Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
MSDS Name TrimBonderTM Bonding System - 200ml Cartridge
Manufacturer Name ITW Devcon
Stock No.: 74701
Components :
TrimBonderTM Activator
TrimBonderTM Adhesive
ITW Devcon Product Code : 74701
View MSDS : 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Product Name: TrimBonderTM Adhesive
HMIS
MSDS Manufacturer 0577
Number: Health Hazard 2*
Manufacturer Name: ITW Devcon
Fire Hazard 3
Address: 30 Endicott Street
Danvers, MA 01923
REACTIVITY 2
General Phone Number: (978) 777-1100
Emergency Phone (800) 424-9300 Personal X
Number: Protection
CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300
* Chronic Health
Canutec: In Canada, call CANUTEC: (613) 996-6666 (call collect)
Effects:
MSDS Revision Date: 06/15/2009
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS# Ingredient Percent
Methacrylic acid 79-41-4 5 - 10 by weight
Diisodecyl phthalate 26761-40-0 5 - 10 by weight
Methyl Methacrylate Monomer 80-62-6 30 - 60 by weight
2,6-Di-tertiary-butyl-para-cresol 128-37-0 1 - 5 by weight
Chlorosulfonated polyethylene 68037-39-8 10 - 30 by weight
Trade secret. N/A 10 - 30 by weight
Titanium dioxide 13463-67-7 10 - 30 by weight
SECTION 3 - HAZARDS IDENTIFICATION
Page 1 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: WARNING! Flammable. Harmful. Skin Sensitizer.. Irritant.
Route of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye: Can cause moderate irritation, burning sensation, tearing, redness, and
swelling. Overexposure may cause lacrimation, conjunctivitis, corneal
damage and permanent injury.
Skin: Can cause skin irritation; itching, redness, rashes, hives, burning, and
swelling. Allergic reactions are possible.
May cause skin sensitization, an allergic reaction, which becomes evident on
reexposure to this material.
Inhalation: Respiratory tract irritant. High concentration may cause dizziness, headache,
and anesthetic effects. May cause respiratory sensitization with asthma-like
symptoms in susceptible individuals.
Ingestion: Causes irritation, a burning sensation of the mouth, throat and
gastrointestinal tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe
reddening, swelling, and possible tissue destruction.
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs: Eyes. Skin. Respiratory system. Digestive system. Liver. Kidney. Olfactory
Function.
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Conditions: sensitization may be more susceptible to the effects of this product.
SECTION 4 - FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes.
Ensure adequate flushing of the eyes by separating the eyelids with fingers.
Get immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes,
while removing contaminated clothing and shoes.
Get medical attention if irritation develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or
give oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if
ingested. Provide a glass of water to dilute the material in the stomach. If
vomiting occurs naturally, have the person lean forward to reduce the risk of
aspiration.
SECTION 5 - FIRE FIGHTING MEASURES
Flammable Properties: Flammable. Fine mists explosive below flash point.
Flash Point: 50癋 (10癈)
Flash Point Method: Tag closed cup (TCC)
Auto Ignition Temperature: 789癋
Lower Flammable/Explosive 1.7%
Limit:
Upper Flammable/Explosive 12.5%
Limit:
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire
space without full protective gear. If possible, contain fire run-off water.
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Unsuitable Media: Water may cause frothing.
Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA),
MSHA/NIOSH (approved or equivalent) and full protective gear.
Unusual Fire Hazards: Sealed containers at elevated temperatures may rupture explosively and
Page 2 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
Unusual Fire Hazards: Sealed containers at elevated temperatures may rupture explosively and
spread fire due to polymerization.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a
chemical waste container. Provide ventilation. Collect spill with a
non-sparking tool. Place into a suitable container for disposal. Clean up spills
immediately observing precautions in the protective equipment section. After
removal, flush spill area with soap and water to remove trace residue.
