Page 1/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 19.12.2007 Revision: 19.12.2007
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: UltraStar TR-33 Red
?MSDS number: UST06
?Application of the substance / the preparation Printing inks
?Manufacturer/Supplier:
ECKART GmbH
Kaiserstr. 30
D-90763 F黵th/Bay.
?Further information obtainable from:
ORD-IP-RT
Tel. +49 (0)9152 - 77 4492
Angelika.HartlGunselmann@altana.com
?Information in case of emergency:
GBK Gefahrgut B黵o GmbH, Ingelheim, Germany:
From Outside US: (001) 352-323-3500
(First call in English / Response in your language is possible)
Toll free (US&Canada): 1-800-5355053
2 Hazards identification
?Hazard description: Not applicable.
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 10 Flammable.
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 107-98-2 1-methoxy-2-propanol R 10 50-100%
EINECS: 203-539-1
CAS: 108-32-7 propylene carbonate Xi; R 36 10-25%
EINECS: 203-572-1
?Additional information: For the wording of the listed risk phrases refer to section 16.
4 First-aid measures
?General information:
Take affected persons out into the fresh air.
Take affected persons out of danger area and lay down.
?After inhalation: Supply fresh air; consult doctor in case of complaints.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact: Rinse opened eye for several minutes under running water.
(Contd. on page 2)
GB
DR
Page 2/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 19.12.2007 Revision: 19.12.2007
Trade name: UltraStar TR-33 Red
(Contd. of page 1)
?After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire extinguishing methods suitable to surrounding conditions.
?For safety reasons unsuitable extinguishing agents: Water with full jet
?Special hazards caused by the substance, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
?Additional information Cool endangered receptacles with water spray.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
7 Handling and storage
?Handling:
?Information for safe handling:
Keep receptacles tightly sealed.
Keep away from heat and direct sunlight.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
Store in cool, dry place in tightly closed receptacles.
Ensure good ventilation/exhaustion at the workplace.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: Store in a cool location.
?Information about storage in one common storage facility:
Store away from flammable substances.
Do not store together with oxidizing and acidic materials.
?Further information about storage conditions:
Store receptacle in a well ventilated area.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
* 8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
107-98-2 1-methoxy-2-propanol
WEL () Short-term value: 560 mg/m? 150 ppm
Long-term value: 375 mg/m? 100 ppm
Sk
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Wash hands before breaks and at the end of work.
The usual precautionary measures are to be adhered to when handling chemicals.
(Contd. on page 3)
GB
DR
Page 3/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 19.12.2007 Revision: 19.12.2007
Trade name: UltraStar TR-33 Red
(Contd. of page 2)
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Do not eat, drink, smoke or sniff while working.
?Respiratory protection: Suitable respiratory protective device recommended.
?Protection of hands:
Solvent resistant gloves
Preventive skin protection by use of skin-protecting agents is recommended.
Prior to contact with the watersoluble substance / product / preparation apply waterinsoluble skin-protecting
agent (fat-containing film former or W/O-emulsions).
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection: Safety glasses
?Body protection: Protective work clothing
9 Physical and chemical properties
?General Information
Fluid
Form:
According to product specification
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 120癈
31癈
?Flash point:
270癈
?Ignition temperature:
Product is not selfigniting.
?Self-igniting:
Product is not explosive. However, formation of explosive air/vapour
?Danger of explosion:
mixtures are possible.
?Explosion limits:
1.9 Vol %
Lower:
12 hPa
?Vapour pressure at 20癈:
Not determined.
?Density:
?Solubility in / Miscibility with
Soluble.
water:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
GB
(Contd. on page 4)
DR
Page 4/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 19.12.2007 Revision: 19.12.2007
Trade name: UltraStar TR-33 Red
(Contd. of page 3)
11 Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and
headache, dizziness, etc.
12 Ecological information
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow product to reach ground water, water course or sewage system.
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?European waste catalogue
08 03 12 waste ink containing dangerous substances
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
3 Flammable liquids.
?ADR/RID class:
?Danger code (Kemler): 30
1210
?UN-Number:
III
?Packaging group:
3
?Hazard label
?Description of goods: 1210 DRUCKFARBE, Sondervorschrift 640E
1210 PRINTING INK, Special provision 640E
?Maritime transport IMDG:
3
?IMDG Class:
1210
?UN Number:
3
?Label
III
?Packaging group:
F-E,S-D
?EMS Number:
No
?Marine pollutant:
?Proper shipping name: PRINTING INK
?Air transport ICAO-TI and IATA-DGR:
3
?ICAO/IATA Class:
1210
?UN/ID Number:
3
?Label
III
?Packaging group:
?Proper shipping name: PRINTING INK
GB
(Contd. on page 5)
DR
Page 5/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 19.12.2007 Revision: 19.12.2007
Trade name: UltraStar TR-33 Red
(Contd. of page 4)
15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Risk phrases:
10 Flammable.
?Safety phrases:
7/8 Keep container tightly closed and dry.
24 Avoid contact with skin.
?National regulations:
?Technical instructions (air):
Class Share in %
NK 50-100
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
36 Irritating to eyes.
?Department issuing MSDS: ORD-IP-RT
?Contact:
Dr. Angelika Hartl-Gunselmann
Tel.: ++49 (0) 9152 77 4492
FAX: ++49 (0) 9152 77 4499
Angelika.HartlGunselmann@altana.com
?* Data compared to the previous version altered.
GB