Material Safety Data Sheet
X-Tenda CoatTM Plus MSDS No.310546
Date of Preparation: 4/1/2008 Revision: 001
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: X-Tenda CoatTM Plus
Chemical Formula: Mixture
CAS Number: N/A
Other Designations: N/A
General Use: Roof Coating
Manufacturer: Carlisle SynTec Incorporated, 1285 Ritner Highway, Carlisle, PA 17013, Phone: 800-4SYNTEC
Emergency Phone Number: CHEMTREC (USA) 800-424-9300
Section 2 - Hazards Identification
HMIS
Emergency Overview 1
H
Appearance: Highly thixotropic liquid with faint ammonia-like smell 0
F
Skin and eye irritant, may cause respiratory irritation. 0
R
PPE I
Potential Health Effects Sec. 8
Primary Entry Routes: Skin contact, inhalation, ingestion.
Target Organs: None known
Acute Effects:
Inhalation: Vapor or spray mist can cause headache, nausea and irritation of the nose, throat and lungs.
Eye: Contact with vapor and/or spray mist may irritate the eyes. Eye contact with liquid may result in severe irritation.
Skin: Moderately irritating to the skin.
Ingestion: May cause abdominal pain, nausea and vomiting.
Carcinogenicity: NTP, and OSHA do not list this product as a carcinogen.
This product contains Titanium Dioxide, which is listed by IARC in Group 2 ?Possibly carcinogenic in humans.
Medical Conditions Aggravated by Long-Term Exposure: None known.
Chronic Effects: None known.
Section 3 ?Ingredient Information
CAS Number
Hazardous Ingredients % wt
Fluoropolymer MIXTURE 40
Titanium Dioxide 13463-67-7 15
(contains Aluminum hydroxide, CAS# 21645-51-2 ?no
exposure limits established)
Acrylic polymer MIXTURE 9
(contains 0.2% max. Aqua Ammonia CAS# 1336-21-6)
Urethane Polymer Dispersion MIXTURE 9
(contains 2-Pyrrolidinone, 1-methyl) (872-50-4) (6.8)
(contains Triethylamine) (121-44-8) (1.2)
2,2,4-Trimethyl-1,3-Pentanediol Monoisobutyrate 25265-77-40 4
CAS Number
Additional Ingredients % wt
Water 7732-18-5 16
Section 4 - First Aid Measures
Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing.
Eye Contact: Immediately flush eyes with running water for at least 15 minutes. If redness, itching or a burning sensation
develops, see a physician.
Skin Contact: Remove contaminated clothing/shoes and wipe off excess from skin. Wash exposed area with soap and water. If
redness, itching or a burning sensation develops, get medical attention.
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MSDS No. 310546 X-Tenda CoatTM Plus Revision: 001
Ingestion: Do not induce vomiting. If swallowed, give 2 glasses of water to drink. Get medical attention immediately.
Inhalation: Remove from source of exposure and into fresh air. If symptoms persist consult a physician immediately. If not
breathing, give artificial respiration and call emergency medical services immediately.
After first aid, get appropriate in-plant, paramedic, or community medical support.
Note to Physicians: When heated to 600?F and above, thermal decomposition occurs. The Hexafluoropropylene-vinylidene
fluoride in this product may release Hydrogen Fluoride gas (HF) under these conditions. Hydrogen Fluoride is extremely
corrosive and can cause severe burns, which may not be immediately visible or painful. Exposure to HF may be fatal if absorbed
through the skin, inhaled or swallowed. Patients that have been exposed to HF should be monitored for hypocalcemia, delayed
pulmonary edema and edema of the upper respiratory tract.
Section 5 - Fire-Fighting Measures
NFPA
Flash Point: 248癋 /(120癈)
Burning Rate: Not available.
1
Autoignition Temperature: Not available.
0
0
Lower Flammable Limit: 0.62
Upper Flammable Limit: 4.24
Flammability Classification: Not flammable.
Extinguishing Media: Use dry chemical, carbon dioxide, foam, water fog or spray as appropriate for surrounding fire.
Unusual Fire or Explosion Hazards: None known
Hazardous Combustion Products: Toxic gases or vapors, such as carbon monoxide, carbon dioxide, or oxides of nitrogen may
be released in a fire.
Fire-Fighting Instructions: Do not enter any enclosed or confined fire space without full protective equipment, including self-
contained breathing apparatus (pressure-demand MSHA/NIOSH approved or equivalent) to protect against the hazardous
effects of combustion products and oxygen deficiency.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing
apparatus (SCBA) with a full-face piece operated in pressure-demand or positive-pressure mode.
Section 6 - Accidental Release Measures
Personal Precautions: Use personal protection recommended in Section 8.