Flammable, eliminate ignition sources. Vapors can form an ignitable mixture
with air. . Vapors can flow along surfaces to distant ignition sources and flash
back. Ventilate area. Use proper personal protective equipment as listed in
section 8.
Personnel Precautions: Evacuate area and keep unnecessary and unprotected personnel from
entering the spill area.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Other Precautions: Pump or shovel to storage/salvage vessels. Add inhibitor to prevent
polymerization.
SECTION 7 - HANDLING and STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist.
Material will accumulate static charges which may cause an electrical spark
(ignition source). Use proper grounding procedures. Do not reuse containers
without proper cleaning or reconditioning.
Storage: Store in a cool, dry, well ventilated area away from sources of heat,
combustible materials, direct sunlight, and incompatible substances. Keep
container tightly closed when not in use.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
products (see Section 10) during welding/flame cutting operations and to
protect against dust during sanding/grinding of cured product. Hazardous
liquid or vapor residue may remain in emptied container. Do not reuse, heat,
burn, pressurize, cut, weld, braze, solder, drill, grind, expose to sparks,
flame, or ignition sources of empty containers without proper commercial
cleaning or reconditioning.
Hygiene Practices: Wash thoroughly after handling.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES
Engineering Controls: Use appropriate engineering control such as process enclosures, local
exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits. Good general ventilation should be
sufficient to control airborne levels. Where such systems are not effective
wear suitable personal protective equipment, which performs satisfactorily
and meets OSHA or other recognized standards. Consult with local
procedures for selection, training, inspection and maintenance of the personal
protective equipment.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29
CFR 1910.133, OSHA eye and face protection regulation, or the European
standard EN 166.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent
skin contact. Consult manufacturer's data for permeability data.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided
by air purifying respirators is limited. Use a positive pressure air supplied
respirator if there is any potential for an uncontrolled release, exposure
levels are not known, or any other circumstances where air purifying
respirators may not provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an
Page 3 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
Other Protective: Facilities storing or utilizing this material should be equipped with an
eyewash and a deluge shower safety station.
EXPOSURE GUIDELINES
Methacrylic acid :
Guideline ACGIH: 20 ppm
TLV-TWA: 20 ppm
Methyl Methacrylate Monomer :
Guideline ACGIH: 50 ppm
Sensitizer.: Sen
TLV-STEL: 100 ppm
TLV-TWA: 50 ppm
Guideline OSHA: 100 ppm
PEL-TWA: 100 ppm
2,6-Di-tertiary-butyl-para-cresol :
Guideline ACGIH: 2 mg/m3
TLV-TWA: 2 mg/m3 Inhalable vapor fraction (IVF)
Titanium dioxide :
Guideline ACGIH: 10 mg/m3
TLV-TWA: 10 mg/m3
Notes : Only established PEL and TLV values for the ingredients are listed.
SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
Physical State Appearance: Paste..
Odor: Strong acrid.
Boiling Point: >200癋 (93.3癈)
Melting Point: Not determined.
Specific Gravity: Not determined.
Solubility: Not determined.
Vapor Density: 3.5 (air = 1)
Vapor Pressure: 28 mmHg @68癋
Percent Volatile: Not determined.
Evaporation Rate: 3 (butyl acetate = 1)
pH: Not determined.
Molecular Formula: Mixture
Molecular Weight: Mixture
Flash Point: 50癋 (10癈)
Flash Point Method: Tag closed cup (TCC)
Auto Ignition Temperature: 789癋
VOC Content:
Percent Solids by Weight Not determined.
SECTION 10 - STABILITY and REACTIVITY
Chemical Stability: Unstable.
Hazardous Polymerization: Polymerization may occur under certain conditions.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions. Oxygen-free atmospheres or inert gas blanketing.
Freezing conditions. Material can soften paint and rubber.
Incompatible Materials: Oxidizing agents (eg peroxides, nitrates), reducing agents, acids, bases,
azo-compounds, catalytic metals (eg copper, iron), halogens. Free radical
initiators. Oxygen scavengers.
