WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900
Page 1 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: PermaGrip Adhesive, Part A Item No.: 83674
Product Type: Acrylics Region: United States / Canada
Company address: WrapMaster, Inc. Contact Information:
2701 State Highway 322 Emergency: Chem-Tel (800) 255-3924
Longview, Texas 75603 Other Calls: Chem-Tel (877) 486-1122
Tel: (903) 643-8080 Fax: (903) 643-8181
2. COMPOSITION / INFORMATION ON INGREDENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Methyl methacrylate 30-60 100 ppm STEL 100 ppm TWA 50 ppm
?br>
80-62-6 50 ppm TWA 410 mg/m TWA
Polyethylene based rubber 10-30 None None None
Proprietary
Hydroxyalkyl methacrylate 10-30 None None 3 ppm (ceiling)
868-77-9
?br>
2,6-Di-t-butyl-p-cresol 1-5 2 mg/m TWA inhalable None None
128-37-0 fraction and vapor
Methacrylic acid 1-5 20 ppm TWA None None
79-41-4
?br>
Talc 0.1-1 2 mg/m TWA respirable = 20 mppcf TWA 50 ppm
14807-96-6 fraction, particulate matter
containing no asbestos
and < 1% crystalline silica
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Paste HEALTH: 2*
Color: Blue Opaque FLAMMABILITY: 3
Odor: Sharp PHYSICAL HAZARD: 1
Personal Protection: See Section 8
WARNING: FLAMMABLE LIQUID AND VAPOR.
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
HARMFUL IF SWALLOWED.
MAY CAUSE ALLERGIC SKIN REACTION.
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion
Potential Health Effects
Inhalation: Vapors may cause headaches, nausea, dizziness and respiratory tract irritation.
Skin contact: Irritating to skin. May cause allergic skin reaction.
Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation.
Ingestion: May be harmful if swallowed. Ingestion causes irritation and effects similar to inhalation.
Existing conditions aggravated by Eye, skin, and respiratory disorders.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If symptoms develop and persist, get medical attention.
Skin contact: Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before
reuse. Get medical attention if symptoms occur.
Eye contact: Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes,
holding eyelids open all the time. Get medical attention.
Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention.
WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900
Page 2 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
5. FIRE- FIGHTING MEASURES
Flash point: 14癈 (58癋) Setaflash Closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
Unusual fire or explosion hazards: Vapors may accumulate in low or confined areas, travel considerable distance to source of
ignition, and flash back.
Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. Hydrogen cyanide. Hydrogen chloride.
Acids. Aldehydes. Alcohols. Toxic fumes. Acrid smoke and fumes. Irritating organic vapors.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Remove all ignition sources. Ensure adequate ventilation. Soak up with inert absorbent. Store
in a closed container until ready for disposal.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash
thoroughly after handling. During use and until all vapors are gone: Keep area ventilated -
do not smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical tools
and appliances, and any other sources of ignition. Make sure containers are properly
grounded before use or transfer of material.
Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container
tightly closed until ready for use. For safe storage, store at or below 32癈 (90癋).
Incompatible products: Refer to Section 10.
For information on product shelf life contact WrapMaster, Inc. at (903) 643-8080
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure
limits.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Skin protection: Chemical resistant, impermeable gloves. Nitrile gloves.
Eye/face protection: Safety goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Paste
Color: Blue Opaque
Odor: Sharp
Vapor pressure: 28 mmHg @20癈 (68?F)
pH: Not applicable
Boiling point/range: Greater than 38癈 (100癋)
Melting point/range: Not available
Specific gravity: 1.03
Vapor density: Greater than 1
Evaporation rate: Faster than ether
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available
VOC content: Not available
WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900
Page 3 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: May occur.
Hazardous decomposition products: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. Hydrogen cyanide. Hydrogen
chloride. Acids. Aldehydes. Alcohols. Carbon tetrachloride. Styrene. Acrolein. Acetophenone.
