MSDS 280
REV #4
March 23, 2010
Material Safety Data Sheet
Section 1. Chemical Product and Company Identification
Product Name: 280 Oil
Synonyms: Mineral oil based lubricant
Product Use: Bearing Oil
Supplier/ Manufacturer: Permawick Company
255 E. Brown Street, Suite 100
Birmingham, Michigan 48009
Tel: (248) 433-3500 Fax: (248) 433-1824
Emergency Phone Numbers:
Monday - Friday, 8 am - 5 p.m. (EST) (812) 376-0703
Chemtrec 24 hr. : (800) 424-9300 (US and Canada)
Information Contacts:
For technical information, contact your sales representative.
Section 2. Composition / Information on Ingredients
Criteria for Listing Components in the Composition Section:
Carcinogens are listed at 0.1% or greater.
Components considered hazardous by OSHA are listed at 1.0 % or greater.
Non-hazardous components are listed at 3.0 % or greater.
*This is not intended to be a complete compositional disclosure.*
Hazardous classification:
Percent
CASRN (by wt.)
1. Solvent-refined heavy
paraffinic distillate 64741-88-4 33-55%
2. Hydro-treated heavy
paraffinic distillate 64742-54-7 25-47%
3. Zinc alkyldithiophosphate 68649-42-3 < 1.0%
See section 8 for Exposure Guidelines
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March 23, 2010
Section 3. Hazards Identification
****Emergency Overview****
This compound is not an acute or physical hazard under normal conditions of use. Under fire
conditions there is a possibility of toxic phosphorous oxide vapors being released.
Potential Health Effects, Signs and Symptoms of Exposure:
Inhalation: Irritation possible. Fumes from heated material may cause irritation. Sprays or
mists may be irritating to the upper respiratory tract.
Ingestion: May cause gastrointestinal irritation.
Eye
Contact: May cause tearing, reddening, or swelling.
Skin
Contact: Prolonged or repeated contact may result in defatting, and/or
drying of the skin which may lead to skin irritation and dermatitis. Harmful if
absorbed through the skin.
Medical Conditions aggravated by exposure: None
Section 4. First Aid Measures
FIRST AID
Eye Contact: Immediately flush eyes with plenty of water. If irritation
develops or persists seek medical attention immediately.
Ingestion: Call a physician or poison control center immediately. Only
induce vomiting at the instruction of a physician.
Inhalation: Immediately remove victim to fresh air. If victim has stopped
breathing give artificial respiration, preferably by mouth to mouth.
Get medical attention immediately.
Skin
Contact: Wash affected area immediately with soap and plenty of water.
Remove contaminated clothing and wash clothing before reuse. If
symptoms occur obtain medical attention immediately.
Section 5. Fire Fighting Measures
Flash Point : 400癋 Method used: ASTM D92
Auto-ignition Point: 620癋 (estimated)
Lower explosive limit: not available Upper explosive limit: N/A
NFPA rating:
none
Other Flammable Properties:
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Can burn in a fire and form carbon dioxide and some carbon monoxide.
Extinguishing Media: Water spray or fog, foam, dry chemical or CO2.
Fire Fighting Precautions and Procedure:
Firefighters should wear self - contained breathing apparatus (MSHA / NIOSHA approved or
equivalent) in the positive - pressure mode with full protective gear especially when there is
the possibility of exposure to smoke, fumes or hazardous decomposition of products. Frothing
may occur and may be quite violent. Water spray carefully applied has frequently been used
with success in extinguishing such fires by causing the frothing to occur only on the surface
and this foaming action blankets and extinguishes the fire (NFPA 325M - 1984). Containers
can build up pressure if exposed to heat (fire). Cool with water spray.
Section 6. Accidental Release Measures
Spill or Release Procedures:
Ventilate area. Absorb spill with inert material and place in appropriate chemical waste
container. Obey any federal, state, and local laws and regulations. U.S. Coast
Guard regulations require immediate reporting of spills that could reach any waterway
including intermittant dry creeks. Do not flush into sewers discharging into domestic
water systems or natural waterways. Use personal protective equipment
(Sec.8). Spilled material will cause a slippery surface. Avoid trips and falls.