Page 4 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
SECTION 11 - TOXICOLOGICAL INFORMATION
Methacrylic acid :
RTECS Number: OZ2975000
Skin: Unreported - Rat LD50: 1600 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Oral - Mouse LD50: 1250 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Intraperitoneal. - Mouse LD50: 48 mg/kg [Details of toxic effects not
reported other than lethal dose value.]
Unreported - Mouse LD50: 1250 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Oral - Rabbit LD50: 1200 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Administration onto the skin - Rabbit LD50: 500 mg/kg [Details of toxic
effects not reported other than lethal dose value.]
Administration onto the skin - Guinea pig LD50: 1 gm/kg [Details of toxic
effects not reported other than lethal dose value.]
Oral - Rat LD50: 1060 mg/kg [Details of toxic effects not reported other than
lethal dose value.]
Ingestion: Oral - Mouse LD50: 1250 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Oral - Rat LD50: 1060 mg/kg [Details of toxic effects not reported other than
lethal dose value.]
Diisodecyl phthalate :
RTECS Number: TI1270000
Skin: Oral - Rat LD50: 64 gm/kg [Details of toxic effects not reported other than
lethal dose value.]
Administration onto the skin - Rabbit LD50: >3160 mg/kg [Details of toxic
effects not reported other than lethal dose value.]
Ingestion: Oral - Rat LD50: 64 gm/kg [Details of toxic effects not reported other than
lethal dose value.]
Methyl Methacrylate Monomer :
RTECS Number: OZ5075000
Eye: Eye - Rabbit Standard Draize Test.: 150 mg
Skin: Intraperitoneal. - Guinea pig LD50: 1890 mg/kg [Behavioral - Somnolence
(general depressed activity)]
Subcutaneous - Guinea pig LD50: 5954 mg/kg [Behavioral - Somnolence
(general depressed activity)]
Oral - Rat LD50: 7872 mg/kg [Behavioral - Muscle weakness Behavioral -
Coma Lungs, Thorax, or Respiration - Respiratory depression]
Intraperitoneal. - Rat LD50: 1328 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Subcutaneous - Rat LD50: 7088 mg/kg [Behavioral - Somnolence (general
depressed activity)]
Oral - Mouse LD50: 3625 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Intraperitoneal. - Mouse LD50: 945 mg/kg [Behavioral - Somnolence
(general depressed activity)]
Subcutaneous - Mouse LD50: 5954 mg/kg [Behavioral - Somnolence (general
depressed activity)]
Oral - Rabbit LD50: 8700 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Administration onto the skin - Rabbit LD50: >5 gm/kg [Skin and Appendages
- Dermatitis, other (After systemic exposure)]
Oral - Guinea pig LD50: 5954 mg/kg [Behavioral - Somnolence (general
depressed activity) Behavioral - Ataxia Gastrointestinal - Changes in
structure or function of salivary glands]
Administration onto the skin - Rabbit Open irritation test: 10 gm
Inhalation: Inhalation. - Rat LC50: 78000 mg/m3/4H [Details of toxic effects not
reported other than lethal dose value.]
Inhalation. - Mouse LC50: 18500 mg/m3/2H [Details of toxic effects not
reported other than lethal dose value.]