Ethylbenzene. Cumene. 4-Vinyl cyclohexene. Phenols. Irritating organic vapors. Toxic
fumes. Smoke.
Incompatability: Oxidizing agents. Reducing agents. Acids. Bases.
" " " "
Conditions to avoid: See Handling and Storage (Section 7) and Incompatabilty (Section 10). Do not mix in
batches greater than 100 grams (0.220 pounds) unless you plan to use immediately.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Methyl methacrylate No No No
80-62-6
Polyethylene based rubber No No No
Proprietary
Hydroxyalkyl methacrylate No No No
868-77-9
2,6-Di-t-butyl-p-cresol No No No
128-37-0
Methacrylic acid No No No
79-41-4
Talc No No No
14807-96-6
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Methyl methacrylate Allergen, Irritant, Kidney, Liver, Nervous System, Respiratory, Mutagen
80-62-6
Polyethylene based rubber No Target Organs
Proprietary
Hydroxyalkyl methacrylate Allergen, Irritant
868-77-9
2,6-Di-t-butyl-p-cresol Mutagen, Irritant
128-37-0
Methacrylic acid Allergen, Corrosive, Irritant
79-41-4
Talc Some evidence of carcinogenicity, Lung, Irritant
14807-96-6
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.
EPA hazardous waste number: D001: Ignitable.
WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900
Page 4 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
14. TRANSPORTATION INFORMATION
Department of Transportation Ground (49 CFR):
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
Exceptions: Consumer Commodity ORM-D (Not more than 5 L)
Marine pollutant: None
International Air Transportation (ICAO/IATA):
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
WaterTransportation (IMO/IMDG):
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
Marine pollutant: None
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: 4-Methoxyphenol (150-76-5).
CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 31 1/312: Immediate Health Hazard, Delayed Health Hazard, Fire
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Methyl Methacrylate (CAS# 80-62-6).
California Proposition 65: This product contains a chemical known to the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: B.2, D.2.A, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: 14
Prepared for: WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603 (903) 643-8080
Prepared by: Elvin C. Loyd, Vice President
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, WrapMaster,
Inc. does not assume responsibility for any results obtained by persons over whose methods WrapMaster, Inc. has no control.
'
It is the user s responsibility to determine the suitability of WrapMaster's products or any production methods mentioned
herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons
against any hazards that may be involved in the handling and use of any of WrapMaster's products. In light of the foregoing,
WrapMaster, Inc. specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a
particular purpose, arising from sale or use of WrapMaster's products. WrapMaster, Inc. further disclaims any liability for
consequential or incidental damages of any kind, including lost profits.
WM2000A-B Adhesive Activator Material Safety Data Sheet
Part No.: WM2000A-B (Subcomponents of AKD-400 thru AKC3900)
Page 1 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: PermaGrip Adhesive, Part B Item No.: 83046
Product Type: Adhesives, Activator Region: United States / Canada
Company address: WrapMaster, Inc. Contact Information:
2701 State Highway 322 Emergency: Chem-Tel (800) 255-3924
Longview, Texas 75603 Other Calls: Chem-Tel (877) 486-1122
Tel: (903) 643-8080 Fax: (903) 643-8181
2. COMPOSITION / INFORMATION ON INGREDENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Aldehyde-amine condensate 10-30 None None None
Proprietary
Methyl methacrylate 60-100 100 ppm STEL 100 ppm TWA 50 ppm
?br>
80-62-6 50 ppm TWA 410 mg/m TWA
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Paste HEALTH: 2*
Color: Yellow Opaque FLAMMABILITY: 3
Odor: Sharp PHYSICAL HAZARD: 1
Personal Protection: See Section 8
WARNING: FLAMMABLE LIQUID AND VAPOR.
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
HARMFUL IF SWALLOWED.
MAY CAUSE ALLERGIC SKIN REACTION.
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion
Potential Health Effects
Inhalation: Vapors may cause headaches, nausea, dizziness and respiratory tract irritation.
Skin contact: Irritating to skin. May cause allergic skin reaction.
Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation.