Spill /Leak Procedures:
Small Spills: Dike and absorb with inert material such as sand. If spill is in a confined area ventilate the area well. Remove all
liquid by absorbing with sand, saw dust or commercial absorbent, then scoop up and place in containers for proper disposal.
Keep spills and cleaning runoff out of the municipal sewers and open bodies of water. Decontaminate all clothing and the spill
area with a detergent and large amounts of water. If spill occurs near an air inlet, or inside, turn off all heating and air-
conditioning equipment to avoid contaminating other areas of building.
Large Spills: Use same procedure as small spill.
Containment: See Small Spills procedure.
Cleanup: See Small Spills procedure.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions: Avoid skin or eye contact. Avoid prolonged or repeated breathing of vapors and mists. If spilled on
clothing, launder before reuse. Do not take internally. Use only in a well ventilated area. Keep out of the reach of children.
Storage Requirements: Keep from freezing. Product will coagulate. Keep container tightly closed when not in use. Do not get
in eyes, on skin or on clothing. Monomer vapors can be evolved when material is heated. Containers, even those that have
been emptied, will retain product residue and vapors and are subject to proper waste disposal, (Section 13).
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
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Revision: 001 X-Tenda CoatTM Plus MSDS No.310546
Section 8 - Exposure Controls / Personal Protection
OSHA PEL ACGIH TLV NIOSH
TWA STEL TWA STEL TWA IDLH
Ingredient
50 ppm 25 ppm 35 ppm
Aqueous Acrylic Emulsion
Ammonia
2 ppm
Fluoropolymer (limit for
Hydrogen fluoride HF)
Urethane Polymer Dispersion 100 ppm (manufacturer
-2-Pyrrolidinone, 1-methyl recommendation)
15 ppm 1 ppm 3 ppm
- Triethylamine 10 ppm
5,000 mg/m3
10 mg/m3
15 mg/m3 c
Titanium Dioxide
Engineering Controls: Use local exhaust ventilation with a minimum capture velocity of 100 ft/min (.05 m. sec.) at the point of
vapor evolution. Refer to the current edition of industrial ventilation: a manual of recommended practice published by the
American Conference of Governmental Industrial Hygienists for Information on the Design, Installation, Use and Maintenance
of Exhaust Systems.
Administrative Controls: None required.
Respiratory Protection: A respirator protection that meets OSHA respirator regulations (1910.134) and ANSI (Z88.2) or
applicable federal/provincial requirements must be followed whenever workplace conditions warrant a respirator's use.
NIOSH's "Respirator Decision Logic" may be useful in determining the suitability of various types of respirators.
Protective Clothing/Equipment: The use of nitrile rubber gloves is recommended to prevent skin contact. Use Chemical
Goggles if splashing may occur. During spray operations wear a face shield, unless a full-face piece respirator is used. Do not
wear contact lenses as they may contribute to the severity of injury to the eye from exposure to liquid and/or vapors and spray
mist.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.
Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this
material from your shoes and clean personal protective equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before
eating, drinking, smoking, using the toilet, or applying cosmetics.
Section 9 - Physical and Chemical Properties
Physical State: Liquid Water Solubility: Miscible
Appearance and Odor: White liquid with a faint pH: Neutral
ammonia-like odor Boiling Range: 193癋(89.4癈) to 471癋(243癈)
Flash Point: 248癋 /(120癈) Freezing/Melting Point: NA
Burning Rate: Not available. VOC EPA24: 192 g/l (coating)
Autoignition Temperature: Not available. 77 g/l (material)
Lower Flammable Limit: 0.62 Weight Solids: 45% ?2%
Upper Flammable Limit: 4.24 Volume Solids: 31% ?2%
Vapor Pressure: <17 mm Hg at 68 癋 (20 癈) water Specific Gravity (H2O=1, at 4 癈): 1.2493
Vapor Density (Air=1): Lighter than air Flash Point: 248癋 /(120癈)
Burning Rate: Not available.
Autoignition Temperature: Not available.
Lower Flammable Limit: 0.62
Upper Flammable Limit: 4.24
Section 10 - Stability and Reactivity
Stability: Stable.
Possibility of Hazardous Reactions: Will not occur.
Chemical Incompatibilities: Avoid strong oxidizing agents, such as liquid chlorine, concentrated oxygen, sodium hypochlorite
or calcium hypochlorite, and strong bases.
Conditions to Avoid: Avoid storage in extreme heat or cold.
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MSDS No. 310546 X-Tenda CoatTM Plus Revision: 001
Hazardous Decomposition Products: Thermal decomposition may yield hydrogen fluoride gas, which can cause severe burns,
as well as acrylic monomer, carbon monoxide and carbon dioxide. Unidentified organic compounds in fumes and smoke may
be formed during combustion.
