MATERIAL SAFETY DATA SHEET
Prescription Treatment?brand 1300 Orthene Micro Total Release Insecticide
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (PROSAR) TRANSPORTATION: 800-424-9300 (CHEMTREC)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION SECTION 5. FIRE FIGHTING MEASURES
Product Name: Prescription Treatment brand 1300 Orthene FIRE AND EXPLOSION
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Micro Total Release Insecticide Flash Point (Tag Closed Cup): 53?F (concentrate)
EPA Reg. No.: 499-421 Flame Extension (CSMA Flame Projection Test): > 18"
Product Code: 09-1321 (12 x 6 oz.) Flammable Limits in Air (% by volume):
EPA Signal Word: CAUTION Lower (LEL) = 1.3% Upper (UEL) = 9.5%
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc. NFPA 30B Flammability: Level II Aerosol
3568 Tree Court Industrial Blvd. UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
St. Louis MO 63122-6682 Contents under pressure. Exposure to temperatures above 130?F may cause
bursting.
ACTIVE INGREDIENTS (12%) % CAS NO.
IN CASE OF FIRE
Acephate 12% 30560-19-1
Extinguisher Media: CO2, Dry Chemical, Foam
OTHER INGREDIENTS (88%) % CAS NO. Special Fire Fighting Procedures: None required.
Isopropanol proprietary 67-63-0
N-methyl-2-pyrrolidone 25% 872-50-4 SECTION 6. ACCIDENTAL RELEASE MEASURES
Dimethyl Ether proprietary 115-10-6
IN CASE OF SPILL OR LEAK
If container begins to leak (through puncture, etc.) allow to discharge completely
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
in well ventilated area, then dispose of as directed below. This product contains no
OSHA PEL ACGIH TLV Comprehensive Environmental Response, Compensation, and Liability Act (CER-
Material STEL TWA STEL TWA CLA) listed chemicals. Releases of this product are not reportable to the National
Response Center.
Acephate NE NE NE NE
Emergency Telephone Number of Chemtrec: (800) 424-9300 (for trans-
Isopropanol NE 400 ppm 500 ppm 400 ppm
portation spills)
N-methyl-2-pyrrolidone NE 100 ppm NE 100 ppm
Dimethyl Ether NE NE NE 1000 ppm PROTECTIVE EQUIPMENT
Eyes: None required. Protective eyewear such as goggles, face shield or safety
SECTION 3. HAZARDS IDENTIFICATION glasses is recommended.
Skin: Wear chemical-resistant gloves, such as Barrier laminate 14 mils or Butyl
NOTES TO PHYSICIAN rubber 14 mils or Nitrile rubber 14 mils or Neoprene rubber 14 mils or
If symptoms of cholinesterase inhibition are present, atropine sulfate is antidotal. PVC 14 mils or viton 14 mils, coveralls, and shoes plus socks.
2-PAM is also antidotal and may be administered in conjunction with atropine. Inhalation: Wear a respirator with either an organic vapor-removing cartridge with
SIGNS/SYMPTOMS OF EXPOSURE a prefilter approved for pesticides (MSHA/NIOSH approval number prefix TC-23C)
Product may cause eye irritation. Prolonged exposure may cause skin irritation. or a canister approved for pesticides (MSHA/NIOSH approval number prefix TC-
Excessive exposure may cause signs of cholinesterase depression (see below). 14G) or a NIOSH approved respirator with an organic vapor (OV) cartridge or canis-
Note: when used according to label directions, this level will not be attained. ter with any N, R, P or HE prefilter.
SIGNS OF CHOLINESTERASE DEPRESSION WASTE DISPOSAL METHOD
Discomfort or tightness in chest, difficulty in breathing, stomach pains, nausea, Full or leaking containers should be taken to a local disposal company for biologi-
vomiting, diarrhea, cramps, headache, nervousness, weakness, nonactive pinpoint cal treatment or incineration. Whitmire Micro-Gen suggests that all Local , State,
pupils or blurred vision. Symptoms may not occur until 1-12 hours after exposure. and Federal regulations concerning health and pollution be reviewed to determine
approved disposal procedures. Do not contaminate water, food or feed by storage
HAZARDOUS DECOMPOSITION PRODUCTS
or disposal.
