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MATERIAL SAFETY DATA SHEET
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03-04-2002 08-08-2000
REVISION DATE: SUPERSEDES:
SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
COMPANY INFORMATION
Foster Products Corporation
H.B. Fuller Company Subsidiary
2900 Granada Lane
Oakdale, MN 55128
Phone: 651-236-3700
Medical Emergency Phone Number (24 Hours): 1-888-853-1758
Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300
PRODUCT INFORMATION
PRODUCT IDENTIFIER: 802386PM
PRODUCT NUMBER: FD8110
REGISTERED TRADE NAME: S.M. GREEN ADHESIVE?br>
TRADEMARK: S.M. GREEN ADHESIVE TM
PRODUCT DESCRIPTION: Adhesive
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
Unlisted ingredients are not 'hazardous' per the Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200) and/or are not found on the Canadian Workplace Hazardous
Materials Information System ingredient disclosure list. See Section 8 for any additional exposure limit guidelines.
Chemical Name CAS # PERCENT OSHA PEL
Hexane, n 110-54-3 50 - 70 TWA 50 ppm
Methylcyclopentane 96-37-7 10 - 30 Not established
Toluene 108-88-3 1-5 TWA 100 ppm
STEL 150 ppm
Heptane 142-82-5 1-5 TWA 400 ppm
STEL 500 ppm
Chlorinated paraffin 63449-39-8 1-5 Not established
Cyclohexane 110-82-7 1-5 TWA 300 ppm
Calcium carbonate 1317-65-3 1-5 TWA (Total dust) 15 MG/M3
TWA (Respirable dust) 5 MG/M3
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Extremely flammable.
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Can cause eye irritation.
Can cause skin irritation.
Moderate respiratory tract irritant.
Harmful if swallowed.
HMIS RATING: HEALTH -- 1 FLAMMABILITY -- 4 REACTIVITY -- 0
See SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for personal protective equipment
recommendations.
POTENTIAL HEALTH EFFECTS BY ROUTE OF ENTRY
EYE: Can cause irritation.
SKIN: Can cause skin irritation.
INHALATION: Can cause moderate respiratory irritation. Inhalation of dusts produced during cutting, grinding or
sanding of this product may cause irritation of the respiratory tract.
Inhalation of vapors may cause loss of feeling and weakness in the hands and feet and loss of manual dexterity.
Inhalation of high concentrations may result in central nervous system (CNS) effects such as dizziness, weakness,
fatigue, nausea, headache, and lack of coordination.
INGESTION: Ingestion is not an anticipated route of exposure. Harmful if swallowed. Irritating to mouth, throat,
and stomach.
LONG-TERM (CHRONIC) HEALTH EFFECTS
REPRODUCTIVE: Contains a substance that is a possible reproductive hazard based on animal
studies at doses that could be encountered in the workplace.
TARGET ORGAN(S): Central nervous system Peripheral nervous system Reproductive system Liver
Kidneys
REGULATED CARCINOGEN STATUS:
Unless noted below, this product does not contain regulated levels of NTP, IARC, ACGIH, or OSHA listed
carcinogens.
EXISTING HEALTH CONDITIONS AFFECTED BY EXPOSURE: Liver disease; Kidney disease
SECTION 4: FIRST AID MEASURES
IF IN EYES: Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the
head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention and monitor
the eye daily as advised by your physician.
IF ON SKIN: Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if
irritation develops or persists.
IF VAPORS INHALED: Remove to fresh air. Restore breathing, if necessary. Call a physician if symptoms
persist.
IF SWALLOWED: Do not induce vomiting and seek medical attention immediately. Drink two glasses of water or
milk to dilute. Do not give anything by mouth to an unconscious person. Induce vomiting as a last measure. Induced
vomiting may lead to aspiration of the material into the lungs potentially causing chemical pneumonitis that may be
fatal.