Section 7. Handling and Storage -
Handling:
Thoroughly wash after handling. Use adequate ventilation and avoid breathing vapor
or mist. Avoid contact with eyes, skin, clothing.
Storage:
Keep container tightly closed when not in use and during transport.
Section 8. Exposure Controls / Personal Protection
Exposure Guidelines:
Component CAS# Exposure Limits
Solvent - refined heavy
3
paraffinic distillate 64741-88-4 OSHA PEL: 5 mg/m (oil mist)
3
ACGIH TLV-TWA: 5 mg/m
(oil mist)
3
ACGIH: TLV-STEL: 10 mg/m
(oil mist)
Hydro-treated heavy
3
paraffinic distillate 64742-54-7 OSHA PEL: 5 mg/m (oil mist)
3
ACGIH TLV-TWA: 5 mg/m
(oil mist)
3
ACGIH TLV-STEL: 10 mg/m
(oil mist)
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March 23, 2010
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Zinc alkyldithiophosphate 68649-42-3 OSHA PEL: 5 mg/m (oil mist)
3
ACGIH STEL: 10 mg/m (oil mist)
Engineering Controls:
Adequate ventilation must be provided to control concentrations below exposure guidelines.
Personal Protective Equipment:
Eye/Face Protection: Use chemical splash goggles or other
approved eye protection.
Skin Protection: Wear impermeable gloves to minimize skin
contact.
Respiratory Protection: Where exposure is likely to exceed acceptable
criteria, use NIOSH/OSHA approve respiratory equipment.
Respirators should be selected based on the form and
concentration of contaminant in air with OSHA concentration
of contaminant in air and in accordance with OSHA (29 CFR
1910.134).
Other Protective Equipment: In order to identify additional Personal
Protective Equipment requirements, the
recommendation is made that a hazard assessment
in accordance with the OSHA PPE Standard ( 29
CFR 1910.132) be conducted before product use.
Section 9. Physical and Chemical Properties
>440癋 @ 760 mm Hg pressure
Boiling Point:
-35F ( ASTM D-97 )
Pour Point:
Vapor Pressure: < 0.05 mm Hg @ 300癋
Vapor Density -
(Air = 1): heavier than air
Specific Gravity: 0.86 - 0.88
@ 60 / 60 F
Density: see specific gravity
pH: Not available
270 - 300 SUS @ 100癋
Viscosity:
55 - 58 SUS @ 210癋
Evaporation Rate: slower than Butyl Acetate
Evaporation Loss
(Ethyl Ether = 1): 1000x slower
Solubility in water: Negligible
Appearance
& color: Amber viscous liquid
Odor: mild odor
% volatiles by
volume: 0
Volatility by weight: not available
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Section 10. Stability and Reactivity
Stability: Stable under normal storage conditions.
Hazardous Polymerization: Will not occur during normal conditions
Conditions to avoid: Mechanical impact: none Static discharge: none
Material Incompatibility: Avoid chlorine, fluorine, acids and other strong oxidizers
Hazardous Decomposition Products:
Carbon Dioxide, Carbon Monoxide, Aldehydes, Hydrogen sulfide, alkyl
mercaptans, and sulfides. Under combustion conditions, oxides of the
following elements will be formed: Phosphorus, Sulfur, Zinc.
Section 11. Toxicological Properties
Inhalation: Testing not conducted
Ingestion: LD50 : > 15 g / kg ( rat ) . Nontoxic
Dermal: LD50: > 5 g / kg ( rabbits) . Nontoxic
Mutagenicity: No data available
Carcinogens: no NTP : no IARC: no
Other Toxicological Information:
Based on testing of similar products by dermal application to rats 5 days / week for 90 days
at doses significantly higher than those expected during industrial exposure, evaluations
including microscopic examination of internal organs and clinical chemistry of body fluids,
showed no adverse effects.