Thermal decomposition in open flame will result in carbon dioxide and carbon
monoxide.
SECTION 7. HANDLING AND STORAGE
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
Contents under pressure. Exposure to temperatures above 130?F may cause HAZARDS TO HUMANS AND DOMESTIC ANIMALS
bursting. Keep out of reach of children. CAUTION ?Harmful if swallowed or absorbed
through skin. Causes moderate eye irritation. Avoid contact with eyes, skin and
SECTION 4. FIRST AID MEASURES clothing. Wash thoroughly with soap and water after handling.
USER SAFETY RECOMMENDATIONS
Have the product container or label with you when calling a poison control center or
Users should: Wash hands before eating, drinking, chewing gum, using tobacco
doctor or going for treatment. Describe any symptoms and follow the advice given.
or using the toilet. Remove clothing immediately if pesticide gets inside. Then
This product contains an organophosphate insecticide. wash thoroughly and put on clean clothing. Remove PPE immediately after han-
Eye Contact: Flush eyes with plenty of water. Call a physician if irritation persists. dling this product. Wash the outside of gloves before removing. As soon as possi-
ble, wash thoroughly and change into clean clothing.
Ingestion: Call a physician or Poison Control Center immediately. Drink one or two
glasses of water and induce vomiting by touching back of throat with finger. Do not PHYSICAL OR CHEMICAL HAZARDS
induce vomiting or give anything by mouth to an unconscious person. Extremely Flammable. Contents under pressure. Keep away from heat, sparks, and
Inhalation: Remove person to fresh air. Apply artificial respiration if indicated. Get open flame. Do not puncture or incinerate container. Exposure to temperatures above
medical attention. 130?F may cause bursting. This product contains a highly flammable ingredient. It
may cause a fire or explosion if not used properly. Follow the "Directions for Use" on
Skin Contact: Wash with plenty of soap and water. Get medical attention.
the label very carefully.
Note to Physician: If symptoms of cholinesterase inhibition are present, atropine
sulfate is antidotal. 2-PAM is also antidotal and may be administered in conjunc- STORAGE
tion with atropine. Do not contaminate water, food or feed by storage or disposal. Store in a cool dry
Medical Conditions Generally Aggravated by Exposure: None known. place away from heat or open flame.
Page 1 of 2
MATERIAL SAFETY DATA SHEET
Prescription Treatment?brand 1300 Orthene Micro Total Release Insecticide
SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION SECTION 12. ECOLOGICAL INFORMATION
Do not enter or allow worker entry into treated areas during the restricted entry inter- This product is toxic to fish. Do not apply directly to water, or to areas where surface
val (REI) of 24 hours. water is present or to intertidal areas below the mean high water mark. Do not con-
taminate water when disposing of equipment washwaters. Apply this product only as
PERSONAL PROTECTIVE EQUIPMENT (PPE)
specified on this label.
Respiratory Protection: Wear a respirator with either an organic vapor-removing
cartridge with a prefilter approved for pesticides (MSHA/NIOSH approval number
prefix TC-23C) or a canister approved for pesticides (MSHA/NIOSH approval num- SECTION 13. DISPOSAL CONSIDERATION
ber prefix TC-14G) or a NIOSH approved respirator with an organic vapor (OV) car-
Do not contaminate water, food or feed by disposal.
tridge or canister with any N, R, P or HE prefilter.
