MATERIAL SAFETY DATA SHEET
NEOPRENE CONTACT ADHESIVES
7/11/05
PRODUCT COVERED: BA-A, BA-S, BT-A, BT-A05, TA-A
SECTION I MANUFACTURER
Crest Industries, Inc., 1337 King Road, Trenton, MI 48183 Phone: (734) 479-4141 FAX: (734) 479-4040
24 HOUR EMERGENCY TELEPHONE (CHEMTEL): (800) 255-3924 INTERNATIONAL CALLS: (813) 248-0585
SECTION II PRODUCTS
Stock Numbers of Ingre- HMIS RATING Solubility Volatile
Number Product Name on Label dients in Products H F R Appearance and Odor % in Water Volume%
BA-A Amber Tack 1, 3, 4, 5, 6 230 Yellow liquid, strong solvent 40-45 85-95
BA-S Speedy Tack 1, 3, 4, 5, 6 230 Yellow liquid, strong solvent 10-15 85-95
BT-A Vinyl Tack 1, 3, 4, 5, 6 230 Yellow liquid, strong solvent 40-45 85-95
BT-A05 Vinyl Tack 1, 2, 3, 4, 5, 6 230 Yellow liquid, strong solvent 15-20 85-95
TA-A Amber Tack 1, 3, 4, 5, 6 230 Yellow liquid, strong solvent 40-45 85-95
SECTION III HAZARDOUS INGREDIENTS
Exposure Limits* Flash Vapor Pres- Evap. Rate Boiling Flammable Autoig-
CAS in ppm (parts Point sure (mm Hg (n-Butyl Point Limits in % nition Pt.
Ingredients Number per million) 癋 癈 at 20癈) Acetate=1) 癋 癈 Low r Upp r 癋 癈
1. Acetone 67-64-1 750 ppm A, O -4 -20 185 7.7 132 56 2.6 12.8 869 465
2. Aliphatic Petroleum
Distillate 64742-89-8 400 O <20 <-7 60 3.9 206 97 1.2 6.8 536 280
3. n-Hexane** 110-54-3 50 A, 500 O** -7 -22 140 E 8.1 156 69 1.2 7.4 437 225
4. Methylcyclopentane 96-37-7 500 A, O -20 -29 140 CE 8 CE 161 72 1.2CE 7.5 496 258
5. Methylpentane 43133-95-5 500 A, O -20 -29 140 CE 8 CE 140 60 1.2CE 7.5 507 264
6. Toluene 108-88-3 50 A Skin, 200 O 45 7 38 1.5 230 110 1.2 7.0 896 480
3
*A means ACGIH TLV, O means OSHA PEL. Other abbreviations: E means Suppliers Number, CE means Crest Estimate, mg/m
means milligrams per cubic meter, > means greater than, < means less than, Unk means Unknown, NE means Not Established, NA
means Not Applicable. **See NOTES in SECTION VI.
SECTION IV PHYSICAL DATA DELIBERATELY CONCENTRATING AND INHALING ANY
Evaporation Rate: See SECTIONS II, II. Vapor Density: Heav- SOLVENT VAPORS MAY BE HARMFUL OR FATAL!
ier than air. Solubility in Water (Wt%): See SECTION II. Volatile SKIN CONTACT:
Volume %: See SECTION II. Approximate Boiling Point: See Acute Exposure: Repeated or prolonged skin contact
SECTIONS II, III. Flammable Limits Volume %: See SECTION with solvents can result in dry, defatted and cracked skin causing
II. Product Density (water = 1): Less than 1. Appearance and increased susceptibility to infection. Skin irritation may develop
Odor: See SECTION II. into contact dermatitis.
SECTION V FIRE AND EXPLOSION DATA Chronic Exposure: Exposure to small amounts of solvent
Flammability Class: Flammable Liquid. Flash Point (Tag over long periods may cause some or all of the symptoms as in
Closed Cup Method): See SECTIONS II, III. acute exposure to solvents.
Approximate Flammable Limits: See SECTIONS II, III. EYE CONTACT:
Autoignition Temperature: See SECTIONS II, III. Acute Exposure: Irritation of the eyes with itching, burning,
Extinguishing Media: Foam, carbon dioxide, dry chemical. redness and even permanent tissue damage if sprayed directly
Special Fire Fighting Procedures: Full protective equipment, into the eyes and not flushed out immediately.
including self-contained breathing apparatus, is recommended Chronic Exposure: Irritation of the eyes with itching, burning,
because highly toxic gasses may be generated by combustion or redness.
thermal decomposition. Water from fog nozzles may be used to INGESTION:
cool closed containers to prevent pressure build up (containers Acute Exposure: (Not likely unless deliberately sprayed into
may leak or burst when heated). mouth.) Irritation to the mouth, and if swallowed, to the esopha-
Unusual Fire and Explosion Hazards: Vapors are heavier than gus, stomach tissue and digestive tract. If swallowed, vomiting
air and may travel along the ground or be moved by ventilation may cause breathing of liquid solvent resulting in chemical
and ignited by pilot lights, other flames, sparks, heaters, electric pneumonia.
motors, smoking or other ignition sources at locations far from Chronic Exposure: Unknown.
material handling point. At elevated temperatures [130癋 (54癈) MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
or over] containers may vent, rupture or burst. (See NOTEs) None specifically known to Crest Industries, Inc.
