Hexane
Material Safety Data Sheet
CITGO Petroleum Corporation
19041
MSDS No.
1701 Golf Road, Suite 1-1101
Hazard Rankings
Rolling Meadows, IL 60008-4295 12/18/2008
Revision Date
HMIS NFPA
IMPORTANT: This MSDS is prepared in accordance with 29 CFR 1910.1200. Read this
MSDS before transporting, handling, storing or disposing of this product and forward this 2 2
Health Hazard *
information to employees, customers and users of this product.
Fire Hazard 3 3
Emergency Overview 0
Reactivity 0
Physical State Liquid.
* = Chronic Health Hazard
Transparent, Characteristic hydrocarbon
Color Odor
colorless. solvent odor.
DANGER: Protective Equipment
EXTREMELY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY
Minimum Recommended
CAUSE FLASH FIRE. See Section 8 for Details
Vapor may travel considerable distance to source of ignition
and flash back.
Harmful or fatal if swallowed - can enter lungs and cause
damage.
Breathing high concentrations can cause irregular heartbeats
which may be fatal.
May be harmful if inhaled or absorbed through the skin.
Can cause eye, skin or respiratory tract irritation.
Overexposure can cause central nervous system (CNS)
depression and/or other target organ effects.
Harmful to aquatic organisms.
SECTION 1. PRODUCT IDENTIFICATION
Hexane (847) 734-7699
Trade Name Technical Contact
(8am - 4pm CT M-F)
Product Number Medical Emergency
19041 (832) 486-4700
64742-49-0 (800) 424-9300
CAS Number CHEMTREC Emergency
(United States Only)
Petroleum hydrocarbon solvent
Product Family
Commercial Hexane;
Synonyms
C6-rich Solvent;
CITGO ?Material Code: 19041
SECTION 2. COMPOSITION
This product may be composed, in whole or in part, of any of the following refinery streams:
Naphtha, petroleum, hydrotreated light [CAS No.: 64742-49-0]
This product contains the following components:
Concentration (%)
Component Name(s) CAS Registry No.
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Hexane
n-Hexane 110-54-3 40 - 60
Hexane, other isomers Mixture 40 - 60
Methylcyclopentane 96-37-7 5 - 20
Heptane, all isomers Mixture. <3
Cyclohexane 110-82-7 <2
SECTION 3. HAZARDS IDENTIFICATION
Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS.
Major Route(s) of Entry Skin contact. Eye contact. Inhalation. Ingestion.
Signs and Symptoms of Acute Exposure
Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs.
Inhalation
Breathing this material may cause central nervous system depression with symptoms
including nausea, headache, dizziness, fatigue, drowsiness, or unconsciousness. Breathing
high concentrations of this material, for example, in an enclosed space or by intentional
abuse, can cause irregular heartbeats which can cause death.
Eye Contact This product can cause transient mild eye irritation with short-term contact with liquid sprays
or mists. Symptoms include stinging, watering, redness, and swelling.
This material can cause skin irritation. The severity of irritation will depend on the amount of
Skin Contact
material that is applied to the skin and the speed and thoroughness that it is removed.
Symptoms include redness, itching, and burning of the skin. Repeated or prolonged skin
contact can produce moderate irritation (dermatitis).
Ingestion If swallowed, this material may irritate the mucous membranes of the mouth, throat, and
esophagus. It can be readily absorbed by the stomach and intestinal tract. Symptoms
include a burning sensation of the mouth and esophagus, nausea, vomiting, dizziness,
staggered gait, drowsiness, loss of consciousness and delirium, as well as additional central
nervous system (CNS) effects.
Due to its light viscosity, there is a danger of aspiration into the lungs during swallowing and
subsequent vomiting. Aspiration can result in severe lung damage or death. Cardiovascular
effects include shallow rapid pulse with pallor (loss of color in the face) followed by flushing
(redness of the face). Also, progressive CNS depression, respiratory insufficiency and
ventricular fibrillation leads to death.