Ingestion: Oral - Rat LD50: 7872 mg/kg [Behavioral - Muscle weakness Behavioral -
Coma Lungs, Thorax, or Respiration - Respiratory depression]
Oral - Mouse LD50: 3625 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
2,6-Di-tertiary-butyl-para-cresol :
RTECS Number: GO7875000
Eye: Eye - Rabbit Standard Draize Test.: 100 mg/24H
Skin: Oral - Mouse LD50: 650 mg/kg [Behavioral - Tremor Lungs, Thorax, or
Page 5 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
Skin: Oral - Mouse LD50: 650 mg/kg [Behavioral - Tremor Lungs, Thorax, or
Respiration - Chronic pulmonary edema]
Intraperitoneal. - Mouse LD50: 138 mg/kg [Lungs, Thorax, or Respiration -
Chronic pulmonary edema Lungs, Thorax, or Respiration - Other changes
Blood - Hemorrhage]
Intravenous. - Mouse LD50: 180 mg/kg [Behavioral - Sleep]
Oral - Guinea pig LD50: 10700 mg/kg [Gastrointestinal - Hypermotility,
diarrhea Behavioral - Tremor Lungs, Thorax, or Respiration - Respiratory
depression]
Oral - Rabbit LD50: 2100 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Intraperitoneal. - Rat LD50: 8 gm/kg [Details of toxic effects not reported
other than lethal dose value.]
Oral - Mouse LD50: 650 mg/kg [Behavioral - Tremor Behavioral - Ataxia
Lungs, Thorax, or Respiration - Other changes]
Intraperitoneal. - Mouse LD50: 138 mg/kg [Lungs, Thorax, or Respiration -
Acute pulmonary edema Blood - Hemorrhage]
Oral - Rat LD50: 890 mg/kg [Details of toxic effects not reported other than
lethal dose value.]
Oral - Mouse LD50: 1040 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Intraperitoneal. - Mouse LD50: 138 mg/kg [Details of toxic effects not
reported other than lethal dose value.]
Subcutaneous - Mouse LD50: 650 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Oral - Guinea pig LD50: 10700 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Ingestion: Oral - Mouse LD50: 650 mg/kg [Behavioral - Tremor Lungs, Thorax, or
Respiration - Chronic pulmonary edema]
Oral - Mouse LD50: 650 mg/kg [Behavioral - Tremor Behavioral - Ataxia
Lungs, Thorax, or Respiration - Other changes]
Oral - Rat LD50: 890 mg/kg [Details of toxic effects not reported other than
lethal dose value.]
Oral - Mouse LD50: 1040 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Titanium dioxide :
RTECS Number: XR2275000
Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans.
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
RCRA Number: D001, D019
Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may
spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool or
waste in a sealed, water-filled, metal container.
SECTION 14 - TRANSPORT INFORMATION
DOT Shipping Name: Adhesives
DOT UN Number: 1133
Page 6 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
DOT Hazard Class: 3
DOT Packing Group: II
DOT Exemption: ORM-D Small quantity exemption
SECTION 15 - REGULATORY INFORMATION
Methacrylic acid :
TSCA Inventory Status: Listed
Massachussetts: Listed: Massachusetts Oil and Hazardous List
Pennsylvania: Listed
Canada DSL: Listed
Diisodecyl phthalate :
TSCA Inventory Status: Listed
California PROP 65: Listed: developmental
Canada DSL: Listed
Methyl Methacrylate Monomer :
TSCA Inventory Status: Listed
SARA: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical.
New Jersey: Listed: NJ Hazardous List; Substance Number: 1277
Massachussetts: Listed: Massachusetts Oil and Hazardous List
Pennsylvania: Listed
Canada DSL: Listed
2,6-Di-tertiary-butyl-para-cresol :
TSCA Inventory Status: Listed
Massachussetts: Listed
Pennsylvania: Listed
Canada DSL: Listed
Chlorosulfonated polyethylene :
TSCA Inventory Status: Listed
Canada DSL: Listed
Titanium dioxide :
TSCA Inventory Status: Listed
Massachussetts: Listed
Pennsylvania: Listed
Canada DSL: Listed
Canadian Regulations. WHMIS Hazard Class(es): B2; D2B
All components of this product are on the Canadian Domestic Substances List.
