TECH LINE COATINGS, INC.
MATERIAL SAFETY DATA SHEET
Section 1
Product Identification
Product Name: 83000 Date Prepared: 1/13/2006
Part Number: 83000 Formula:
Manufacturer / Supplier: Chemical Family:
Tech line Coatings, Inc
26844 ADAMS AVE.
MURRIETA, CA 92562
USA
Emergency Phone:
Phone 972-775-6130
Chemtrec
Fax 951-461-9658
1-800-424-9300
www.techlinecoatings.com
1-703-527-3887
Section 2
Composition / Data On Components
Component CAS# % of Weight OSHA PEL ACGIH TLV Sara 313
Polyamide-imide polymer Trade Secret <30 Not Established Not Established
Triethylamine 12-44-8 <3 25PPM 1PPM N/A
4,4'-methylenedianiline 101-77-9 <.1 .01PPM .1PPM Yes
SILOXANES & SILICONES, DIMETHYL- 73138-88-2 <10 Not Established Not Established
POLYMERS W/ PHENYL
SILSESQUIOXANES
XYLENE 1330-20-7 >10 100 PPM 100 PPM YES
BENZENE 71-43-2 <11 PPB 5 PPM 1 PPM Yes
TOLUENE 108-88-3 <1 150 PPM 100 PPM Yes
Polytrafluoroethylene 9002-84-0 <20 5mg/m3 (dust) 10mg/m3 (dust)
1-Methyl-2-pyrrolidone (N- 872-50-4 <50 Not Established Not Established Yes
methylpyrrolidone)
Ingredients not precisely identified are proprietary or non-hazardous
Section 3
Hazards Identification
Appearance and Odor: Tan Liquid with Solvent Odor
Emergency Overview: Danger! Contains MDA, which may cause cancer. Liver toxin. May be absorbed through the skin. Causes
eye irritation.
Hazard Description: Flammable. Hidden text
Vapors are heavier than air. Vapors may travel across the ground and reach remote ignition sources causing a flashback fire
danger. Hidden text
Electrostatic charges may be generated during pumping. Electrostatic discharge may cause fire. Smoking should not be permitted
when working with this material
Toxic to aquatic organisms.
Vapors may cause drowsiness and dizziness. Hidden text
Irritating to skin. Hidden text
Harmful: may cause lung damage if swallowed.
Section 4
First Aid Measures
After EYE Contact:
Immediately flush with plenty of water for at least 15 minutes. If redness, itching or a burning sensation develops, have eyes
examined and treated by medical personnel
After SKIN Contact: Wash material off the skin with plenty of soap and water. If redness, itching or a burning sensation develops,
seek medical attention. For thermal burns, cool quickly with water and get medical attention. Do not peel off solidified material.
Remove contaminated clothing without delay. Do not reuse clothing without laundering.
After INHALATION:
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Remove victim to fresh air. If cough or other respiratory symptoms develop, consult medical personnel. Administer oxygen if there is
difficulty in breathing. Obtain medical attention immediately if necessary.
After SWALLOWING:
Give one or two glasses of water to drink. If gastrointestinal symptoms develop, consult medical personnel. (Never give anything by
mouth to an unconscious person)
Section 5
Fire Fighting Measures
Flash Point: 79癋 Flammable Limits LEL-: Flammable Limits UEL-: Stability: See Section 10
N/A N/A Stable under normal
Method:
conditions
Extinguishing Media: Special Fire Fighting Procedures:
Water, fog, foam, carbon dioxide, dry chemical, halogenated Self-contained breathing apparatus with full face piece and
agents protective clothing
Unusual Fire And Explosion Hazards:
Keep away from ignition sources. At temperatures above
600F, some polymer fumes may be emitted due to oxidation
of the fluorocarbon polymer.
Section 6
Accidental Release Measures
Steps to be taken in case material is released or spilled:
? Remove sources of ignition.
? Warn other workers of spill.
? Wear protective equipment
? NIOSH Approved Respirator
? Gloves
? Safety Glasses
? Do not allow material to be released into the environment without proper governmental permits
Measures for cleaning / collecting: Wear skin, respiratory and eye protection during clean-up. Sweep up and recover or mix
material with moist absorbent and shovel into waste container
Additional Information:
? See Section 7 for safe handling information.