Ingestion: May be harmful if swallowed. Ingestion causes irritation and effects similar to inhalation.
Existing conditions aggravated by Eye, skin, and respiratory disorders.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If symptoms develop and persist, get medical attention.
Skin contact: Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before
reuse. Get medical attention if symptoms occur.
Eye contact: Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes,
holding eyelids open all the time. Get medical attention.
Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention.
5. FIRE- FIGHTING MEASURES
Flash point: 14癈 (58癋) Setaflash Closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: None
Unusual fire or explosion hazards: Vapors may accumulate in low or confined areas, travel considerable distance to source of
WM2000A-B Adhesive Activator Material Safety Data Sheet
Part No.: WM2000A-B (Subcomponents of AKD-400 thru AKC3900)
Page 2 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
ignition, and flash back.
Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Hydrogen cyanide. Aldehydes. Ketones. Toxic fumes.
Acrid smoke and fumes. Irritating organic vapors.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Remove all ignition sources. Ensure adequate ventilation. Soak up with inert absorbent. Store
in a closed container until ready for disposal.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash
thoroughly after handling. During use and until all vapors are gone: Keep area ventilated -
do not smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical tools
and appliances, and any other sources of ignition. Make sure containers are properly
grounded before use or transfer of material.
Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container
tightly closed until ready for use. For safe storage, store at or below 32癈 (90癋).
Incompatible products: Refer to Section 10.
For information on product shelf life contact WrapMaster, Inc. at (903) 643-8080
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure
limits.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Skin protection: Chemical resistant, impermeable gloves. Nitrile gloves.
Eye/face protection: Safety goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Paste
Color: Yellow Opaque
Odor: Sharp
Vapor pressure: 28 mmHg @20癈 (68?F)
pH: Not applicable
Boiling point/range: Greater than 38癈 (100癋)
Melting point/range: Not available
Specific gravity: 0.96
Vapor density: Greater than 1
Evaporation rate: Faster than ether
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available
VOC content: 2.60%; 26.0 grams/liter (Adhesive and Activator mixed)
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: May occur.
Hazardous decomposition products: Oxides of carbon. Oxides of nitrogen. Hydrogen cyanide. Aldehydes. Styrene. Acrolein.
Acetophenone. Ethylbenzene. Cumene. 4-Vinyl cyclohexene. Phenols. Ketones. Irritating
organic vapors. Toxic fumes. Smoke.
Incompatability: Oxidizing agents. Reducing agents. Acids. Bases.
" " " "
Conditions to avoid: See Handling and Storage (Section 7) and Incompatabilty (Section 10). Do not mix in
batches greater than 100 grams (0.220 pounds) unless you plan to use immediately.
WM2000A-B Adhesive Activator Material Safety Data Sheet
Part No.: WM2000A-B (Subcomponents of AKD-400 thru AKC3900)
Page 3 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Aldehyde-amine condensate No No No
Proprietary
Methyl methacrylate No No No
80-62-6
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Aldehyde-amine condensate No data
Proprietary
Methyl methacrylate Allergen, Irritant, Kidney, Liver, Nervous System, Respiratory, Mutagen
80-62-6
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.
EPA hazardous waste number: D001: Ignitable.
14. TRANSPORTATION INFORMATION
Department of Transportation Ground (49 CFR):
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
Exceptions: Consumer Commodity ORM-D (Not more than 5 L)
Marine pollutant: None
International Air Transportation (ICAO/IATA):
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
Exceptions: May Qualify as Consumer Commodity ID8000 (Not more than 500 ml)
WaterTransportation (IMO/IMDG):
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
Marine pollutant: None
15. REGULATORY INFORMATION
United States Regulatory Information
WM2000A-B Adhesive Activator Material Safety Data Sheet
Part No.: WM2000A-B (Subcomponents of AKD-400 thru AKC3900)
Page 4 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: 4-Methoxyphenol (150-76-5).
CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 31 1/312: Immediate Health Hazard, Delayed Health Hazard, Fire
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Methyl Methacrylate (CAS# 80-62-6).