Chronic Health Effects Prolonged and/or repeated contact may cause skin irritation and inflammation. Symptoms
include defatting, redness, blistering, lesions, and scaly dermatitis.
Summary
Chronic effects of ingestion and subsequent aspiration into the lungs may cause
pneumatocele (lung cavity) formation and chronic lung dysfunction.
Reports have associated repeated and prolonged occupational overexposure to light
petroleum products with irreversible brain and nervous system damage (sometimes referred
to as "Solvent or Painter's Syndrome"). Intentional misuse by deliberately concentrating and
inhaling this product may be harmful or fatal.
Repeated and prolonged overexposure to n-hexane has been associated with peripheral
nerve tissue damage. Adverse effects include numbness, tingling, pain, and loss of muscle
control in the extremities, disorientation, impaired vision and reflexes, decline in motor
function and paralysis.
Conditions Aggravated Disorders of the following organs or organ systems that may be aggravated by significant
exposure to this material or its components include: Skin, Respiratory System, Liver,
by Exposure
Kidneys, Peripheral Nervous System, Central Nervous System (CNS)
Target Organs May cause damage to the following organs: liver, mucous membranes, peripheral nervous
system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea
Carcinogenic Potential This product is not known to contain any components at concentrations above 0.1% which
are considered carcinogenic by OSHA, IARC or NTP.
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Hexane
OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present,
the product does not exhibit the hazard as defined in the OSHA Hazard Communication Standard (29 CFR
1910.1200).
OSHA Physical Hazard Classification
OSHA Health Hazard Classification
Combustible Explosive Pyrophoric
Irritant Sensitizer
X
Highly Toxic Water-reactive
Toxic Oxidizer
X
Flammable
Corrosive Carcinogenic Compressed Gas Organic Peroxide Unstable
SECTION 4. FIRST AID MEASURES
Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid.
For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS.
Immediately move victim to fresh air. If victim is not breathing, immediately begin rescue
Inhalation
breathing. If heart has stopped, immediately begin cardiopulmonary resuscitation (CPR). If
breathing is difficult, 100 percent humidified oxygen should be administered by a qualified
individual. Seek medical attention immediately.
Flush eyes with cool, clean, low-pressure water for at least 15 minutes. Hold eyelids apart to
Eye Contact
ensure complete irrigation of the eye and eyelid tissue. If easily accomplished, check for and
remove contact lenses. If contact lenses cannot be removed, seek immediate medical
attention. Do not use eye ointment. Seek medical attention.
Remove contaminated shoes and clothing. Flush affected area with large amounts of water.
Skin Contact
If skin surface is damaged, apply a clean dressing and seek medical attention. Do not use
ointments. If skin surface is not damaged, clean affected area thoroughly with mild soap and
water. Seek medical attention if tissue appears damaged or if pain or irritation persists.
Do not induce vomiting. If spontaneous vomiting is about to occur, place victim's head below
Ingestion
knees. If victim is drowsy or unconscious, place on the left side with head down. Never give
anything by mouth to a person who is not fully conscious. Do not leave victim unattended.
Seek medical attention immediately.
INHALATION: Inhalation overexposure can produce toxic effects. Monitor for respiratory
Notes to Physician
distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract
inflammation, bronchitis, and pneumonitis. Administer supplemental oxygen with assisted
ventilation, as required.
This material (or a component) sensitizes the heart to the effects of sympathomimetic amines.
Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in individuals
exposed to this material. Administration of sympathomimetic drugs should be avoided.
INGESTION: If ingested, this material presents a significant aspiration and chemical
pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal
and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal
intubation or by placement of the body in a Trendelenburg and left lateral decubitus position.
SECTION 5. FIRE FIGHTING MEASURES
NFPA Class-IB flammable liquid.
