MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 02/17/2009
Material Safety Data Sheet
Copyright, 2009, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol)
MANUFACTURER: 3M
DIVISION: Stationery Products
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 02/17/2009
Supercedes Date: 09/16/2008
Document Group: 22-0408-9
Product Use:
Intended Use: Adhesive
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
NON-VOLATILE COMPONENTS - N.J. TRADE SECRET REGISTRY NO. Trade Secret 20 - 30
04499600-6433P
ACETONE 67-64-1 20 - 30
PROPANE 74-98-6 15 - 25
2-METHYLPENTANE 107-83-5 5 - 15
3-METHYLPENTANE 96-14-0 3- 9
CYCLOHEXANE 110-82-7 4- 8
2,2-DIMETHYLBUTANE 75-83-2 2- 6
2,3-DIMETHYLBUTANE 79-29-8 2- 6
HEXANE 110-54-3 < 1.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Aerosol
Odor, Color, Grade: Clear, sweet fruity odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 02/17/2009
explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and
flash back. Aerosol container contains flammable material under pressure. May cause target organ effects. Contains a
chemical or chemicals which can cause birth defects or other reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
May be absorbed through skin and cause target organ effects.
Inhalation:
Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Single exposure, above recommended guidelines, may cause:
Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache,
incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause:
Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of
the hands and feet, tremors and muscle atrophy.
Dermal Effects: Signs/symptoms may include localized redness, itching, drying and cracking of skin.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 02/17/2009
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. Get immediate medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
-42.00 篎 [Test Method: Tagliabue Closed Cup] [Details:
Flash Point
CONDITIONS: Propellant]
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
Class IA Flammable Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely
flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol
container contains flammable material under pressure.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 02/17/2009
dikes to prevent entry into sewer systems or bodies of water. If possible, seal leaking container. Place leaking containers in a well-
ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging
for the leaking container or its contents is available. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam
(AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does
not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools.
Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Collect the
resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Seal the
container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static
or properly grounded shoes. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray
near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors,
mists, or spray. Keep out of the reach of children. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors -
open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation.
Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or
ignite matches, lighters, etc. Do not breathe vapors. Avoid contact with oxidizing agents.
7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Do not store containers on
their sides. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. Do not
remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control
airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use
respiratory protection equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not
adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended
exposure limits and/or control spray or mist.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Fluoroelastomer (Viton), Nitrile Rubber, Polyvinyl Alcohol (PVA),
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 02/17/2009
Polyethylene/Ethylene Vinyl Alcohol.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. Do not breathe vapors.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges, Half facepiece or fullface
pressure demand self-contained breathing apparatus. Consult the current 3M Respiratory Selection Guide for additional information
or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ACETONE ACGIH TWA 500 ppm Table A4
ACETONE ACGIH STEL 750 ppm Table A4
ACETONE OSHA TWA, Vacated 750 ppm
ACETONE OSHA TWA 1000 ppm Table Z-1
ACETONE OSHA STEL, Vacated 1000 ppm
CYCLOHEXANE ACGIH TWA 100 ppm
CYCLOHEXANE OSHA TWA 300 ppm Table Z-1
HEXANE ACGIH TWA 50 ppm Skin Notation*
HEXANE OSHA TWA, Vacated 50 ppm Table Z-1A
HEXANE OSHA TWA 500 ppm Table Z-1A
HEXANE (ISOMERS OTHER THAN N- ACGIH TWA 500 ppm
HEXANE)
HEXANE (ISOMERS OTHER THAN N- ACGIH STEL 1000 ppm
HEXANE)
PROPANE ACGIH TWA 1000 ppm
PROPANE OSHA TWA 1000 ppm Table Z-1
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Aerosol
Specific Physical Form:
Clear, sweet fruity odor
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
-42.00 篎 [Test Method: Tagliabue Closed Cup] [Details:
Flash Point
CONDITIONS: Propellant]
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
Not Applicable
Boiling point
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 02/17/2009
0.726 g/ml
Density
2.97 [Ref Std: AIR=1]
Vapor Density
0.726 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
Not Applicable
Melting point
Negligible
Solubility in Water
1.90 [Ref Std: ETHER=1]
Evaporation rate
0.4 % weight [Test Method: Calculated]
Hazardous Air Pollutants
0.016 lb HAPS/lb solids
Hazardous Air Pollutants
0.02 lb HAPS/gal [Test Method: Calculated]
Hazardous Air Pollutants
Approximately 51 % [Test Method: calculated SCAQMD rule
Volatile Organic Compounds
443.1]
<=75 % weight
Percent volatile
468 g/l
VOC Less H2O & Exempt Solvents
Not Applicable
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat; Sparks and/or flames
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 02/17/2009
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product
in a permitted hazardous waste facility.
Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
62-4977-2926-9, 62-4977-4830-1, 70-0050-1481-9, 70-0050-1706-9, 70-0050-1808-3, 70-0050-1809-1, 70-0714-2173-2, 70-0714-
2194-8, 70-0714-8197-5, 70-0714-9203-0, 70-0714-9575-1
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
CYCLOHEXANE 110-82-7 4- 8
HEXANE 110-54-3 < 1.5
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
CYCLOHEXANE 110-82-7 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
Contact 3M for more information.
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 02/17/2009
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Non hazardous according to WHMIS criteria.
This material contains one or more ingredients that may be regulated by the International Traffic in Arms Regulation (ITAR), an
export control of US military technology and chemicals. Prior to export of this material or any product containing this material,
determine whether a proper license from the Department of State must be obtained. See 22CFR 120-130 for any specific requirements.
Contact 3M for more information.
WHMIS: Non-hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None
Aerosol Storage Code: 3
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 4 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and
Coatings Association (NPCA).
Revision Changes:
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 02/17/2009
Copyright was modified.
Section 14: ID Number(s) Template 1 was modified.
Section 2: Ingredient table was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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