? See Section 8 for PPE information
? See Section 13 for disposal information
Section 7
Handling and Storage
Handling: Ware skin, respiratory and eye protection. Avoid prolonged or repeated contact with skin.
Storage: Do not allow material to freeze. Keep containers tightly sealed. Do not store with acids. Avoid exposure to moisture; this
product is hygroscopic.
Section 8
Exposure Controls and Personal Protection
Engineering Controls: Exhaust ventilation. Showers, Eyewash stations
Respiratory Protection: Use NIOSH approved respirator if TWA/TLV limits are exceeded
Protective Gloves: Impervious gloves.
Eye Protection: Safety glasses with side shields
Other Protective Equipment: Impervious apron.
Ventilation: Local Exhaust: Use To Maintain Below TWA Limits
Mechanical: Use Non-Sparking Equipment
Work / Hygienic Practices: wash thoroughly after handling product and before eating, drinking or smoking
Section 9
Physical And Chemical Properties
Appearance and Odor: Tan Liquid with Solvent Odor
Boiling Point: Not Established
Vapor Density (Air = 1): Not Established
Vapor Pressure: Not Established
Melting Point: Not Established
Solubility in Water: Miscible
Reactivity in Water: None
VOC's: Not Established
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SECTION 10
STABILITY AND REACTIVITY
Stability: Stable under normal conditions
Incompatibility (Conditions to Avoid): Do not heat above 750?for prolonged periods of time
Avoid heat, sparks, open flames and other ignition sources. Prevent vapor
Incompatibility (Materials to Avoid):
accumulation. Strong oxidizing agents. Molten alkali metals and interhalogen compounds (e.g. bromine trifluoride)
Hazardous Decomposition Products: Carbon Dioxide/Carbon Monoxide, Hydrogen Fluoride (at temperatures above 800?f)
Hazardous Polymerization: Will not occur
Section 11
Toxicological Information
No toxicity information is available on this specific preparation; this product has components that are considered to have
the following toxicological hazards:
: DO NOT DELAY.
InhalationHidden text
Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility
Inhalation
for additional treatment.
Hidden text
: Remove contaminated clothing. Immediately flush skin with large amounts of water for at
Skin ContactHidden text
least 15 minutes, and follow by washing with soap and water if available. If redness,
Hidden text Skin Contact
swelling, pain and/or blisters occur, transport to the nearest medical facility for additional
treatment.
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: Immediately flush eyes with large amounts of water for at least 15 minutes while holding
Eye ContactHidden text
eyelids open. Transport to the nearest medical facility for additional treatment.
Hidden text Eye Contact
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: If swallowed, do not induce vomiting: transport to nearest medical facility for additional
IngestionHidden text
treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration.
Ingestion
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: Potential for chemical pneumonitis. Consider: gastric lavage with protected airway,
Advice to PhysicianHidden
administration of activated charcoal.
text Advice to physicians
Potential for cardiac sensitisation, particularly in abuse situations. Hypoxia or negative
inotropes may enhance these effects. Consider oxygen therapy.