NFPA Flammability
Classification
Closed cup: -18癈 (0癋). (Tagliabue (ASTM D-56))
Flash Point
Upper Flammable Limit AP 7.4 %
Lower Flammable Limit AP 1 %
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Hexane
Autoignition 252癈 (486癋)
Temperature
Hazardous Combustion Carbon dioxide, carbon monoxide, smoke, fumes, and/or unburned hydrocarbons.
Products
Special Properties Flammable Liquid! This material releases vapors at or below ambient temperatures. When
mixed with air in certain proportions and exposed to an ignition source, its vapor can cause a
flash fire. Use only with adequate ventilation. Vapors are heavier than air and may travel
long distances along the ground to an ignition source and flash back. A vapor and air
mixture can create an explosion hazard in confined spaces such as sewers. If container is
not properly cooled, it can rupture in the heat of a fire.
Extinguishing Media SMALL FIRE: Use dry chemicals, carbon dioxide, foam, or inert gas (nitrogen). Carbon
dioxide and inert gas can displace oxygen. Use caution when applying carbon dioxide or
inert gas in confined spaces.
LARGE FIRE: Use foam, water fog, or water spray. Water may be ineffective. Water may
not extinguish the fire. Water fog and spray are effective in cooling containers and adjacent
structures. However, water can be used to cool the external walls of vessels to prevent
excessive pressure, autoignition or explosion. DO NOT use a solid stream of water directly
on the fire as the water may spread the fire to a larger area.
Firefighters must use full bunker gear including NIOSH-approved positive pressure
Protection of Fire
self-contained breathing apparatus to protect against potential hazardous combustion or
Fighters
decomposition products and oxygen deficiencies. Evacuate area and fight the fire from a
maximum distance or use unmanned hose holders or monitor nozzles. Cover pooling liquid
with foam. Containers can build pressure if exposed to radiant heat; cool adjacent containers
with flooding quantities of water until well after the fire is out. Withdraw immediately from the
area if there is a rising sound from a venting safety device or discoloration of vessels, tanks,
or pipelines. Be aware that burning liquid will float on water. Notify appropriate authorities of
potential fire and explosion hazard if liquid enter sewers or waterways.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For
more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal
Protection in Section 8 and Disposal Considerations in Section 13 of this MSDS.
Flammable Liquid! Release causes an immediate fire or explosion hazard. Evacuate all
non-essential personnel from immediate area and establish a "regulated zone" with site
control and security. A vapor-suppressing foam may be used to reduce vapors. Eliminate all
ignition sources. All equipment used when handling this material must be grounded. Stop the
leak if it can done without risk. Do not touch or walk through spilled material. Remove
spillage immediately from hard, smooth walking areas. Prevent spilled material from entering
waterways, sewers, basements, or confined areas. Absorb or cover with dry earth, sand, or
other non-combustible material and transfer to appropriate waste containers. Use clean,
non-sparking tools to collect absorbed material.
For large spills, secure the area and control access. Prevent spilled material from entering
sewers, storm drains, other drainage systems, and natural waterways. Dike far ahead of a
liquid spill to ensure complete collection. Water mist or spray may be used to reduce or
disperse vapors; but, it may not prevent ignition in closed spaces. This material will float on
water and its run-off may create an explosion or fire hazard. Verify that responders are
properly HAZWOPER-trained and wearing appropriate respiratory equipment and
fire-resistant protective clothing during cleanup operations. In an urban area, cleanup spill as
soon as possible; in natural environments, cleanup on advice from specialists. Pick up free
liquid for recycle and/or disposal if it can be accomplished safely with explosion-proof
equipment. Collect any excess material with absorbant pads, sand, or other inert
non-combustible absorbent materials. Place into appropriate waste containers for later
disposal. Comply with all applicable local, state and federal laws and regulations.