Section 11- Toxicological Information
Toxicity Data:
Eye Effects: Hexafluoropropylene-vinylidene Inhalation Effects: Aluminum trihydroxide: Breathing airborne
fluoride copolymer - Rabbit: Slightly irritating. nuisance dust can cause chronic breathing difficulty.
Skin Effects: Hexafluoropropylene-vinylidene Titanium dioxide: LC50 (rat) >6.82 mg/l (4 hr)
fluoride copolymer - Rabbit: Slightly irritating Acute Oral Effects: Nausea, abdominal pain, irritation of the throat.
Repeated contact with cured copolymer Acute Inhalation effects: Headache and irritation of the nose, throat,
produced irritation in rabbits. and lungs.
Titanium Dioxide: Dermal LD50 (rabbit) >10 Acute Skin/Eye Effects: Skin and eye irritation.
g/kg. Chronic Effects: No data available.
Ingestion: Hexafluoropropylene-vinylidene Carcinogenicity: No data available.
fluoride copolymer. Reversible liver effects Mutagenicity: No data available.
were observed in rats given a diet containing Teratogenicity: No data available.
25% of the uncured copolymer for 2 weeks. Reproductive: No data available
Titanium Dioxide: Oral LD50 (rat) >25 g/kg.
Section 12 - Ecological Information
Ecotoxicity:
Titanium Dioxide CAS# 13463-67-7; 96 Hr LC50 (Fathead Minnows) > 1,000 mg/l
This product is not expected to be biodegradable. Avoid spillage into the environment.
Soil Absorption/Mobility: Product spills on porous surfaces can contaminate groundwater. This product is not expected to be
biodegradable.
Section 13 - Disposal Considerations
Disposal: Dispose of unused product or contaminated product and materials used in cleaning up spills or leaks in a manner
approved for this material. Consult appropriate federal, state and local regulatory agencies to ascertain proper disposal
procedures. Incineration is acceptable and the preferred method of disposal, however; nitrogen oxide emissions controls may
be required to meet specifications. Chemical and biological degradation is possible. Empty containers will retain product
residue and vapors and are subject to proper waste disposal, as above.
Section 14 - Transport Information
DOT Transportation Data (49 CFR 172.101):
Not a DOT regulated material. (United States)
Section 15 - Regulatory Information
EPA Regulations:
RCRA Hazardous Waste Number: Not listed (40 CFR 261.33)
CERCLA Hazardous Substance (40 CFR 302.4) listed/unlisted specific per RCRA, Sec. 3001; CWA, Sec. 311 (b)(4); CWA,
Sec. 307(a), CAA, Sec. 112
CERCLA Reportable Quantity (RQ): None Known.
SARA 311/312 Codes:
SARA Toxic Release Chemical (40 CFR 372.65):
2-Pyrrolidinone, 1-methyl CAS# 872-50-4 (see Section 3)
Triethylamine CAS# 121-44-8 (see Section 3)
SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Not listed
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Revision: 001 X-Tenda CoatTM Plus MSDS No.310546
TSCA : The components of this product are listed or excluded from listing on the US Toxic Substances Control Act (TSCA)
chemical substance inventory. Mixtures shall be assumed to present the same health hazards as do the components that
comprise one percent (by weight or volume) or greater of the mixture, except that the mixture shall be assumed to present a
carcinogenic hazard if it has a component in concentrations of 0.1 percent or greater. The remaining percentage of
unspecified ingredients, if any, are not contained in above DeMinimis concentrations and/or are believed to be non-hazardous
under the OSHA Hazard Communication Standard (29 CFR 1910. 1200).
TSCA Flags:
OSHA Regulations:
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed
OSHA Specifically Regulated Substance (29CFR 1910.1200)
Canadian WHMIS: This product is not listed in any division, class, or subdivision.
This product contains the following in recordable amounts: Titanium Dioxide CAS# 13463-67-7
WHMIS Classification: D2A ?Very Toxic
Canadian Environmental Protection Act (CEPA): No Information.
EINECS: All of the components of this product are listed in the EINECS inventory or are exempt from notification
requirements.
State Regulations:
California Proposition 65: These chemicals are listed in the California Proposition 65 to be carcinogens or
reproductive toxicants: 2-Pyrrolidinone, 1-methyl CAS# 872-50-4
In addition to the above named chemical, this product may contain trace amounts of chemicals known to the State of
California, to cause Cancer or Birth Defects and other Reproductive harm.