Other Toxicity Data:
This product contains N-methylpyrrolidone (NMP)
Toxicology Test Data:
Rat/ Oral LD50 - 4990 MG/KG - Moderately Toxic
Mouse, Oral LD50 - 5270 MG/KG - Slightly Toxic
Rat, Inhalation Safety Screen, 8 hr - SLIGHTLY IRRITATING
No deaths after 8 hour exposure
Rat, 4 hr Inhalation LC50 - > 5.1 MG/L - Moderately Toxic
Rabbit, Primary Skin Irritation - MARKEDLY IRRITATING
TOX TEST RATING NOT FOUND
Rabbit, Eye Irritation - MARKEDLY IRRITATING
TOX TEST RATING NOT FOUND
Rat, 28-day oral study - 257 - 2056 MG/KG - Testicular effects in highest dose group
Rat, 28-Day Feeding Study - NOAEL: 429 MG/KG/DAY - Decreased body weights at high doses
Mouse, 28 day dietary study - NOAEL: 820 MG/KG/DAY - Target organ: kidney
Rat, 90 day feeding & neurotoxicity study @ 169 - 1344 MG/KG/DAY - NOAEL: Low Dose
Mouse, 3-month oral toxicity, dietary - ?277 - 1931 MG/KG/DAY - NOAEL: Low Dose
Rat, 90 day Inhalation with Recovery - 0, 0.5, 1, 3 MG/L - Testicular effects in highest dose group
Ames Salmonella Assay with or without S9 ?NEGATIVE - No increase in mutation frequency
Mouse Lymphoma Assay with or without S-9 ?NEGATIVE - No increase in mutation frequency
Mouse Micronucleus Test: Bone Marrow NEGATIVE - No clastogenic effects reported
Rat, oral 2 year oncogenicity study @ 66.4 - 939 MG/KG/DAY - Not carcinogenic in rats
Rat, Inhalation Oncogenicity Study - @ 0.04 &; 0.4 MG/L - No evidence of carcinogenicity
Rat, Oral 2-Gen Reproduction Study - NOAEL: 160 MG/KG/DAY - Reduced fertility &; pup survival @ 500
Rat, Oral Developmental Toxicity Study - @ 332 & 997 MG/KG/DAY - Embryotoxic and teratogenic at high dose
Mouse, Oral Developmental Toxicifcy Study - @ 263 & 1055 MG/KG/DAY - Embryotoxic and teratogenic at high dose
Rat dermal teratology range finding test - NOEL: 500 MG/KG/DAY - Maternal toxicity and embryolethality
Rat, Dermal Developmental Toxicity Study - NOEL: 237 MG/KG/DAY - Maternal toxicity and embryolethality
Rat, Inhalation Developmental Toxicity - @ 0.1 & 0.36 MG/L - No maternal or developmental toxicity
Rat, Inhalation Developmental/Repro Test - 10, 50, 116 PPM - No repro effects; smaller pups @ 116 ppm
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Mouse, 18 month oral oncogenicity study - @ 89 - 1399 MG/KG DAY - Increased liver tumors at high dose only.
Acute Overexposure Effects:
Contact with the liquid can result in irritation. Skin contact should be avoided. Prolonged skin contact may result in redness
and dermatitis. NMP is moderately toxic by all routes of exposure; however, due to its low vapor pressure, dermal exposure
represents the primary hazard in most settings. Contact with the liquid results in moderate eye irritation and may cause
temporary corneal clouding. Skin contact results in mild irritation; prolonged skin contact may cause redness and dermatitis.
Inhalation of the vapors of NMP may result in respiratory irritation. Accidental ingestion of the liquid causes gastric
disturbances and may result in nausea and vomiting.
Chronic Overexposure Effects:
In animal studies NMP was embryotoxic by the oral, dermal and intraperitoneal routes, but only after repeated high doses
that approached the LD50 or were maternally toxic. Embryotoxicity without maternal toxicity was observed at a high
concentration in one rat inhalation study, but not in others. Testicular effects in rats were noted after repeated, high-dose
oral and inhalation exposures. NMP was not carcinogenic in rats receiving lifetime exposures via inhalation (100 ppm) or the
diet. This product contains a chemical known to the state of California to cause birth defects or other reproductive harm. In
a mouse cancer study, high doses of NMP produced liver carcinomas &: adenomas in males (1089 Mg/kg) and liver
adenomas in females (1399 mg/kg). Middle doses caused liver hypertrophy in males (173 mg/kg) but not females (221
mg/kg). No effects were noted at low doses in either males (89 mg/kg) or females (115 mg/kg).
This product contains xylene:
: Information given is based on product testing.
Basis for AssessmentHidden
text Basis for assessment
: Low toxicity: LD50 >2000 mg/kg , Rat
Acute Oral ToxicityHidden
text Acute Oral toxicity
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis
which can be fatal.
: Low toxicity: LD50 >2000 mg/kg , Rabbit
Acute Dermal ToxicityHidden
text Acute dermal toxicity
: Low toxicity: LC50>5000 ppm /
Acute Inhalation
1 hours, Rat
ToxicityHidden text Acute
inhalation toxicity
High concentrations may cause central nervous system depression resulting in
headaches, dizziness and nausea; continued inhalation may result in unconsciousness
and/or death.