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Hexane
SECTION 7. HANDLING AND STORAGE
A spill or leak can cause an immediate fire or explosion hazard. Keep containers closed and
Handling
do not handle or store near heat, sparks, or any other potential ignition sources. Avoid
contact with oxidizing agents. Do NOT breathe vapor. Use only with adequate ventilation and
personal protection. Never siphon by mouth. Avoid contact with eyes, skin, and clothing.
Prevent contact with food and tobacco products. Do NOT take internally.
When performing repairs and maintenance on contaminated equipment, keep unnecessary
persons away from the area. Eliminate all potential ignition sources. Drain and purge
equipment, as necessary, to remove material residues. Follow proper entry procedures,
including compliance with 29 CFR 1910.146 prior to entering confined spaces such as tanks
or pits. Use gloves constructed of impervious materials and protective clothing if direct
contact is anticipated. Use appropriate respiratory protection when concentrations exceed
any established occupational exposure level (See Section 8) Promptly remove contaminated
clothing. Wash exposed skin thoroughly with soap and water after handling.
Non-equilibrium conditions may increase the fire hazard associated with this product. A
static electrical charge can accumulate when this material is flowing through pipes, nozzles or
filters and when it is agitated. A static spark discharge can ignite accumulated vapors
particularly during dry weather conditions. Always bond receiving containers to the fill pipe
before and during loading. Always confirm that receiving container is properly grounded.
Bonding and grounding alone may be inadequate to eliminate fire and explosion hazards
associated with electrostatic charges. Carefully review operations that may increase the risks
associated with static electricity such as tank and container filling, tank cleaning, sampling,
gauging, loading, filtering, mixing, agitation, etc. In addition to bonding and grounding, efforts
to mitigate the hazards of an electrostatic discharge may include, but are not limited to,
ventilation, inerting and/or reduction of transfer velocities. Dissipation of electrostatic charges
may be improved with the use of conductivity additives when used with other mitigation
efforts, including bonding and grounding. Always keep nozzle in contact with the container
throughout the loading process.
Do NOT fill any portable container in or on a vehicle. Do NOT use compressed air for filling,
discharging or other handling operations. Product container is NOT designed for elevated
pressure. Do NOT pressurize, cut, weld, braze solder, drill, or grind on containers. Do NOT
expose product containers to flames, sparks, heat or other potential ignition sources. Empty
containers may contain material residues which can ignite with explosive force. Observe label
precautions.
Keep container tightly closed. Store in a cool, dry, well-ventilated area. Store only in
Storage
approved containers. Do not store with oxidizing agents. Do not store at elevated
temperatures or in direct sunlight. Protect containers against physical damage. Head spaces
in tanks and other containers may contain a mixture of air and vapor in the flammable range.
Vapor may be ignited by static discharge. Storage area must meet OSHA requirements and
applicable fire codes. Additional information regarding the design and control of hazards
associated with the handling and storage of flammable and combustible liquids may be found
in professional and industrial documents including, but not limited to, the National Fire
Protection Association (NFPA) publications NFPA 30 ("Flammable and Combustible Liquid
Code"), NFPA 77 ("Recommended Practice on Static Electricity") and the American
Petroleum Institute (API) Recommended Practice 2003, ("Protection Against Ignitions Arising
Out of Static, Lightning, and Stray Currents").
Consult appropriate federal, state and local authorities before reusing, reconditioning,
reclaiming, recycling or disposing of empty containers or waste residues of this product.
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Hexane
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls Provide ventilation or other engineering controls to keep the airborne concentrations of
vapor or mists below the applicable workplace exposure limits indicated below. All electrical
equipment should comply with the National Electrical Code. An emergency eye wash station
and safety shower should be located near the work-station.
Personal protective equipment should be selected based upon the conditions under which
Personal Protective
this material is used. A hazard assessment of the work area for PPE requirements should
Equipment
be conducted by a qualified professional pursuant to OSHA regulations. The following
pictograms represent the minimum requirements for personal protective equipment. For
certain operations, additional PPE may be required.