SECTION VI HEALTH HAZARD DATA but it is possible that eye, respiratory tract, skin, liver, kidney,
PRIMARY ROUTES OF EXPOSURE: Inhalation, Skin contact, blood cell formation, nervous system and brain diseases may be
Eye contact. aggravated by overexposure to the products on this MSDS.
SIGNS AND SYMPTOMS OF EXPOSURE: CARCINOGENICITY: Products not listed by NTP, IARC or
INHALATION: OSHA.
Acute Exposure: Solvent vapors at concentrations above the SECTION VII EMERGENCY AND FIRST
TLV can irritate the respiratory tract (nose, throat, lungs) causing AID PROCEDURES
a burning sensation, runny nose, sore throat, coughing, chest EYE CONTACT: Flush with clean, lukewarm water (low pres-
discomfort (tightness). May cause central nervous system de- sure) for at least 15 minutes while lifting eyelids. Refer person to
pression with the following progressive symptoms: headache, physician for immediate attention.
dizziness, nausea, staggering gait, confusion, unconsciousness, SKIN CONTACT: Remove contaminated clothing immediately.
cessation of breathing and death. Clean affected areas thoroughly with waterless hand cleaner and
Chronic Exposure: Reports have associated repeated and wash with soap and water. Dry clean contaminated clothing thor-
prolonged occupational overexposure to solvents with permanent oughly before reuse. Seek medical attention if irritation develops
brain and nervous system damage. Symptoms include: loss of or persists.
memory, loss of intellectual ability and loss of coordination. INHALATION: Move to an area free from risk of further expo-
NOTE: Prolonged and/or repeated overexposure to 3. n-Hexane sure. Administer oxygen or artificial respiration as needed. Obtain
may cause Peripheral Neuropathy (damage to nerve tissue of the medical attention.
arms or legs) resulting in muscular weakness and loss of sensa- INGESTION: DO NOT INDUCE VOMITING! Consult physician,
tion in some or all of the following: fingers, hands, arms, toes, hospital emergency room or poison control center immediately.
feet or legs. NOTE: INTENTIONAL MISUSE BY Have list of ingredients available.
Neoprene Contact Adhesives MSDS 7/11/05 page 2
NOTES TO PHYSICIAN: and fire: carbon dioxide, carbon monoxide, hydrocarbon vapors,
Eyes: May cause conjunctivitis. Stain for evidence of corneal hydrogen chloride, chlorine, phosgene and chlorinated hydrocar-
injury. bon vapors, smoke.
Skin: Treat as any contact dermatitis. SECTION X SPILL OR LEAK PROCEDURES
Inhalation: Treat as for solvent vapor inhalation. Broncho- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR
dilators, expectorants and antitussives may help. SPILLED: Put on protective equipment including respiratory pro-
Ingestion: Treat as for solvent ingestion. Inducing vomiting is tection. Prevent further spillage. Evacuate nonessential per-
contraindicated because of the possibility of chemical pneumonia sonnel. Remove all sources of ignition and ventilate the area.
caused by aspiration of solvent liquid. Keep spill from reaching sewers and waterways. Cover the spill
SECTION VIII EMPLOYEE PROTECTION with sawdust, vermiculite, Fuller's Earth or other absorbent mate-
RECOMMENDATIONS rial. Collect material with non-sparking tools and put in a tightly
EYE PROTECTION: Wear safety glasses, splash goggles or sealed container. Remove container to a safe place.
face shield. Contact lenses should not be worn. WASTE DISPOSAL METHOD: Follow all federal, state and
SKIN PROTECTION: Cover as much of the skin as possible local environmental control regulations. Incineration is the pre-
with appropriate clothing. Wear solvent resistant gloves. ferred method. Containers must be handled with care due to
VENTILATION AND RESPIRATORY PROTECTION: If exhaust flammable and toxic residue.
ventilation sufficient to keep the airborne concentrations of sol- RCRA STATUS: Since these products contain ignitable and
vents below their respective TLV's is not possible, an toxic chemicals, they are hazardous when discarded.