Protective Gloves: Wear chemical- resistant gloves, such as Barrier laminate Container Disposal: Dispose of container in accordance with all Federal, state
14 mils or Butyl rubber 14 mils and local regulations. If steel aerosol can recycling is available, this container
Eye Protection: None required. Protective eyewear such as goggles, face shield may be recycled.Before offering for recycling, empty the can by using the product
or safety glasses is recommended. according to the label. (DO NOT PUNCTURE!) If recycling is not available and if
Other Protective Equipment: Long-sleeved shirt and long pants, and shoes
allowed by state and local regulations, wrap container and discard in trash.
plus socks.
Waste Disposal: Wastes resulting from use of this product may be disposed
VENTILATION of on site or at an approved waste disposal facility.
Local Exhaust: None required.
Mechanical: None required.
SECTION 14. TRANSPORT INFORMATION
Special: None required.
Other: Ventilate room before re-entering. DOT CLASSIFICATION
Proper Shipping Name: Consumer Commodity
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
DOT Hazard Class: ORM-D
Appearance: Sprays as strong, Odor: Slight odor.
INTERNATIONAL TRANSPORTATION
dry mist.
Not available
pH: NE Vapor Pressure: 50 psig @ 70?C
Viscosity: NE Vapor Density: NE
SECTION 15. REGULATORY INFORMATION
Boiling Point: NE Freezing/Melting Point: NE
CERCLA
Solubility in Water: Miscible Specific Gravity: 1.27 g/ml @ 20?C
This product contains no CERCLA listed chemicals.
SECTION 10. STABILITY AND REACTIVITY SARA TITLE III SECTION 311/312 HAZARD CLASS
This product has been reviewed according to the EPA "Hazard Categories" prom-
REACTIVITY
ulgated under Section 311 and 312 of the Superfund Amendment and
Stability: Indefinite when used according to label directions.
Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
Conditions to Avoid: Do not spray into open flame or onto very hot surfaces.
definitions, to meet the following categories:
Incompatibility (Material to Avoid): None known.
Hazardous Polymerization: Will not occur. Immediate Health Hazard
Fire Hazard
HAZARDOUS DECOMPOSITION PRODUCTS
Release of Pressure (Puncture) Hazard
Thermal decomposition in open flame will result in carbon dioxide and carbon
monoxide. SARA TITLE III SECTION 313 CHEMICALS
This product contains the following substances subject to the reporting require-
SECTION 11. TOXICOLOGICAL INFORMATION ments of Section 313 of the Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
ACUTE
Acephate 12.0%
Eyes: Produced conjunctival irritation and corneal opacity in rabbits, reversible
N-methyl-2-pyrrolidinone 25.0%
within 7 days. No iritis was noted.
Skin: Acute dermal LD50 > 2,000 mg/kg (rabbits). Primary skin irritation index = TSCA
0.00 (rabbits). Not a skin sensitizer when tested on guinea pigs. All components of this product are listed or excluded from listing on the US Toxic
Ingestion and Inhalation: Unlikely due to the product being pressurized and Substance Control Act (TSCA) Chemical Substance Inventory.
producing particles large enough not to be respirable. Acute oral toxicity (rats)
LD50 > 2,000 mg/kg and < 5,000 mg/kg. Acute inhalation toxicity (rats) LC50 > SECTION 16. OTHER INFORMATION
6,880 mg/L.
NFPA HEALTH RATING INFORMATION:
CHRONIC / CARCINOGENICITY
HEALTH - 1
This product is not classified as a carcinogen by the National Toxicity Program
FLAMMABILITY - 2
(NTP), the International Agency for Research on Cancer (IARC) or the
Occupational Safety and Health Administration (OSHA). REACTIVITY - 1
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or
implied, is made with respect to the information contained herein.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable
NE - Not Established
WHITMIRE MICRO-GEN
PEL - Permissible Exposure Limit WMG Part No. 19-0117
TLV - Threshold Limit Value Effective Date: 6/7/01
RESEARCH LABORATORIES, INC.
STEL - Short Term Exposure Limit (15 min.) Supersedes Revision Dated: NA
TWA - Time Weighted Average (8 hrs) Code #: 203-003
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