: Irritating to skin.
Skin IrritationHidden text
Skin irritation
: Moderately irritating to eyes.
Eye IrritationHidden text Eye
irritation
: Inhalation of vapours or mists may cause irritation to the respiratory system.
Respiratory IrritationHidden
text Respiratory irritation
: Liver: can cause liver damage.
Repeated Dose
ToxicityHidden text Repeated
dose toxicity
Kidney: can cause kidney damage.
Central nervous system: repeated exposure affects the nervous system.
Auditory system: prolonged and repeated exposures to high concentrations have resulted
in hearing loss in rats. Solvent abuse and noise interaction in the work environment may
cause hearing loss.
Cardiovascular system: chronic abuse of similar materials has been associated with
irregular heart rhythms and cardiac arrest.
: Not mutagenic.
MutagenicityHidden text
Mutagenicity
: Not carcinogenic in animal studies. (Xylene, Mixed Isomers)
CarcinogenicityHidden text
Carcinogenicity
Limited evidence of carcinogenic effect. (Ethylbenzene)
: Does not impair fertility.
Reproductive and
(Xylene, Mixed Isomers)
Developmental Toxicity
Hidden text Reproductive
and developmental toxicity
Repeated inhalation of Ethyl Benzene for 186 days at levels well exceeding the TLV
caused degeneration of the germinal epithelium in the testes of rabbits and monkeys
but not of rats.
Causes foetotoxicity in animals at doses which are maternally toxic.
(Xylene, Mixed Isomers)
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In developmental toxicity studies conducted in laboratory animals, there is no evidence
of teratogenicity following inhalation exposure to xylene, but delayed development and
some behavioural impairments have been observed in offspring.
Hidden text
: Over exposures of humans to xylene or xylene solvent mixtures produced
Hidden text Additional
predominately central nervous system (CNS) effects with less common effects reported
InformationHidden text
to the lung, gastrointestinal tract, liver, kidney and heart.
Additional information
: Carcinogenicity Classification
Material
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Ethylbenzene : Hidden text
ACGIH Group A3: Confirmed animal carcinogen with unknown relevance to
humans.Hidden text
Ethylbenzene : IARC 2B: Possible carcinogen.Hidden text
Xylene, Mixed Isomers : Hidden text
ACGIH Group A4: Not classifiable as a human carcinogen.Hidden text
Xylene, Mixed Isomers : IARC 3: Classification not possible from current data.Hidden text
This product contains < .2% residual 4,4'-methylenedianiline (MDA):
Dermal absorption of MDA is rapid. Acute exposure via inhalation, ingestion or absorption through the skin can induce liver toxicity
and symptoms indicative of hepatitis. These effects are totally reversible at exposure levels below the recommended workplace
exposure limits. Direct contact with the eye or ingestion of MDA can result in damage to the retina of the eye. Direct contact may be
irritating to the skin, causing dermatitis. Long term overexposure to MDA via inhalation, ingestion or dermal absorption is suspected
to cause bladder cancer in humans, MDA is considered a suspected human carcinogen by OSHA, the international Agency for
Research on Cancer (IARC), the National Toxicology Program (NTP), the American Conference of Governmental Industrial
Hygienists (ACGIH, and the National Institute for Occupational Safety and Health (NIOSH).
Section 12
Ecological Information
General Comments: Do not allow material to be released into the environment without proper governmental permits
Section 13
Disposal Considerations
Waste Disposal Method: Recover or recycle if possible.
It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine
the proper waste classification and disposal methods in compliance with applicable regulations. Empty container retains product
residue. Observe all precautions. Do not distribute, make available, furnish or reuse empty container except for storage and
shipment of original product. Remove all product residue and puncture of otherwise destroy empty container before disposal.
Disposal should be made in accordance with federal, state and local regulations.
Section 14
Transportation Information
Hazardous for Shipping: Yes
DOT Shipping Name: Paint
Technical Name: N/A
DOT Hazard Class: 3
DOT Labels: Flammable
UN Number: UN1263
Placards: UN1263 Flammable
Packing Group: III
Air (IATA): Paint, 3, UN1263, PGIII
Sea (IMDG): Paint, 3, UN1263, PGIII
Section 15
Regulations
The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.Hidden text
The regulatory information provided is not intended to be comprehensive. Other regulations may apply to this material.
