WingManTM Page 1 of 7
EPA Reg. No. 81943-22
MATERIAL SAFETY DATA SHEET
Phoenix Environmental Care, LLC General Information No. 229-245-8845
P.O. Box 370 In Case of Emergency, Call
Valdosta, GA 31603-0370 PROSAR: 888-875-1724
I. PRODUCT IDENTIFICATION
Product Name: WingMan (75.0%)
Active ingredient: Mancozeb
II. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS Number % by Wt.
Sodium lauryl sulfate 151-21-3 5
Zinc manganese ethylenebis dithiocarbamate 8018-01-7 80
Ethylene thiourea 96-45-7 0-0.5
III. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Mild eye irritation. Harmful by inhalation, in contact with skin and if swallowed.
POTENTIAL HEALTH EFFECTS
- Inhalation
- Skin contact
Eye: May cause slight irritation.
Skin: Irritating to skin.
Inhalation: Slightly toxic if inhaled.
Ingestion: May be harmful if swallowed.
IV. FIRST AID MEASURES
If Swallowed: Immediately call a poison control center or doctor for treatment advice.
Have person sip a glass of water if able to swallow. Do not induce
vomiting unless told to do so by the poison control center or doctor. Do
not give anything by mouth to an unconscious person.
If Inhaled: Move person to fresh air. If person is not breathing, call 911 or an
ambulance, then give artificial respiration, preferably by mouth-to-
mouth, if possible. Call a poison control center or doctor for further
treatment advice.
If in Eyes: Hold eye open and rinse slowly and gently with water for 15-20
minutes. Remove contact lenses, if present, after the first 5 minutes,
then continue rinsing eye. Call a poison control center or doctor for
treatment advice.
If on Skin or Clothing: Take off contaminated clothing. Rinse skin immediately with plenty of
water for 15-20 minutes. Call a poison control center or doctor for
treatment advice.
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EPA Reg. No. 81943-22
V. FIRE FIGHTING MEASURES
Flash point: Not available
Autoignition Temperature: 152?C
Lower 80 g/m3 (for dust in air)
Flammable Limits (LFL):
Extinguishing Media: Water spray Carbon dioxide (CO2) Foam Dry chemical
Fire and Explosion Hazards: Firefighters and other who may be exposed to products of combustion
should wear a full fire fighting turn out gear and self-contained
breathing apparatus. Fire fighting equipment should be thoroughly
decontaminated after use.
Hazardous Combustion Products: Carbon disulfide, ethylene thiourea (ETU), if heated to decomposition
(> 235篎) flammable ethylene is produced.
NFPA: Health 2 Flammability 0 Instability 1
VI. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Avoid contact with skin, eyes and clothing. Avoid dust formation. Use
personal protective equipment.
Environmental Precautions: Consult a regulatory specialist to determine appropriate state of local
reporting requirements, for assistance in waste characterization and/ or
hazardous waste disposal and other requirements listed in pertinent
environmental permits. Do not flush into surface water or sanitary
sewer system.
Methods for Clean-up: Sweep up spills and shovel into suitable containers for disposal.
VII. HANDLING AND STORAGE
Handling: Avoid dust formation. Avoid breathing dust. Keep out of the reach of
children. In case of insufficient ventilation, wear suitable respiratory
equipment.
Storage: Keep tightly closed in a dry and cool place.. If allowed to become wet
the product will deteriorate and represent a fire hazard.
VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Engineering Controls: Investigate engineering techniques to reduce exposures. Local
mechanical exhaust ventilation is preferred. Consult ACGIH
ventilation manual or NFPA Standard 91 for design of exhaust systems.
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EPA Reg. No. 81943-22
Personal Protective Equipment:
Eye/face Protection: Avoid contact with eyes. Goggles.
Skin Protection: Rubber gloves. Wear protective gloves/clothing.
Respiratory Pro:tection Where airborne exposure is likely, use NIOSH approved respiratory
protection equipment appropriate to the material and/or its components.
Full face piece equipment is recommended and, if used, replaces need
for face shield and/or chemical goggles. If exposures cannot be kept at
a minimum with engineering controls, consult respirator manufacturer
to determine appropriate type equipment for given application.
Observe respirator use limitations specified by NIOSH or the
manufacturer. For emergency and other conditions where there may be
a potential for significant exposure, use an approved full face positive-
pressure, self contained breathing apparatus. Respiratory protection
programs must comply with 29 CFR 1910.134
General Hygiene Considerations: Handle in accordance with good industrial hygiene and safety practice.
IX. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Grey green yellow
Physical State: Powder
Odor: Slight rotten egg-like
pH: (1% solution) approx. 7
Melting Point/Range: Decomposes before melting
Bulk Density: 0.59 g/mL
Solubility in Water: Dispersible
X. STABILITY AND REACTIVITY
Stability: Stable under recommended storage conditions.
Conditions to avoid: Protect from water.
Incompatibility with other materials: Strong acids. Strong oxidizing agents. Water. Quaternary ammonium
salts.
Hazardous decomposition products: Carbon disulfide, ethylene thiourea.
Polymerization: Hazardous polymerization does not occur.