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SECTION 5: FIRE FIGHTING MEASURES
FLASH POINT: -22C; -8F
AUTOIGNITION TEMPERATURE: Not established
LOWER EXPLOSIVE LIMIT (% in air): Not established
UPPER EXPLOSIVE LIMIT (% in air): Not established
EXTINGUISHING MEDIA: Use water spray, foam, dry chemical or carbon dioxide.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are heavier than air and can travel to a source of ignition
and flash back.
SPECIAL FIRE FIGHTING INSTRUCTIONS: Persons exposed to products of combustion should wear self-
contained breathing apparatus and full protective equipment.
HAZARDOUS COMBUSTION PRODUCTS: Carbon dioxide, Carbon monoxide Chlorine containing gases
SECTION 6: ACCIDENTAL RELEASE MEASURES
SPECIAL PROTECTION: No health effects expected from the cleanup of this material if contact can be
avoided. Follow personal protective equipment recommendations found in
Section 8 of this MSDS. Evaporation of volatile substances can lead to the
displacement of air creating an environment that can cause asphyxiation.
CLEAN-UP: Dike if necessary, contain spill with inert absorbent and transfer to containers
for disposal. Keep spilled product out of sewers, watersheds, or water
systems.
Shut off ignition sources; including electrical equipment and flames. Do not
allow smoking in the area.
Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300
SECTION 7: HANDLING AND STORAGE
Handling: Mildly irritating material. Avoid unnecessary exposure.
Keep away from heat, sparks and flame.
Wash thoroughly after handling.
Keep container closed.
Emptied container retains vapor and product residue.
Observe all labeled precautions until container is cleaned.
Drums of this material should be grounded when pouring.
DO NOT CUT OR WELD ON OR NEAR THIS CONTAINER.
This product contains an ingredient that may release formaldehyde at heated cure
temperatures.
Storage: Store in a cool, dry, ventilated location. Keep away from heat, sparks, flame and other
sources of ignition. Keep container closed.
Consult the Technical Data Sheet for specific storage instructions.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION: Wear safety glasses with side shields when handling this product.
Wear additional eye protection such as chemical splash goggles
and/or face shield when the possibility exists for eye contact with
splashing or spraying liquid, or airborne material. Have an eye wash
station available.
SKIN PROTECTION: Avoid skin contact by wearing chemically resistant gloves and long
sleeved shirt. An apron may be appropriate if splashing can occur.
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Skin absorption may potentially contribute to the overall exposure to
this material. Appropriate measures should be taken to prevent
absorption so that the TLV is not invalidated.
GLOVES: Nitrile
RESPIRATORY PROTECTION: Respiratory protection may be required to avoid overexposure when
handling this product. Use a respirator if general room ventilation is
not available or sufficient to eliminate symptoms. NIOSH approved
air purifying respirator with organic vapor cartridge.
Respirators should be selected by and used following requirements
found in OSHA's respirator standard (29 CFR 1910.134).
VENTILATION: Use local exhaust ventilation or other engineering controls to
minimize exposures.
EXPOSURE LIMITS:
Chemical Name ACGIH EXPOSURE LIMITS AIHA WEEL
Hexane, n TWA 50 ppm Not established
Skin notation
Methylcyclopentane Not established Not established
Toluene TWA 50 ppm Not established
Skin notation
Heptane TWA 400 ppm Not established
STEL 500 ppm
Chlorinated paraffin Not established Not established
Cyclohexane TWA 300 ppm Not established
Calcium carbonate TWA (Total dust) 10 MG/M3 Not established
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
COLOR: Green
ODOR: Solvent
ODOR THRESHOLD: Not established
WEIGHT PER GALLON (lbs.): 6.1
SPECIFIC GRAVITY: 0.73
SOLIDS (% by weight): 22.3
pH: Not established
BOILING POINT (deg. C): Not established
FREEZING/MELTING POINT (deg. C): Not established
VAPOR PRESSURE (mm Hg): Not established
VAPOR DENSITY: Not established
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EVAPORATION RATE: Not established
OCTANOL/WATER COEFFICIENT: Not established
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions.
