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Material Safety Data Sheet
Printing date 02/13/2009 Reviewed on 02/13/2009
* 1 Identification of substance
Product details
Trade name: Preprufe SCS Hydrophilic Grout Part A
MSDS ID Number: M-85821
Manufacturer/Supplier:
W.R. Grace & Co. -Conn.
62 Whittemore Avenue
Cambridge, MA 02140 USA
Information department:
Environmental Health & Safety
USA: +1-617-876-1400 (24 hours)
+1-800-354-5414 (8AM - 5PM)
Transport Emergency: Chemtrec +1-800-424-9300 (24 hours)
* 2 Composition/Data on components
Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Hazardous components:
Acrylate and Methacrylate Monomers in Water CAS#'s 5698-98-6 and 79-41-4 90 - 99%
Polysaccharide WHMIS Non-Hazardous 0.0-1.0%
Additional information: For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
Hazard description:
Product polymerization will produce heat.
Do not seal containers if contaminated with water.
Closed containers may explode due to exothermic reaction.
Contact with hot material may result in burns.
Irritating to eyes and skin.
Information pertaining to particular dangers for man and environment:
Irritating to eyes and skin.
Potential Health Effects:
Inhalation:
May cause respiratory tract irritation.
Eye Contact: Causes eye irritation.
Skin Contact: Causes skin irritation.
Skin Absorption: Not expected to be harmful if absorbed through the skin.
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Material Safety Data Sheet
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Trade name: Preprufe SCS Hydrophilic Grout Part A
(Cont. from page 1)
Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon from
company and literature data.
NFPA ratings (scale 0 - 4)
Health = 1
1 Fire = 1
1 0 Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH *2 Health = *2
Flammability = 1
FIRE 1
Reactivity = 0
REACTIVITY 0
* 4 First aid measures
General information: No special measures required.
After inhalation:
If symptoms develop, supply fresh air. If required, provide artificial respiration and seek immediate medical
treatment.
After skin contact:
Immediately wash contaminated skin with soap or mild detergent and water. If this chemical soaks clothing,
immediately remove clothing and wash skin.
Do not use solvents or thinners to clean skin.
If skin irritation continues, consult a doctor.
After eye contact:
Rinse opened eye for several minutes under running water.
Seek immediate medical advice.
After swallowing: Do not induce vomiting; immediately call for medical help.
5 Fire fighting measures
Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Do not breathe smoke and gasses created by overheating or burning material.
Decomposition products can be highly toxic and irritating.
Firefighters should wear self-contained breathing appartus and appropriate firefighting protective equipment.
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Material Safety Data Sheet
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* 6 Accidental release measures
Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
Measures for cleaning/collecting:
Dispose contaminated material as waste according to section 13 of the MSDS.
Contain spill the place in a suitable container.
Additional information: No dangerous substances are released.
* 7 Handling and storage
Handling:
Information for safe handling:
Open and handle receptacle with care.
Avoid contact with skin and eyes.
Wear appropriate eye and skin protection.
Wash thoroughly after handling.
Decomposition products can be highly toxic. Do not heat or burn this material. Closed containers may explode due to
exothermic reaction if product is contaminated with water.
Information about protection against explosions and fires:
Empty containers may retain hazardous residue, both liquid and vapor.
Do not cut, drill, grind or weld on or near container, whether empty or full.
Storage:
Information about storage in one common storage facility:
Store in tightly closed containers to prevent moisture contamination. Do not reseal if contamination is suspected.
Further information about storage conditions: Storage Temperature 40 - 90 degrees F.
* 8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the
workplace.
Additional information: The lists that were valid during the creation were used as basis.
Personal protective equipment:
General protective and hygienic measures: Avoid contact with the eyes and skin.
Breathing equipment:
Respiratory protection is not normally required. If a vapor or mist is created, use an approved dust/mist respirator
(NIOSH N95).
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Material Safety Data Sheet
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(Cont. from page 3)
Protection of hands:
Gloves should be worn to prevent skin contact and should be impermeable and resistant to the product.
Material of gloves
Gloves should be impermeable and resistant to the product. Selection of material should be considered before use.
Eye protection:
Safety glasses with side shields should be worn to prevent contact due to splashing. Under high vapor mist
concentrations, tightly sealed goggles should be worn.
Safety glasses.
Body protection: Protective work clothing
* 9 Physical and chemical properties
General Information
Liquid
Form:
Clear to turbid yellow
Color:
Sweet
Odor:
Change in condition
Undetermined.
Melting point/Melting range:
> 100癈 (> 212癋)
Boiling point/Boiling range:
Flash point: > 100癈 (> 212癋)
(estimated) Aqueous system.
Method:
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Density at 20癈 (68癋): 1.18 g/cm?br>
Solubility in / Miscibility with
g/l
Water at 20癈 (68癋):
pH-value at 20癈 (68癋): 6.0 - 8.0
* 10 Stability and reactivity
Thermal decomposition: No decomposition if used according to specifications.
Dangerous products of decomposition: No dangerous reactions known.
Additional information: See section 7 for information on handling, storage and conditions to be avoided.
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* 11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Stated in Section 3
12 Ecological information
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13 Disposal considerations
Product: Comply with Federal, State and local regulations.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
DOT regulations: Not Regulated for DOT
-
Hazard class:
Land Transport ADR/RID (cross-border):
-
ADR/RID class:
Not Regulated
Maritime Transport IMDG:
-
IMDG Class:
No
Marine pollutant:
Air Transport ICAO-TI and IATA-DGR: Not Regulated for ICAO and IATA-DGR
-
ICAO/IATA Class:
* 15 Regulations
SARA (Superfund Amendments and Reauthorization Act)
Section 302/304 (extremely hazardous substances):
None of the ingredients is listed.
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Section 313 (specific toxic chemical listings):
None of the ingredients is listed.
SARA Section 312/Tier I & II Hazardard Catagories:
Health Delayed (chronic) Yes
Health Immediate (acute) Yes
Flammable No
Reactive No
Pressure No
National Chemical Inventory Status
TSCA (Toxic Substances Control Act - United States):
All ingredients are listed or exempt from listing unless otherwise noted below.
CEPA (Canadian DSL):
All ingredients are listed or exempt from listing unless otherwise noted below.
California Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
WHMIS Classification(s):
D2B - Toxic material causing other toxic effects
Carcinogenicity Categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV-ACGIH (Threshold Limit Value for Carcinogens established by ACGIH)
None of the ingredients is listed.
NIOSH-Cancer (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
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Trade name: Preprufe SCS Hydrophilic Grout Part A
(Cont. from page 6)
OSHA-Cancer (Occupational Safety & Health Administration)
None of the ingredients is listed.
European EINECS
All ingredients are listed.
Philippines Inventory of Chemicals and Chemical Substances PICCS
All ingredients are listed.
Inventory of Existing Chemical Substances manufactured or imported in China IECSC
Not evaluated.
Existing and New Chemical Substance List ENCS
All ingredients are listed.
ENCA/MITI
All ingredients are listed.
Korean Existing Chemical Inventory
All ingredients are listed.
Product related hazard information:
Risk phrases:
Irritating to eyes and skin.
Non-hazardous Ingredients
7732-18-5 Water 50-100%
16 Other information
"The data included herein are presented in accordance with various environment, health and safety regulations. It is
the responsibility of a recipient of the data to remain currently informed on chemical hazard information, to design
and update its own program and to comply with all national, federal, state and local laws and regulations applicable to
safety, occupational health, right-to-know and environmental protection."
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