Eye Protection Safety glasses equipped with side shields are recommended as minimum protection in
industrial settings. Chemical goggles should be worn during transfer operations or when
there is a likelihood of misting, splashing, or spraying of this material. A suitable emergency
eye wash water and safety shower should be located near the work station.
Hand Protection Avoid skin contact. Use heavy duty gloves constructed of chemical resistant materials such
as Viton?or heavy nitrile rubber. Wash hands with plenty of mild soap and water before
eating, drinking, smoking, use of toilet facilities or leaving work. DO NOT use gasoline,
kerosene, solvents or harsh abrasives as skin cleaners.
Avoid skin contact. Wear long-sleeved fire-retardant garments (e.g., Nomex? while
Body Protection
working with flammable and combustible liquids. Additional chemical-resistant protective
gear may be required if splashing or spraying conditions exist. This may include an apron,
boots and additional facial protection. If product comes in contact with clothing, immediately
remove soaked clothing and shower. Promptly remove and discard contaminated leather
goods.
Respiratory Protection For known vapor concentrations above the occupational exposure guidelines (see below),
use a NIOSH-approved organic vapor respirator if adequate protection is provided.
Protection factors vary depending upon the type of respirator used. Respirators should be
used in accordance with OSHA requirements (29 CFR 1910.134). For airborne vapor
concentrations that exceed the recommended protection factors for organic vapor
respirators, use a full-face, positive-pressure, supplied air respirator. Due to fire and
explosion hazards, do not enter atmospheres containing concentrations greater than 10% of
the lower flammable limit of this product.
Warning! Use of this material in spaces without adequate ventilation may result in
General Comments
generation of hazardous levels of combustion products and/or inadequate oxygen levels for
breathing. Odor is an inadequate warning for hazardous conditions.
Occupational Exposure Guidelines
Substance Applicable Workplace Exposure Levels
n-Hexane ACGIH (United States). Skin
TWA: 50 ppm 8 hour(s).
OSHA (United States).
TWA: 500 ppm 8 hour(s).
Hexane, other isomers ACGIH (United States).
TWA: 500 ppm 8 hour(s).
STEL: 1000 ppm 15 minute(s).
Heptane, all isomers ACGIH (United States).
TWA: 400 ppm 8 hour(s).
STEL: 500 ppm 15 minute(s).
OSHA (United States).
TWA: 500 ppm 8 hour(s).
MSDS No. Revision Date
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Hexane
Cyclohexane ACGIH (United States).
TWA: 100 ppm 8 hour(s).
OSHA (United States).
TWA: 300 ppm 8 hour(s).
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES (TYPICAL)
Characteristic hydrocarbon
Odor
Color
Liquid. Transparent,
Physical State
solvent odor.
colorless.
AP 3 (Air = 1)
Vapor
0.68 (Water = 1) Not Applicable.
Specific Gravity pH
Density
Not available.
Boiling Range 66 to 70癈 (151 to 158癋) Melting/Freezing
Point
Volatility 675 g/l VOC (w/v)
18.7 kPa (140 mm Hg) (at 20癈)
Vapor Pressure
Viscosity
Very slightly soluble in cold water. (<0.1 % AP 0.5
Solubility in
w/w) (cSt @ 40癈)
Water
Closed cup: -18癈 (0癋). (Tagliabue (ASTM D-56))
Flash Point
Conductivity = <5 picosiemens/meter (unadditized)
Additional
Properties
SECTION 10. STABILITY AND REACTIVITY
Hazardous Polymerization Not expected to occur.
Stable.
Chemical Stability
Keep away from heat, flame and other potential ignition sources. Keep away from strong
Conditions to Avoid
oxidizing conditions and agents.
Strong acids, alkalies, and oxidizers such as liquid chlorine and oxygen.
Materials
Incompatibility
No additional hazardous decomposition products were identified other than the combustion
Hazardous
products identified in Section 5 of this MSDS.
