Monomethyl Ether 107-98-2 25 N/A 100
Iso-Propanol Alcohol 67-63-0 5 400 400
Ethyl Acetate 99% 141-78-6 5 400 400
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: Flammable liquid. Harmful. Keep Liquid and vapors away from igniting sources, heat
and static discharge. Avoid contact with eyes and skin. Avoid inhalation of mist or vapor.
POTENTIAL HEALTH EFFECTS:
INHALATION: Can cause nasal or respiratory tract irritation. Short-term inhalation toxicity is low. Breathing small amounts
during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful.
EYE CONTACT: Avoid contact with eyes. May cause severe irritation or chemical burns.
SKIN CONTACT: Wash thoroughly after handling. May cause mild irritation or burns.
EFFECTS OF OVEREXPOSURE: Intentional misuse of this product may be harmful or fatal.
CHRONIC: Does not contain materials listed as cancer causative by NTP, IARC, or OSHA
4. FIRST AID MEASURES
INHALATION: Remove to fresh air. Call a physician in case of complaints.
EYE CONTACT: Flush opened eye with plenty of water for fifteen minutes. Call a physician if irritation persists.
INGESTION: Do not induce vomiting. Call a physician. Wash out mouth if person is conscious.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES:
Flash Point: 54?(12?C) Method: Pensky-Martens C.C.
F Flammable Limits: LEL 1.6% UEL: 11.5%
EXTINGUISHING MEDIA: C02, dry chemical, foam, water fog.
SPECIAL FIRE FIGHTING INSTRUCTIONS: Wear self-contained breathing apparatus and protective clothing to prevent
contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
SPILL: Eliminate all sources of ignition. Spills should be contained and absorbed with liquid binding material, and placed
in a leak proof container. Liquid should be disposed of following all Federal, State and local regulations.
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PRODUCT NAME: METALHEAD PAINT MARKER AND METALHEAD PAINT Page 2
7. HANDLING AND STORAGE
HANDLING: Keep containers closed.
STORAGE: Store in a cool, well ventilated area away from heat, sparks, or flames.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
ENGINEERING CONTROLS: Local and general exhaust should minimize any exposure.
RESPIRATORY PROTECTION: Use a suitable NIOSH/MSHA respiratory device in case of insufficient ventilation or if
exposure limits are exceeded.
SKIN PROTECTION: Not required for minor contact. Wash hands before breaks and at end of work.
EYE PROTECTION: Wear chemical splash goggles if splashing is anticipated.
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR: Mild BOILING POINT: 171 - 248?(77 - 120?br>
F C)
APPEARANCE: Colored, opaque liquid. SPECIFIC GRAVITY: 0.9788
IGNITION TEMPERATURE: not available.
10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Strong oxidizing agents, excessive heat, sources of ignition.
INCOMPATIBILITY: Avoid contact with strong bases, strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: May form Carbon Dioxide, Carbon Monoxide, Oxides of Nitrogen and
other potentially toxic fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. TOXICOLOGICAL INFORMATION
64-17-5 Denatured Alcohol LD/LC50 values oral 7060 MG/KG (Rat); Dermal 20.00 gm/kg (Rabbit)
107-98-2 Propylene Glycol Monomethyl Ether LD/LC50 values oral 5660 mg/kg (Rat); Dermal 5,000 mg/kg (Rabbit)
67-63-0 Iso-Propanol Alcohol LD/LC50 values oral 4396 mg/kg (Rat); Dermal 12870 mg/kg (Rabbit)
141-78-6 Ethyl Acetate 99% LD/LC50 values oral 5620 mg/kg (Rat); Dermal >18000 mg/kg (Rabbit)
12. ECOLOGICAL INFORMATION
No information is available
13. DISPOSAL CONSIDERATIONS
Disposal must be made according to Federal, State, and Local laws.
14. TRANSPORTATION INFORMATION
IATA, IMDG, DOT: Printing Ink, 3, UN 1210, PG II, Ltd. Qty.
USA GROUND Shipments: Consumer Commodity, ORM-D
15. REGULATORY INFORMATION
SARA Sec. 313 Reportable Materials: None. CERCLA ?SARA Section 311 and 312 Hazard Category: Fire Hazard.
16. OTHER INFORMATION
HMIS and NFPA Ratings: Health 2, Flammability 3, Reactivity 0
(4=Extreme, 3=High, 2=Moderate, 1=Slight, 0=Least)
CAUTION!
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable
to the best of our knowledge and belief but is not guaranteed to be so. Since conditions of use are beyond our control, we
make no warrantees, expressed or implied, except those that may be contained in our written contract of sale or
acknowledgement. This MSDS is supplied under the condition that all persons receiving it will make their own evaluation
as to its suitability for their purpose before using it. Responsibility for compliance with all applicable Federal, State or local
regulations concerning the use and dissemination of this MSDS and sale and use of the material described herein rests
solely upon the purchaser.
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