CHEMICAL INCOMPATIBILITY: Strong oxidizing agents
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide Chlorine
containing gases
SECTION 11: TOXICOLOGICAL INFORMATION
CHEMICAL NAME LD50/LC50
Hexane, n Oral LD50 Rat =28710 mg/kg
Inhalation LC50 Rat =48000 ppm/4H
Methylcyclopentane Not established
Toluene Oral LD50 Rat = 636 mg/kg
Inhalation LC50 Rat =49000 mg/cu m/4H
Dermal LD50 Rabbit = 14.1 ml/kg
Heptane
Inhalation LC50 Rat =103000 mg/cu m/4H
Chlorinated paraffin Oral LD50 Rat >21500 ml/kg
Dermal LD50 Rabbit > 10 ml/kg
Cyclohexane Oral LD50 Rat =12705 mg/kg
Calcium carbonate Oral LD50 Rat = 6250 mg/kg
TOXICOLOGY SUMMARY: No additional health information available.
SECTION 12: ECOLOGICAL INFORMATION
OVERVIEW: No ecological information available
579.5 g VOC/liter of material, less water and exempt solvents
(VOC theoretically determined using EPA Publication 450/3-84-019.)
SECTION 13: DISPOSAL CONSIDERATIONS
This product meets the definition of hazardous waste under the U.S. EPA Hazardous Waste Regulations 40 CFR
261. It is ignitable waste class D001. Disposal via incineration is recommended. Consult your state, local, or
provincial authorities for more restrictive requirements.
LAND DISPOSAL RESTRICTIONS: Toluene
SECTION 14: TRANSPORTATION INFORMATION
Consult Bill of Lading for transportation information.
DOT: ADHESIVES , 3, UN1133, PG.II
SECTION 15: REGULATORY INFORMATION
INVENTORY STATUS
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U.S. EPA TSCA: This product is in compliance with the Toxic Substances Control Act's
Inventory requirements.
CANADIAN CEPA DSL: This product is in compliance with the Canadian Domestic Substance List
requirements.
If you need more information about the inventory status of this product call 651-236-5858.
TSCA Section 12(b) - Export Notice Requirements
This product contains a chemical substance that is currently on the EPA's Section 12(b) Export List. Contact the
company Global Regulatory Group at 651/236-5858 for the identity of the Section 12(b) chemical(s).
This product contains a chemical substance that is Cyclohexane
subject to a Consent Order:
FEDERAL REPORTING
EPA SARA Title III Section 313
Unless listed below, this product does not contain toxic chemical(s) subject to the reporting requirements of section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR part 72. EPA
has advised that when a percentage range is listed the midpoint may be used to fulfill reporting obligations.
Chemical Name CAS# %
n-Hexane 110-54-3 50 - 70
Toluene 108-88-3 1-5
Polychlorinated alkanes 63449-39-8 1-5
Cyclohexane 110-82-7 1-5
WHMIS STATUS: Unless listed below, this product is not controlled under the Canadian Workplace Hazardous
Materials Information System.
B2
D2B D2A
STATE REPORTING
This MSDS is not prepared for distribution in California.
SECTION 16: ADDITIONAL INFORMATION
This Material Safety Data Sheet is prepared to comply with the United States Occupational Safety and Health
Administration (OSHA) Hazard Communication Standard (29 CFR 1910.1200) and the Canadian Workplace
Hazardous Materials Information System (WHMIS).
Prepared by: The Global Regulatory Department
Phone: 651-236-5842
The information and recommendations set forth herein are believed to be accurate. Because some of the information
is derived from information provided to Foster Products Corporation from its suppliers, and because Foster Products
Corporation has no control over the conditions of handling and use, Foster Products Corporation makes no warranty,
expressed or implied, regarding the accuracy of the data or the results to be obtained from the use thereof. The
information is supplied solely for your information and consideration, and Foster Products Corporation assumes no
responsibility for use or reliance thereon. It is the responsibility of the user of Foster Products Corporation products
to comply with all applicable federal, state and local laws and regulations.
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