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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : DAP-4000
UPC NUMBER : 7079825028, 7079825117
PRODUCT USE/CLASS : Construction Adhesive
MANUFACTURER: 24 HOUR EMERGENCY:
DAP INC. TRANSPORTATION: 1-800-535-5053 (352-323-3500)
2400 BOSTON STREET MEDICAL : 1-800-327-3874 (513-558-5111)
BALTIMORE, MD 21224
PREPARE DATE: 01/30/1999 GENERAL INFORMATION
REVISION NO. : 14 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)
REVISION DATE: 05/31/2000
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER RANGE
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01 Toluene 108-88-3 5.0-10.0 %
02 N-Hexane 110-54-3 5.0-10.0 %
03 Aliphatic Petroleum Distillate 64742-89-8 5.0-10.0 %
04 2-Methyl Pentane 107-83-5 5.0-10.0 %
05 3-Methyl Pentane 96-14-0 5.0-10.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
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01 50 ppm. N.E. 200 ppm. N.E. N.E. NO
02 50 ppm N.E. 50 ppm N.E. N.E. NO
03 400 ppm N.E. 400 ppm N.E. N.E. NO
04 N.E. N.E. N.E. N.E. N.E. NO
05 N.E. N.E. N.E. N.E. N.E. NO
(See Section 16 for abbreviation legend)
Remaining ingredients are not considered hazardous per the OSHA Hazard
Communication Standard.
Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor
OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states.
(Continued on Page 2)
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Product Name: DAP-4000
Revision Date: 05/31/2000 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: DANGER! Extremely flammable liquid and vapor. Vapor
harmful. Harmful or fatal if swallowed. Vapors may cause flash fire or
explosion. Aspiration hazard if swallowed - can enter lungs and cause
damage. Harmful if inhaled.
POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May irritate skin. Prolonged
or repeated contact can result in defatting and drying of the skin which
may result in skin irritation and dermatitis (rash).
EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor
may irritate nose and upper respiratory tract. Vapor inhalation may affect
the brain or nervous system causing dizziness, headache or nausea.
EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or
fatal if swallowed. Aspiration of material into the lungs due to vomiting
can cause chemical pneumonitis which can be fatal. If ingested, this
product may cause vomiting, diarrhea, and depressed respiration.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated
permanent brain and nervous system damage with prolonged and repeated
occupational overexposure to solvents. Hexane exposure may cause nerve
damage to the arms and legs which may be permanent. Overexposure or misuse
of toluene can cause liver, kidney, and brain damage as well as cardiac
abnormalities. Symptoms include: loss of memory, loss of intellectual
ability, and loss of coordination.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Flush with large quantities of water until irritation
subsides.
SKIN CONTACT: Wash with soap and water.
INHALATION: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen.
Note: Only trained personnel should give artificial respiration or
administer oxygen.
(Continued on Page 3)
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Product Name: DAP-4000
Revision Date: 05/31/2000 Page 3
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| SECTION 4 - FIRST AID MEASURES |
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INGESTION: DO NOT INDUCE VOMITING. If irritation or complications arise,
contact a physician or Regional Poison Control Center immediately.
COMMENTS: Call 1-800-327-3874 if irritation or complications arise from
any of the above exposures.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: -20 F LOWER EXPLOSIVE LIMIT: N.A.
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: N.E.
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely Flammable! Material will
readily ignite at room temperature. Vapors may form an explosive mixture
with air. Vapors can travel long distances to a source of ignition and
flashback. Containers may explode if exposed to extreme heat. Eliminate
sources of ignition: heat, electrical equipment, sparks, and flames. Do
not put in contact with oxidizing or caustic materials.
SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including
self-contained breathing apparatus, is recommended to protect from
combustion products. Cool exposed containers with water.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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SPILL OR LEAK PROCEDURES: Dike spill area. Immediately eliminate sources
of ignition. Use absorbent material or scrape up dried material and place
into containers.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye
contact. Avoid breathing vapors. Use only in a well ventilated area.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away
from heat, spark, and flame. Keep containers tightly closed when not in
use. Keep containers from excessive heat and freezing. Do not store at
temperatures above 120 degrees F.
(Continued on Page 4)
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Product Name: DAP-4000
Revision Date: 05/31/2000 Page 4
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| SECTION 7 - HANDLING AND STORAGE |
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OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and
inhaling vapors may be harmful or fatal. Do not take internally.
Construction and repair activities can adversely affect indoor air quality.
Consult with the occupants or a representative(i.e. maintenance, building
manager, industrial hygienist, or safety officer) to determine ways to
minimize any impact.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or
general exhaust) to maintain exposure below PEL and TLV. Vapors are
heavier than air and will collect in low areas. Check all low areas
(basements, sumps, etc.) for vapors before entering.