California Proposition 65: This product contains a chemical known to the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: B.2, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: 14
Prepared for: WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603 (903) 643-8080
Prepared by: Elvin C. Loyd, Vice President
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, WrapMaster,
Inc. does not assume responsibility for any results obtained by persons over whose methods WrapMaster, Inc. has no control.
'
It is the user s responsibility to determine the suitability of WrapMaster's products or any production methods mentioned
herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons
against any hazards that may be involved in the handling and use of any of WrapMaster's products. In light of the foregoing,
WrapMaster, Inc. specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a
particular purpose, arising from sale or use of WrapMaster's products. WrapMaster, Inc. further disclaims any liability for
consequential or incidental damages of any kind, including lost profits.
WM2000F-A Epoxy Adhesive Material Safety Data Sheet
Part No.: WM2000F-A (Subcomponent of FKC-500)
Page 1 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: PermaPutty Part A Item No.: 83206
Product Type: Epoxy Adhesive Resin Region: United States / Canada
Company address: WrapMaster, Inc. Contact Information:
2701 State Highway 322 Emergency: Chem-Tel (800) 255-3924
Longview, Texas 75603 Other Calls: Chem-Tel (877) 486-1122
Tel: (903) 643-8080 Fax: (903) 643-8181
2. COMPOSITION / INFORMATION ON INGREDENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
'
Epichlorohydrin-4,4 - 30-60 None None None
isopropylidene diphenol resin
25068-38-6
?br>
Tremolite 10-30 1 mg/m TWA as Fe = 0.1 f/cc TWA see None
14567-73-8 1910.1001
Antigorite 10-30 None None None
12135-86-3
?br>
Talc 10-30 2 mg/m TWA respirable = 20 mppcf TWA 50 ppm
14807-96-6 fraction, particulate matter
containing no asbestos
and < 1% crystalline silica
Anthophyllite 1-5 None 0.1 fiber/cc TWA fibers None
17068-78-9 longer than 5 祄
1.0 fiber/cc Excursion
Limit 30 min. Cancer and
lung disease hazard - see
29 CFR 1910.1001 - does
not include non-
asbestiform actinolite,
tremolite or anthophylite
? ?br>
Titanium dioxide 1-5 10 mg/m TWA 15 mg/m TWA total dust None
13463-67-7
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Viscous liquid HEALTH: 2*
Color: White FLAMMABILITY: 1
Odor: None PHYSICAL HAZARD: 1
Personal Protection: See Section 8
WARNING: MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
Relevant routes of exposure: Eye contact, Ingestion, Inhalation, Skin contact
Potential Health Effects
Inhalation: May cause irritation to nose and throat. Mild respiratory tract irritation. Coughing.
Skin contact: Allergic skin reaction. Moderate skin irritation. Itching. Redness.
Eye contact: Moderate eye irritation. Redness.
Ingestion: Not expected under normal conditions of use.
Existing conditions aggravated by Skin disorders. Skin allergies. Respiratory disorders. Eye disorders.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial
respiration. Get medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated
clothing and shoes. Get medical attention if symptoms occur.
WM2000F-A Epoxy Adhesive Material Safety Data Sheet
Part No.: WM2000F-A (Subcomponent of FKC-500)
Page 2 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual
calm. Get medical attention if symptoms develop and persist.
5. FIRE- FIGHTING MEASURES
? ?br>
Flash point: Greater than 93 C (200 F) Pensky Martens closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
Unusual fire or explosion hazards: In the event of fire, cool tanks with water spray. Closed containers may rupture (due to
build up of pressure) when exposed to extreme heat.
.
Hazardous combustion products: Oxides of carbon. Irritating organic fragments. Acids. Aldehydes.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Remove all ignition sources. Immediately contact emergency personnel. Scrape up as
much material as possible. Clean residue with soap and water. Store in a closed container
until ready for disposal.