WHMIS Pictograms
SECTION 16 - ADDITIONAL INFORMATION
HMIS Fire Hazard: 3
HMIS Health Hazard: 2*
HMIS Reactivity: 2
HMIS Personal Protection: X
MSDS Revision Date: 06/15/2009
MSDS Author: Actio Corporation
Disclaimer: This Health and Safety Information is correct to the best of our knowledge
Page 7 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
Disclaimer: This Health and Safety Information is correct to the best of our knowledge
and belief at the date of its publication but we cannot accept liability for any
loss, injury or damage which may result from its use. The information given
in the Data Sheet is designed only as a guidance for safe handling, storage
and the use of the substance. It is not a specification nor does it guarantee
any specific properties. All chemicals should be handled only by competent
personnel, within a controlled environment.
Copyright?1996-2008 Actio Software Corporation. All Rights Reserved.
View MSDS : 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Product Name: TrimBonderTM Activator
HMIS
MSDS Manufacturer 0905
Number: Health Hazard 2*
Manufacturer Name: ITW Devcon
Fire Hazard 3
Address: 30 Endicott Street
Danvers, MA 01923
REACTIVITY 2
General Phone Number: (978) 777-1100
Emergency Phone (800) 424-9300 Personal X
Number: Protection
CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300
* Chronic Health
Canutec: In Canada, call CANUTEC: (613) 996-6666 (call collect)
Effects:
MSDS Revision Date: 06/15/2009
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS# Ingredient
Percent
60 - 100 by
Methyl Methacrylate Monomer 80-62-6
weight
5 - 10 by
Trade secret. N/A
weight
3,5-Diethyl-1,2-dihydro-1-phenyl-2-propylpyridine 34562-31-7 1 - 5 by weight
10 - 30 by
Non-hazardous ingredients. N/A
weight
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: WARNING! Flammable. Harmful. Skin Sensitizer.. Irritant.
Route of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye: Can cause moderate irritation, burning sensation, tearing, redness, and
Page 8 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
Eye: Can cause moderate irritation, burning sensation, tearing, redness, and
swelling. Overexposure may cause lacrimation, conjunctivitis, corneal
damage and permanent injury.
Skin: Can cause skin irritation; itching, redness, rashes, hives, burning, and
swelling. Allergic reactions are possible.
May cause skin sensitization, an allergic reaction, which becomes evident on
reexposure to this material.
Inhalation: Respiratory tract irritant. High concentration may cause dizziness, headache,
and anesthetic effects. May cause respiratory sensitization with asthma-like
symptoms in susceptible individuals.
Ingestion: Causes irritation, a burning sensation of the mouth, throat and
gastrointestinal tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe
reddening, swelling, and possible tissue destruction.
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs: Eyes. Skin. Respiratory system. Digestive system. Liver. Kidney. Olfactory
Function.
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Conditions: sensitization may be more susceptible to the effects of this product.
SECTION 4 - FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes.
Ensure adequate flushing of the eyes by separating the eyelids with fingers.
Get immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes,
while removing contaminated clothing and shoes.
Get medical attention if irritation develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or
give oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if
ingested. Provide a glass of water to dilute the material in the stomach. If
vomiting occurs naturally, have the person lean forward to reduce the risk of
aspiration.
SECTION 5 - FIRE FIGHTING MEASURES
Flammable Properties: Flammable. Fine mists explosive below flash point.
Flash Point: 50癋 (10癈)
Flash Point Method: Tag closed cup (TCC)
Auto Ignition Temperature: Not determined.
Lower Flammable/Explosive 2.1%
Limit:
Upper Flammable/Explosive 12.5%
Limit:
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire
space without full protective gear. If possible, contain fire run-off water.
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Unsuitable Media: Water may cause frothing.
Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA),
MSHA/NIOSH (approved or equivalent) and full protective gear.
Unusual Fire Hazards: Sealed containers at elevated temperatures may rupture explosively and
spread fire due to polymerization.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Page 9 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a
chemical waste container. Provide ventilation. Collect spill with a
non-sparking tool. Place into a suitable container for disposal. Clean up spills
immediately observing precautions in the protective equipment section. After
removal, flush spill area with soap and water to remove trace residue.