OSHA/MSHA approved TC23C Paint Spray Respirator with Par- SECTION XI SPECIAL PRECAUTIONS &
ticulate Prefilter (use Prefilter when spraying BT-A05) or TC19C STORAGE DATA
Air Supplied Respirator must be used. Observe OSHA regula- STORAGE TEMPERATURE
tions (29 CFR 1910.134) for respirator use. NOTE: THERE MINIMUM / MAXIMUM: 50癋 (10癈) / 120癋 (49癈)
MUST ALWAYS BE ENOUGH VENTILATION TO KEEP VA- RECOMMENDED SHELF LIFE: One year
POR CONCENTRATION BELOW THE LOWER FLAMMABLE PRECAUTIONS TO BE TAKEN IN HANDLING, STORAGE
LIMIT! AND USE: Keep away from heat, sparks and open flame. Do
OTHER PROTECTIVE MEASURES: Eyewash stations should not store in temperatures above 120癋 (49癈) or in direct
be available. Educate and train employees in safe use of prod- sunlight. Do not inhale vapors or spray mist. Avoid contact with
ucts. Follow all label instructions. skin and eyes. Wash hands after use and before eating, drinking,
SECTION IX REACTIVITY DATA smoking or using the toilet. Employee education and training in
STABILITY: Stable under normal room conditions. the safe use and handling of these materials are required under
HAZARDOUS POLYMERIZATION: Will not occur. the OSHA Hazard Communication Standard (29CFR
INCOMPATIBILITY (Materials to Avoid): Strong oxidizers 1910.1200).
HAZARDOUS DECOMPOSITION PRODUCTS: By high heat
KEEP OUT OF THE REACH OF CHILDREN
SECTION XII FEDERAL EPA REGULATION COMPLIANCE INFORMATION
EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT of 1986
1) Section 313 Supplier Notification: Chemicals marked with an * in the following tables are subject to the Toxic Chemical Re-
lease Inventory Reporting Requirements using EPA FORM R (40 CFR Part 372).
2) Section 312: All the chemicals listed are subject to Emergency and Hazardous Chemical Inventory Forms and Community Right-
to-Know Reporting Requirements: Tier I and Tier II Reports (40 CFR Part 370).
NOTE: This information should be included in all MSDSs that are copied and distributed for materials covered by this MSDS.
HAZARDOUS INGREDIENTS IN NEOPRENE CONTACT ADHESIVES APPROXIMATE PERCENTAGES BY WEIGHT
Ingredients (Chemicals) CAS Number BA-A BA-S BT-A BT-A05 TA-A
*1. Acetone 67-64-1 40-45 10-15 40-45 15-20 40-45
2. Aliphatic Petroleum Distillate 64742-89-8 10-15
*3. n-Hexane 110-54-3 25-30 10-15 25-30 25-30 25-30
4. Methylcyclopentane 96-37-7 1-5 10-15 1-5 1-5 1-5
5. Methylpentane 43133-95-5 1-5 10-15 1-5 1-5 1-5
*6. Toluene 108-88-3 10-15 30-35 10-15 15-20 10-15
Physical Hazard-Fire 75-90 75-90 75-90 75-90 75-90
Physical Hazard-Pressure Release NOT A HAZARD
Health Hazard-Acute 75-90 75-90 75-90 75-90 75-90
Health Hazard-Chronic 25-30 10-15 25-30 25-30 25-30
Physical Hazard-Reactivity NOT A HAZARD
SECTION XIII VOLATILE ORGANIC COMPOUND (V.O.C.) CONTENT ACCORDING TO THE FEDERAL EPA
BAA BAS BTA BTA05 TAA
Percent by Weight 37.4 69.5 37.4 63.0 36.2
Pounds per Gallon 2.61 4.88 2.61 5.17 2.55
Grams per Liter 313 581 313 620 305
Pounds per Container 0.163 0.305 0.163 25.9 0.159
SECTION XIV CALIFORNIA PROPOSITION 65 WARNINGS
According to the California Safe Drinking Water and Toxic Enforcement Act (PROPOSITION 65) "No person in the course of doing
business shall knowingly and intentionally expose any individual to a chemical known to the state of California to cause cancer, birth
defects or reproductive toxicity without first giving clear and reasonable warning to such individuals of such an exposure".
The following warning applies: WARNING: These products contain chemicals known to the State of California
to cause cancer and birth defects or other reproductive harm.
SECTION XV OZONE DEPLETION IN THE UPPER ATMOSPHERE
None of the products on this MSDS contains Upper Atmosphere ozone depleting substances.
DISCLAIMER: The information contained in this MSDS is believed to be accurate and reliable as of the date indicated.
Crest Industries, Inc. assumes no legal responsibility and makes no representation, warranty or guarantee, expressed
or implied, as to the completeness or accuracy of the information. It is offered solely for your consideration, investigation
and verification. The user is ultimately responsible for the safe use of the material in accordance with applicable federal,
state, provincial and local laws and regulations.
|