7. HANDLING AND STORAGE
Handling: Keep away from heat, spark and flame. Do not breathe mist or vapors. Keep container
closed. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.
Storage: Store in original container until ready to use. Keep in a cool, well ventilated area away from
heat, sparks and open flame. Keep container tightly closed until ready for use.
Incompatible products: Refer to Section 10.
For information on product shelf life contact WrapMaster, Inc. at (903) 643-8080
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure
limits.
Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established
exposure limits exists.
Skin protection: Chemical resistant, impermeable gloves.
Eye/face protection: Chemical splash goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Viscous liquid
Color: White
Odor: None
Vapor pressure: Nil
pH: Not applicable
Boiling point/range: Greater than 260癈 (500癋)
Melting point/range: Not available
Specific gravity: 1.57
Vapor density: Not available
Evaporation rate: Not available
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not available
VOC content: < 0.05% (value for resin and hardener together) (estimated)
WM2000F-A Epoxy Adhesive Material Safety Data Sheet
Part No.: WM2000F-A (Subcomponent of FKC-500)
Page 3 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: Will not occur.
Hazardous decomposition products: None
Incompatability: Strong acids. Strong bases. Strong oxidizers. Amines. Water.
Conditions to avoid: Excessive heat. Storage with incompatible materials.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
'
Epichlorohydrin-4,4 - No No No
isopropylidene diphenol resin
25068-38-6
Tremolite No Group 1 Yes
14567-73-8
Antigorite No No No
12135-86-3
Talc No No No
14807-96-6
Anthophyllite Known Carcinogen No Yes
17068-78-9
Titanium dioxide No No No
13463-67-7
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
'
Epichlorohydrin-4,4 - Allergen, Irritant
isopropylidene diphenol resin
25068-38-6
Tremolite Lung, Mutagen, Carcinogen
14567-73-8
Antigorite Lung, Some evidence of carcinogenicity, Mutagen
12135-86-3
Talc Some evidence of carcinogenicity, Lung, Irritant
14807-96-6
Anthophyllite Carcinogen, Mutagen, Lung
17068-78-9
Titanium dioxide Irritant, Respiratory
13463-67-7
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.
EPA hazardous waste number: Not a RCRA hazardous waste.
WM2000F-A Epoxy Adhesive Material Safety Data Sheet
Part No.: WM2000F-A (Subcomponent of FKC-500)
Page 4 of 4 Printing date 07.27.2006 Reviewed on 07.27.2006
14. TRANSPORTATION INFORMATION
Department of Transportation Ground (49 CFR):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
International Air Transportation (ICAO/IATA):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
WaterTransportation (IMO/IMDG):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
Marine pollutant: None known
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 31 1/312: Immediate Health Hazard, Delayed Health Hazard
CERCLA/SARA 313: None above reporting de minimus.
California Proposition 65: This product contains a chemical known to the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: First issue
Prepared for: WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603 (903) 643-8080
Prepared by: Elvin C. Loyd, Vice President
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, WrapMaster,
Inc. does not assume responsibility for any results obtained by persons over whose methods WrapMaster, Inc. has no control.
'
It is the user s responsibility to determine the suitability of WrapMaster's products or any production methods mentioned
herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons
against any hazards that may be involved in the handling and use of any of WrapMaster's products. In light of the foregoing,
WrapMaster, Inc. specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a
particular purpose, arising from sale or use of WrapMaster's products. WrapMaster, Inc. further disclaims any liability for
consequential or incidental damages of any kind, including lost profits.