XI. TOXICOLOGICAL INFORMATION
Maneb
Acute oral toxicity: LD50 (rat): > 5,000 mg/kg; practically non-toxic if swallowed
Acute dermal toxicity: LD50 (rabbit): > 2,000 mg/kg; slightly toxic if absorbed
Acute inhalation toxicity: LC50 (rat, 4 hr): 5.34-7.38 mg/L
Eye irritant: Rabbit ?slight irritant
Skin irritation: Rabbit ?slight irritant
Sensitization: Guinea pig ?skin allergy observed following repeat exposure.
An increased risk of retinal degeneration was observed in some workers. Repeated and long-term oral
administration produced adverse effects on the thyroid in mice, rats, and dogs. Long-term oral administration
produced an increased incidence of lung tumors in mice and one strain, but not in three other strains. No effects
were seen on the ability of male and female rats to reproduce when exposed orally for multiple generations,
although adverse effects were noted in the liver and thyroid. Developmental delays, but not birth defects, were
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EPA Reg. No. 81943-22
observed in the offspring of rats exposed orally during pregnancy, but only at doses that produced adverse
effects on the mothers. No genetic changes were observed in tests using bacteria, animal cells or animals.
Chronic Toxicity: The information below indicates whether any agency has listed any
ingredient as a carcinogen.
Carcinogenicity:
IARC: A trace contaminant, Ethylene thiourea (ETU) a breakdown product of
Maneb, has been catergorized as a probable human carcinogen by NTP.
XII. ECOLOGICAL INFORMATION
Chem Fate: No information available
XIII. DISPOSAL CONSIDERATIONS
Pesticide Disposal: Dispose of contents/container in accordance with local regulation.
Pesticide wastes are acutely hazardous. Improper disposal of excess
pesticide or rinsate is a violation of Federal law. If the wastes cannot be
disposed of by use or according to label instructions, contact your State
Pesticide or Environmental Control Agency, or the Hazardous Waste
representative at the nearest EPA Regional Office for guidance.
Container Disposal: Empty containers should be taken for local recycling, recovery or waste
disposal.
XIV. TRANSPORT INFORMATION
DOT: When shipped in bulk use IMDG shipping description.
ICAO: Not regulated
IATA: Not regulated
IMDG/IMO
Proper Shipping Name: Environmentally hazardous substance, solid, N.O.S. Mancozeb
Hazard Class or Division: 9
UN/NA Number: 3077
Packing Group: PG III
Marine Pollutant: This product contains a chemical which is listed as a marine pollutant
according to IMDG/IMO.
XV. REGULATORY INFORMATION
International Inventories
Sodium lauryl sulfate
DSL Listed
ElNECSlELlNCS Listed
ENCS Listed
CHINA Listed
KECL Listed
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EPA Reg. No. 81943-22
Zinc manganese ethylenebis dithiocarbamate
ENCS Listed
CHINA Listed
KECL Listed
Ethylene thiourea
DSL Listed
ElNECS/ELlNCS Listed
ENCS Listed
CHINA Listed
KECL Listed
U.S. FEDERAL REGULATIONS
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product
does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40n of the
Code of Federal Regulations, Part 372.
SARA 311/312 Hazardous Categorization
Chronic Health Hazard Yes
Acute Health Hazard Yes
Fire Hazard No
Sudden Release of Pressure Hazard No
Reactive Hazard No
Clean Water Act
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following HAPs:
Chemical Name CAS No. Weight % HAPS data VOC Class 1 Class 2
Chemicals Ozone Ozone
Depletors Depletors
Zinc Manganese 8018-01-7 80 Listed
ethylenebis
dithiocarbamate
Ethylene thiourea 96-45-7 0-0.5 Listed
CERCLA
RCRA
Pesticide Information
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EPA Reg. No. 81943-22
State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
Chemical Name CAS No. Category California Prop. 65
Zinc manganese 8018-01-7 Listed
ethylenebis
dithiocarbamate
Ethylene thiourea 96-45-7 Listed
State Right-to ?Know
Chemical Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Name
Zinc manganese Listed
ethylenebis
dithiocarbamate
Ethylene Listed Listed
thiourea
International Regulations
Mexico-Grade Not available.
Canada This product has been classified in accordance with the hazard criteria
of the Controlled Products Regulations (CPR) and the MSDS containa
all the information required by the CPR.
WHMIS Hazard Class Not determined.
Chemical Name NPRI
Zinc manganese ethylenebis dithiocarbamate X
Ethylene thiourea X
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EPA Reg. No. 81943-22
XVI. OTHER INFORMATION
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by CPR.
DISCLAIMER:
Phoenix Environmental Care, LLC believes the information and recommendations provided above to be
accurate. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF
MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE
CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided above relates only to
the specific product designated and may not be applicable where such product is used in combination with any
other materials or in any process. Use of this product is regulated by the U.S. Environmental Protection Agency
(EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
Additionally, as the conditions and methods of use are beyond the control of Phoenix Environmental Care, LLC,
Phoenix Environmental Care, LLC expressly disclaims any and all liability as to any results obtained or arising
from any use of the product or reliance on such information.
Phoenix Environmental Care LLC Date: 6/19/08
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