Flammable, eliminate ignition sources. Vapors can form an ignitable mixture
with air. . Vapors can flow along surfaces to distant ignition sources and flash
back. Ventilate area. Use proper personal protective equipment as listed in
section 8.
Personnel Precautions: Evacuate area and keep unnecessary and unprotected personnel from
entering the spill area.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Other Precautions: Pump or shovel to storage/salvage vessels. Add inhibitor to prevent
polymerization.
SECTION 7 - HANDLING and STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist.
Material will accumulate static charges which may cause an electrical spark
(ignition source). Use proper grounding procedures. Do not reuse containers
without proper cleaning or reconditioning.
Storage: Store in a cool, dry, well ventilated area away from sources of heat,
combustible materials, direct sunlight, and incompatible substances. Keep
container tightly closed when not in use.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
products (see Section 10) during welding/flame cutting operations and to
protect against dust during sanding/grinding of cured product. Hazardous
liquid or vapor residue may remain in emptied container. Do not reuse, heat,
burn, pressurize, cut, weld, braze, solder, drill, grind, expose to sparks,
flame, or ignition sources of empty containers without proper commercial
cleaning or reconditioning.
Hygiene Practices: Wash thoroughly after handling.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES
Engineering Controls: Use appropriate engineering control such as process enclosures, local
exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits. Good general ventilation should be
sufficient to control airborne levels. Where such systems are not effective
wear suitable personal protective equipment, which performs satisfactorily
and meets OSHA or other recognized standards. Consult with local
procedures for selection, training, inspection and maintenance of the personal
protective equipment.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29
CFR 1910.133, OSHA eye and face protection regulation, or the European
standard EN 166.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent
skin contact. Consult manufacturer's data for permeability data.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided
by air purifying respirators is limited. Use a positive pressure air supplied
respirator if there is any potential for an uncontrolled release, exposure
levels are not known, or any other circumstances where air purifying
respirators may not provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an
eyewash and a deluge shower safety station.
EXPOSURE GUIDELINES
Methyl Methacrylate Monomer :
Guideline ACGIH: 50 ppm
Page 10 of 13
Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
Guideline ACGIH: 50 ppm
Sensitizer.: Sen
TLV-STEL: 100 ppm
TLV-TWA: 50 ppm
Guideline OSHA: 100 ppm
PEL-TWA: 100 ppm
Notes : Only established PEL and TLV values for the ingredients are listed.
SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
Physical State Appearance: Paste..
Odor: Fragrant.
Boiling Point: 213癋 (100.5癈)
Melting Point: Not determined.
Specific Gravity: 0.96
Solubility: Not determined.
Vapor Density: 3.5 (air = 1)
Vapor Pressure: 28 mmHg @68癋
Percent Volatile: Not determined.
Evaporation Rate: 3 (butyl acetate = 1)
pH: 4.5-5.5 @ 5 Percent Solution
Molecular Formula: Mixture
Molecular Weight: Mixture
Flash Point: 50癋 (10癈)
Flash Point Method: Tag closed cup (TCC)
Auto Ignition Temperature: Not determined.
VOC Content:
Percent Solids by Weight Not determined.
SECTION 10 - STABILITY and REACTIVITY
Chemical Stability: Unstable.
Hazardous Polymerization: Polymerization may occur under certain conditions.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions. Oxygen-free atmospheres or inert gas blanketing.
Freezing conditions. Material can soften paint and rubber.
Incompatible Materials: Oxidizing agents (eg peroxides, nitrates), reducing agents, acids, bases,
azo-compounds, catalytic metals (eg copper, iron), halogens. Free radical
initiators. Oxygen scavengers.