WM2000F-B Epoxy Activator Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500)
Page 1 of 5 Printing date 07.27.2006 Reviewed on 07.27.2006
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: PermaPutty Part B Item No.: 36765
Product Type: Epoxy Hardener Region: United States / Canada
Company address: WrapMaster, Inc. Contact Information:
2701 State Highway 322 Emergency: Chem-Tel (800) 255-3924
Longview, Texas 75603 Other Calls: Chem-Tel (877) 486-1122
Tel: (903) 643-8080 Fax: (903) 643-8181
2. COMPOSITION / INFORMATION ON INGREDENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Silica, Quartz 10-30 0.05mg/m3 TWA 0.1mg/m3 TWA None
14808-60-7 respirable fraction (respirable)
Talc 10-30 2 mg/m3 TWA = 20 mppcf TWA 50 ppm
14807-96-6 respirable fraction,
particulate matter
containing no asbestos
Diethylene Triamine 10-30 1 ppm skin None None
111-40-0 (skin)
Epoxy resin/Curing agent 10-30 None None None
Proprietary
4,4 '- IsopropylidenedIphenol 1-5 None None None
80-05-7
Carbon Black 0.1-1 3.5 mg/m3 TWA 3.5 mg/m3 TWA None
1333-86-4
N-(2-Aminoethyl)piperazine 0.1-1 None None None
140-31-8
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Viscous liquid HEALTH: 3
Color: Black FLAMMABILITY: 1
Odor: Strong Ammoniacal PHYSICAL HAZARD: 0
Personal Protection: See Section 8
DANGER: CAUSES EYE AND SKIN BURNS.
MAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION.
HARMFUL IF SWALLOWED.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
Relevant routes of exposure: Eye, Skin, Inhalation, Ingestion
Potential Health Effects
Inhalation: May cause respiratory tract irritation. May cause irritation to nose and throat. May cause
sensitization by inhalation. May cause allergic respiratory reaction. Contains crystalline
silica (quartz), which is classified as a possible carcinogen. However, the crystalline silica
present in this product is encapsulated in the epoxy resin and will only be liberated if the
product is sanded or abraded, and even then what is liberated will not be a pure crystalline
silica. Appropriate precautions, however, should be taken if the product is sanded or
abraded to prevent personnel from breathing the dust.
Skin contact: May cause skin burns. May cause allergic skin reaction.
Eye contact: Possible burns to eyes. May cause corneal injury. May cause severe eye irritation.
Ingestion: Harmful if swallowed.
Existing conditions aggravated by Eye, skin, and respiratory disorders. Pre-existing skin or lung allergies may increase the
exposure: chance of developing exaggerated allergic symptoms from exposure to this product.
See Section 11 for additional toxicological information.
WM2000F-B Epoxy Activator Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500)
Page 2 of 5 Printing date 07.27.2006 Reviewed on 07.27.2006
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. If symptoms develop and persist, get medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. If
irritation persists, get medical attention.
Eye contact: Check for and remove any contact lenses. Immediately flush eyes with plenty of water for
at least 15 minutes. If eye irritation persists, consult a specialist.
Ingestion: Keep individual calm. DO NOT induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Give a conscious
person several glasses of water.Get medical attention if symptoms develop and persist.
5. FIRE- FIGHTING MEASURES
Flash point: 215癋 Open cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Firefighters should wear self contained breathing apparatus (SCBA) and full turn out gear.
Unusual fire or explosion hazards: Violent steam generation may occur upon application of direct water stream.
Hazardous combustion products: Oxides of carbon. Smoke. Oxides of nitrogen.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Immediately contact emergency personnel. Evacuate and ventilate spill area; dike spill to
prevent entry into water system; wear full protective equipment during clean-up. Remove all
sources of ignition. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Scrape up. Store in a closed container until ready for disposal.
7. HANDLING AND STORAGE
Handling: Keep away from heat, spark and flame. Avoid contact with eyes, skin and clothing. Avoid
breathing
vapor. Do not taste or swallow. Keep container closed. Wash thoroughly after handling.
Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep
container tightly closed until ready for use.
Incompatible products: Refer to Section 10.
For information on product shelf life contact WrapMaster, Inc. at (903) 643-8080
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation if the potential for airborne exposure exists.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body
suit to prevent skin contact.