Delaware: The following chemicals are listed on the Delaware Air Quality Management list:
Aqua Ammonia, CAS # 1336-21-6; DRQ 1000#
2-Pyrrolidinone, 1-methyl, CAS# 872-50-4; RQ 100 (RQ State - State requirement differs from Federal)
Triethylamine, CAS# 121-44-8; DRQ 5000 (RQ State ?Federal Regulations Apply)
Idaho:
Dipropylene glycol monomethyl ether, CAS# 34590-94-8
Idaho Air Pollutant List:
Title 585 ?AAC: 30
Title 585 ?EL: 40
Title 585 ?OEL: 600
Triethylamine, CAS# 121-44-8
Idaho Air Pollutant List:
Title 585 ?AAC: 0.2
Title 585 ?EL: 0.27
Title 585 ?OEL: 4.0
Massachusetts Haz substance codes:
Aqua Ammonia, CAS # 1336-21-6 Substance Code: F8
Dipropylene glycol monomethyl ether, CAS# 34590-94-8 Substance Codes: 2, 4, F8
Calcium Carbonate, CAS# 1317-65-3 Substance Codes: 4
Titanium Dioxide, CAS# 13463-67-7 Substance Codes: 4
2-Pyrrolidinone, 1-methyl, CAS# 872-50-4 Substance Codes: 6
Triethylamine, CAS# 121-44-8 Substance Codes: 2, 4, 5, 6, F8
Minnesota Haz Substance:
Calcium Carbonate, CAS# 1317-65-3 Codes: A, Carcinogen? No
Titanium Dioxide, CAS# 13463-67-7 Codes: A, Carcinogen? No
2-Pyrrolidinone, 1-methyl, CAS# 872-50-4 Codes: I, Status: Title III. TRI.
Triethylamine, CAS# 121-44-8 Codes: AO, Ratings: 9.82, Status: Air Pollutant. Title III. TRI.
Dipropylene glycol monomethyl ether, CAS# 34590-94-8 Codes: AO
New Jersey:
New Jersey Extraordinarily Hazardous Substance:
Aqua Ammonia, CAS# 1336-21-6 RTK Substance number: 0084
New Jersey RTK Hazardous Substances
2-Pyrrolidinone, 1-methyl, CAS# 872-50-4 Substance number: 3716
Triethylamine, CAS# 121-44-8 Substance number: 1907, DOT: 1296
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MSDS No. 310546 X-Tenda CoatTM Plus Revision: 001
New York:
Aqua Ammonia, CAS# 1336-21-6 RQ Air: 1000, RQ Land/Water 100
Triethylamine, CAS# 121-44-8 RQ Air: 5000, RQ Land: 1
Pennsylvania Haz. Substance code:
Ammonia Hydroxide (Aqua Ammonia), CAS# 1336-21-6 Code: E
N-Methyl Pyrrolidone (2-Pyrrolidinone, 1-methyl), CAS# 872-50-4 Code: --
Dipropylene glycol monomethyl ether, CAS# 34590-94-8 Code: --
Calcium Carbonate, CAS# 1317-65-3 Code: E
Triethylamine, CAS# 121-44-8 Code: E
Titanium Dioxide, CAS# 13463-67-7 Code: --
Washington Air Contaminant:
Dipropylene glycol monomethyl ether, CAS# 34590-94-8
(mg/m3)
ppm
TWA: 100 600
STEL: 150 900
Calcium Carbonate (Respirable), CAS# 1317-65-3
(mg/m3)
ppm
TWA Unk. 5
Titanium Dioxide (Total dust), CAS# 13463-67-7
(mg/m3)
ppm
TWA Unk. 10
Triethylamine, CAS# 121-44-8
(mg/m3)
ppm
TWA: 10 40
STEL: 15 60
Wisconsin:
Wisconsin Hazardous Air Contaminant List:
Triethylamine, CAS# 121-44-8 Table A.
West Virginia:
The following chemicals are on the West Virginia Toxic Air Pollutants list:
Ammonium Hydroxide (Aqua Ammonia), CAS# 1336-21-6
Dipropylene glycol monomethyl ether, CAS# 34590-94-8
Calcium Carbonate, CAS# 1317-65-3
Titanium Dioxide, CAS# 13463-67-7
2-Pyrrolidinone, 1-methyl, CAS# 872-50-4
Triethylamine, CAS# 121-44-8
Section 16 - Other Information
Prepared By: Research and Development
Revision Notes: Formatting Changes.
Additional Hazard Rating Systems:
Disclaimer: The information contained in this document is based upon data that was supplied to Carlisle by other companies and
organizations. No warranty of merchantability or fitness for a particular purpose is expressed or implied regarding the accuracy or
completeness of the data and/or information in this material safety data sheet.
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