The base oils in this product are severely solvent refined and/or severely hydro-treated.
Two year mouse skin painting studies of similar oils showed no evidence of carcinogenic
effects.
Section 12. Ecological Information
Ecological Fate: No data available
Environmental Effects: 96 hr. LC50 ( Rainbow trout ) = 0.75 (0.54 - 1.04) mg/l
( ICG / T79 - 069 )
96 hr. LC50 ( Fathead minnow ) = 100 mg / l ( ICG / T79 - 069 )
48 hr. LC50 ( Daphnia Magna ) = 0.27 mg / l (ICG / T79 - 069 )
96 hr. LC50 ( Bluegill Sunfish ) = 7000 mg / l ( ICG/ T79 - 069)
Section 13. Disposal Considerations
Disposal Method: All recovered material should be packaged, labeled, transported,
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and disposed or reclaimed in accordance with federal, state and
local regulations. Incineration is the preferred method. Reclaim
where possible.
Section 14. Transportation Information
U.S. Department of Transportation:
DOT proper shipping name: not regulated
DOT classification: not regulated
Section 15. Regulatory Information
U.S. Federal Regulations
OSHA:
Preparation of this document is in accordance with the MSDS requirements of the OSHA
Hazard Communication Standard.
SARA Section 311 / 312:
Hazard classification: Hazardous by OSHA under 29 CFR 1910.1200 (d).
SARA Section 302:
Extremely hazardous substances : none
SARA Section 313:
This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR Part 372:
From 0.4-0.45 % , Zinc compounds; contains < 0.05 % as Zn.
TSCA:
This product or its components are listed in the TSCA inventory .
This product contains n-methyl pyrrolidine (CAS 872-50-4) which is currently undergoing
review and testing under TSCA Section 4. Notification to the U.S. EPA Office of Toxic
Substances is required prior to export of this material from the United States.
CERCLA Hazardous Materials: None reported
OSHA Hazard Communication Standard:
Contains a component listed by OSHA. Contains a component listed by ACGIH.
RCRA:
The unused product is not specifically listed by the E.P.A. as a hazardous waste
(40 CFR, Part 261D).
The used product may be regulated by state or local laws.
State Regulations - None
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MSDS 280
REV #4
March 23, 2010
MSDS 280
REV. # 2
REV. DATE: 9/17/04
Section 16. Other Information
HMIS Rating System: Health : 1 Flammability: 1 Reactivity: 0
Ratings key: 4 = Highest hazard , 0 = Lowest hazard, * = Chronic Health Hazard
Revision summary:
This is the first issue of this MSDS in the ANSI Z400.1 - 1993 format
Approval date : 1/10/97
Supersedes: 4/15/96
This information presented herein is believed to be factual as it has been derived form works and
opinions of persons believed to be qualified experts; however, nothing contained in this information is
to be taken as warranty or representation for which Permawick bears legal responsibility. Conditions
of use and suitability of the product for particular uses are beyond our control. Any
recommendations should be reviewed by the user in the specific context of the intended use to
determine whether they are appropriate. Nothing is intended as a recommendation for uses which
infringe valid patents or as extending license under valid patents.
ACGIH: American Conference of Governmental Industrial Hygienists
ANSI: American National Standards Institute
CASRN: Chemical Abstracts Service Registry Number
CERCLA: Comprehensive Emergency Response, Compensation and Liability Act
HMIS: Hazardous Material Identification System
IARC: International Agency for Resource and Conservation
NTP: National Toxicology Program
OSHA: Occupational Health and Safety Organization
PEL: OSHA Permissable Exposure Limit
RCRA: Resource Conservation and Recovery Act
SARA: Superfund Amendment Reauthorization Act
STEL: Short Term Exposure Limit
TLV: Threshold Limit Values
TSCA: Toxic Substances Control Act
TW A: Time W eighted Average
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