Eye/face protection: Chemical splash goggles or safety glasses with side shields. Full face protection should be
used if the potential for splashing or spraying of product exists.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Viscous liquid
WM2000F-B Epoxy Activator Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500)
Page 3 of 5 Printing date 07.27.2006 Reviewed on 07.27.2006
Color: Black
Odor: Strong, Ammoniacal
Vapor pressure: <1 mmHg @ 20癈 (68癋)
pH: Not applicable
Boiling point/range: 207癈 (404癋)
Melting point/range: Not available
Specific gravity: 1.65
Vapor density: 3.5
Evaporation rate: Not available
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available
VOC content: Not available
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions of storage and use.
Hazardous polymerization: None under normal processing.
Hazardous decomposition products: Oxides of carbon. Smoke. Oxides of nitrogen.
Incompatability: Oxidizing agents. Metals. Acids. Acrylates.
Conditions to avoid: Storage with incompatible materials. Avoid temperatures above 294 癈 (561 癋). Avoid
mixing resin (Part A) and curing agent (Part B) in batches greater than 2 pound (.9 kg)
unless you plan to use immediately. Failure to observe these precautions may result in
excessive heat build-up causing an exotherm. The exotherm has the potential for release of
toxic gasses.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Silica, Quartz Known Carcinogen Group 1 Yes
14808-60-7
Talc No No No
14807-96-6
Diethylene Triamine No No No
111-40-0
Epoxy resin No No No
Proprietary
4,4 '- IsopropylidenedIphenol No No No
80-05-7
Carbon Black No Group 2B Yes
1333-86-4
N-(2-Aminoethyl)piperazine No No No
140-31-8
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Silica, Quartz Some evidence of carcinogenicity, Lung, Immune system
14808-60-7
Talc Some evidence of carcinogenicity, Lung, Irritant
14807-96-6
Diethylene Triamine Allergen, Eyes, Irritant
111-40-0
Epoxy resin No data
Proprietary
4,4 '- IsopropylidenedIphenol Allergen, Blood, Irritant, Kidney, Spleen, Reproductive
80-05-7
Carbon Black Respiratory, Some evidence of carcinogenicity
1333-86-4
N-(2-Aminoethyl)piperazine Irritant, Corrosive, Allergen
140-31-8
12. ECOLOGICAL INFORMATION
WM2000F-B Epoxy Activator Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500)
Page 4 of 5 Printing date 07.27.2006 Reviewed on 07.27.2006
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.
EPA hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORTATION INFORMATION
Department of Transportation Ground (49 CFR):
Proper shipping name: Amines, Solid, Corrosive, n.o.s.
(Diethylenetriamine)
Hazard class or division: 8
Identification number: UN 3259
Packing group: III
International Air Transportation (ICAO/IATA):
Proper shipping name: Amines, Solid, Corrosive, n.o.s.
(Diethylenetriamine)
Hazard class or division: 8
Identification number: UN 3259
Packing group: III
WaterTransportation (IMO/IMDG):
Proper shipping name: Amines, Solid, Corrosive, n.o.s.
(Diethylenetriamine)
Hazard class or division: 8
Identification number: UN 3259
Packing group: III
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None.
CERCLA/SARA Section 311/312: Immediate Health Hazard, Delayed Health Hazard
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). 4,4'-Isopropylidenediphenol (CAS# 80-05-7).
California Proposition 65: This product contains a chemical known to the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: D.2.A, D.2.B, E
WM2000F-B Epoxy Activator Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500)
Page 5 of 5 Printing date 07.27.2006 Reviewed on 07.27.2006
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format.
Prepared for: WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603 (903) 643-8080
Prepared by: Elvin C. Loyd, Vice President
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, WrapMaster,
Inc. does not assume responsibility for any results obtained by persons over whose methods WrapMaster, Inc. has no control.
'
It is the user s responsibility to determine the suitability of WrapMaster's products or any production methods mentioned
herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons
against any hazards that may be involved in the handling and use of any of WrapMaster's products. In light of the foregoing,
WrapMaster, Inc. specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a
particular purpose, arising from sale or use of WrapMaster's products. WrapMaster, Inc. further disclaims any liability for
consequential or incidental damages of any kind, including lost profits.
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