RESPIRATORY PROTECTION: If 8 hour exposure limit or value is exceeded for
any component, use an approved NIOSH respirator. Consult your safety
equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator
requirements. A respiratory protection program that meets OSHA 1910.134 and
ANSI Z88.2 requirements must be followed whenever workplace conditions
warrant a respirator's use.
EYE PROTECTION: Goggles or safety glasses with side shields.
SKIN PROTECTION: Solvent impervious gloves.
OTHER PROTECTIVE EQUIPMENT: Provide eyewash and solvent impervious apron
if body contact may occur.
HYGIENIC PRACTICES: Remove contaminated clothing and wash before reuse.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 130 - 180 F VAPOR DENSITY : Is heavier than air
ODOR : Strong Solvent
APPEARANCE : Lt. gray paste EVAPORATION RATE: Is faster than
Butyl Acetate
SOLUBILITY IN H2O : Negligible
SPECIFIC GRAVITY : 1.0621
VAPOR PRESSURE : 100 mm Hg @ 68F
PHYSICAL STATE : Paste VISCOSITY : 150,000-175,000 cPs
(See Section 16 for abbreviation legend)
(Continued on Page 5)
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Product Name: DAP-4000
Revision Date: 05/31/2000 Page 5
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Excessive heat and freezing.
INCOMPATIBILITY: Strong oxidizers and caustics.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx,
NOx
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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---------------------- TOXICITY DATA --------------------
ITEM ORAL-LD50 SKIN-LD50 INHALATION-LC50
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01 5000 mg/kg (rat) 2124 mg/kg (rabbit) 640 mg/kg (mouse)
02 28710 mg/kg (rat) N.A. N.A.
Toluene: An experimental teratogen. Experimental reproductive effects.
Mutagenic data. See RTECS for data.
(See Section 16 for abbreviation legend)
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| SECTION 12 - ECOLOGICAL INFORMATION |
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No Information.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and
Local Standards. Discarded material should be incinerated at a permitted
facility. Liquids cannot be disposed of in a landfill. Do not reuse empty
container. State and Local regulations/restrictions are complex and may
differ from Federal regulations. Responsibility for proper waste disposal
is with the owner of the waste.
EPA WASTE CODE - If discarded (40 CFR 261): None, yields no liquid
component when evaluated by EPA method 1311 (TCLP)
(Continued on Page 6)
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Product Name: DAP-4000
Revision Date: 05/31/2000 Page 6
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Adhesive (Consumer Commodity*)
DOT HAZARD CLASS: 3 (ORM-D*)
DOT UN/NA NUMBER: 1133 (NONE*) PACKING GROUP: III (None*)
* For containers of 1 gallon or less.
Note: The shipping information provided is applicable for domestic ground
transport only. Different categorization may apply is shipped via other
modes of transportation and/or to non-domestic destinations.
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| SECTION 15 - REGULATORY INFORMATION |
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U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % Range
Toluene 108-88-3 5.0-10.0 %
N-Hexane 110-54-3 5.0-10.0 %
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
Cyclohexane 110-82-7
Methylcyclopentane 96-37-7
All ingredients are on the TSCA inventory
(Continued on Page 7)
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Product Name: DAP-4000
Revision Date: 05/31/2000 Page 7
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| SECTION 15 - REGULATORY INFORMATION |
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NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Hydrocarbon resin TSRN618608-5036P
Styrene Rubber TSRN618608-5037P
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Hydrocarbon resin Proprietary
Styrene Rubber Proprietary
CALIFORNIA PROPOSITION 65:
WARNING: The chemical noted below and contained in this product, are
known to the state of California to cause, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
Toluene 108-88-3
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: Class B2, D2A, D2B.
(Continued on Page 8)
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Product Name: DAP-4000
Revision Date: 05/31/2000 Page 8
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 07/21/1999
REASON FOR REVISION:
SECTION 1: ADDRESS CHANGE AND NEW EMERGENGY CONTACT PHONE NUMBERS
SECTION 11: TOXICOLOGY INFORMATION ADDED
VOC less water, less exempt solvents: 400-410 g/L (38-39 weight%)
VOC of material : 400-410 g/L
LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
PEL - PERMISSIBLE EXPOSURE LIMIT
NTP - NATIONAL TOXICOLOGY PROGRAM
SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
STEL - SHORT TERM EXPOSURE LIMIT
TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOC - VOLATILE ORGANIC COMPOUND
NJRTK - NEW JERSEY RIGHT TO KNOW LAW
N.D. - NOT DETERMINED
MSDS# 10303
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This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
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< End OF MSDS >
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