SECTION 11 - TOXICOLOGICAL INFORMATION
Methyl Methacrylate Monomer :
RTECS Number: OZ5075000
Eye: Eye - Rabbit Standard Draize Test.: 150 mg
Skin: Intraperitoneal. - Guinea pig LD50: 1890 mg/kg [Behavioral - Somnolence
(general depressed activity)]
Subcutaneous - Guinea pig LD50: 5954 mg/kg [Behavioral - Somnolence
(general depressed activity)]
Oral - Rat LD50: 7872 mg/kg [Behavioral - Muscle weakness Behavioral -
Coma Lungs, Thorax, or Respiration - Respiratory depression]
Intraperitoneal. - Rat LD50: 1328 mg/kg [Details of toxic effects not reported
other than lethal dose value.]
Subcutaneous - Rat LD50: 7088 mg/kg [Behavioral - Somnolence (general
depressed activity)]
Oral - Mouse LD50: 3625 mg/kg [Details of toxic effects not reported other
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Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
than lethal dose value.]
Intraperitoneal. - Mouse LD50: 945 mg/kg [Behavioral - Somnolence (general
depressed activity)]
Subcutaneous - Mouse LD50: 5954 mg/kg [Behavioral - Somnolence (general
depressed activity)]
Oral - Rabbit LD50: 8700 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
Administration onto the skin - Rabbit LD50: >5 gm/kg [Skin and Appendages
- Dermatitis, other (After systemic exposure)]
Oral - Guinea pig LD50: 5954 mg/kg [Behavioral - Somnolence (general
depressed activity) Behavioral - Ataxia Gastrointestinal - Changes in structure
or function of salivary glands]
Administration onto the skin - Rabbit Open irritation test: 10 gm
Inhalation: Inhalation. - Rat LC50: 78000 mg/m3/4H [Details of toxic effects not
reported other than lethal dose value.]
Inhalation. - Mouse LC50: 18500 mg/m3/2H [Details of toxic effects not
reported other than lethal dose value.]
Ingestion: Oral - Rat LD50: 7872 mg/kg [Behavioral - Muscle weakness Behavioral -
Coma Lungs, Thorax, or Respiration - Respiratory depression]
Oral - Mouse LD50: 3625 mg/kg [Details of toxic effects not reported other
than lethal dose value.]
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
RCRA Number: D001
Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may
spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool or
waste in a sealed, water-filled, metal container.
SECTION 14 - TRANSPORT INFORMATION
DOT Shipping Name: Adhesives
DOT UN Number: 1133
DOT Hazard Class: 3
DOT Packing Group: II
DOT Exemption: ORM-D Small quantity exemption
SECTION 15 - REGULATORY INFORMATION
Methyl Methacrylate Monomer :
TSCA Inventory Status: Listed
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Product Name: TrimBonderTM Bonding System - 200ml Cartridge MSDS No: 74701
SARA: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical.
New Jersey: Listed: NJ Hazardous List; Substance Number: 1277
Massachussetts: Listed: Massachusetts Oil and Hazardous List
Pennsylvania: Listed
Canada DSL: Listed
3,5-Diethyl-1,2-dihydro-1-phenyl-2-propylpyridine :
TSCA Inventory Status: Listed
Canada DSL: Listed
Canadian Regulations. WHMIS Hazard Class(es): B2; D2B
All components of this product are on the Canadian Domestic Substances List.
WHMIS Pictograms
SECTION 16 - ADDITIONAL INFORMATION
HMIS Fire Hazard: 3
HMIS Health Hazard: 2*
HMIS Reactivity: 2
HMIS Personal Protection: X
MSDS Revision Date: 06/15/2009
MSDS Author: Actio Corporation
Disclaimer: This Health and Safety Information is correct to the best of our knowledge
and belief at the date of its publication but we cannot accept liability for any
loss, injury or damage which may result from its use. The information given
in the Data Sheet is designed only as a guidance for safe handling, storage
and the use of the substance. It is not a specification nor does it guarantee
any specific properties. All chemicals should be handled only by competent
personnel, within a controlled environment.
Copyright?1996-2008 Actio Software Corporation. All Rights Reserved.
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