Decomposition
Products
SECTION 11. TOXICOLOGICAL INFORMATION
For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification
in Section 3 of this MSDS.
Toxicity Data n-Hexane:
This material contains n-hexane. Long-term or repeated exposure to n-hexane can cause
permanent peripheral nerve damage. Initial symptoms are numbness of the fingers and toes.
Also, motor weakness can occur in the digits, but may also involve muscles of the arms,
thighs and forearms. The onset of these symptoms may be delayed for several months to a
year after the beginning of exposure. Co-exposure to methylethyl ketone or methyl isobutyl
ketone increases the neurotoxic properties of n-hexane. In laboratory studies, prolonged
exposure to elevated concentrations of n-hexane was associated with decreased sperm
count and degenerative changes in the testicles of rats.
:
Heptane, all isomers
n-Heptane was not mutagenic in the Salmonella/microsome (Ames) assay and is not
considered to be carcinogenic.
:
Cyclohexane
ORAL (LD50): Acute: 12705 mg/kg [Rat]. 813 mg/kg [Mouse].
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Hexane
Cyclohexane can cause eye, skin and mucous membrane irritation, CNS depressant and
narcosis at elevated concentrations. In experimental animals exposed to lethal
concentrations by inhalation or oral route, generalized vascular damage and degenerative
changes in the heart, lungs, liver, kidneys and brain were identified.
Cyclohexane has been the focus of substantial testing in laboratory animals. Cyclohexane
was not found to be genotoxic in several tests including unscheduled DNA synthesis,
bacterial and mammalian cell mutation assays, and in vivo chromosomal aberration. An
increase in chromosomal aberrations in bone marrow cells of rats exposed to cyclohexane
was reported in the 1980's. However, a careful re-evaluation of slides from this study by the
laboratory which conducted the study indicates these findings were in error, and that no
significant chromosomal effects were observed in animals exposed to cyclohexane. Findings
indicate long-term exposure to cyclohexane does not promote dermal tumorigenesis.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity data are not available for this product. Aquatic toxicity values are expected to be
Ecotoxicity
in the range of 1 - 10 mg/l based upon data from components and similar products. This
mixture contains components that are potentially toxic to freshwater and saltwater
ecosystems.
Environmental Fate This product will normally float on water. Components will evaporate rapidly. This material
may be harmful to aquatic organisms and may cause long term adverse effects in the aquatic
environment. The octanol-water partition coefficient (log Kow) for this product is expected to
be in the range of 2.1 to 5.
SECTION 13. DISPOSAL CONSIDERATIONS
Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is
the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal
methodologies for spent materials and residues at the time of disposition.
Maximize material recovery for reuse or recycling. Recovered non-usable material may be
regulated by US EPA as a hazardous waste due to its ignitibility (D001) and/or its toxic
(D018) characteristics. Conditions of use may cause this material to become a "hazardous
waste", as defined by federal or state regulations. It is the responsibility of the user to
determine if the material is a RCRA "hazardous waste" at the time of disposal.
Transportation, treatment, storage and disposal of waste material must be conducted in
accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State and/or
local regulations may be more restrictive. Contact your regional US EPA office for guidance
concerning case specfic disposal issues.
SECTION 14. TRANSPORT INFORMATION
The shipping description below may not represent requirements for all modes of transportation, shipping
methods or locations outside of the United States.
A U.S. Department of Transportation regulated material.
US DOT Status
Proper Shipping Name RQ, Hexanes, 3, UN 1208, PGII, ERG: 128
3 II
Hazard Class Packing Group
UN 1208
UN/NA Number
Reportable Quantity RQ 5000 lbs. [Based upon maximum Hexane concentration of 100% and an RQ of 5000
lbs.]
Placard(s)
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Hexane
128
Emergency Response
Guide No.
Not a DOT "Marine
MARPOL III Status
Pollutant" per 49 CFR
FLAMMABLE LIQUID
171.8.