Federal Regulatory Status
Notification Status Hidden text Notification status
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EINECS Hidden 215-535-7
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KECI (KR) Hidden 97-1-275
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Comprehensive Environmental Release, Compensation & Liability Act (CERCLA) Hidden text Comprehensive
Environmental Release, Compensation &Liability Act (CERCLA)
Hidden text Note: Tthis null group is necesssary, but why (see ZISIWWI_MSDSUS_FILTER)???
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XyleneHidden text (1330-20-7) Reportable quantity:
100
lbs
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Hidden text Note: Tthis null group is necesssary, but why (see ZISIWWI_MSDSUS_FILTER)???
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Xylene, Mixed Isomers (1330-20-7) Reportable quantity:
100
lbs
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Ethylbenzene (100-41-4) Reportable quantity:
1,000
lbs
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Benzene (71-43-2) Reportable quantity:
10
lbs
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Clean Water Act (CWA) Section 311 Hidden text Clean Water Act (CWA) Section 311
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XyleneHidden text (1330-20-7) Hidden text Reportable quantity:
Hidden text 100
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Hidden text Note: Tthis null group is necesssary, but why (see ZISIWWI_MSDSUS_FILTER)???
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Xylene, Mixed Isomers (1330-20-7) Hidden text Reportable quantity:
Hidden text 100
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Ethylbenzene (100-41-4) Hidden text Reportable quantity:
Hidden text 1,000
Hidden text lbs
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Benzene (71-43-2) Hidden text Reportable quantity:
Hidden text 10
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SARA Hazard Categories (311/312) Hidden text SARA Hazard categories (311/312)
Hidden text Immediate (Acute) Health Hazard. Hidden text Delayed (Chronic) Health Hazard. Hidden
text Fire Hazard.
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SARA Toxic Release Inventory (TRI) (313) Hidden text SARA Toxic Release Inventory (TRI) (313)
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Xylene, Mixed Isomers (1330-20-7) < 35.00Hidden text %
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Ethylbenzene (100-41-4) < 10.00Hidden text %
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Benzene (71-43-2) < 0.02Hidden text %
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Hidden text Note: Tthis null group is necesssary, but why (see ZISIWWI_MSDSUS_FILTER)???
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State Regulatory Status
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65) Hidden text California Safe Drinking Water and
Toxic EnforcementHidden text Hidden text Act (Proposition 65):
This product contains one or more chemicals known to the State of California to cause cancer, birth defects or other reproductive
harm.
Hidden text pulling information from component level
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Ethylbenzene (100-41-4) < 10.00Hidden text % Carcinogenic.
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Benzene (71-43-2) < 0.02Hidden text % Carcinogenic.
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Developmental toxin.
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Male reproductive toxin.
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Hidden text New Jersey Right-To-Know Chemical List Hidden text New Jersey Right-To-Know Chemical List:
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Xylene, Mixed Isomers (1330-20-7) 32.00Hidden text %Hidden text
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Ethylbenzene (100-41-4) < 10.00Hidden text %Hidden text
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Benzene (71-43-2) < 0.02Hidden text %Hidden text
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Pennsylvannia Right-To-Know Chemical List Hidden text Pennsylvannia Right-To-Know Chemical List:
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Xylene, Mixed Isomers (1330-20-7) < 35.00Hidden text %Hidden text Environmental hazard.
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Ethylbenzene (100-41-4) < 10.00Hidden text %Hidden text Environmental hazard.
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Benzene (71-43-2) < 0.02Hidden text %Hidden text Special hazard.
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Environmental hazard.
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Section 16
Other Information
This information is furnished without warranty, representation, inducement or license of any kind, except that it is accurate
to the best of Tech Line Coatings, Inc., knowledge or obtained from sources believed by Tech Line Coatings, Inc. to be
accurate. Tech Line Coatings, Inc. does not assume any legal responsibility for use or reliance upon same. Before using
any chemical, read its label, instructions and material safety data sheet.
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