3
SECTION 15. REGULATORY INFORMATION
TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA)
inventory.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
SARA 302/304
facilities subject to Subparts 302 and 304 to submit emergency planning and notification
Emergency Planning
information based on Threshold Planning Quantities (TPQs) and Reportable Quantities
and Notification
(RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No
components were identified.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
SARA 311/312 Hazard
facilities subject to this subpart to submit aggregate information on chemicals by "Hazard
Identification
Category" as defined in 40 CFR 370.2. This material would be classified under the following
hazard categories:
Fire, Acute (Immediate) Health Hazard, Chronic (Delayed) Health Hazard
This product contains the following components in concentrations above de minimis levels
SARA 313 Toxic
Chemical Notification that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section
and Release Reporting 313 of SARA:
n-Hexane [CAS No.: 110-54-3] Concentration: <60%
Cyclohexane [CAS No.: 110-82-7] Concentration: <2%
The Comprehensive Environmental Response, Compensation, and Liability Act of 1980
CERCLA
(CERCLA) requires notification of the National Response Center concerning release of
quantities of "hazardous substances" equal to or greater than the reportable quantities (RQ's)
listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not
include petroleum, including crude oil or any fraction thereof which is not otherwise
specifically designated in 40 CFR 302.4. Chemical substances present in this product or
refinery stream that may be subject to this statute are:
n-Hexane [CAS No.: 110-54-3] RQ = 5000 lbs. (2268 kg) Concentration: 60%
Cyclohexane [CAS No.: 110-82-7] RQ = 1000 lbs. (453.6 kg) Concentration: <2%
Benzene [CAS No.: 71-43-2] RQ = 10 lbs. (4.536 kg) Concentration: <0.05%
Clean Water Act This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the
(CWA) Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters
of the United States, their adjoining shorelines, or into conduits leading to surface waters must
be reported to the EPA's National Response Center at (800) 424-8802.
California This material may contain the following components which are known to the State of California
Proposition 65 to cause cancer, birth defects or other reproductive harm, and may be subject to the
requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5):
Toluene: <0.01%
Benzene: <0.001%
Ethylbenzene: <0.001%
Naphthalene: <0.001%
New Jersey For New Jersey R-T-K labeling requirements, refer to components listed in Section 2.
Right-to-Know Label
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Hexane
Federal Hazardous Substances Act, related statutes, and Consumer Product Safety
Additional Remarks
Commission regulations, as defined by 16 CFR 1500.14(b)(3) and 1500.83(a)(13): This
product contains "Petroleum Distillates" which may require special labeling if distributed in a
manner intended or packaged in a form suitable for use in the household or by children.
Precautionary label dialogue should display the following: DANGER: Contains Petroleum
Distillates! Harmful or fatal if swallowed! Call Physician Immediately. KEEP OUT OF
REACH OF CHILDREN!
SECTION 16. OTHER INFORMATION
Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product.
REVISION INFORMATION
5.0
Version Number
12/18/2008
Revision Date
ABBREVIATIONS
AP: Approximately EQ: Equal >: Greater Than <: Less Than
NA: Not Applicable ND: No Data NE: Not Established
ACGIH: American Conference of Governmental Industrial Hygienists
AIHA: American Industrial Hygiene Association
IARC: International Agency for Research on Cancer
NIOSH: National Institute of Occupational Safety and Health
NPCA: National Paint and Coating Manufacturers Association
EPA: US Environmental Protection Agency
HMIS: Hazardous Materials Information System
OSHA: Occupational Safety and Health Administration
NTP: National Toxicology Program
NFPA: National Fire Protection Association
DISCLAIMER OF LIABILITY
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE.
HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED
REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE
FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER
PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN
INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR
PARTICULAR PURPOSE.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE
BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO
NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE
ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE
PRODUCT.
***** END OF MSDS *****
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